Flexible lithium metal batteries with high capacity and power density have been regarded as the core power resources of wearable electronics.However,the main challenge lies in the limited electrochemical performance o...Flexible lithium metal batteries with high capacity and power density have been regarded as the core power resources of wearable electronics.However,the main challenge lies in the limited electrochemical performance of solid-state polymer electrolytes,which hinders further practical applications.Incorporating functional inorganic additives is an effective approach to improve the performance,including increasing ionic conductivity,achieving dendrite inhibiting capability,and improving safety and stability.Herein,this review summarizes the latest developments of functional inorganic additives in composite solid-state electrolytes for flexible metal batteries with special emphasis on their mechanisms,strategies,and cutting-edge applications,in particular,the relationship between them is discussed in detail.Finally,the perspective on future research directions and the key challenges on this topic are outlooked.展开更多
In this paper,we review recent research developments regarding the tribological performances of a series of inorganic nano-additives in lubricating fluids.First,we examine several basic types of inorganic nanomaterial...In this paper,we review recent research developments regarding the tribological performances of a series of inorganic nano-additives in lubricating fluids.First,we examine several basic types of inorganic nanomaterials,including metallic nanoparticles,metal oxides,carbon nanomaterials,and"other"nanomaterials.More specifically,the metallic nanoparticles we examine include silver,copper,nickel,molybdenum,and tungsten nanoparticles;the metal oxides include CuO,ZnO,Fe_(3)O_(4),TiO_(2),ZrO,Al_(2)O_(3),and several double-metal oxides;the carbon nanomaterials include fullerene,carbon quantum dots,carbon nanotubes,graphene,graphene oxides,graphite,and diamond;and the"other"nanomaterials include metal sulfides,rare-earth compounds,layered double hydroxides,clay minerals,hexagonal boron nitride,black phosphorus,and nanocomposites.Second,we summarize the lubrication mechanisms of these nano-additives and identify the factors affecting their tribological performance.Finally,we briefly discuss the challenges faced by inorganic nanoparticles in lubrication applications and discuss future research directions.This review offers new perspectives to improve our understanding of inorganic nano-additives in tribology,as well as several new approaches to expand their practical applications.展开更多
Coking coal dust is extremely hydrophobic;therefore,combination with droplets in the air is difficult and dust suppression is challenging.Here,a dust suppressant spray for coking coal dust was studied in order to impr...Coking coal dust is extremely hydrophobic;therefore,combination with droplets in the air is difficult and dust suppression is challenging.Here,a dust suppressant spray for coking coal dust was studied in order to improve of the combination of droplets and coking coal dust.Based on monomer optimization and compounding analysis,two surfactant monomers,fatty alcohol ether sodium sulfate(AES)and sodium dodecyl benzene sulfonate(SDBS)were selected as the surfactant components of the dust suppressant.The surfactant monomers were combined with four inorganic salts and the reverse osmosis moisture absorption of each solution was determined.By combining the reverse osmosis moisture absorption values with the water retention experimental results,CaCl_(2)was identified as the optimal inorganic salt additive for the dust suppressant.Finally,the optimal concentration of each component was obtained using orthogonal experimental design i.e.,AES(0.03%),SDBS(0.05%),and CaCl_(2)(0.4%).The dust suppressant solution formulated using this method had a high moisture absorption capacity and excellent performance.展开更多
基金supported by the Natural Science Foundation of China(No.22179062,52125202,22171136,and U2004209)financial support by the Fundamental Research Funds for the Central Universities(No.30922010303)the financial support by the Natural Science Foundation of Jiangsu Province(BK20220079).
文摘Flexible lithium metal batteries with high capacity and power density have been regarded as the core power resources of wearable electronics.However,the main challenge lies in the limited electrochemical performance of solid-state polymer electrolytes,which hinders further practical applications.Incorporating functional inorganic additives is an effective approach to improve the performance,including increasing ionic conductivity,achieving dendrite inhibiting capability,and improving safety and stability.Herein,this review summarizes the latest developments of functional inorganic additives in composite solid-state electrolytes for flexible metal batteries with special emphasis on their mechanisms,strategies,and cutting-edge applications,in particular,the relationship between them is discussed in detail.Finally,the perspective on future research directions and the key challenges on this topic are outlooked.
基金The authors are very grateful to the financial supports by the National Natural Science Foundation of China(51805336,11604224,and 61973224)the Natural Science Foundation of Liaoning Province(20170540740,20180550861,2019-ZD-0670,and 2019-ZD-0687)+2 种基金the Scientific Research Project of Education Department of Liaoning Province(lnjc201918)the Tribology Science Fund of State Key Laboratory of Tribology(SKLTKF16B07)the Open Fund of Shenyang Key Laboratory of Aero-engine Materials Tribology(SKLAMT201901).
文摘In this paper,we review recent research developments regarding the tribological performances of a series of inorganic nano-additives in lubricating fluids.First,we examine several basic types of inorganic nanomaterials,including metallic nanoparticles,metal oxides,carbon nanomaterials,and"other"nanomaterials.More specifically,the metallic nanoparticles we examine include silver,copper,nickel,molybdenum,and tungsten nanoparticles;the metal oxides include CuO,ZnO,Fe_(3)O_(4),TiO_(2),ZrO,Al_(2)O_(3),and several double-metal oxides;the carbon nanomaterials include fullerene,carbon quantum dots,carbon nanotubes,graphene,graphene oxides,graphite,and diamond;and the"other"nanomaterials include metal sulfides,rare-earth compounds,layered double hydroxides,clay minerals,hexagonal boron nitride,black phosphorus,and nanocomposites.Second,we summarize the lubrication mechanisms of these nano-additives and identify the factors affecting their tribological performance.Finally,we briefly discuss the challenges faced by inorganic nanoparticles in lubrication applications and discuss future research directions.This review offers new perspectives to improve our understanding of inorganic nano-additives in tribology,as well as several new approaches to expand their practical applications.
基金The project was supported by the National Natural Science Foundation of China(No.51574123)the Scientific Research Project of Hunan Province Office of Education(No.18A185),which is gratefully acknowledged.
文摘Coking coal dust is extremely hydrophobic;therefore,combination with droplets in the air is difficult and dust suppression is challenging.Here,a dust suppressant spray for coking coal dust was studied in order to improve of the combination of droplets and coking coal dust.Based on monomer optimization and compounding analysis,two surfactant monomers,fatty alcohol ether sodium sulfate(AES)and sodium dodecyl benzene sulfonate(SDBS)were selected as the surfactant components of the dust suppressant.The surfactant monomers were combined with four inorganic salts and the reverse osmosis moisture absorption of each solution was determined.By combining the reverse osmosis moisture absorption values with the water retention experimental results,CaCl_(2)was identified as the optimal inorganic salt additive for the dust suppressant.Finally,the optimal concentration of each component was obtained using orthogonal experimental design i.e.,AES(0.03%),SDBS(0.05%),and CaCl_(2)(0.4%).The dust suppressant solution formulated using this method had a high moisture absorption capacity and excellent performance.