The present study focuses on the formulation of new composite consisting of plaster and raffia vinifera particle (RVP) with the purpose to reducing energy consumption. The aim of this study is to test this new compoun...The present study focuses on the formulation of new composite consisting of plaster and raffia vinifera particle (RVP) with the purpose to reducing energy consumption. The aim of this study is to test this new compound as an insulating eco-material in building in a tropical climate. The composites samples were developed by mixing plaster with raffia vinifera particles (RVP) using three different sizes (1.6 mm, 2.5 mm and 4 mm). The effects of four different RVP incorporations rates (i.e., 0wt%, 5wt%;10wt%;15wt%) on physical, thermal, mechanicals properties of the composites were investigated. In addition, the use of the raffia vinifera particles and plaster based composite material as building envelopes thermal insulation material is studied by the habitable cell thermal behavior instrumentation. The results indicate that the incorporation of raffia vinifera particle leads to improve the new composite physical, mechanical and thermal properties. And the parametric analysis reveals that the sampling rate and the size of raffia vinifera particles are the most decisive factor to impact these properties, and to decreases in the thermal conductivity which leads to an improvement to the thermal resistance and energy savings. The best improvement of plaster composite was obtained at the raffia vinifera particles size between 2.5 and 4.0 mm loading of 5wt% (C95P5R) with a good ratio of thermo-physical-mechanical properties. Additionally, the habitable cell experimental thermal behavior, with the new raffia vinifera particles and plaster-based composite as thermal insulating material for building walls, gives an average damping of 4°C and 5.8°C in the insulated house interior environment respectively for cold and hot cases compared to the outside environment and the uninsulated house interior environment. The current study highlights that this mixture gives the new composite thermal insulation properties applicable in the eco-construction of habitats in tropical environments.展开更多
A thermal insulating material is synthesized via a non-steam-cured and non-fired route by using fly-ash, sorel cement and hydrogen peroxide solution as raw material. Properties such as apparent density, compressive st...A thermal insulating material is synthesized via a non-steam-cured and non-fired route by using fly-ash, sorel cement and hydrogen peroxide solution as raw material. Properties such as apparent density, compressive strength, bending strength, thermal conductivity, water resistance, and thermal tolerance of this matrial are studied, some influencing factors on its performance discussed. This material has an apparent density of 360 kg/m^3, a compressive strength of 1.86 MPa, a thermal conduction coefficient of 0.072 W/(m·K), a softening coefficient of 0.55, and a thermal tolerant temperature of 300 ℃. Test results show that this material is light in weight, of high strength, and good thermal insulation. In addition, neither steam-curing nor sintering is needed in producing it. Further more, large amount of fly ash is used in this material, making it a low cost and environment-friendly building material.展开更多
The nanoporous thermal insulating material was prepared by using fumed silica,SiC powder and glass fiber as starting materials,the appropriate thickness of the nanoporous thermal insulating material lined in ladle was...The nanoporous thermal insulating material was prepared by using fumed silica,SiC powder and glass fiber as starting materials,the appropriate thickness of the nanoporous thermal insulating material lined in ladle was discussed by the simulation method,and the effect of its application as ladle lining was investigated.The results show that the thermal conductivity of the nanoporous thermal insulating material prepared in composition of fumed silica: SiC powder: glass fiber =75: 20:5 (in mass) is 0.023 W · m^-1 · K^-1 at 1 000 ℃,the appropriate thickness of the nanoporous thermal insulating material lined in ladle is ≤ 5 mm and the average temperature of the ladle outside surface when lined with the nanoporous thermal insulating material is 95 ℃ lower than that with the ordinary thermal insulating material.展开更多
Pakistan is at 12th number in the rank of rice production countries. Along with the production of 4,500 thousand metric tons of rice enormous quantity of rice husk is left as waste. Light weight thermal insulating mat...Pakistan is at 12th number in the rank of rice production countries. Along with the production of 4,500 thousand metric tons of rice enormous quantity of rice husk is left as waste. Light weight thermal insulating material was prepared from rice husk. Epoxy resin was used as a binder and was mixed with rice husk to give it strength, the sample was compressed at 7000 psi to produce cylindrical shape block. The thermal conductivity of the sample A, B, C and D of thickness 1, 2, 3 and 4 cm respectively was measured 0.0241, 0.0240, 0.239 and 0.0219 watts/m-k, which was lower than the common mortar by 51.74%, therefore it could be used in buildings and roof as an insulating material. This would be a suitable alternative which would not only save energy but also solve the environmental disposal problems as well. The results are very promising and we hope insulation material prepared would be useable in hot climate regions like Pakistan in buildings to prevent heat transfer.展开更多
Deep oil and gas reservoirs are under high-temperature conditions,but traditional coring methods do not consider temperature-preserved measures and ignore the influence of temperature on rock porosity and permeability...Deep oil and gas reservoirs are under high-temperature conditions,but traditional coring methods do not consider temperature-preserved measures and ignore the influence of temperature on rock porosity and permeability,resulting in distorted resource assessments.The development of in situ temperaturepreserved coring(ITP-Coring)technology for deep reservoir rock is urgent,and thermal insulation materials are key.Therefore,hollow glass microsphere/epoxy resin thermal insulation materials(HGM/EP materials)were proposed as thermal insulation materials.The materials properties under coupled hightemperature and high-pressure(HTHP)conditions were tested.The results indicated that high pressures led to HGM destruction and that the materials water absorption significantly increased;additionally,increasing temperature accelerated the process.High temperatures directly caused the thermal conductivity of the materials to increase;additionally,the thermal conduction and convection of water caused by high pressures led to an exponential increase in the thermal conductivity.High temperatures weakened the matrix,and high pressures destroyed the HGM,which resulted in a decrease in the tensile mechanical properties of the materials.The materials entered the high elastic state at 150℃,and the mechanical properties were weakened more obviously,while the pressure led to a significant effect when the water absorption was above 10%.Meanwhile,the tensile strength/strain were 13.62 MPa/1.3%and 6.09 MPa/0.86%at 100℃ and 100 MPa,respectively,which meet the application requirements of the self-designed coring device.Finally,K46-f40 and K46-f50 HGM/EP materials were proven to be suitable for ITP-Coring under coupled conditions below 100℃ and 100 MPa.To further improve the materials properties,the interface layer and EP matrix should be optimized.The results can provide references for the optimization and engineering application of materials and thus technical support for deep oil and gas resource development.展开更多
As socioeconomic development continues,the issue of building energy consumption has attracted significant attention,and improving the thermal insulation performance of buildings has become a crucial strategic measure....As socioeconomic development continues,the issue of building energy consumption has attracted significant attention,and improving the thermal insulation performance of buildings has become a crucial strategic measure.Simultaneously,the application of solid waste in insulation materials has also become a hot topic.This paper reviews the sources and classifications of solid waste,focusing on research progress in its application as insulation materials in the domains of daily life,agriculture,and industry.The research shows that incorporating household solid waste materials,such as waste glass,paper,and clothing scraps into cementitious thermal insulation can significantly reduce the thermal conductivity of the materials,leading to excellent thermal insulation properties.Insulation materials prepared from agricultural solid waste,such as barley straw,corn stalk,chicken feather,and date palm fibers,possess characteristics of lightweight and strong thermal insulation.Industrial solid waste,including waste tires,iron tailings,and coal bottom ash,can also be utilized in the preparation of insulation materials.These innovative applications not only have positive environmental significance by reducing waste emissions and resource consumption,but also provide efficient and sustainable insulation solutions for the construction industry.However,to further optimize the mix design and enhance the durability of insulation materials,continuous research is required to investigate the mechanisms through which solid waste impacts the performance of insulation materials.展开更多
There has not been an effective method to measure the resistivity of small-size sample of mineral and solid insulating material until now.According to the Chinese National Standard(GB/T1410-2006) and features of digit...There has not been an effective method to measure the resistivity of small-size sample of mineral and solid insulating material until now.According to the Chinese National Standard(GB/T1410-2006) and features of digital high resistance meter,a small electrode experimental installation was developed;it can work with current high resistance meter;the sample decreases to 18 mm from standard size 100 mm in diameter and reduces by 30.86 times in area.A three-electrode system is supported and precisely positioned by two insulating bases whose diameter is 60 mm and height is 20 mm,which ensures accuracy of device structure and reliability of measuring results.The key technological parameters are as follows:diameter of high voltage electrode is 18mm;diameter of measuring electrode is 14.6 mm;internal diameter and external diameter of guard electrode are 16 and 18 mm,respectively;the gap between guard electrode and measuring electrode is set at 0.6 mm.These parameters are adequate for the measurement of flat specimen of mineral and solid insulating material whose diameter is 18 mm.According to the confirmatory experiment on the volume resistivity and surface resistivity,the measuring results are almost the same,using a small electrode experimental installation and a standard electrode.展开更多
Low grade magnesite is one of the main research directions in the future as the raw material for the preparation of magnesia based insulating refractories.Periclase-forsterite(MgO-Mg_(2)SiO_(4)) lightweight insulating...Low grade magnesite is one of the main research directions in the future as the raw material for the preparation of magnesia based insulating refractories.Periclase-forsterite(MgO-Mg_(2)SiO_(4)) lightweight insulating refractories were prepared by the molten salt method with high silica magnesite and tertiary talc ore as raw materials by pretreating them to get light burnt magnesia and talc,and NaCl molten salt as the reaction medium.The effects of the NaCl addition,the sintering temperature,the holding time and the raw material ratio on the sample preparation were studied.The results show that when the NaCl addition is 20% of the mass of light burnt magnesia and talc mixture,the sintering temperature is 1 200 ℃,the holding time is 6 h,and m(light burnt magnesia):m(talc)=5:5,the sample has the optimal comprehensive properties:the bulk density of 1.46 g·cm^(-3) and the apparent porosity of 55.0%.In addition,it is found that self-decomposition of talc and the formation of forsterite can form pores inside the sample.展开更多
The sol-gel method is used to prepare a new nano-alumina aerogel structure and the thermal properties of this nanomaterial are investigated comprehensively using electron microscope scanning,thermal analysis,X-ray and...The sol-gel method is used to prepare a new nano-alumina aerogel structure and the thermal properties of this nanomaterial are investigated comprehensively using electron microscope scanning,thermal analysis,X-ray and infrared spectrometer analysis methods.It is found that the composite aerogel alumina material has a multi-level porous nano-network structure.When employed for the thermal insulation of high-rise buildings,the alumina nanocomposite aerogel material can lead to effective energy savings in winter.However,it has almost no energy-saving effect on buildings where energy is consumed for cooling in summer.展开更多
Thermal insulation materials play an increasingly important role in protecting mechanical parts functioning at high temperatures.In this study,a new porous high-entropy(La_(1/6)Ce_(1/6)Pr_(1/6)Sm_(1/6)Eu_(1/6)Gd_(1/6)...Thermal insulation materials play an increasingly important role in protecting mechanical parts functioning at high temperatures.In this study,a new porous high-entropy(La_(1/6)Ce_(1/6)Pr_(1/6)Sm_(1/6)Eu_(1/6)Gd_(1/6))PO_(4)(HE(6RE_(1/6))PO_(4))ceramics was prepared by combining the high-entropy method with the pore-forming agent method and the effect of different starch contents(0–60vol%)on this ceramic properties was systematically investigated.The results show that the porous HE(6RE_(1/6))PO_(4)ceramics with 60vol%starch exhibit the lowest thermal conductivity of 0.061 W·m^(-1)·K^(-1)at room temperature and good pore structure stability with a linear shrinkage of approximately1.67%.Moreover,the effect of large regular spherical pores(>10μm)on its thermal insulation performance was discussed,and an optimal thermal conductivity prediction model was screened.The superior properties of the prepared porous HE(6RE_(1/6))PO_(4)ceramics allow them to be promising insulation materials in the future.展开更多
Using carbide slag as the calcareous materials, xonotlite thermal insulation material was successfully prepared via dynamic hydrothermal synthesis. The experimental results show that the xonotlite thermal insulation m...Using carbide slag as the calcareous materials, xonotlite thermal insulation material was successfully prepared via dynamic hydrothermal synthesis. The experimental results show that the xonotlite thermal insulation material is made up of large numbers of "chestnut bur shape" particles. Optimum conditions of calcination temperature of carbide slag, synthesis reaction temperature and time, stirring rate, CaO/SiO2 mol ratio, water/solid weight ratio, amount of fiberglass, molding pressures, dryness temperatures and the presence of dispersant (glycol and polyvinyl alcohol) favor the preparation of xonotlite thermal insulation material. The evaluation of xonotlite thermal insulation material reveals that the product is ultra-light and excellent in physical performances. Such a little amount of impurities in carbide slag has no effect on the phase, morphology, stability at high temperature and physical performances of products.展开更多
A new approach is provided to resolve the large-scale applications of coal tar pitch. Carbon foams with uniform pore size are prepared at the foaming pressure of normal pressure using coal tar pitch as raw materials. ...A new approach is provided to resolve the large-scale applications of coal tar pitch. Carbon foams with uniform pore size are prepared at the foaming pressure of normal pressure using coal tar pitch as raw materials. The physical and chemical performance of high softening point pitch(HSPP) can be regulated by vacuumizing owing to the cooperation of vacuumizing and polycondensation. Results indicate that the optimum softening point and weight ratio of quinoline insoluble are about 292℃ and 65.7%, respectively. And the optimum viscosity of HSPP during the foaming process is distributed in the range of 1000-10000 Pa·s. The resultant carbon foam exhibits excellent performance, such as uniform pore structure, high compressive strength(4.7 MPa), low thermal conductivity(0.07 W·m^(-1) ·K^(-1)), specially, it cannot be fired under the high temperature of 1200 ℃.Thus, this kind of carbon foam is a potential candidate for thermal insulation material applied in energy saving building.展开更多
Deep petroleum resources are stored under high temperature and pressure conditions,with the temperature having a significant influence on the properties of rocks.Deep in-situ temperature-preserved coring(ITP-coring)de...Deep petroleum resources are stored under high temperature and pressure conditions,with the temperature having a significant influence on the properties of rocks.Deep in-situ temperature-preserved coring(ITP-coring)devices were developed to assess deep petroleum reserves accurately.Herein,hollow glass microspheres(HGMs)/silicone rubber(SR)composites that exhibit excellent thermal insulation properties were prepared as thermal insulation materials for deep ITP-coring devices.The mechanism and process of heat transfer in the composites were explored,as well as their other properties.The results show that the HGMs exhibit good compatibility with the SR matrix.When the volume fraction of the HGMs is increased to 50%,the density of the HGMs/SR composites is reduced from 0.97 to 0.56 g/cm^(3).The HGMs filler introduces large voids into the composites,reducing their thermal conductivity to 0.11 W/m·K.The addition of HGMs into the composites further enhances the thermal stability of the SR,wherein the higher the HGMs filler content,the better the thermal stability of the composites.HGMs significantly enhance the mechanical strength of the SR.HGMs increase the compressive strength of the composites by 828%and the tensile strength by 164%.Overall,HGMs improve the thermal insulation,pressure resistance,and thermal stability of HGMs/SR composites.展开更多
This study is planned to investigate the problems associated with the wasted sheep fleece in Jordan and to suggest methods to decrease its environmental impact. Results indicate that sheep fleece in Jordan makes an ex...This study is planned to investigate the problems associated with the wasted sheep fleece in Jordan and to suggest methods to decrease its environmental impact. Results indicate that sheep fleece in Jordan makes an excellent resource for buildings insulation material. A linear regression model is used to predict sheep number for the period (2017-2030). Based on the predicted number of Sheep an estimated annual average production of wool is found for the period (2017-2030) to be (3.586 × 10<sup>3</sup> ton). The average cost per kg of fleece produced is calculated to be 0.39 JD, and the estimated price of fleece per head, if market is available for raw fleece, is 1 JD. Average annual financial losses by farmers are calculated to be (3.743 × 10<sup>6</sup> JD) for the period 2002-2016, and they were estimated to be (9.421 × 10<sup>6</sup> JD) for the years 2017-2030. Physical characteristics of sheep-wool are presented and compared to other competitive insulation materials (polystyrene and rockwool). Sustainability of sheep-wool production to be utilized as an insulation material is found to be an excellent solution to the huge waste of wool with respect to farmers and National income and to the problems associated with environmental impact. Results can be generalized to similar cases worldwide.展开更多
To solve the problem of over-high density of lightweight insulation refractory bricks prepared with fly ash, new lightweight insulation refractory materials with density 〈 0. 89 g · cm^-3 were .synthesized using...To solve the problem of over-high density of lightweight insulation refractory bricks prepared with fly ash, new lightweight insulation refractory materials with density 〈 0. 89 g · cm^-3 were .synthesized using pyrophyl-lite, .fly ash, and Suzhou clay as the main starting materials and saw dast as the pore forming substance, and controlling the addition of the pyrophyllite (20%, 30% , and 40% by mass ) and the treating temperature (1 250, 1 300, 1 350, and 1 400 ℃ ). The synthesized materials were characterized by the XRD, SEM and the thermal conductivity measuring in.strument. The results show at pyrophyllite addition of 30% and treat temperature of l 400 ℃ , the material can achieve linear shrinkage of 6. 6%, apparent porosity of 57%, bulk density of 0. 75 g · cm^-3, compressive strength of 2.7 MPa, and thermal conductivity at 350 ℃ of 0. 152 -0. 216 W·( m·K)^-1.This indicates that the pyrophyllite decomposition at high temperatures forms mullite and amorphous quartz introducing volume expansion, which counteracts some shrinkage at high temperatures. So it is feasible to use pyrophyllite, fly ash waste and clay to prepare lightweight insulation refractory materials.展开更多
A hollow glass microsphere(HGM)/TiO2 composite hollow sphere was successfully prepared via a simple precipitation method.The TiO2 coating layers grew on the surface of the HGMs that range from 20 to 50μm in diameter ...A hollow glass microsphere(HGM)/TiO2 composite hollow sphere was successfully prepared via a simple precipitation method.The TiO2 coating layers grew on the surface of the HGMs that range from 20 to 50μm in diameter as nanoparticles with the formation of the SiO Ti bonds.The growth mechanism accounting for the formation of the TiO2 nanolayers was proposed.The morphology,composition,thermal insulation properties,and visible-near infrared(VIS-NIR)refl ectance of the HGMs/TiO2 composite hollow spheres were characterized.The VIS-NIR reflectance of the HGMs/TiO2 composite hollow spheres increased by more than 30%compared to raw HGMs.The thermal conductivity of the particles is 0.058 W/(m K).The result indicates that the VIS-NIR reflectance of the composite hollow spheres is strongly influenced by the coating of TiO2.The composite hollow spheres were used as the main functional filler to prepare the organic-inorganic composite coatings.The glass substrates coated by the organic-inorganic coatings had lower thermal conductivity and higher near infrared reflectivity.Therefore,the HGMs/TiO2 composite hollow spheres can reflect most of the solar energy and effectively keep out the heat as a thermal insulation coating for energy-saving constructions.展开更多
In order to reduce the thermal energy loss of high temperature kilns and furnaces and lower the surface temperature of the kiln body,magnesia insulation materials were prepared using self-made magnesia porous aggregat...In order to reduce the thermal energy loss of high temperature kilns and furnaces and lower the surface temperature of the kiln body,magnesia insulation materials were prepared using self-made magnesia porous aggregates(using high purity magnesia powder as starting material and potassium oleate as the foaming agent),middle grade magnesia powder,calcium aluminate cement,and SiO_(2) micropowder as starting materials,introducing walnut shell powder impregnated with silica sol(short for Sws)as a pore-forming agent.The effects of the Sws addition(0,10%,15%,and 20%,by mass)and the sintering temperature(1300,1350,1400,and 1480℃)on the properties of magnesia insulation materials were studied.The results show that(1)for the specimens fired at 1480℃,when the Sws addition is 10%,the cold compressive strength is 22 MPa;when the Sws addition is 20%,the thermal conductivity is 0.368 W·m^(-1)·K^(-1)(350℃);(2)nano-silica in the silica sol reacts with MgO in the matrix to form forsterite,which encapsulates the pores volatilized from the walnut shell powder and forms closed pores.展开更多
ZrO_(2)-strengthened porous mullite insulation materials were prepared by foaming technology utilizing ZrSiO_(4) and Al_(2)O_(3) as primary materials and Y_(2)O_(3) as an additive.The effects of Y_(2)O_(3) contents on...ZrO_(2)-strengthened porous mullite insulation materials were prepared by foaming technology utilizing ZrSiO_(4) and Al_(2)O_(3) as primary materials and Y_(2)O_(3) as an additive.The effects of Y_(2)O_(3) contents on the phase composition,microstructure,mechanical properties,and heat conductivity of the porous mullite insulation materials were investigated.A suitable Y_(2)O_(3) content could promote phase transition of monoclinic ZrO_(2)(m-ZrO_(2))to tetragonal ZrO_(2)(t-ZrO_(2)),reduce pore size,and improve the strengths of as-prepared specimens.The cold crushing strength and bending strength of as-prepared specimens with a 119µm spherical pore size using 6 wt.%Y_(2)O_(3) were 35.2 and 13.0 MPa,respectively,with a heat conductivity being only 0.248 W/(m K).展开更多
Polypropylene(PP)-based recyclable materials have attracted tremendous interest for HVDC cable insulation applications due to their superior electrical properties,e.g.,high thermal stability and superior recyclability...Polypropylene(PP)-based recyclable materials have attracted tremendous interest for HVDC cable insulation applications due to their superior electrical properties,e.g.,high thermal stability and superior recyclability.Compared with crosslinked polyethylene(XLPE),PP-based materials exhibit the advantages of not only higher working temperatures but also facile and efficient cable manufacturing with reduced costs,which are highly desirable in HVDC cable manufacturing.Considering their promising advantages,PP-based materials have received significant attention from both academia and industry in the field of HVDC cable insulation.In order to adopt PP as a cable insulation material,the mechanical flexibility of PP should be improved.However,regulations of the mechanical properties inevitably influences the electrical properties of PP.So extensive research has been conducted on the regulation of the mechanical and electrical properties of PP.This review summarizes the research progress on recyclable PP-based materials for HVDC cable insulation applications.Particular attention is placed on the electrical property regulations and material structure-property relationships.The challenges that remain to be addressed and the opportunities for future studies on PP-based recyclable HVDC cable insulation materials are also presented.展开更多
文摘The present study focuses on the formulation of new composite consisting of plaster and raffia vinifera particle (RVP) with the purpose to reducing energy consumption. The aim of this study is to test this new compound as an insulating eco-material in building in a tropical climate. The composites samples were developed by mixing plaster with raffia vinifera particles (RVP) using three different sizes (1.6 mm, 2.5 mm and 4 mm). The effects of four different RVP incorporations rates (i.e., 0wt%, 5wt%;10wt%;15wt%) on physical, thermal, mechanicals properties of the composites were investigated. In addition, the use of the raffia vinifera particles and plaster based composite material as building envelopes thermal insulation material is studied by the habitable cell thermal behavior instrumentation. The results indicate that the incorporation of raffia vinifera particle leads to improve the new composite physical, mechanical and thermal properties. And the parametric analysis reveals that the sampling rate and the size of raffia vinifera particles are the most decisive factor to impact these properties, and to decreases in the thermal conductivity which leads to an improvement to the thermal resistance and energy savings. The best improvement of plaster composite was obtained at the raffia vinifera particles size between 2.5 and 4.0 mm loading of 5wt% (C95P5R) with a good ratio of thermo-physical-mechanical properties. Additionally, the habitable cell experimental thermal behavior, with the new raffia vinifera particles and plaster-based composite as thermal insulating material for building walls, gives an average damping of 4°C and 5.8°C in the insulated house interior environment respectively for cold and hot cases compared to the outside environment and the uninsulated house interior environment. The current study highlights that this mixture gives the new composite thermal insulation properties applicable in the eco-construction of habitats in tropical environments.
基金Project 20062147 supported by the Liaoning Province Natural Science Foundation of China
文摘A thermal insulating material is synthesized via a non-steam-cured and non-fired route by using fly-ash, sorel cement and hydrogen peroxide solution as raw material. Properties such as apparent density, compressive strength, bending strength, thermal conductivity, water resistance, and thermal tolerance of this matrial are studied, some influencing factors on its performance discussed. This material has an apparent density of 360 kg/m^3, a compressive strength of 1.86 MPa, a thermal conduction coefficient of 0.072 W/(m·K), a softening coefficient of 0.55, and a thermal tolerant temperature of 300 ℃. Test results show that this material is light in weight, of high strength, and good thermal insulation. In addition, neither steam-curing nor sintering is needed in producing it. Further more, large amount of fly ash is used in this material, making it a low cost and environment-friendly building material.
文摘The nanoporous thermal insulating material was prepared by using fumed silica,SiC powder and glass fiber as starting materials,the appropriate thickness of the nanoporous thermal insulating material lined in ladle was discussed by the simulation method,and the effect of its application as ladle lining was investigated.The results show that the thermal conductivity of the nanoporous thermal insulating material prepared in composition of fumed silica: SiC powder: glass fiber =75: 20:5 (in mass) is 0.023 W · m^-1 · K^-1 at 1 000 ℃,the appropriate thickness of the nanoporous thermal insulating material lined in ladle is ≤ 5 mm and the average temperature of the ladle outside surface when lined with the nanoporous thermal insulating material is 95 ℃ lower than that with the ordinary thermal insulating material.
文摘Pakistan is at 12th number in the rank of rice production countries. Along with the production of 4,500 thousand metric tons of rice enormous quantity of rice husk is left as waste. Light weight thermal insulating material was prepared from rice husk. Epoxy resin was used as a binder and was mixed with rice husk to give it strength, the sample was compressed at 7000 psi to produce cylindrical shape block. The thermal conductivity of the sample A, B, C and D of thickness 1, 2, 3 and 4 cm respectively was measured 0.0241, 0.0240, 0.239 and 0.0219 watts/m-k, which was lower than the common mortar by 51.74%, therefore it could be used in buildings and roof as an insulating material. This would be a suitable alternative which would not only save energy but also solve the environmental disposal problems as well. The results are very promising and we hope insulation material prepared would be useable in hot climate regions like Pakistan in buildings to prevent heat transfer.
基金supported by the Sichuan Science and Technology Program (Grant Nos.2023NSFSC0004,2023NSFSC0790)the National Natural Science Foundation of China (Grant Nos.51827901,52304033)the Sichuan University Postdoctoral Fund (Grant No.2024SCU12093)。
文摘Deep oil and gas reservoirs are under high-temperature conditions,but traditional coring methods do not consider temperature-preserved measures and ignore the influence of temperature on rock porosity and permeability,resulting in distorted resource assessments.The development of in situ temperaturepreserved coring(ITP-Coring)technology for deep reservoir rock is urgent,and thermal insulation materials are key.Therefore,hollow glass microsphere/epoxy resin thermal insulation materials(HGM/EP materials)were proposed as thermal insulation materials.The materials properties under coupled hightemperature and high-pressure(HTHP)conditions were tested.The results indicated that high pressures led to HGM destruction and that the materials water absorption significantly increased;additionally,increasing temperature accelerated the process.High temperatures directly caused the thermal conductivity of the materials to increase;additionally,the thermal conduction and convection of water caused by high pressures led to an exponential increase in the thermal conductivity.High temperatures weakened the matrix,and high pressures destroyed the HGM,which resulted in a decrease in the tensile mechanical properties of the materials.The materials entered the high elastic state at 150℃,and the mechanical properties were weakened more obviously,while the pressure led to a significant effect when the water absorption was above 10%.Meanwhile,the tensile strength/strain were 13.62 MPa/1.3%and 6.09 MPa/0.86%at 100℃ and 100 MPa,respectively,which meet the application requirements of the self-designed coring device.Finally,K46-f40 and K46-f50 HGM/EP materials were proven to be suitable for ITP-Coring under coupled conditions below 100℃ and 100 MPa.To further improve the materials properties,the interface layer and EP matrix should be optimized.The results can provide references for the optimization and engineering application of materials and thus technical support for deep oil and gas resource development.
基金funded by the National Natural Science Foundation of China (52078068)Postgraduate Research&Practice Innovation Program of Jiangsu Province (SJCX22_1391)+1 种基金the National Science Foundation of Jiangsu Province (BK20220626)Changzhou Leading Innovative Talent Introduction and Cultivation Project (CQ20210085).
文摘As socioeconomic development continues,the issue of building energy consumption has attracted significant attention,and improving the thermal insulation performance of buildings has become a crucial strategic measure.Simultaneously,the application of solid waste in insulation materials has also become a hot topic.This paper reviews the sources and classifications of solid waste,focusing on research progress in its application as insulation materials in the domains of daily life,agriculture,and industry.The research shows that incorporating household solid waste materials,such as waste glass,paper,and clothing scraps into cementitious thermal insulation can significantly reduce the thermal conductivity of the materials,leading to excellent thermal insulation properties.Insulation materials prepared from agricultural solid waste,such as barley straw,corn stalk,chicken feather,and date palm fibers,possess characteristics of lightweight and strong thermal insulation.Industrial solid waste,including waste tires,iron tailings,and coal bottom ash,can also be utilized in the preparation of insulation materials.These innovative applications not only have positive environmental significance by reducing waste emissions and resource consumption,but also provide efficient and sustainable insulation solutions for the construction industry.However,to further optimize the mix design and enhance the durability of insulation materials,continuous research is required to investigate the mechanisms through which solid waste impacts the performance of insulation materials.
基金supported by the National Natural Science Foundation of China (Grant No. 50974025)the National Key Technologies R & D Program of China (Grant No. 2004BA810B02)+2 种基金the Applied Foundation of Basic Research in Sichuan Province (Grant No. 07JY029-029)the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20095122110015)the Scientific Research Foundation of the Education Ministry for Returned Chinese Scholars, China (Grant No. 2010-32)
文摘There has not been an effective method to measure the resistivity of small-size sample of mineral and solid insulating material until now.According to the Chinese National Standard(GB/T1410-2006) and features of digital high resistance meter,a small electrode experimental installation was developed;it can work with current high resistance meter;the sample decreases to 18 mm from standard size 100 mm in diameter and reduces by 30.86 times in area.A three-electrode system is supported and precisely positioned by two insulating bases whose diameter is 60 mm and height is 20 mm,which ensures accuracy of device structure and reliability of measuring results.The key technological parameters are as follows:diameter of high voltage electrode is 18mm;diameter of measuring electrode is 14.6 mm;internal diameter and external diameter of guard electrode are 16 and 18 mm,respectively;the gap between guard electrode and measuring electrode is set at 0.6 mm.These parameters are adequate for the measurement of flat specimen of mineral and solid insulating material whose diameter is 18 mm.According to the confirmatory experiment on the volume resistivity and surface resistivity,the measuring results are almost the same,using a small electrode experimental installation and a standard electrode.
文摘Low grade magnesite is one of the main research directions in the future as the raw material for the preparation of magnesia based insulating refractories.Periclase-forsterite(MgO-Mg_(2)SiO_(4)) lightweight insulating refractories were prepared by the molten salt method with high silica magnesite and tertiary talc ore as raw materials by pretreating them to get light burnt magnesia and talc,and NaCl molten salt as the reaction medium.The effects of the NaCl addition,the sintering temperature,the holding time and the raw material ratio on the sample preparation were studied.The results show that when the NaCl addition is 20% of the mass of light burnt magnesia and talc mixture,the sintering temperature is 1 200 ℃,the holding time is 6 h,and m(light burnt magnesia):m(talc)=5:5,the sample has the optimal comprehensive properties:the bulk density of 1.46 g·cm^(-3) and the apparent porosity of 55.0%.In addition,it is found that self-decomposition of talc and the formation of forsterite can form pores inside the sample.
文摘The sol-gel method is used to prepare a new nano-alumina aerogel structure and the thermal properties of this nanomaterial are investigated comprehensively using electron microscope scanning,thermal analysis,X-ray and infrared spectrometer analysis methods.It is found that the composite aerogel alumina material has a multi-level porous nano-network structure.When employed for the thermal insulation of high-rise buildings,the alumina nanocomposite aerogel material can lead to effective energy savings in winter.However,it has almost no energy-saving effect on buildings where energy is consumed for cooling in summer.
基金the National Key R&D Program of China(No.2021YFB3701404)the National Natural Science Fund for Distinguished Young Scholars(No.52025041)+1 种基金the National Natural Science Foundation of China(Nos.52250091,51904021,and 52174294)the Fundamental Research Funds for the Central Universities(Nos.FRF-TP-20-02C2 and FRF-BD-22-05).
文摘Thermal insulation materials play an increasingly important role in protecting mechanical parts functioning at high temperatures.In this study,a new porous high-entropy(La_(1/6)Ce_(1/6)Pr_(1/6)Sm_(1/6)Eu_(1/6)Gd_(1/6))PO_(4)(HE(6RE_(1/6))PO_(4))ceramics was prepared by combining the high-entropy method with the pore-forming agent method and the effect of different starch contents(0–60vol%)on this ceramic properties was systematically investigated.The results show that the porous HE(6RE_(1/6))PO_(4)ceramics with 60vol%starch exhibit the lowest thermal conductivity of 0.061 W·m^(-1)·K^(-1)at room temperature and good pore structure stability with a linear shrinkage of approximately1.67%.Moreover,the effect of large regular spherical pores(>10μm)on its thermal insulation performance was discussed,and an optimal thermal conductivity prediction model was screened.The superior properties of the prepared porous HE(6RE_(1/6))PO_(4)ceramics allow them to be promising insulation materials in the future.
基金Funded by the Guizhou Province Technological Breakthroughs Fund(No.20063030)the Guiyang City Technology and Industry Fund(No.200616-9)the Guizhou Science and Technology Founda-tion(No.[2009]2052)
文摘Using carbide slag as the calcareous materials, xonotlite thermal insulation material was successfully prepared via dynamic hydrothermal synthesis. The experimental results show that the xonotlite thermal insulation material is made up of large numbers of "chestnut bur shape" particles. Optimum conditions of calcination temperature of carbide slag, synthesis reaction temperature and time, stirring rate, CaO/SiO2 mol ratio, water/solid weight ratio, amount of fiberglass, molding pressures, dryness temperatures and the presence of dispersant (glycol and polyvinyl alcohol) favor the preparation of xonotlite thermal insulation material. The evaluation of xonotlite thermal insulation material reveals that the product is ultra-light and excellent in physical performances. Such a little amount of impurities in carbide slag has no effect on the phase, morphology, stability at high temperature and physical performances of products.
基金Supported by the National Natural Science Foundation of China(51472086,51002051)CAS Key Laboratory of Carbon Materials(No KLCMKFJJ1703)
文摘A new approach is provided to resolve the large-scale applications of coal tar pitch. Carbon foams with uniform pore size are prepared at the foaming pressure of normal pressure using coal tar pitch as raw materials. The physical and chemical performance of high softening point pitch(HSPP) can be regulated by vacuumizing owing to the cooperation of vacuumizing and polycondensation. Results indicate that the optimum softening point and weight ratio of quinoline insoluble are about 292℃ and 65.7%, respectively. And the optimum viscosity of HSPP during the foaming process is distributed in the range of 1000-10000 Pa·s. The resultant carbon foam exhibits excellent performance, such as uniform pore structure, high compressive strength(4.7 MPa), low thermal conductivity(0.07 W·m^(-1) ·K^(-1)), specially, it cannot be fired under the high temperature of 1200 ℃.Thus, this kind of carbon foam is a potential candidate for thermal insulation material applied in energy saving building.
基金supported by the Program for Guangdong Introducing Innovative and Entrepreneurial Teams(No.2019ZT08G315)Shenzhen Basic Research Program(General Program)(No.JCYJ20190808153416970)National Natural Science Foundation of China No.51827901 and U2013603。
文摘Deep petroleum resources are stored under high temperature and pressure conditions,with the temperature having a significant influence on the properties of rocks.Deep in-situ temperature-preserved coring(ITP-coring)devices were developed to assess deep petroleum reserves accurately.Herein,hollow glass microspheres(HGMs)/silicone rubber(SR)composites that exhibit excellent thermal insulation properties were prepared as thermal insulation materials for deep ITP-coring devices.The mechanism and process of heat transfer in the composites were explored,as well as their other properties.The results show that the HGMs exhibit good compatibility with the SR matrix.When the volume fraction of the HGMs is increased to 50%,the density of the HGMs/SR composites is reduced from 0.97 to 0.56 g/cm^(3).The HGMs filler introduces large voids into the composites,reducing their thermal conductivity to 0.11 W/m·K.The addition of HGMs into the composites further enhances the thermal stability of the SR,wherein the higher the HGMs filler content,the better the thermal stability of the composites.HGMs significantly enhance the mechanical strength of the SR.HGMs increase the compressive strength of the composites by 828%and the tensile strength by 164%.Overall,HGMs improve the thermal insulation,pressure resistance,and thermal stability of HGMs/SR composites.
文摘This study is planned to investigate the problems associated with the wasted sheep fleece in Jordan and to suggest methods to decrease its environmental impact. Results indicate that sheep fleece in Jordan makes an excellent resource for buildings insulation material. A linear regression model is used to predict sheep number for the period (2017-2030). Based on the predicted number of Sheep an estimated annual average production of wool is found for the period (2017-2030) to be (3.586 × 10<sup>3</sup> ton). The average cost per kg of fleece produced is calculated to be 0.39 JD, and the estimated price of fleece per head, if market is available for raw fleece, is 1 JD. Average annual financial losses by farmers are calculated to be (3.743 × 10<sup>6</sup> JD) for the period 2002-2016, and they were estimated to be (9.421 × 10<sup>6</sup> JD) for the years 2017-2030. Physical characteristics of sheep-wool are presented and compared to other competitive insulation materials (polystyrene and rockwool). Sustainability of sheep-wool production to be utilized as an insulation material is found to be an excellent solution to the huge waste of wool with respect to farmers and National income and to the problems associated with environmental impact. Results can be generalized to similar cases worldwide.
基金financial support from the National Nature Science Foundation of China(51502213)
文摘To solve the problem of over-high density of lightweight insulation refractory bricks prepared with fly ash, new lightweight insulation refractory materials with density 〈 0. 89 g · cm^-3 were .synthesized using pyrophyl-lite, .fly ash, and Suzhou clay as the main starting materials and saw dast as the pore forming substance, and controlling the addition of the pyrophyllite (20%, 30% , and 40% by mass ) and the treating temperature (1 250, 1 300, 1 350, and 1 400 ℃ ). The synthesized materials were characterized by the XRD, SEM and the thermal conductivity measuring in.strument. The results show at pyrophyllite addition of 30% and treat temperature of l 400 ℃ , the material can achieve linear shrinkage of 6. 6%, apparent porosity of 57%, bulk density of 0. 75 g · cm^-3, compressive strength of 2.7 MPa, and thermal conductivity at 350 ℃ of 0. 152 -0. 216 W·( m·K)^-1.This indicates that the pyrophyllite decomposition at high temperatures forms mullite and amorphous quartz introducing volume expansion, which counteracts some shrinkage at high temperatures. So it is feasible to use pyrophyllite, fly ash waste and clay to prepare lightweight insulation refractory materials.
文摘A hollow glass microsphere(HGM)/TiO2 composite hollow sphere was successfully prepared via a simple precipitation method.The TiO2 coating layers grew on the surface of the HGMs that range from 20 to 50μm in diameter as nanoparticles with the formation of the SiO Ti bonds.The growth mechanism accounting for the formation of the TiO2 nanolayers was proposed.The morphology,composition,thermal insulation properties,and visible-near infrared(VIS-NIR)refl ectance of the HGMs/TiO2 composite hollow spheres were characterized.The VIS-NIR reflectance of the HGMs/TiO2 composite hollow spheres increased by more than 30%compared to raw HGMs.The thermal conductivity of the particles is 0.058 W/(m K).The result indicates that the VIS-NIR reflectance of the composite hollow spheres is strongly influenced by the coating of TiO2.The composite hollow spheres were used as the main functional filler to prepare the organic-inorganic composite coatings.The glass substrates coated by the organic-inorganic coatings had lower thermal conductivity and higher near infrared reflectivity.Therefore,the HGMs/TiO2 composite hollow spheres can reflect most of the solar energy and effectively keep out the heat as a thermal insulation coating for energy-saving constructions.
文摘In order to reduce the thermal energy loss of high temperature kilns and furnaces and lower the surface temperature of the kiln body,magnesia insulation materials were prepared using self-made magnesia porous aggregates(using high purity magnesia powder as starting material and potassium oleate as the foaming agent),middle grade magnesia powder,calcium aluminate cement,and SiO_(2) micropowder as starting materials,introducing walnut shell powder impregnated with silica sol(short for Sws)as a pore-forming agent.The effects of the Sws addition(0,10%,15%,and 20%,by mass)and the sintering temperature(1300,1350,1400,and 1480℃)on the properties of magnesia insulation materials were studied.The results show that(1)for the specimens fired at 1480℃,when the Sws addition is 10%,the cold compressive strength is 22 MPa;when the Sws addition is 20%,the thermal conductivity is 0.368 W·m^(-1)·K^(-1)(350℃);(2)nano-silica in the silica sol reacts with MgO in the matrix to form forsterite,which encapsulates the pores volatilized from the walnut shell powder and forms closed pores.
基金supported by the Natural Science Foundation of Anhui Provincial Education Department(2023AH051130 and KJ2021ZD0040)the University Synergy Innovation Program of Anhui Province(GXXT-2019-015)+2 种基金National Natural Science Foundation of China(51972002)the Student Research Training Program(SRTP)of Anhui University of Technology(S202310360191)National Innovation and Entrepreneurship Training Program for College Students(202210360023).
文摘ZrO_(2)-strengthened porous mullite insulation materials were prepared by foaming technology utilizing ZrSiO_(4) and Al_(2)O_(3) as primary materials and Y_(2)O_(3) as an additive.The effects of Y_(2)O_(3) contents on the phase composition,microstructure,mechanical properties,and heat conductivity of the porous mullite insulation materials were investigated.A suitable Y_(2)O_(3) content could promote phase transition of monoclinic ZrO_(2)(m-ZrO_(2))to tetragonal ZrO_(2)(t-ZrO_(2)),reduce pore size,and improve the strengths of as-prepared specimens.The cold crushing strength and bending strength of as-prepared specimens with a 119µm spherical pore size using 6 wt.%Y_(2)O_(3) were 35.2 and 13.0 MPa,respectively,with a heat conductivity being only 0.248 W/(m K).
基金supported by the National Natural Science Foundation of China(No.51921005).
文摘Polypropylene(PP)-based recyclable materials have attracted tremendous interest for HVDC cable insulation applications due to their superior electrical properties,e.g.,high thermal stability and superior recyclability.Compared with crosslinked polyethylene(XLPE),PP-based materials exhibit the advantages of not only higher working temperatures but also facile and efficient cable manufacturing with reduced costs,which are highly desirable in HVDC cable manufacturing.Considering their promising advantages,PP-based materials have received significant attention from both academia and industry in the field of HVDC cable insulation.In order to adopt PP as a cable insulation material,the mechanical flexibility of PP should be improved.However,regulations of the mechanical properties inevitably influences the electrical properties of PP.So extensive research has been conducted on the regulation of the mechanical and electrical properties of PP.This review summarizes the research progress on recyclable PP-based materials for HVDC cable insulation applications.Particular attention is placed on the electrical property regulations and material structure-property relationships.The challenges that remain to be addressed and the opportunities for future studies on PP-based recyclable HVDC cable insulation materials are also presented.