Aiming at overcoming the difficulties in integral forming of thin-walled tubes with complex shapes, a novel forming method by inner and outer pressure through viscous was proposed. In this method, by dividing large de...Aiming at overcoming the difficulties in integral forming of thin-walled tubes with complex shapes, a novel forming method by inner and outer pressure through viscous was proposed. In this method, by dividing large deformation of the part into inner and outer pressure forming deformations, the limit deformation of tube part can be increased by several times. Meanwhile, the principle of viscous inner and outer pressure forming was provided, and key problems during the forming process such as reduction of the wall-thickness and instability wrinkling were analyzed. Thereby, the complex curved surface super-alloy GH3044 thin-walled tube with varying diameter ratio of 1.35(the ratio between the maximum and minimum diameters of the part) can be integrally formed by this method. The experimental surface of the formed part is superior in quality and the wall-thickness distribution is uniform. The results show that the viscous inner and outer pressure forming can provide a new approach for integral forming of thin-walled tubes with complex shapes.展开更多
A new synchronization technique of inner and outer couplings is proposed in this work to investigate the synchro- nization of network group. Some Haken-Lorenz lasers with chaos behaviors are taken as the nodes to cons...A new synchronization technique of inner and outer couplings is proposed in this work to investigate the synchro- nization of network group. Some Haken-Lorenz lasers with chaos behaviors are taken as the nodes to construct a few nearest neighbor complex networks and those sub-networks are also connected to form a network group. The effective node controllers are designed based on Lyapunov function and the complete synchronization among the sub-networks is realized perfectly under inner and outer couplings. The work is of potential applications in the cooperation output of lasers and the communication network.展开更多
Forward Masking Temporal audiotory resolution is the ability of the auditory system to resolve auditory signals in the time domain. Forward masking is a means of studying temporal resolution where one tone, the probe,...Forward Masking Temporal audiotory resolution is the ability of the auditory system to resolve auditory signals in the time domain. Forward masking is a means of studying temporal resolution where one tone, the probe, is masked by a preceding tone, the masker. Forward masking is展开更多
Nucleation of ice by contact takes place when an aerosol particle collides with asurface of supercooled water drop.Aerosol particle may either bounce off the watersurface or be captured on it.McCully et al.(1956) and ...Nucleation of ice by contact takes place when an aerosol particle collides with asurface of supercooled water drop.Aerosol particle may either bounce off the watersurface or be captured on it.McCully et al.(1956) and Rosinski et al.(1963) have shownthat capture of hydrophilic particles was four times larger than of hydrophobic ones.Hydrophobic aerosol particles will nucleate ice preferentially during the brief time ofcontact when they bounce off the surface.Patricles that become captured on the surfacewill float and produce clusters that may nucleate ice at some later time (delayed on surface展开更多
This study investigates the effect of the initial tropical cyclone(TC)vortex structure on the intensity change during the eyewall replacement cycle(ERC)of TCs based on two idealized simulations using the Weather Resea...This study investigates the effect of the initial tropical cyclone(TC)vortex structure on the intensity change during the eyewall replacement cycle(ERC)of TCs based on two idealized simulations using the Weather Research and Forecasting(WRF)model.Results show that an initially smaller TC with weaker outer winds experienced a much more drastic intensity change during the ERC than an initially larger TC with stronger outer winds.It is found that an initially larger TC vortex with stronger outer winds favored the development of more active spiral rainbands outside the outer eyewall,which slowed down the contraction and intensification of the outer eyewall and thus prolonged the duration of the concentric eyewall and slow intensity evolution.In contrast,the initially smaller TC with weaker outer winds corresponded to higher inertial stability in the inner core and weaker inertial stability but stronger filamentation outside the outer eyewall.These led to stronger boundary layer inflow,stronger updraft and convection in the outer eyewall,and suppressed convective activity outside the outer eyewall.These resulted in the rapid weakening during the formation of the outer eyewall,followed by a rapid re-intensification of the TC during the ERC.Our study demonstrates that accurate initialization of the TC structure in numerical models is crucial for predicting changes in TC intensity during the ERC.Additionally,monitoring the activity of spiral rainbands outside the outer eyewall can help to improve short-term intensity forecasts for TCs experiencing ERCs.展开更多
In considering of high proportion of renewable energy supply in 2050, the accelerating of energy consumption gross, source and environment can affect the energy system restrict affection are stronger. Add wind and sol...In considering of high proportion of renewable energy supply in 2050, the accelerating of energy consumption gross, source and environment can affect the energy system restrict affection are stronger. Add wind and solar to electricity energy with large amount of energy source exploitation. The energy source amount per person is lower. Considering the renewable energy amount and supply, primary energy storage and structure problem is standing out. Before the wide spread of renewable energy, Using the high-carbon energy in China can pollute seriously. Chinese energy supply and demand problem is research key point. This paper researches Chinese energy supply and demand pattern system and evaluation methodology, gives out the inner and outer influencing elements. And evaluate Chinese energy supply and demand pattern from energy gross, structure, distribution and transportation. Use energy supply synthesize radar comparison chart in certain time period. From energy security, economy, clean and efficiency, analyze the benefit comparisons of Chinese energy supply and demand pattern. This energy supply and demand pattern model will give one certain theoretical analysis and practice reference to the further high proportion of renewable energy.展开更多
have been done in the past by many researchers.Many factors which affect scour around piers such as shape of piers,size,positioning and orientation etc.have been studied in detail by them.However,similar studies in me...have been done in the past by many researchers.Many factors which affect scour around piers such as shape of piers,size,positioning and orientation etc.have been studied in detail by them.However,similar studies in meandering channels are scanty.Very few researchers have studied the effect of angular displacement which has considerable effects of scour around bridge piers.In this paper an attempt has been made to carry out a detailed study of angular displacement on scour.A constant diameter bridge pier of circular shape has been tested in a meandering channel bend with bend angle as 800.The test bed was prepared by using uniform sand having d50 as 0.27 mm and run was taken for a discharge of 2.5 l/s.展开更多
This paper presented an investigation on a stiffened joint in practical engineering which was between concrete-filled steel tubular column and steel beam with narrow outer diaphragm and partial joint penetration welds...This paper presented an investigation on a stiffened joint in practical engineering which was between concrete-filled steel tubular column and steel beam with narrow outer diaphragm and partial joint penetration welds. Through the low-frequency cyclic loading test, the cyclic behavior and failure mode of the specimen were investigated. The results of the test indicated the failure mode and bearing capacity of the specimen which were influenced by the axial compression ratio of the concrete-filled tubular column. On the contrary, the inner diaphragm and inner stiffeners had limited impacts on the hysteretic behavior of the joint. There was no hysteresis damage fracture on the narrow outer diaphragm connected to the concrete-filled steel tubular column with partial joint penetration welds. Due to the excellent ductility and energy dissipating capacity, the proposed joint could be applied to the seismic design of high-rise buildings in highly intensive seismic region, but axial compression ratio should be controlled to avoid unfavorable failure modes.展开更多
Through the description of the deformational features of the surrounding rockaround high stress engineering soft rock roadways,the coupling stabilization principle ofinner and outer structures in surrounding rock was ...Through the description of the deformational features of the surrounding rockaround high stress engineering soft rock roadways,the coupling stabilization principle ofinner and outer structures in surrounding rock was put forward.The supporting principlesof high stress engineering soft rock roadway (high resistance and yielding support,timelysupport,high strength and high stiffness supports) were proposed,which were applied inengineering practices,and obtained better achievements.展开更多
Positive-instantaneous frequency representation for transient signals has always been a great concern due to its theoretical and practical importance,although the involved concept itself is paradoxical.The desire and ...Positive-instantaneous frequency representation for transient signals has always been a great concern due to its theoretical and practical importance,although the involved concept itself is paradoxical.The desire and practice of uniqueness of such frequency representation(decomposition)raise the related topics in approximation.During approximately the last two decades there has formulated a signal decomposition and reconstruction method rooted in harmonic and complex analysis giving rise to the desired signal representations.The method decomposes any signal into a few basic signals that possess positive instantaneous frequencies.The theory has profound relations to classical mathematics and can be generalized to signals defined in higher dimensional manifolds with vector and matrix values,and in particular,promotes kernel approximation for multi-variate functions.This article mainly serves as a survey.It also gives two important technical proofs of which one for a general convergence result(Theorem 3.4),and the other for necessity of multiple kernel(Lemma 3.7).Expositorily,for a given real-valued signal f one can associate it with a Hardy space function F whose real part coincides with f.Such function F has the form F=f+iHf,where H stands for the Hilbert transformation of the context.We develop fast converging expansions of F in orthogonal terms of the form F=∑k=1^(∞)c_(k)B_(k),where B_(k)'s are also Hardy space functions but with the additional properties B_(k)(t)=ρ_(k)(t)e^(iθ_(k)(t)),ρk≥0,θ′_(k)(t)≥0,a.e.The original real-valued function f is accordingly expanded f=∑k=1^(∞)ρ_(k)(t)cosθ_(k)(t)which,besides the properties ofρ_(k)andθ_(k)given above,also satisfies H(ρ_(k)cosθ_(k))(t)ρ_(k)(t)sinρ_(k)(t).Real-valued functions f(t)=ρ(t)cosθ(t)that satisfy the conditionρ≥0,θ′(t)≥0,H(ρcosθ)(t)=ρ(t)sinθ(t)are called mono-components.If f is a mono-component,then the phase derivativeθ′(t)is defined to be instantaneous frequency of f.The above described positive-instantaneous frequency expansion is a generalization of the Fourier series expansion.Mono-components are crucial to understand the concept instantaneous frequency.We will present several most important mono-component function classes.Decompositions of signals into mono-components are called adaptive Fourier decompositions(AFDs).Wc note that some scopes of the studies on the ID mono-components and AFDs can be extended to vector-valued or even matrix-valued signals defined on higher dimensional manifolds.We finally provide an account of related studies in pure and applied mathematics.展开更多
Any analytic signal fa(e^(it)) can be written as a product of its minimum-phase signal part(the outer function part) and its all-phase signal part(the inner function part). Due to the importance of such decomposition,...Any analytic signal fa(e^(it)) can be written as a product of its minimum-phase signal part(the outer function part) and its all-phase signal part(the inner function part). Due to the importance of such decomposition, Kumarasan and Rao(1999), implementing the idea of the Szeg?o limit theorem(see below),proposed an algorithm to obtain approximations of the minimum-phase signal of a polynomial analytic signal fa(e^(it)) = e^(iN0t)M∑k=0a_k^(eikt),(0.1)where a_0≠ 0, a_M≠ 0. Their method involves minimizing the energy E(f_a, h_1, h_2,..., h_H) =1/(2π)∫_0^(2π)|1+H∑k=1h_k^(eikt)|~2|fa(e^(it))|~2dt(0.2) with the undetermined complex numbers hk's by the least mean square error method. In the limiting procedure H →∞, one obtains approximate solutions of the minimum-phase signal. What is achieved in the present paper is two-fold. On one hand, we rigorously prove that, if fa(e^(it)) is a polynomial analytic signal as given in(0.1),then for any integer H≥M, and with |fa(e^(it))|~2 in the integrand part of(0.2) being replaced with 1/|fa(e^(it))|~2,the exact solution of the minimum-phase signal of fa(e^(it)) can be extracted out. On the other hand, we show that the Fourier system e^(ikt) used in the above process may be replaced with the Takenaka-Malmquist(TM) system, r_k(e^(it)) :=((1-|α_k|~2e^(it))/(1-α_ke^(it))^(1/2)∏_(j=1)^(k-1)(e^(it)-α_j/(1-α_je^(it))^(1/2), k = 1, 2,..., r_0(e^(it)) = 1, i.e., the least mean square error method based on the TM system can also be used to extract out approximate solutions of minimum-phase signals for any functions f_a in the Hardy space. The advantage of the TM system method is that the parameters α_1,..., α_n,...determining the system can be adaptively selected in order to increase computational efficiency. In particular,adopting the n-best rational(Blaschke form) approximation selection for the n-tuple {α_1,..., α_n}, n≥N, where N is the degree of the given rational analytic signal, the minimum-phase part of a rational analytic signal can be accurately and efficiently extracted out.展开更多
Morphology and dispersity are key factors for activating peroxymonosulfate(PMS).In this study,we designed a recyclable open-type NiCo_(2)O_(4) hollow microsphere via a simple hydrothermal method with the assistance of...Morphology and dispersity are key factors for activating peroxymonosulfate(PMS).In this study,we designed a recyclable open-type NiCo_(2)O_(4) hollow microsphere via a simple hydrothermal method with the assistance of an NH_(3) vesicle.The physical structure and chemical properties were characterized using techniques such as scanning electron microscope(SEM),transmission electron microscope(TEM),X-ray diffraction(XRD),N2 adsorption and X-ray photoelectron spectroscopy(XPS).The test results confirm that the inner and outer surfaces of open-type NiCo_(2)O_(4) hollow-sphere can be efficiently utilized because of the hole on the surface of the catalyst,which can minimize the diffusion resistance of the reactants and products.Under optimized conditions,the total orga nic carbon(TOC) removal efficiency of rhodamine B(RhB) can reach up to 80% in 40 min,which is almost 50% shorter than the reported values.The reactive radicals were identified and the proposed reaction mechanism was well described.Moreover,the disturbances of HCO_(3)^(-),NO_(3)^(-),Cl^(-)and H_(2) PO_(4)^(-)were further investigated.As a result,HCO_(3)-and NO_(3)-suppressed the reaction while Cl-and H_(2) PO4-had a double effect on reaction.展开更多
基金Funded by the National Natural Science Foundation of China(No.51205260)
文摘Aiming at overcoming the difficulties in integral forming of thin-walled tubes with complex shapes, a novel forming method by inner and outer pressure through viscous was proposed. In this method, by dividing large deformation of the part into inner and outer pressure forming deformations, the limit deformation of tube part can be increased by several times. Meanwhile, the principle of viscous inner and outer pressure forming was provided, and key problems during the forming process such as reduction of the wall-thickness and instability wrinkling were analyzed. Thereby, the complex curved surface super-alloy GH3044 thin-walled tube with varying diameter ratio of 1.35(the ratio between the maximum and minimum diameters of the part) can be integrally formed by this method. The experimental surface of the formed part is superior in quality and the wall-thickness distribution is uniform. The results show that the viscous inner and outer pressure forming can provide a new approach for integral forming of thin-walled tubes with complex shapes.
基金Project supported by the National Natural Science Foundation of China(Grant No.11004092)the Natural Science Foundation of Liaoning Province,China(Grant Nos.2015020079 and 201602455)the Foundation of Education Department of Liaoning Province,China(Grant No.L201683665)
文摘A new synchronization technique of inner and outer couplings is proposed in this work to investigate the synchro- nization of network group. Some Haken-Lorenz lasers with chaos behaviors are taken as the nodes to construct a few nearest neighbor complex networks and those sub-networks are also connected to form a network group. The effective node controllers are designed based on Lyapunov function and the complete synchronization among the sub-networks is realized perfectly under inner and outer couplings. The work is of potential applications in the cooperation output of lasers and the communication network.
文摘Forward Masking Temporal audiotory resolution is the ability of the auditory system to resolve auditory signals in the time domain. Forward masking is a means of studying temporal resolution where one tone, the probe, is masked by a preceding tone, the masker. Forward masking is
基金This work was supported by the National Natural Science Foundation of China under Project(49736200)National Basic Research 973 Project(G1999043503)
文摘Nucleation of ice by contact takes place when an aerosol particle collides with asurface of supercooled water drop.Aerosol particle may either bounce off the watersurface or be captured on it.McCully et al.(1956) and Rosinski et al.(1963) have shownthat capture of hydrophilic particles was four times larger than of hydrophobic ones.Hydrophobic aerosol particles will nucleate ice preferentially during the brief time ofcontact when they bounce off the surface.Patricles that become captured on the surfacewill float and produce clusters that may nucleate ice at some later time (delayed on surface
基金National Key R&D Program of China (2022YFC3004200)National Natural Science Foundation of China (42305007,41730960,41875057)National Science Foundation (AGS-1834300)。
文摘This study investigates the effect of the initial tropical cyclone(TC)vortex structure on the intensity change during the eyewall replacement cycle(ERC)of TCs based on two idealized simulations using the Weather Research and Forecasting(WRF)model.Results show that an initially smaller TC with weaker outer winds experienced a much more drastic intensity change during the ERC than an initially larger TC with stronger outer winds.It is found that an initially larger TC vortex with stronger outer winds favored the development of more active spiral rainbands outside the outer eyewall,which slowed down the contraction and intensification of the outer eyewall and thus prolonged the duration of the concentric eyewall and slow intensity evolution.In contrast,the initially smaller TC with weaker outer winds corresponded to higher inertial stability in the inner core and weaker inertial stability but stronger filamentation outside the outer eyewall.These led to stronger boundary layer inflow,stronger updraft and convection in the outer eyewall,and suppressed convective activity outside the outer eyewall.These resulted in the rapid weakening during the formation of the outer eyewall,followed by a rapid re-intensification of the TC during the ERC.Our study demonstrates that accurate initialization of the TC structure in numerical models is crucial for predicting changes in TC intensity during the ERC.Additionally,monitoring the activity of spiral rainbands outside the outer eyewall can help to improve short-term intensity forecasts for TCs experiencing ERCs.
文摘In considering of high proportion of renewable energy supply in 2050, the accelerating of energy consumption gross, source and environment can affect the energy system restrict affection are stronger. Add wind and solar to electricity energy with large amount of energy source exploitation. The energy source amount per person is lower. Considering the renewable energy amount and supply, primary energy storage and structure problem is standing out. Before the wide spread of renewable energy, Using the high-carbon energy in China can pollute seriously. Chinese energy supply and demand problem is research key point. This paper researches Chinese energy supply and demand pattern system and evaluation methodology, gives out the inner and outer influencing elements. And evaluate Chinese energy supply and demand pattern from energy gross, structure, distribution and transportation. Use energy supply synthesize radar comparison chart in certain time period. From energy security, economy, clean and efficiency, analyze the benefit comparisons of Chinese energy supply and demand pattern. This energy supply and demand pattern model will give one certain theoretical analysis and practice reference to the further high proportion of renewable energy.
文摘have been done in the past by many researchers.Many factors which affect scour around piers such as shape of piers,size,positioning and orientation etc.have been studied in detail by them.However,similar studies in meandering channels are scanty.Very few researchers have studied the effect of angular displacement which has considerable effects of scour around bridge piers.In this paper an attempt has been made to carry out a detailed study of angular displacement on scour.A constant diameter bridge pier of circular shape has been tested in a meandering channel bend with bend angle as 800.The test bed was prepared by using uniform sand having d50 as 0.27 mm and run was taken for a discharge of 2.5 l/s.
文摘This paper presented an investigation on a stiffened joint in practical engineering which was between concrete-filled steel tubular column and steel beam with narrow outer diaphragm and partial joint penetration welds. Through the low-frequency cyclic loading test, the cyclic behavior and failure mode of the specimen were investigated. The results of the test indicated the failure mode and bearing capacity of the specimen which were influenced by the axial compression ratio of the concrete-filled tubular column. On the contrary, the inner diaphragm and inner stiffeners had limited impacts on the hysteretic behavior of the joint. There was no hysteresis damage fracture on the narrow outer diaphragm connected to the concrete-filled steel tubular column with partial joint penetration welds. Due to the excellent ductility and energy dissipating capacity, the proposed joint could be applied to the seismic design of high-rise buildings in highly intensive seismic region, but axial compression ratio should be controlled to avoid unfavorable failure modes.
基金Supported by the National Natural Science Fundation of China (50674045)the National "973" Planning Project(2007CB209403)
文摘Through the description of the deformational features of the surrounding rockaround high stress engineering soft rock roadways,the coupling stabilization principle ofinner and outer structures in surrounding rock was put forward.The supporting principlesof high stress engineering soft rock roadway (high resistance and yielding support,timelysupport,high strength and high stiffness supports) were proposed,which were applied inengineering practices,and obtained better achievements.
基金Macao University Multi-Year Research Grant(MYRG)MYRG2016-00053-FSTMacao Government Science and Technology Foundation FDCT 0123/2018/A3.
文摘Positive-instantaneous frequency representation for transient signals has always been a great concern due to its theoretical and practical importance,although the involved concept itself is paradoxical.The desire and practice of uniqueness of such frequency representation(decomposition)raise the related topics in approximation.During approximately the last two decades there has formulated a signal decomposition and reconstruction method rooted in harmonic and complex analysis giving rise to the desired signal representations.The method decomposes any signal into a few basic signals that possess positive instantaneous frequencies.The theory has profound relations to classical mathematics and can be generalized to signals defined in higher dimensional manifolds with vector and matrix values,and in particular,promotes kernel approximation for multi-variate functions.This article mainly serves as a survey.It also gives two important technical proofs of which one for a general convergence result(Theorem 3.4),and the other for necessity of multiple kernel(Lemma 3.7).Expositorily,for a given real-valued signal f one can associate it with a Hardy space function F whose real part coincides with f.Such function F has the form F=f+iHf,where H stands for the Hilbert transformation of the context.We develop fast converging expansions of F in orthogonal terms of the form F=∑k=1^(∞)c_(k)B_(k),where B_(k)'s are also Hardy space functions but with the additional properties B_(k)(t)=ρ_(k)(t)e^(iθ_(k)(t)),ρk≥0,θ′_(k)(t)≥0,a.e.The original real-valued function f is accordingly expanded f=∑k=1^(∞)ρ_(k)(t)cosθ_(k)(t)which,besides the properties ofρ_(k)andθ_(k)given above,also satisfies H(ρ_(k)cosθ_(k))(t)ρ_(k)(t)sinρ_(k)(t).Real-valued functions f(t)=ρ(t)cosθ(t)that satisfy the conditionρ≥0,θ′(t)≥0,H(ρcosθ)(t)=ρ(t)sinθ(t)are called mono-components.If f is a mono-component,then the phase derivativeθ′(t)is defined to be instantaneous frequency of f.The above described positive-instantaneous frequency expansion is a generalization of the Fourier series expansion.Mono-components are crucial to understand the concept instantaneous frequency.We will present several most important mono-component function classes.Decompositions of signals into mono-components are called adaptive Fourier decompositions(AFDs).Wc note that some scopes of the studies on the ID mono-components and AFDs can be extended to vector-valued or even matrix-valued signals defined on higher dimensional manifolds.We finally provide an account of related studies in pure and applied mathematics.
基金supported by Cultivation Program for Oustanding Young Teachers of Guangdong Province (Grant No. Yq2014060)Macao Science Technology Fund (Grant No. FDCT/099/ 2014/A2)
文摘Any analytic signal fa(e^(it)) can be written as a product of its minimum-phase signal part(the outer function part) and its all-phase signal part(the inner function part). Due to the importance of such decomposition, Kumarasan and Rao(1999), implementing the idea of the Szeg?o limit theorem(see below),proposed an algorithm to obtain approximations of the minimum-phase signal of a polynomial analytic signal fa(e^(it)) = e^(iN0t)M∑k=0a_k^(eikt),(0.1)where a_0≠ 0, a_M≠ 0. Their method involves minimizing the energy E(f_a, h_1, h_2,..., h_H) =1/(2π)∫_0^(2π)|1+H∑k=1h_k^(eikt)|~2|fa(e^(it))|~2dt(0.2) with the undetermined complex numbers hk's by the least mean square error method. In the limiting procedure H →∞, one obtains approximate solutions of the minimum-phase signal. What is achieved in the present paper is two-fold. On one hand, we rigorously prove that, if fa(e^(it)) is a polynomial analytic signal as given in(0.1),then for any integer H≥M, and with |fa(e^(it))|~2 in the integrand part of(0.2) being replaced with 1/|fa(e^(it))|~2,the exact solution of the minimum-phase signal of fa(e^(it)) can be extracted out. On the other hand, we show that the Fourier system e^(ikt) used in the above process may be replaced with the Takenaka-Malmquist(TM) system, r_k(e^(it)) :=((1-|α_k|~2e^(it))/(1-α_ke^(it))^(1/2)∏_(j=1)^(k-1)(e^(it)-α_j/(1-α_je^(it))^(1/2), k = 1, 2,..., r_0(e^(it)) = 1, i.e., the least mean square error method based on the TM system can also be used to extract out approximate solutions of minimum-phase signals for any functions f_a in the Hardy space. The advantage of the TM system method is that the parameters α_1,..., α_n,...determining the system can be adaptively selected in order to increase computational efficiency. In particular,adopting the n-best rational(Blaschke form) approximation selection for the n-tuple {α_1,..., α_n}, n≥N, where N is the degree of the given rational analytic signal, the minimum-phase part of a rational analytic signal can be accurately and efficiently extracted out.
基金supported by the Hebei Natural Science Foundation (No.B2020208064)the Double Tops Joint Fund of the Yunnan Science and Technology Bureau and Yunnan University (No.2019FY003025)Shijiazhuang Science and Technology Department (No.191240263A)。
文摘Morphology and dispersity are key factors for activating peroxymonosulfate(PMS).In this study,we designed a recyclable open-type NiCo_(2)O_(4) hollow microsphere via a simple hydrothermal method with the assistance of an NH_(3) vesicle.The physical structure and chemical properties were characterized using techniques such as scanning electron microscope(SEM),transmission electron microscope(TEM),X-ray diffraction(XRD),N2 adsorption and X-ray photoelectron spectroscopy(XPS).The test results confirm that the inner and outer surfaces of open-type NiCo_(2)O_(4) hollow-sphere can be efficiently utilized because of the hole on the surface of the catalyst,which can minimize the diffusion resistance of the reactants and products.Under optimized conditions,the total orga nic carbon(TOC) removal efficiency of rhodamine B(RhB) can reach up to 80% in 40 min,which is almost 50% shorter than the reported values.The reactive radicals were identified and the proposed reaction mechanism was well described.Moreover,the disturbances of HCO_(3)^(-),NO_(3)^(-),Cl^(-)and H_(2) PO_(4)^(-)were further investigated.As a result,HCO_(3)-and NO_(3)-suppressed the reaction while Cl-and H_(2) PO4-had a double effect on reaction.