Achieving nanoconfinement-controlled synthesis of nanoplatelets(NPLs)via solution process under ambient condition remains a challenge.In this work,we developed a general ligand-induced strategy to synthesize colloidal...Achieving nanoconfinement-controlled synthesis of nanoplatelets(NPLs)via solution process under ambient condition remains a challenge.In this work,we developed a general ligand-induced strategy to synthesize colloidal stable all-inorganic semiconductor NPLs with controllable lateral dimensions.By introducing certain metal salts(cations:Zn^(2+)and In^(3+),anions:NO_(3)^(−),BF_(4)^(−),or triflate OTf−),wurtzite-structured(WZ-)CdS,CdSe,CdTe,and alloy Cd1−xZnxSe NPLs were directly synthesized in solution through the controlled diffusion of magic-size clusters(MSCs)at room temperature.Mechanism studies revealed that destabilization of MSCs and nanoconfined growth in templates facilitated the formation of NPLs.The present study not only provides a new synthetic route for the preparation of NPLs but also helps to provide insight into their probable formation mechanism and presents an important advance toward the rational design of functional nanomaterials.展开更多
Selective separation of gallium from aluminum by ion flotation using sodium dodecyl sulfate(SDS) as an anionic surfactant and fluoride as an inorganic ligand was investigated. The experimental results were analyzed us...Selective separation of gallium from aluminum by ion flotation using sodium dodecyl sulfate(SDS) as an anionic surfactant and fluoride as an inorganic ligand was investigated. The experimental results were analyzed using the stability constants and speciation diagrams of fluoride metal complexes. The presence of fluoride in the solution has a positive influence upon the separation of gallium from aluminum. The results show that increasing the fluoride concentration makes a more effective separation of gallium from aluminum because of a simultaneous increase in the complexion of aluminum with fluoride and a change in the electrical charge of the aluminum(ALF_4^-). The dehydration model of LIU and DOYLE was also applied to compare the ion flotation and the selectivity coefficients of gallium over aluminum with experimental results.展开更多
基金supported by the National Natural Science Foundation of China(No.22171132)the Innovation Fund from Nanjing University(No.020514913419)the Program for Innovative Talents and Entrepreneurs in Jiangsu(Nos.020513006012 and 020513006014).
文摘Achieving nanoconfinement-controlled synthesis of nanoplatelets(NPLs)via solution process under ambient condition remains a challenge.In this work,we developed a general ligand-induced strategy to synthesize colloidal stable all-inorganic semiconductor NPLs with controllable lateral dimensions.By introducing certain metal salts(cations:Zn^(2+)and In^(3+),anions:NO_(3)^(−),BF_(4)^(−),or triflate OTf−),wurtzite-structured(WZ-)CdS,CdSe,CdTe,and alloy Cd1−xZnxSe NPLs were directly synthesized in solution through the controlled diffusion of magic-size clusters(MSCs)at room temperature.Mechanism studies revealed that destabilization of MSCs and nanoconfined growth in templates facilitated the formation of NPLs.The present study not only provides a new synthetic route for the preparation of NPLs but also helps to provide insight into their probable formation mechanism and presents an important advance toward the rational design of functional nanomaterials.
基金the Iran National Elites FoundationIranian Mines&Mining Industries Development&the Renovation and Geological Survey of Iran for financial support
文摘Selective separation of gallium from aluminum by ion flotation using sodium dodecyl sulfate(SDS) as an anionic surfactant and fluoride as an inorganic ligand was investigated. The experimental results were analyzed using the stability constants and speciation diagrams of fluoride metal complexes. The presence of fluoride in the solution has a positive influence upon the separation of gallium from aluminum. The results show that increasing the fluoride concentration makes a more effective separation of gallium from aluminum because of a simultaneous increase in the complexion of aluminum with fluoride and a change in the electrical charge of the aluminum(ALF_4^-). The dehydration model of LIU and DOYLE was also applied to compare the ion flotation and the selectivity coefficients of gallium over aluminum with experimental results.
