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基于Photo Sphere Viewer的轻量化可量测街景系统研究
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作者 刘一宁 王琳 岳照溪 《测绘通报》 CSCD 北大核心 2024年第S01期11-17,共7页
随着新型基础测绘体系发展,测绘技术和装备不断升级,大量街景数据随着车载激光扫描工作一并被采集。针对该数据路线随机性大、密集程度高等特点,以及传统街景地图系统插件受限、扩展性不强、无法量测等局限,本文设计了基于Photo Sphere ... 随着新型基础测绘体系发展,测绘技术和装备不断升级,大量街景数据随着车载激光扫描工作一并被采集。针对该数据路线随机性大、密集程度高等特点,以及传统街景地图系统插件受限、扩展性不强、无法量测等局限,本文设计了基于Photo Sphere Viewer的轻量化可量测街景系统,在开源插件的基础上实现了对其组件的扩充、实现了行进方向、地图交互等系统功能的设计优化,进一步实现了基于深度图的街景地图量测功能。生产作业队伍对系统的使用结果表明,该系统可以辅助生产作业队伍进行属性采集、纹理更新、数据检查等多项工作,操作灵活便捷,且具有较强的可扩展性,便于基于生产需求进行改进调整,提高了生产效率,为新型基础测绘成果进一步深化应用提供了良好的借鉴作用。 展开更多
关键词 Photo sphere Viewer 轻量化 街景量测 街景数据组织 新型基础测绘
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Intelligent Small Sample Defect Detection of Concrete Surface Using Novel Deep Learning Integrating Improved YOLOv5 被引量:1
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作者 Yongming Han Lei Wang +1 位作者 Youqing Wang Zhiqiang Geng 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2024年第2期545-547,共3页
Dear Editor,This letter presents an intelligent small sample defect detection of concrete surface using novel deep learning integrating the improved YOLOv5 based on the Wasserstein GAN(WGAN)enhancement algorithm.The p... Dear Editor,This letter presents an intelligent small sample defect detection of concrete surface using novel deep learning integrating the improved YOLOv5 based on the Wasserstein GAN(WGAN)enhancement algorithm.The proposed method is capable of producing top-notch data sets to address the issues of insufficient samples and substandard quality. 展开更多
关键词 CONCRETE integrating ALGORITHM
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CLASSIFICATIONS OF DUPIN HYPERSURFACES IN LIE SPHERE GEOMETRY
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作者 Thomas E.CECIL 《Acta Mathematica Scientia》 SCIE CSCD 2024年第1期1-36,共36页
This is a survey of local and global classification results concerning Dupin hypersurfaces in S^(n)(or R^(n))that have been obtained in the context of Lie sphere geometry.The emphasis is on results that relate Dupin h... This is a survey of local and global classification results concerning Dupin hypersurfaces in S^(n)(or R^(n))that have been obtained in the context of Lie sphere geometry.The emphasis is on results that relate Dupin hypersurfaces to isoparametric hypersurfaces in spheres.Along with these classification results,many important concepts from Lie sphere geometry,such as curvature spheres,Lie curvatures,and Legendre lifts of submanifolds of S^(n)(or R^(n)),are described in detail.The paper also contains several important constructions of Dupin hypersurfaces with certain special properties. 展开更多
关键词 Dupin hypersurfaces isoparametric hypersurfaces Lie sphere geometry Lie sphere transformations Lie curvatures
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Core-shell mesoporous carbon hollow spheres as Se hosts for advanced Al-Se batteries
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作者 Haiping Lei Tianwei Wei +1 位作者 Jiguo Tu Shuqiang Jiao 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第5期899-906,共8页
Incorporating a selenium(Se)positive electrode into aluminum(Al)-ion batteries is an effective strategy for improving the overall battery performance.However,the cycling stability of Se positive electrodes has challen... Incorporating a selenium(Se)positive electrode into aluminum(Al)-ion batteries is an effective strategy for improving the overall battery performance.However,the cycling stability of Se positive electrodes has challenges due to the dissolution of intermediate reaction products.In this work,we aim to harness the advantages of Se while reducing its limitations by preparing a core-shell mesoporous carbon hollow sphere with a titanium nitride(C@TiN)host to load 63.9wt%Se as the positive electrode material for Al-Se batteries.Using the physical and chemical confinement offered by the hollow mesoporous carbon and TiN,the obtained core-shell mesoporous carbon hollow spheres coated with Se(Se@C@TiN)display superior utilization of the active material and remarkable cycling stability.As a result,Al-Se batteries equipped with the as-prepared Se@C@TiN composite positive electrodes show an initial discharge specific capacity of 377 mAh·g^(-1)at a current density of 1000 mA·g^(-1)while maintaining a discharge specific capacity of 86.0 mAh·g^(-1)over 200 cycles.This improved cycling performance is ascribed to the high electrical conductivity of the core-shell mesoporous carbon hollow spheres and the unique three-dimensional hierarchical architecture of Se@C@TiN. 展开更多
关键词 aluminum-selenium batteries intermediate products core-shell mesoporous carbon hollow sphere cycling performance
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Spherically Symmetric Problem of General Relativity for a Fluid Sphere
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作者 Valery V. Vasiliev Leonid V. Fedorov 《Journal of Modern Physics》 2024年第4期401-415,共15页
The paper is devoted to a spherically symmetric problem of General Relativity (GR) for a fluid sphere. The problem is solved within the framework of a special geometry of the Riemannian space induced by gravitation. A... The paper is devoted to a spherically symmetric problem of General Relativity (GR) for a fluid sphere. The problem is solved within the framework of a special geometry of the Riemannian space induced by gravitation. According to this geometry, the four-dimensional Riemannian space is assumed to be Euclidean with respect to the space coordinates and Riemannian with respect to the time coordinate. Such interpretation of the Riemannian space allows us to obtain complete set of GR equations for the external empty space and the internal spaces for incompressible and compressible perfect fluids. The obtained analytical solution for an incompressible fluid is compared with the Schwarzchild solution. For a sphere consisting of compressible fluid or gas, a numerical solution is presented and discussed. 展开更多
关键词 General Relativity Spherically Symmetric Problem Fluid sphere
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Exactly Solvable Two-Parameter Models of Relativistic δ′s -Sphere Interactions in Quantum Mechanics
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作者 Jules Manirambona Juma Shabani Alfred Vyabandi 《Journal of Applied Mathematics and Physics》 2024年第4期1263-1285,共23页
We make a systematic study of two-parameter models of δ ′ s -sphere interaction and δ ′ s -sphere plus a Coulomb interaction. Where δ ′ s interaction denotes the δ ′ -sphere interaction of the second kind. We ... We make a systematic study of two-parameter models of δ ′ s -sphere interaction and δ ′ s -sphere plus a Coulomb interaction. Where δ ′ s interaction denotes the δ ′ -sphere interaction of the second kind. We provide the mathematical definitions of Hamiltonians and obtain new results for both models, in particular the resolvents equations, spectral properties and some scattering quantities. 展开更多
关键词 Boundary Conditions Problem -sphere Interactions Self-Adjoint Operator Resolvent Equation Spectral Properties Scattering Theory
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Development of the integrated integrating sphere cold atom clock 被引量:2
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作者 于明圆 孟艳玲 +6 位作者 叶美凤 王鑫 欧阳鑫川 万金银 肖玲 成华东 刘亮 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第7期184-187,共4页
We develop an integrated integrating sphere cold atom clock(ISCAC), which mainly consists of physical package,laser system, microwave source, and electronics.This compact system is more stable and reliable than the pr... We develop an integrated integrating sphere cold atom clock(ISCAC), which mainly consists of physical package,laser system, microwave source, and electronics.This compact system is more stable and reliable than the previous version.The experimental results show that the short term frequency stability of 5.4×10^-13τ-1/2 and 2.9× 10^-15 at 1-day integrating time are achieved. 展开更多
关键词 integrating sphere COLD ATOM CLOCK PHYSICAL PACKAGE laser system frequency stability
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Calibration chain design based on integrating sphere transfer radiometer for SI-traceable on-orbit spectral radiometric calibration and its uncertainty analysis 被引量:1
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作者 赵维宁 方伟 +2 位作者 孙立微 崔立红 王玉鹏 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第9期276-283,共8页
In order to satisfy the requirement of SI-traceable on-orbit absolute radiation calibration transfer with high accuracy for satellite remote sensors,a transfer chain consisting of a fiber coupling monochromator(FBM)... In order to satisfy the requirement of SI-traceable on-orbit absolute radiation calibration transfer with high accuracy for satellite remote sensors,a transfer chain consisting of a fiber coupling monochromator(FBM) and an integrating sphere transfer radiometer(ISTR) was designed in this paper.Depending on the Sun,this chain based on detectors provides precise spectral radiometric calibration and measurement to spectrometers in the reflective solar band(RSB) covering 300–2500 nm with a spectral bandwidth of 0.5–6 nm.It shortens the traditional chain based on lamp source and reduces the calibration uncertainty from 5% to 0.5% by using the cryogenic radiometer in space as a radiometric benchmark and trap detectors as secondary standard.This paper also gives a detailed uncertainty budget with reasonable distribution of each impact factor,including the weak spectral signal measurement with uncertainty of 0.28%.According to the peculiar design and comprehensive uncertainty analysis,it illustrates that the spectral radiance measurement uncertainty of the ISTR system can reach to 0.48%.The result satisfies the requirements of SI-traceable on-orbit calibration and has wider significance for expanding the application of the remote sensing data with high-quality. 展开更多
关键词 SI-traceable calibration on-orbit high-accuracy transfer chain integrating sphere transfer radiometer uncertainty analysis
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Development of an Integrating Sphere Cold Atom Clock 被引量:2
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作者 郑本昌 成华东 +3 位作者 孟艳玲 肖玲 万金银 刘亮 《Chinese Physics Letters》 SCIE CAS CSCD 2013年第12期30-32,共3页
The Ramsey fringes with a linewidth of 45 Hz and a signal-to-noise ratio of 120 are demonstrated for a integrating sphere atom clock.The cycle time of the atom clock is reduced to 80 ms with the help of a pulsed cooli... The Ramsey fringes with a linewidth of 45 Hz and a signal-to-noise ratio of 120 are demonstrated for a integrating sphere atom clock.The cycle time of the atom clock is reduced to 80 ms with the help of a pulsed cooling method.This result indicates that the short-term stability of the clock is in the order of 10^(-12). 展开更多
关键词 METHOD integrating CLOCK
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Determination of optical properties of normal and adenomatous human colon tissues in vitro using integrating sphere techniques 被引量:2
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作者 Hua-JiangWei DaXing +3 位作者 Jian-JunLu Huai-MinGu Guo-YongWu YingJin 《World Journal of Gastroenterology》 SCIE CAS CSCD 2005年第16期2413-2419,共7页
AIM: The purpose of the present study is to compare the optical properties of normal human colon mucosa/submucosa and muscle layer/chorion, and adenomatous human colon mucosa/submucosa and muscle layer/chorion in vitr... AIM: The purpose of the present study is to compare the optical properties of normal human colon mucosa/submucosa and muscle layer/chorion, and adenomatous human colon mucosa/submucosa and muscle layer/chorion in vitro at 476.5, 488, 496.5, 514.5 and 532 nm. We believe these differences in optical properties should help differential diagnosis of human colon tissues by using optical methods.METHODS: In vitro optical properties were investigated for four kinds of tissues: normal human colon mucosa/submucosa and muscle layer/chorion, and adenomatous human colon mucosa/submucosa and muscle layer/chorion. Tissue samples were taken from 13 human colons (13 adenomatous, 13 normal). From the normal human colons a total of 26 tissue samples, with a mean thickness of 0.40 mm, were used (13 from mucosa/submucosa and 13 from muscle layer/chorion), and from the adenomatous human bladders a total of 26 tissue samples, with a mean thickness of 0.40 mm, were used (13 from mucosa/submucosa and 13 from muscle layer/chorion). The measurements were performed using a double-integratingsphere setup and the optical properties were assessed from these measurements using the adding-doubling method that was considered reliable.RESULTS: The results of measurement showed that there were significant differences in the absorption coefficients and scattering coefficients between normal and adenomatous human colon mucosa/submucosa at the same wavelength,and there were also significant differences in the two optical parameters between both colon muscle layer/chorion at the same wavelength. And there were large differences in the anisotropy factors between both colon mucosa/submucosa at the same wavelength, there were also large differences in the anisotropy factors between both colon muscle layer/chorion at the same wavelength.There were large differences in the value ranges of the absorption coefficients, scattering coefficients and anisotropy factors between both colon mucosa/submucosa,and there were also large differences in these value ranges between both colon muscle layer/chorion. There are the same orders of magnitude in the absorption coefficients for four kinds of colon tissues. The scattering coefficients of these tissues exceed the absorption coefficients by at least two orders of magnitude.CONCLUSION: There were large differences in the three optical parameters between normal and adenomatous human colon mucosa/submucosa at the same laser wavelength, and there were also large differences in these parameters between both colon muscle layer/chorion at the same laser wavelength. Large differences in optical parameters indicate that there were large differences in compositions and structures between both colon mucosa/submucosa, and between both colon muscle layer/chorion.Optical parameters for four kinds of colon tissues are wavelength dependent, and these differences would be useful and helpful in clinical applications of laser and tumors photodynamic therapy (PDT). 展开更多
关键词 光学道具 肿瘤 结肠组织 黏膜 球形结合技术 光学治疗
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Dick Effect in the Integrating Sphere Cold Atom Clock
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作者 王秀梅 孟艳玲 +7 位作者 王亚宁 万金银 于明圆 王鑫 肖玲 李唐 成华东 刘亮 《Chinese Physics Letters》 SCIE CAS CSCD 2017年第6期44-47,共4页
The Dick effect is an important factor limiting the frequency stability of sequentially-operating atomic frequency standards. Here we study the impact of the Dick effect in the integrating sphere cold atom clock (IS... The Dick effect is an important factor limiting the frequency stability of sequentially-operating atomic frequency standards. Here we study the impact of the Dick effect in the integrating sphere cold atom clock (ISCAC). To reduce the impact of the Dick effect, a 5 MHz local oscillator with ultra-low phase noise is selected and a new microwave synthesizer is built in-house. Consequently, the phase noise of microwave signal is optimized. The contribution of the Dick effect is reduced to 2.5× 10^-13τ-1/2 (3- is the integrating time). The frequency stability of 4.6 × 10-13τ-1/2 is achieved. The development of this optimization can promote the space applications of the compact ISCA C. 展开更多
关键词 ISC AC Dick Effect in the integrating sphere Cold Atom Clock
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Low-temperatures synthesis of CuS nanospheres as cathode material for magnesium second batteries 被引量:1
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作者 Qin Zhang Yaobo Hu +1 位作者 Jun Wang Fusheng Pan 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第1期192-200,共9页
Rechargeable magnesium batteries(RMBs),as one of the most promising candidates for efficient energy storage devices with high energy,power density and high safety,have attracted increasing attention.However,searching ... Rechargeable magnesium batteries(RMBs),as one of the most promising candidates for efficient energy storage devices with high energy,power density and high safety,have attracted increasing attention.However,searching for suitable cathode materials with fast diffusion kinetics and exploring their magnesium storage mechanisms remains a great challenge.Cu S submicron spheres,made by a facile low-temperature synthesis strategy,were applied as the high-performance cathode for RMBs in this work,which can deliver a high specific capacity of 396mAh g^(-1)at 20 mA g^(-1) and a remarkable rate capacity of 250 m Ah g^(-1)at 1000 mA g^(-1).The excellent rate performance can be assigned to the nano needle-like particles on the surface of Cu S submicron spheres,which can facilitate the diffusion kinetics of Mg^(2+).Further storage mechanism investigations illustrate that the Cu S cathodes experience a two-step conversion reaction controlled by diffusion during the electrochemical reaction process.This work could make a contribution to the study of the enhancement of diffusion kinetics of Mg2+and the reaction mechanism of RMBs. 展开更多
关键词 Magnesium second batteries Cathode material CUS Submicron spheres Low-temperature synthesis.
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An Improved Approach for Interaction of Wave with Floating Spheres and Its Applications
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作者 LIU Can DONG Zhi-yong +2 位作者 PAN Yun TONG Huan-huan YANG li-jing 《China Ocean Engineering》 SCIE EI CSCD 2023年第1期115-130,共16页
To develop and utilize marine resources in the deep sea, the higher requirements for floating structures, which are operated in marine environment for a long term, have been put forward. Reasonable structure type and ... To develop and utilize marine resources in the deep sea, the higher requirements for floating structures, which are operated in marine environment for a long term, have been put forward. Reasonable structure type and accurate force analysis are favorable guarantees to improve the survival performance and working performance of the floating structures. Floating spheres fastened by mooring cable were widely used in floating structures. In this paper, the wave forces of the floating sphere are efficiently and accurately calculated by solving the geometric relationship between the non-submerged floating sphere and wave surface. Combined with the hydrodynamic calculation of mooring cables based on the lumped mass method, the coupled motion model of multi-floating spheres fastened by multi-mooring cable was established under wave action. Furthermore, according to the floating structures fastened by mooring cable in the actual ocean engineering, the topological method of multi-mooring cables fastening the multifloating spheres was expounded from simple to complex. Finally, the modeling method and preliminarily hydrodynamic characteristics of the fastened floating structures, including the mooring system of renewable energy devices, ocean buoy, and coral nursery, were presented and analyzed in detail. The obtained results showed that the method for calculating the wave force on the floating sphere developed in this paper can accurately describe the motion process of the floating mooring sphere and the force on the mooring cable. Also, the topological method of multiple buoys and multiple mooring cables could efficiently establish various numerical hydrodynamic models of fastened buoys in ocean engineering. 展开更多
关键词 floating sphere mooring cable wave forces hydrodynamic model ocean engineering
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Strength and failure characteristics of marble spheres subjected to paired point loads
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作者 Rui Zhao Ming Tao +2 位作者 Wenzhuo Cao Kun Du Jianbo Zhu 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第9期2280-2290,共11页
Failure of irregular rock samples may provide implications in the rapid estimation of rock strength,which is imperative in rock engineering practice.In this work,analytical,experimental and numerical investigations we... Failure of irregular rock samples may provide implications in the rapid estimation of rock strength,which is imperative in rock engineering practice.In this work,analytical,experimental and numerical investigations were carried out to study the mechanical properties and failure characteristics of rock spheres under paired point loads.Analytical solutions indicted that with the increase in sample size(contact angle)and decrease in Poisson’s ratio,the uneven tensile stress in theta direction decreased.Then laboratory experiments were carried out to investigate the load characteristics and failure mode of spherical marble samples with different sizes subjected to a pair of diametral point loads.The discrete element method(DEM)was adopted to study the failure process of rock spheres.The effect of the sphere diameter on the point load contact angle was examined in terms of peak load,crushed zone distribution and energy dissipation.Experimental and numerical results showed that the samples primarily fail in tension,with crushed zones formed at both loading points.With increase in the sample size,the contact angle,crushed area and total work increase.As the specimen diameter increases from 30 mm to 50 mm,the peak load on the specimen increases from 3.6 kN to 8.8 kN,and the percentage of crushed zone(ratio of crushing zone to sample radius,d/r)increased from 0.191 to 0.262.The results of the study have implications for understanding the failure of irregular rock specimens under point loading conditions and their size effects. 展开更多
关键词 Rock sphere Point load Contact angle Energy dissipation Failure analysis
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ON THE FIGIEL TYPE PROBLEM AND EXTENSION OFε-ISOMETRY BETWEEN UNIT SPHERES
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作者 刘锐 尹际富 《Acta Mathematica Scientia》 SCIE CSCD 2023年第4期1503-1517,共15页
This paper studies two isometric problems between unit spheres of Banach spaces.In the first part,we introduce and study the Figiel type problem of isometric embeddings between unit spheres.However,the classical Figie... This paper studies two isometric problems between unit spheres of Banach spaces.In the first part,we introduce and study the Figiel type problem of isometric embeddings between unit spheres.However,the classical Figiel theorem on the whole space cannot be trivially generalized to this case,and this is pointed out by a counterexample.After establishing this,we find a natural necessary condition required by the existence of the Figiel operator.Furthermore,we prove that when X is a space with the T-property,this condition is also sufficient for an isometric embedding T:S_(X)→S_(Y) to admit the Figiel operator.This answers the Figiel type problem on unit spheres for a large class of spaces.In the second part,we consider the extension of bijectiveε-isometries between unit spheres of two Banach spaces.It is shown that every bijectiveε-isometry between unit spheres of a local GL-space and another Banach space can be extended to be a bijective 5ε-isometry between the corresponding unit balls.In particular,whenε=0,this recovers the MUP for local GL-spaces obtained in[40]. 展开更多
关键词 unit spheres isometric embedding Figiel type problem ε-isometry EXTENSION
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Experimental observation on water entry of a sphere in regular wave
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作者 Qian Wang Changze Zhao +1 位作者 Haocheng Lu Hua Liu 《Theoretical & Applied Mechanics Letters》 CSCD 2023年第5期367-374,共8页
This paper presents a novel experiment to observe the whole water entry process of a free-falling sphere into a regular wave.A time-accurate synchronizing system modulates the moment elaborately to ensure the sphere i... This paper presents a novel experiment to observe the whole water entry process of a free-falling sphere into a regular wave.A time-accurate synchronizing system modulates the moment elaborately to ensure the sphere impacting onto the water surface at the desirable wave phase.Four high-speed cameras focus locally to measure the high-precision size of the cavity evolution.Meanwhile,the aggregated field view of the camera array covers both the splash above the free surface and the entire cavity in the wave.The detailed methodologies are described and verified for the hardware set-up and the image post-processing.The theoretical maximum deviation is 1.7%on the space scale.The integral morphology of the cavity is captured precisely in the coordinate system during the sphere penetrates through the water at four representative wave phases and the still water.The result shows that the horizontal velocity of the fluid particle in the wave impels the cavity and changes the shape distinctly.Notably,the wave motion causes the cavity to pinch offearlier at the wave trough phase and later at the wave crest phase than in the still water.The wave motion influences the falling process of the sphere slightly in the present parameters. 展开更多
关键词 Physical experiment Water entry Free-falling sphere Regular wave
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Geographical Information Visualization on a Panoramic Sphere in an Immersive Environment
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作者 MA Ying TIAN Fenglin +3 位作者 LIU Wen TANG Moran LI Jinyu CHEN Ge 《Journal of Ocean University of China》 SCIE CAS CSCD 2023年第4期961-974,共14页
In this paper,we propose a novel approach to visualizing global geographical information:a panoramic sphere in an immersive environment.The whole geographical surface can be observed through the rotating of heads as t... In this paper,we propose a novel approach to visualizing global geographical information:a panoramic sphere in an immersive environment.The whole geographical surface can be observed through the rotating of heads as the viewpoint of the panoramic sphere is inside the sphere.We compared three approaches to visualizing the earth for rendering the geographical information in a virtual reality environment.On the tasks of terrestrial and marine geographical information,we compare the visualization effects on a)a globe,b)a flat map and c)a panoramic sphere.Terrestrial geographical information tasks include the area comparison and direction determination.Marine geographical information tasks contain the visualization of sea surface temperature and sea surface currents.For terrestrial geographical information tasks,the experimental results show that the panoramic sphere outperforms the globe and the flat map,with a higher average accuracy and a shorter time.On marine geographical information task,the panoramic sphere visualization is also superior to the flat map and the globe in an immersive environment for the sea surface temperature data and the sea surface current fields.In all three visualization experiments,the panoramic sphere is most preferred by the participants,particularly for global,transcontinental and transoceanic needs. 展开更多
关键词 the panoramic sphere immersive environment virtual reality oceanographic information visualization
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Electrochemical hydrogen evolution efficiently boosted by interfacial charge redistribution in Ru/MoSe_(2) embedded mesoporous hollow carbon spheres
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作者 Yubin Kuang Wei Qiao +1 位作者 Fulin Yang Ligang Feng 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第10期447-454,I0012,共9页
The strong metal-support interaction inducing combined effect plays a crucial role in the catalysis reaction. Herein, we revealed that the combined advantages of MoSe_(2), Ru, and hollow carbon spheres in the form of ... The strong metal-support interaction inducing combined effect plays a crucial role in the catalysis reaction. Herein, we revealed that the combined advantages of MoSe_(2), Ru, and hollow carbon spheres in the form of Ru nanoparticles(NPs) anchored on a two-dimensionally ordered MoSe_(2) nanosheet-embedded mesoporous hollow carbon spheres surface(Ru/MoSe_(2)@MHCS) for the largely boosted hydrogen evolution reaction(HER) performance. The combined advantages from the conductive support, oxyphilic MoSe_(2), and Ru active sites imparted a strong synergistic effect and charge redistribution in the Ru periphery which induced high catalytic activity, stability, and kinetics for HER. Specifically, the obtained Ru/MoSe_(2)@MHCS required a small overpotential of 25.5 and 38.4 mV to drive the kinetic current density of 10 mA cm^(-2)both in acid and alkaline media, respectively, which was comparable to that of the Pt/C catalyst. Experimental and theoretical results demonstrated that the charge transfer from MoSe_(2) to Ru NPs enriched the electronic density of Ru sites and thus facilitated hydrogen adsorption and water dissociation. The current work showed the significant interfacial engineering in Ru-based catalysts development and catalysis promotion effect understanding via the metal-support interaction. 展开更多
关键词 Hydrogen evolution reaction RUTHENIUM ELECTROCATALYST MoSe_(2) Mesoporous hollow carbon spheres
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Spherically Symmetric Problem of General Relativity for an Elastic Solid Sphere
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作者 Valery V. Vasiliev Leonid V. Fedorov 《Journal of Modern Physics》 CAS 2023年第6期818-832,共15页
The paper is devoted to a spherically symmetric problem of General Relativity (GR) for an elastic solid sphere. Originally developed to describe gravitation in continuum (vacuum, gas, fluid and solid) GR does not prov... The paper is devoted to a spherically symmetric problem of General Relativity (GR) for an elastic solid sphere. Originally developed to describe gravitation in continuum (vacuum, gas, fluid and solid) GR does not provide the complete set of equations for solids and, in contrast to the Newton gravitation theory, does not allow us to study the stresses induced by gravitation in solids, because the compatibility equations which are attracted in the Euclidean space for this purpose do not exist in the Riemannian space. To solve the problem within the framework of GR, a special geometry of the Riemannian space induced by gravitation is proposed. According to this geometry, the four-dimensional Riemannian space is assumed to be Euclidean with respect to the space coordinates and Riemannian with respect to the time coordinate. Such interpretation of the Riemannian space in GR allows us to supplement the conservation equations for the energy-momentum tensor with compatibility equations of the theory of elasticity and to arrive to the complete set of equations for stresses. The analytical solution of the Einstein equations for the empty space surrounding the sphere and the numerical solution for the internal space inside the sphere with the proposed geometry are presented and discussed. 展开更多
关键词 General Relativity Spherically Symmetric Problem Elastic sphere
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Micropores regulating enables advanced carbon sphere catalyst for Zn-air batteries
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作者 Jingsha Li Shijie Yi +3 位作者 Ranjusha Rajagopalan Zejie Zhang Yougen Tang Haiyan Wang 《Green Energy & Environment》 SCIE EI CSCD 2023年第1期308-317,共10页
Energy conversion technologies like fuel cells and metal-air batteries require oxygen reduction reaction(ORR)electrocatalysts with low cost and high catalytic activity.Herein,N-doped carbon spheres(N-CS)with rich micr... Energy conversion technologies like fuel cells and metal-air batteries require oxygen reduction reaction(ORR)electrocatalysts with low cost and high catalytic activity.Herein,N-doped carbon spheres(N-CS)with rich micropore structure have been synthesized by a facile two-step method,which includes the polymerization of pyrrole and formaldehyde and followed by a facile pyrolysis process.During the preparation,zinc chloride(ZnCl2)was utilized as a catalyst to promote polymerization and provide a hypersaline environment.In addition,the morphology,defect content and activity area of the resultant N-CS catalysts could be regulated by controlling the content of ZnCl2.The optimum N-CS-1 catalyst demonstrated much better catalytic activity and durability towards ORR in alkaline conditions than commercial 20 wt%Pt/C catalysts,of which the half-wave potential reached 0.844 V vs.RHE.When applied in the Zn-air batteries as cathode catalysts,N-CS-1 showed a maximum power density of 175 mW cm^(-2) and long-term discharging stability of over 150 h at 10 mA cm^(-2),which outperformed 20 wt%Pt/C.The excellent performance could be due to its ultrahigh specific surface area of 1757 m2 g1 and rich micropore channels structure.Meanwhile,this work provides an efficient method to synthesize an ultrahigh surface porous carbon material,especially for catalyst application. 展开更多
关键词 Zn-air batteries Oxygen reduction reaction N-doped carbon spheres MICROPORES Ultrahigh specific surface
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