For deep tunnel projects,selecting an appropriate initial support distance is critical to improving the self-supporting capacity of surrounding rock.In this work,an intuitive method for determining the tunnel’s initi...For deep tunnel projects,selecting an appropriate initial support distance is critical to improving the self-supporting capacity of surrounding rock.In this work,an intuitive method for determining the tunnel’s initial support distance was proposed.First,based on the convergence-confinement method,a three-dimensional analytical model was constructed by combining an analytical solution of a non-circular tunnel with the Tecplot software.Then,according to the integral failure criteria of rock,the failure tendency coefficients of hard surrounding rock were computed and the spatial distribution plots of that were constructed.On this basis,the tunnel’s key failure positions were identified,and the relationship between the failure tendency coefficient at key failure positions and their distances from the working face was established.Finally,the distance from the working face that corresponds to the critical failure tendency coefficient was taken as the optimal support distance.A practical project was used as an example,and a reasonable initial support distance was successfully determined by applying the developed method.Moreover,it is found that the stability of hard surrounding rock decreases rapidly within the range of 1.0D(D is the tunnel diameter)from the working face,and tends to be stable outside the range of 1.0D.展开更多
Extensive usage of highly conductive carbon materials with large specific surface area(e.g.,carbon nanotubes,CNTs)in lithium ion batteries(LIBs),especially as current collector of anodes,suffers from low initial coulo...Extensive usage of highly conductive carbon materials with large specific surface area(e.g.,carbon nanotubes,CNTs)in lithium ion batteries(LIBs),especially as current collector of anodes,suffers from low initial coulombic efficiency(ICE),large interfacial resistance,and severe embrittlement,as the large specific surface area often results in severe interfacial decomposition of the electrolyte and the formation of thick and fluffy solid electrolyte interphase(SEI)during cycling of LIBs.Herein,we demonstrate that when the CNT-based current collector and Na foil(which are being stacked intimately upon each other)are being placed in Na+-based organic electrolyte,local redox reaction between the Na foil and the electrolyte would occur spontaneously,generating a thin and homogeneous NaF-based passivating layer on the CNTs.More importantly,we found that owing to the weak solvation behaviors of Na+in the organic electrolyte,the resulting passivation layer,which is rich in NaF,is thin and dense;when used as the anode current collector in LIBs,the pre-existing passivating layer can function effectively in isolating the anode from the solvated Li+,thus suppressing the formation of bulky SEI and the destructive intercalation of solvated Li+.The relevant half-cell(graphite as anode)exhibits a high ICE of 92.1%;the relevant pouch cell with thus passivated CNT film as current collectors for both electrodes(LiCoO_(2)as cathode,graphite as anode)displays a high energy density of 255 Wh kg^(-1),spelling an increase of 50%compared with that using the conventional metal current collectors.展开更多
In the context of China’s proactive implementation of the Belt and Road Initiative(BRI),unraveling the BRI’s effect on corporate behavior is of vital importance to China’s policymaking on overseas investment.With t...In the context of China’s proactive implementation of the Belt and Road Initiative(BRI),unraveling the BRI’s effect on corporate behavior is of vital importance to China’s policymaking on overseas investment.With the BRI’s enactment as a quasi-natural experiment,this paper employs the difference in differences(DID)method to investigate the BRI’s effect on the financing constraint for Chinese enterprises.Our study finds that the BRI’s implementation has significantly reduced financing constraints for BRI enterprises,and the effect is more significant for emerging advantageous industries and export-oriented node cities.展开更多
In Nigeria, Universal health coverage has been sub-optimal due to limited access and inequality. This is worsened by poor health-seeking behavior due to out-of-pocket expenditure health system financing being practice...In Nigeria, Universal health coverage has been sub-optimal due to limited access and inequality. This is worsened by poor health-seeking behavior due to out-of-pocket expenditure health system financing being practiced by a greater percentage of the population. However, leveraging on the increasing population of Nigerian’s using communication technologies provides a viable and robust platform for improving patient’s care. Consequently, tele-health initiative provides a complementary approach to improving access to quality health and universal health system coverage. Tele-health initiative is Abia state’s input in progressing the Universal Health Coverage mandate of the Federal Government of Nigeria, anchored on the e-Health policy of Nigeria, after its adoption at the 58th NCH in Sokoto in 2016, of which Abia became the pioneer state for the Project. Abia state’s telecommunication market caters to almost 3.5 million active subscribers, making it the single largest provider of services in the state. Objective: The project is designed to ascertain the impact of the tele-health initiative on healthcare service coverage in Abia State. Methodology: This is a descriptive study with the quantitative and qualitative arm. The study was conducted in all the seventeen local government areas in the State. Result: 29,488 incoming calls were related to general health inquiries about basic information, counseling, and support that improved callers’ knowledge and attitude towards their health, concerns, and symptoms. Also, 66.8% of all calls (19,382) were for routine health information, complaints on mild everyday symptoms, chronic disease management, and follow-up care. About 29.6% of total calls (8751) were made by persons seeking information on socially stigmatizing topics and conditions.展开更多
In order to study the stress characteristics of the initial support and secondary lining of the large section tunnel and to solve the problem of secondary lining cracking during operation. Taking the large section tun...In order to study the stress characteristics of the initial support and secondary lining of the large section tunnel and to solve the problem of secondary lining cracking during operation. Taking the large section tunnel in Zihong village, Qi County as the research object, a numerical simulation method was used to establish a finite element model of the large section tunnel. So as to simulate and analyze the stress characteristics of the support structure of this tunnel. Through the simulation of the initial support and second lining of this large section tunnel in terms of displacement, stress, plastic zone damage and anchor shaft force, the results show that as the excavation progresses, the stress and displacement on the surface of the newly excavated tunnel profile is faster, especially at the side walls and arch footings, the stress and displacement values are slightly larger than other characteristic points, but the final values are stable and converge, and are basically consistent with the field monitoring results, which indicates that this support system is basically in stable state. Therefore, during the tunnel excavation and support process, special attention should be paid to the stability of the sidewalls and footings, and the results of this study will be of great practical significance for tunnel construction and maintenance.展开更多
Face passive failure can severely damage existing structures and underground utilities during shallow shield tunneling,especially in coastal backfill sand.In this work,a series of laboratory model tests were developed...Face passive failure can severely damage existing structures and underground utilities during shallow shield tunneling,especially in coastal backfill sand.In this work,a series of laboratory model tests were developed and conducted to investigate such failure,for tunnels located at burial depth ratios for which C/D=0.5,0.8,1,and 1.3.Support pressures,the evolution of failure processes,the failure modes,and the distribution of velocity fields were examined through model tests and numerical analyses.The support pressure in the tests first rose rapidly to the elastic limit and then gradually increased to the maximum value in all cases.The maximum support pressure decreased slightly in cases where C/D=0.8,1,and 1.3,but the rebound was insignificant where C/D=0.5.In addition,the configuration of the failure mode with C/D=0.5 showed a wedge-shaped arch,which was determined by the outcropping shear failure.The configuration of failure modes was composed of an arch and the inverted trapezoid when C/D=0.8,1,and 1.3,in which the mode was divided into lower and upper failure zones.展开更多
基金Project(2021JLM-49) supported by Natural Science Basic Research Program of Shaanxi-Joint Fund of Hanjiang to Weihe River Valley Water Diversion Project,ChinaProject(42077248) supported by the National Natural Science Foundation of China
文摘For deep tunnel projects,selecting an appropriate initial support distance is critical to improving the self-supporting capacity of surrounding rock.In this work,an intuitive method for determining the tunnel’s initial support distance was proposed.First,based on the convergence-confinement method,a three-dimensional analytical model was constructed by combining an analytical solution of a non-circular tunnel with the Tecplot software.Then,according to the integral failure criteria of rock,the failure tendency coefficients of hard surrounding rock were computed and the spatial distribution plots of that were constructed.On this basis,the tunnel’s key failure positions were identified,and the relationship between the failure tendency coefficient at key failure positions and their distances from the working face was established.Finally,the distance from the working face that corresponds to the critical failure tendency coefficient was taken as the optimal support distance.A practical project was used as an example,and a reasonable initial support distance was successfully determined by applying the developed method.Moreover,it is found that the stability of hard surrounding rock decreases rapidly within the range of 1.0D(D is the tunnel diameter)from the working face,and tends to be stable outside the range of 1.0D.
基金financially supported by the National Key Research and Development Program of China(2022YFB4002103)the National Natural Science Foundation of China(22279107)。
文摘Extensive usage of highly conductive carbon materials with large specific surface area(e.g.,carbon nanotubes,CNTs)in lithium ion batteries(LIBs),especially as current collector of anodes,suffers from low initial coulombic efficiency(ICE),large interfacial resistance,and severe embrittlement,as the large specific surface area often results in severe interfacial decomposition of the electrolyte and the formation of thick and fluffy solid electrolyte interphase(SEI)during cycling of LIBs.Herein,we demonstrate that when the CNT-based current collector and Na foil(which are being stacked intimately upon each other)are being placed in Na+-based organic electrolyte,local redox reaction between the Na foil and the electrolyte would occur spontaneously,generating a thin and homogeneous NaF-based passivating layer on the CNTs.More importantly,we found that owing to the weak solvation behaviors of Na+in the organic electrolyte,the resulting passivation layer,which is rich in NaF,is thin and dense;when used as the anode current collector in LIBs,the pre-existing passivating layer can function effectively in isolating the anode from the solvated Li+,thus suppressing the formation of bulky SEI and the destructive intercalation of solvated Li+.The relevant half-cell(graphite as anode)exhibits a high ICE of 92.1%;the relevant pouch cell with thus passivated CNT film as current collectors for both electrodes(LiCoO_(2)as cathode,graphite as anode)displays a high energy density of 255 Wh kg^(-1),spelling an increase of 50%compared with that using the conventional metal current collectors.
基金Youth Program of the National Natural Sciences Foundation of China (NSFC) “Study on Underwriters’ Behaviors in the Full Life-Cycle of Corporate Bonds” (Grant No. 71802085)Youth Program of the National Humanities and Social Sciences Foundation “Study on the Promotion Incentives of SOE Executives and the Concealment of Corporate Bad News: Theoretical and Empirical Analysis” (Grant No. 18YJC630211)Youth Program of the Humanities and Social Sciences Research Foundation of the Ministry of Education “Study on the Economic Consequences of Corporate Investment and Financing Maturity Mismatch: Analysis Based on a Corporate Risk Perspective” (Grant No. 19YJC630232)
文摘In the context of China’s proactive implementation of the Belt and Road Initiative(BRI),unraveling the BRI’s effect on corporate behavior is of vital importance to China’s policymaking on overseas investment.With the BRI’s enactment as a quasi-natural experiment,this paper employs the difference in differences(DID)method to investigate the BRI’s effect on the financing constraint for Chinese enterprises.Our study finds that the BRI’s implementation has significantly reduced financing constraints for BRI enterprises,and the effect is more significant for emerging advantageous industries and export-oriented node cities.
文摘In Nigeria, Universal health coverage has been sub-optimal due to limited access and inequality. This is worsened by poor health-seeking behavior due to out-of-pocket expenditure health system financing being practiced by a greater percentage of the population. However, leveraging on the increasing population of Nigerian’s using communication technologies provides a viable and robust platform for improving patient’s care. Consequently, tele-health initiative provides a complementary approach to improving access to quality health and universal health system coverage. Tele-health initiative is Abia state’s input in progressing the Universal Health Coverage mandate of the Federal Government of Nigeria, anchored on the e-Health policy of Nigeria, after its adoption at the 58th NCH in Sokoto in 2016, of which Abia became the pioneer state for the Project. Abia state’s telecommunication market caters to almost 3.5 million active subscribers, making it the single largest provider of services in the state. Objective: The project is designed to ascertain the impact of the tele-health initiative on healthcare service coverage in Abia State. Methodology: This is a descriptive study with the quantitative and qualitative arm. The study was conducted in all the seventeen local government areas in the State. Result: 29,488 incoming calls were related to general health inquiries about basic information, counseling, and support that improved callers’ knowledge and attitude towards their health, concerns, and symptoms. Also, 66.8% of all calls (19,382) were for routine health information, complaints on mild everyday symptoms, chronic disease management, and follow-up care. About 29.6% of total calls (8751) were made by persons seeking information on socially stigmatizing topics and conditions.
文摘In order to study the stress characteristics of the initial support and secondary lining of the large section tunnel and to solve the problem of secondary lining cracking during operation. Taking the large section tunnel in Zihong village, Qi County as the research object, a numerical simulation method was used to establish a finite element model of the large section tunnel. So as to simulate and analyze the stress characteristics of the support structure of this tunnel. Through the simulation of the initial support and second lining of this large section tunnel in terms of displacement, stress, plastic zone damage and anchor shaft force, the results show that as the excavation progresses, the stress and displacement on the surface of the newly excavated tunnel profile is faster, especially at the side walls and arch footings, the stress and displacement values are slightly larger than other characteristic points, but the final values are stable and converge, and are basically consistent with the field monitoring results, which indicates that this support system is basically in stable state. Therefore, during the tunnel excavation and support process, special attention should be paid to the stability of the sidewalls and footings, and the results of this study will be of great practical significance for tunnel construction and maintenance.
基金supported by the National Natural Science Foundation of China(Grant No.41972276)the Natural Science Foundation of Fujian Province(No.2020J06013)the“Foal Eagle Program”Youth Top-notch Talent Project of Fujian Province(No.00387088).
文摘Face passive failure can severely damage existing structures and underground utilities during shallow shield tunneling,especially in coastal backfill sand.In this work,a series of laboratory model tests were developed and conducted to investigate such failure,for tunnels located at burial depth ratios for which C/D=0.5,0.8,1,and 1.3.Support pressures,the evolution of failure processes,the failure modes,and the distribution of velocity fields were examined through model tests and numerical analyses.The support pressure in the tests first rose rapidly to the elastic limit and then gradually increased to the maximum value in all cases.The maximum support pressure decreased slightly in cases where C/D=0.8,1,and 1.3,but the rebound was insignificant where C/D=0.5.In addition,the configuration of the failure mode with C/D=0.5 showed a wedge-shaped arch,which was determined by the outcropping shear failure.The configuration of failure modes was composed of an arch and the inverted trapezoid when C/D=0.8,1,and 1.3,in which the mode was divided into lower and upper failure zones.
