The porous hydroxyapatite(HAP)for suspen-sion polymerization dispersant was prepared using calcium carbonate and phosphoric acid as raw materials.The samples were characterized by scanning electron micro-scopy(SEM),X-...The porous hydroxyapatite(HAP)for suspen-sion polymerization dispersant was prepared using calcium carbonate and phosphoric acid as raw materials.The samples were characterized by scanning electron micro-scopy(SEM),X-ray diffraction(XRD)and BET nitrogen adsorption.The results show that the prepared HAP has a porous structure,low particle density,large specific surface area,uniform particle size and does not agglomerate easily between the particles.The preparation conditions for the HAP were optimized as follows:solid content of calcium carbonate aqueous suspension 90 g/L,concentration of phosphoric acid 1.0 mol/L,reaction/aging temperature 50℃,and aging time 3 h.The HAP prepared under optimal preparation conditions has 106.8 m^(2)·g 21 of specific surfacearea,whichisabout1.5–1.8timesasmuchasthatof JapaneseHAPorcommercialHAP.Itsapplicationresultin the suspension polymerization of styrene show that the porous HAP dispersant has high surface activity,excellent suspension dispersibility and stability and can markedly improve the quality of polystyrene beads.展开更多
文摘The porous hydroxyapatite(HAP)for suspen-sion polymerization dispersant was prepared using calcium carbonate and phosphoric acid as raw materials.The samples were characterized by scanning electron micro-scopy(SEM),X-ray diffraction(XRD)and BET nitrogen adsorption.The results show that the prepared HAP has a porous structure,low particle density,large specific surface area,uniform particle size and does not agglomerate easily between the particles.The preparation conditions for the HAP were optimized as follows:solid content of calcium carbonate aqueous suspension 90 g/L,concentration of phosphoric acid 1.0 mol/L,reaction/aging temperature 50℃,and aging time 3 h.The HAP prepared under optimal preparation conditions has 106.8 m^(2)·g 21 of specific surfacearea,whichisabout1.5–1.8timesasmuchasthatof JapaneseHAPorcommercialHAP.Itsapplicationresultin the suspension polymerization of styrene show that the porous HAP dispersant has high surface activity,excellent suspension dispersibility and stability and can markedly improve the quality of polystyrene beads.
