FeS_(2)cathode is promising for all-solid-state lithium batteries due to its ultra-high capacity,low cost,and environmental friendliness.However,the poor performances,induced by limited electrode-electrolyte interface...FeS_(2)cathode is promising for all-solid-state lithium batteries due to its ultra-high capacity,low cost,and environmental friendliness.However,the poor performances,induced by limited electrode-electrolyte interface,severe volume expansion,and polysulfide shuttle,hinder the application of FeS_(2)in all-solid-state lithium batteries.Herein,an integrated 3D FeS_(2)electrode with full infiltration of Li6PS5Cl sulfide electrolytes is designed to address these challenges.Such a 3D integrated design not only achieves intimate and maximized interfacial contact between electrode and sulfide electrolytes,but also effectively buffers the inner volume change of FeS_(2)and completely eliminates the polysulfide shuttle through direct solid-solid conversion of Li2S/S.Besides,the vertical 3D arrays guarantee direct electron transport channels and horizontally shortened ion diffusion paths,endowing the integrated electrode with a remarkably reduced interfacial impedance and enhanced reaction kinetics.Benefiting from these synergies,the integrated all-solid-state lithium battery exhibits the largest reversible capacity(667 mAh g^(-1)),best rate performance,and highest capacity retention of 82%over 500 cycles at 0.1 C compared to both a liquid battery and non-integrated all-solid-state lithium battery.The cycling performance is among the best reported for FeS_(2)-based all-solid-state lithium batteries.This work presents an innovative synergistic strategy for designing long-cycling high-energy all-solid-state lithium batteries,which can be readily applied to other battery systems,such as lithium-sulfur batteries.展开更多
The effects of single Cd^(2+)and Pb^(2+),and combined Cd^(2+)and Pb^(2+)on dehydrogenase activity and polysaccharide content of the substrate biofilms in the integrated vertical-flow constructed wetland(IVCW)were stud...The effects of single Cd^(2+)and Pb^(2+),and combined Cd^(2+)and Pb^(2+)on dehydrogenase activity and polysaccharide content of the substrate biofilms in the integrated vertical-flow constructed wetland(IVCW)were studied.Dehydrogenase activities decreased linearly with the increasing concentrations of Cd^(2+)and Pb^(2+)at different times(6,24,72,and 120 h).The activities at both 6 and 24 h were significantly higher than that at 72 and 120 h in the case of single and combined treatments.The single Cd^(2+)and...展开更多
The spacial distribution characteristics, activity and degradation capability of the biofilm in integrated vertical-flow constructed wetland were investigated. Results showed that the biofilm widely distributed in the...The spacial distribution characteristics, activity and degradation capability of the biofilm in integrated vertical-flow constructed wetland were investigated. Results showed that the biofilm widely distributed in the substrate of integrated vertical-flow constructed wetland and mainly in the 0-10 cm top layer where the activity ofdehydrogenase of the biofilm was also higher than that of other layers. The water quality could also affect the activity of the biofilm, for the TF（1,3,5-Triphenylformazan） amount reduced by the biofim incubated in water of the higher eutrophication was larger, too. The PCP （pentachlorophenol） removal rate by the substrate with biofilm was 1.5 times that without biofilm. In total, the biofilm of the down-flow chamber appeared larger biomass, higher dehydrogenase activity and stronger degradation capability of organic contamination than that in up-flow chamber and it was the major place for removal of the organic matters in waste water.展开更多
To meet the demand of urban rainwater integrated management,we designed and complemented a physical simulation experimental system of urban rainfall infiltration regulation parameters.We discuss the feasibility of qua...To meet the demand of urban rainwater integrated management,we designed and complemented a physical simulation experimental system of urban rainfall infiltration regulation parameters.We discuss the feasibility of quantitative regulations of urban underlying surface rainfall infiltration conditions and a practical application of a simulated experimental system.In a com- prehensive analysis of the composition of an effective rainwater harvesting system and selection of water storage material,we simulated the major parameters of an experimental area rainfall,soil moisture and water storage capacity by providing an effective regulation of the experimental area runoff coefficient,obtained from basic data.展开更多
The integrated vertical-flow constructed wetland（IVCW） was simulated with three suits of designed experiment columns planted with Kandelia candel.Units A,B and C were irrigated with sewage of different salinity（A...The integrated vertical-flow constructed wetland（IVCW） was simulated with three suits of designed experiment columns planted with Kandelia candel.Units A,B and C were irrigated with sewage of different salinity（A：10‰ B：20‰,C：30‰）,respectively.The removal rates of dissolved organic carbon（DOC）,NH3-N and NO3--N dropped 90.4%-48.6%,80.2%-40.3% and 84.8%-60.9%,respectively,when salinity increases from 10‰ to 30‰.The removal rate of TP increased 14%-31.2%,oppositely.A 20-day inflow salinity drastic change shock affective trial was done on units D and E.Unit D was used as a control and irrigated with saline sewage（20‰）.Unit E was irrigated with sewage with low salinity（5‰） as a salinity drastic change shock on the third and fourth days.DOC,NH3-N and NO3--N removal efficiency of unit E showed a three-stage process of change,＂rapidly decrease,increase beyond the normal standard,and then back to the normal standard＂.TP removal value was negative during the 2-day shock period.展开更多
基金supported by the National Natural Science Foundation of China(Grant nos.52272201,52072136,52172229,52302303,and 51972257)Yanchang Petroleum-WHUT Joint Program(yc-whlg-2022ky-05)+1 种基金the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing(Wuhan University of Technology,2022-KF-20)Fundamental Research Funds for the Central Universities(2023IVA106)for financial support
文摘FeS_(2)cathode is promising for all-solid-state lithium batteries due to its ultra-high capacity,low cost,and environmental friendliness.However,the poor performances,induced by limited electrode-electrolyte interface,severe volume expansion,and polysulfide shuttle,hinder the application of FeS_(2)in all-solid-state lithium batteries.Herein,an integrated 3D FeS_(2)electrode with full infiltration of Li6PS5Cl sulfide electrolytes is designed to address these challenges.Such a 3D integrated design not only achieves intimate and maximized interfacial contact between electrode and sulfide electrolytes,but also effectively buffers the inner volume change of FeS_(2)and completely eliminates the polysulfide shuttle through direct solid-solid conversion of Li2S/S.Besides,the vertical 3D arrays guarantee direct electron transport channels and horizontally shortened ion diffusion paths,endowing the integrated electrode with a remarkably reduced interfacial impedance and enhanced reaction kinetics.Benefiting from these synergies,the integrated all-solid-state lithium battery exhibits the largest reversible capacity(667 mAh g^(-1)),best rate performance,and highest capacity retention of 82%over 500 cycles at 0.1 C compared to both a liquid battery and non-integrated all-solid-state lithium battery.The cycling performance is among the best reported for FeS_(2)-based all-solid-state lithium batteries.This work presents an innovative synergistic strategy for designing long-cycling high-energy all-solid-state lithium batteries,which can be readily applied to other battery systems,such as lithium-sulfur batteries.
文摘The effects of single Cd^(2+)and Pb^(2+),and combined Cd^(2+)and Pb^(2+)on dehydrogenase activity and polysaccharide content of the substrate biofilms in the integrated vertical-flow constructed wetland(IVCW)were studied.Dehydrogenase activities decreased linearly with the increasing concentrations of Cd^(2+)and Pb^(2+)at different times(6,24,72,and 120 h).The activities at both 6 and 24 h were significantly higher than that at 72 and 120 h in the case of single and combined treatments.The single Cd^(2+)and...
文摘The spacial distribution characteristics, activity and degradation capability of the biofilm in integrated vertical-flow constructed wetland were investigated. Results showed that the biofilm widely distributed in the substrate of integrated vertical-flow constructed wetland and mainly in the 0-10 cm top layer where the activity ofdehydrogenase of the biofilm was also higher than that of other layers. The water quality could also affect the activity of the biofilm, for the TF（1,3,5-Triphenylformazan） amount reduced by the biofim incubated in water of the higher eutrophication was larger, too. The PCP （pentachlorophenol） removal rate by the substrate with biofilm was 1.5 times that without biofilm. In total, the biofilm of the down-flow chamber appeared larger biomass, higher dehydrogenase activity and stronger degradation capability of organic contamination than that in up-flow chamber and it was the major place for removal of the organic matters in waste water.
基金Projects 40371113 supported by the National Natural Science Foundation of ChinaOF060096 by the Youth Scientific Foundation of China University of Mining & Technology
文摘To meet the demand of urban rainwater integrated management,we designed and complemented a physical simulation experimental system of urban rainfall infiltration regulation parameters.We discuss the feasibility of quantitative regulations of urban underlying surface rainfall infiltration conditions and a practical application of a simulated experimental system.In a com- prehensive analysis of the composition of an effective rainwater harvesting system and selection of water storage material,we simulated the major parameters of an experimental area rainfall,soil moisture and water storage capacity by providing an effective regulation of the experimental area runoff coefficient,obtained from basic data.
基金Supported by the National High Technology Research and Development Program of China (863 Program) (2009ZX07106-002-004)the National Natural Science Foundation of China (50808172,30870221)
文摘The integrated vertical-flow constructed wetland（IVCW） was simulated with three suits of designed experiment columns planted with Kandelia candel.Units A,B and C were irrigated with sewage of different salinity（A：10‰ B：20‰,C：30‰）,respectively.The removal rates of dissolved organic carbon（DOC）,NH3-N and NO3--N dropped 90.4%-48.6%,80.2%-40.3% and 84.8%-60.9%,respectively,when salinity increases from 10‰ to 30‰.The removal rate of TP increased 14%-31.2%,oppositely.A 20-day inflow salinity drastic change shock affective trial was done on units D and E.Unit D was used as a control and irrigated with saline sewage（20‰）.Unit E was irrigated with sewage with low salinity（5‰） as a salinity drastic change shock on the third and fourth days.DOC,NH3-N and NO3--N removal efficiency of unit E showed a three-stage process of change,＂rapidly decrease,increase beyond the normal standard,and then back to the normal standard＂.TP removal value was negative during the 2-day shock period.
