Characteristics and fate behavior of environmentally persistent free radicals in atmospheric particulate matter

Background,aim,and scope Environmentally persistent free radicals(EPFRs)have received significant attention due to their longer lifetime and stable existence in various environments.The strong environmental migration ability of particulate matter allows EPFRs to migrate over long-distance transport,thereby impacting the quality of the local atmospheric environment.Additionally,EPFRs can also adhere to atmospheric particles and interact with typical gaseous pollutants to affect atmospheric chemical reactions.EPFRs can produce some reactive organic species,promoting oxidative stress in the human body,damaging biological macromolecules and ultimately affecting the organism health.EPFRs are considered as a novel type of pollutant that affects human health.Despite their significance,there are few literatures available on the characteristics and fate behaviors of EPFRs up to date.Therefore,supplemental reviews are crucial for providing comprehensive understanding of EPFRs.Materials and methods This review summarizes the characteristics of EPFRs in particulate matter,outlines the generation mechanism and influencing factors of EPFRs,and the impacts of EPFRs on environmental quality and organism health.Results The content of EPFRs in particulate matter ranges from 1017 to 1020 spins∙g−1.Due to the strong mobility of atmospheric particulate matter,the long-term exposure to high levels of EPFRs may aggravate the impact of particulate matter on human health.The interaction between EPFRs and typical gaseous pollutants can alter their fate and influence atmospheric chemical reactions.EPFRs are mainly produced by transition metal elements and substituted aromatic hydrocarbons through electron transfer.Additionally,the chemical bond rupture of organic substances through heat treatment or ultraviolet radiation can also produce EPFRs,and heterogeneous reactions are capable producing them as well.The production of EPFRs is not only influenced by transition metal elements and precursors,but also by various environmental factors such as oxygen,temperature,light radiation,and relative humidity.Discussion EPFRs in atmospheric particulates matters are usually rich in fine particulates with obvious seasonal and regional variations.They can easily enter the human respiratory tract and lungs with inhalable particulates,thereby increasing the risk of exposure.Additionally,EPFRs in atmospheric particulates can interact with some typical gaseous pollutants,impacting the life and fate of EPFRs in the atmosphere,and alter atmospheric chemical reactions.Traditionally,EPFRs are generated by transition metal elements and substituted aromatic hydrocarbons undergoing electron transfer in the post-flame and cool-zone regions of combustion systems and other thermal processes to remove HCl,H_(2)O or CO groups,ultimately produce semiquinones,phenoxyls,and cyclopentadienyls.Recent studies have indicated that EPFRs can also be generated under the conditions of without transition metal elemental.Organics can also produce EPFRs through chemical bond rupture during heat treatment or light radiation conditions,as well as through some heterogeneous reactions and photochemical secondary generation of EPFRs.The presence or absence of oxygen has different effects on the type and yield of EPFRs.The concentration,type,and crystal type of transition metal elements will affect the type,content,and atmospheric lifetime of EPFRs.It is generally believed that the impact of transition metal element types on EPFRs is related to the oxidation-reduction potential.The combustion temperature or heat treatment process significantly affects the type and amount of EPFRs.Factors such as precursor loading content,pH conditions,light radiation and relative humidity also influence the generation of EPFRs.EPFRs can interact with pollutants in the environment during their migration and transformation process in environmental medium.This process accelerates the degradation of pollutants and plays a crucial role in the migration and transformation of organic pollutants in environmental media.The reaction process of EPFRs may lead to the production of reactive oxygen species(ROS)such as∙OH,which can induce oxidative stress,inflammation and immune response to biological lung cells and tissues,leading to chronic respiratory and cardiopulmonary dysfunction,cardiovascular damage and neurotoxic effects,ultimately impacting the health of organisms.Conclusions The interaction mechanism between EPFRs in particulate matter and gaseous pollutants remains unclear.Furthermore,research on the generation mechanism of EPFRs without the participation of transition metals is not comprehensive,and the detection of EPFRs is limited to simple qualitative categories and lack accurate qualitative analysis.Recommendations and perspectives Further research should be conducted on the generation mechanism,measurement techniques,migration pathways,and transformation process of EPFRs.It is also important to explore the interaction between EPFRs in atmospheric particulate matter and typical gaseous pollutants.

Influence of Reservoir on Groundwater Environment in the Ecologically Fragile Area, Northwest of China

As the research proposed reservoirs after impact on the surrounding ecological fragile areas of groundwater level and scope, through the proposed reservoir area and its surrounding data collecting, hydrogeology survey and related test, for Modflow system simulation platform, through to the boundary conditions, initial conditions and source sink term and related hydrogeological parameters, the model identification and verification, The model of hydrogeological parameters in the study area is constructed. The simulation results show that the groundwater depth near the reservoir area will be higher than the critical value (1.8 m) of secondary salinization of soil. At the same time, according to the investigation and experiment, if the reservoir does not do seepage treatment, the water infiltration in the reservoir will aggravate the environmental hydrogeological problems in the ecologically fragile area.

Behavior, distribution and environmental influence of arsenic in a typical lead smelter

A field study was conducted to determine the behavior and distribution of arsenic during the pyrometallurgy process in a typical SKS(Shuikoushan) lead smelter in Hunan province, China. Environmental influences of arsenic in selected samples were evaluated. Arsenic contents in all input and output samples vary from 0.11% in raw lead to 6.66% in collected dust-2. More arsenic is volatilized in blast furnace and fuming furnace(73.02% of arsenic input) than bottom blowing furnace(10.29% of arsenic input).There are 78.97%, 13.69%, 7.31% of total arsenic distributed in intermediate materials, stockpiled materials and unorganized emissions, respectively. Matte slag-2, collected dust-1 and secondary zinc oxide are hazardous based on the arsenic concentrations of toxicity characteristic leaching procedure. According to risk assessment code(RAC) guideline, arsenic in collected dust-1 poses a very serious risk to the surrounding environment, arsenic in speiss, matte slag-2, water-quenched slag and secondary zinc oxide show low risk, while arsenic in matte slag-1, collected dust-2 and post dust has no risk to the environment.

The influence of main ecological and environmental factors on the energy budget of Schlegel＇ s black rockfish Sebastes schlegeli

In the Maidao Ecological Laboratory of the Huanghai Sea Fisheries Research Institute in 1998 ~ 2000, the continuous flow-through method was adopted to determine the energy budget components and models of Schlegel＇ s black rockfish under different ecological and environmental factors, such as temperature, food species, body mass and feeding level, etc. The body mass of test fish ranged from 21.2 to 224.5 g. The specific growth rate tended to invert ＂U＂ change with temperature increase. The ecological conversion efficiency showed the same trend as temperature and feeding level rise. Only the specific growth rate tended to decelerate the increment with the rise of feeding level. From the above quantitative relationships, the maximum and optimal growth temper- atures could be obtained as 17.5 and 16.2 ℃, and the maintenance feeding rate and optimum feeding rate as 0.8% and 4. 1% of the body mass. The specific growth rate and ecological conversion coefficient showed a decelerating decrease trend with body mass increment. The small-sized fish food was more advantageous to the feeding level increase in comparison with the small-sized shrimp food, which led to the increase of growth, metabolism and excretion, but had no significant influence on the ecological conversion coefficient. All of temperature, feeding level, body mass and food species can obviously change the energy budget models. The assigning rate of growth energy tended to change along the invert ＂U＂ curve with the increase of temperature and feeding level, and decrease with the body mass increase, but the assigning rates of metabolism energy and excretion energy were quite reverse. These relationships could be quantitatively described as quadratic or power function curve. If the above relationships proved true to other marine fish, the establishment of energy budget model of the same fish under different conditions can be largely simplified.

Study on the Key Influence Factors of Environmental Mass Incidents by Delphi-PCA-Frequency Analysis Composite Method

In order to prevent and control environmental mass incidents,by comprehensively using literature research,case analysis and logical reasoning method,27 factors influencing environmental mass incidents were selected. Among them,15 key influencing factors were screened by Delphi-PCA-frequency analysis composite method. The key influencing factors were analyzed,and corresponding countermeasures were put forward.

Influence and impact of CAD on environmental art design paradigm under digital background

This paper briefly analyzes the common problems of the environment art design specialty in the course of setting up the courseof the specialty of environmental art and design in CAD. According to the common problems in the teaching process, we put forward the ideaof teaching design based on the application practice. CAD course is an important course of environmental art design major, should meet theprofessional characteristics of the organization of teaching content in the course teaching, knowledge using a variety of teaching methods andteaching, pay attention to the knowledge consistency.

Analysis on the Influencing Factors of Residents' WTP for Environmental Protection in Tourist Destination——A Case Study of Yellow River Stone Forest in Jingtai of Gusu Province

On the basis of questionnaire survey,by adopting Contingent Valuation Method,residents' WTP for the protection of Yellow River Hoodoo National Geopark in Longwan Village,Jingtai County of Gansu Province was investigated.The result showed that tourism development had greatly influenced local society,economy and culture.Residents in this area had a strong awareness of all the factors above mentioned and showed a positive attitude.Local residents would definitely like to provide a certain degree of labor or money to promote the development of tourism,which was different from the residents' attitude of developed countries.To some extent,it reflected the characteristics of tourism development in developing countries.However,the result of this paper that demographic among residents had little effect on WTP also differed from previous researches.The improvement of living standard and residents' consciousness of environmental protection were the main reasons affecting residents' WTP.Besides,the amount of payment was also in remarkable correlation with the improvement of living standard and the destruction degree of local ecological environment.

Prototype observation and influencing factors of environmental vibrationinduced by flood discharge

Due to a wide range of field vibration problems caused by flood discharge at the Xiangjiaba Hydropower Station, vibration characteristics and influencing factors were investigated based on prototype observation. The results indicate that field vibrations caused by flood discharge have distinctive characteristics of constancy, low frequency, small amplitude, and randomness with impact, which significantly differ from the common high-frequency vibration characteristics. Field vibrations have a main frequency of about 0.5-3.0 Hz and the characteristics of long propagation distance and large-scale impact. The vibration of a stilling basin slab runs mainly in the vertical direction. The vibration response of the guide wall perpendicular to the flow is significantly stronger than it is in other directions and decreases linearly downstream along the guide wall. The vibration response of the underground turbine floor is mainly caused by the load of unit operation. Urban environmental vibration has particular distribution characteristics and change patterns, and is greatly affected by discharge, scheduling modes, and geological conditions. Along with the increase of the height of residential buildings, vibration responses show a significant amplification effect. The horizontal and vertical vibrations of the 7th floor are, respectively, about 6 times and 1.5 times stronger than the corresponding vibrations of the 1st floor. The vibration of a large-scale chemical plant presents the combined action of flood discharge and working machines. Meanwhile, it is very difficult to reduce the low-frequency environmental vibrations. Optimization of the discharge scheduling mode is one of the effective measures of reducing the flow impact loads at present. Choosing reasonable dam sites is crucial.

Factor Analysis on the Factors that Influencing Rural Environmental Pollution in the Hilly Area of Sichuan Province,China

By using factor analysis method and establishing analysis indicator system from four aspects including crop production,poultry farming,rural life and township enterprises,the difference,features,and types of factors influencing the rural environmental pollution in the hilly area in Sichuan Province,China.Results prove that the major factor influencing rural environmental pollution in the study area is livestock and poultry breeding,flowed by crop planting,rural life,and township enterprises.Hence future pollution prevention and control should set about from livestock and poultry breeding.Meanwhile,attention should be paid to the prevention and control of rural environmental pollution caused by rural life and township enterprise production.

Spatio-temporal Difference and Influencing Factors of Environmental Adaptability Measurement of Human-sea Economic System in Liaoning Coastal Area

Adaptability theory is an important tool to analyze the degree, mechanism and process of interaction between human and environment, which provides a new perspective for the research of sustainability assessment. Based on the entropy weight-TOPSIS method and the panel Tobit model from the perspective of adaptability, spatio-temporal difference and influencing factors of environmental adaptability assessment of human-sea economic system in Liaoning coastal area was measured by using the city panel data from 2000 to 2014. The results indicate that: 1) The environmental adaptability of human-sea economic system in Liaoning coastal area rose slowly from 2000 to 2014, the developing trend of each city was linearly related, and Dalian was in a leading position. 2) The different adaptability elements and adaptability subsystem show polarization phenomenon and completely different regional evolution characteristics. The adaptability of human-sea environment system and human-sea economic system rose slowly and had the characteristics of linear relationship, and the adaptability of human-sea environment system is the main reason for the difference of environmental adaptability of human-sea economic system. 3) Science and technology, environmental management, marine economic development level, port construction are the driving factors of the healthy development of environmental adaptability of urban human-sea economic system.

New Discoveries of the Influence of Sedimentary Environment on Rearranged Hopanes in Source Rocks

Objective The distribution of rearranged hopanes in hydrocarbon source rocks is influenced by thermal maturity and original source input, and is also controlled by depositional conditions. Through comparison of lacustrine and coal-bearing source rocks, this work attempted to analyze the composition and origin of rearranged hopanes in hydrocarbon source rocks. Taken the source rocks from the Songliao Basin, Ordos Basin and Kuqa Depression as examples, we aimed to investigate the effect of the redox conditions, water salinity and oxygen content of the source-rock depositional environment on the formation of rearranged hopanes to provide theoretical basis for the genesis of rearranged hopanes.

“Do Big Hands Guide Small Hands?”or“do Small Hands Guide Big Hands”:The intergenerational interactions in environmental behaviors and family influencing factors

Families'large pollution and energy consumption cannot be underestimated.In order to realize and internalize environmental awareness as a social consensus,it is imperative for every member of a household to be involved in transforming everyday behavior.Intergenerational interactions are of paramount importance.Accordingly,the focus of this study was on parent-adolescent interactions,their reciprocal impact on environmental behaviors,and the factors that have an influence on these processes.Questionnaires were employed to collect information of 684 families in 10 districts of Jinan,the capital of Shandong Province.Subsequently,interviews were conducted with 15 of these families to comprehend the tangible reasons underlying intergenerational interactions in environmental behaviors.First,a paired sample T-test was employed to compare the frequency of these interactions.The data showed that while the T values were positive in all eight compared groups,there were significant differences in seven of them.These results suggest that the impact of intergenerational interactions on environmental behaviors is not symmetrical:parents'instructions are far more frequent than adolescents'back-feeding of ecological notions.The interviews revealed that this phenomenon was generated primarily by unequal experiences between parents and adolescents because the latter do not participate in housework and family projects.Furthermore,the traditional concept of intergenerational order appears to be permanent.Second,two linear regression models,a Parent-to-Adolescent model and an Adolescent-to-Parent model that encompassed several factors including family structure,intergenerational relationships,living environment,and families'social class were developed.Among these factors,the intergenerational relationship variable played a particularly significant role:the more equal and open-minded dialogs are incorporated into parent-adolescent communication,the more favorable interactions may occur for development of their environmental behaviors.Thus,when an environmental education system with families is constructed,it is imperative to promote a parent's ecological awareness with the help of grass-roots organizations by means of reasonable rewards and punishments to redress their former behaviors so as to let Big Hands Guide Small Hands.It is also crucial to enhance a more equal intergenerational relationship through parents'schooling or other relevant services so as to create a favorable atmosphere for Small Hands Guide Big Hands.

Total Factor Productivity and Influence Factors of Economic Environment in the Yellow River Delta

The paper analyzed total factor productivity of Binzhou City, and key factors that influence its economic growth and effluent discharge. The results showed that(i) production efficiency of the city during 2005–2013 kept stable, mean of Malmquist-Luenberger index was 1.044,9 without considering effluent discharge, and the average annual increase rate was 4.49%, and that was 1.020,4 considering effluent discharge, the average annual increase rate was 2.04%, and the increase rate reduced by 2.45%.(ii) GDP growth showed significant negative correlation and positive correlation with capital input and energy input, but insignificant negative correlation and positive correlation with labor force input and technological progress.(iii) Effluent discharge showed insignificant negative correlation and positive correlation with capital input and energy input, but significant negative correlation and positive correlation with labor force input and technological progress.

Assessment on the Two New Factors That Influence China's International Environment

The development and changes in international situation after September 11 have exerted complicated influence on China’s external security environment. Therefore, how to judge current international security environment that China faces has become a very hot subject for discussion.

Purification Effects of Aquatic Vegetations on Lake Wetland Water Environment and Analysis of the Influencing Factors in Hongze Lake

[Objective] To study the purification effect of plant community on wetland water environment in Hongze Lake, and to provide references to the ecological restoration of this area. [Methed] The typical lakeside zone of Hongze Lake Wetland National Nature Reserve was taken as the study area. Through the field survey based on environmental characteristics of aquatic areas and non-aquatic areas, combined with laboratory test, the content changes of nutrients （N and P）, COD （chemical oxygen demand） and SD （transparency） levels in the water body of lake wetland were measured; the purification effect of the lake wetland ecosystem in the growth process of aquatic vegetation was quantitatively analyzed, and possible influ- encing factors were discussed. [Result] Aquatic vegetation could remove the TN, TP, COD, Chla in wetland water environment and had obvious effects on the changes of SD content. Competition between aquatic plants can inhibit the growth of algae and relieve the eutrophication of water body. [Conclusion] This study provided theoretical basis for ecological restoration and enhancement of self-purification capability in the lakeside zone of Hongze Lake.

Assessing coordination degree of port development and urban environment and its influencing factors

Due to limited resources regarding port development,the contradiction between ports and cities has gradually become prominent.Taking China's coastal ports as an example,this paper measures the degree of coordination between port development and urban environment,and analyzes its influencing factors.We find that this coordination degree is relatively low and needs to be further improved.The regression results of the ordinary panel model show that the scale of port logistics,port infrastructure construction,and the quality of economic development play a significant role in promoting the coordinated development of the port and the urban environment.The regression results of the threshold panel model show that the expansion of the port logistics scale is only conducive to promoting the coordinated development of the port and the urban environment when the levels of port infrastructure are relatively high.In addition,the promotion effect of the port logistics scale on the coordinated development of the port and the urban environment differs depending on the quality of economic development.Therefore,the relevant departments should pay more attention to the construction of port infrastructure and the quality of economic development,making appropriate adjustments to both in order to better promote the coordinated development of the port and city environment.

Coupling and Coordination Characteristics and Influencing Factors of the Livable Environment System for the Elderly in China

The construction of a livable environment for the elderly is an important measure to address the challenges of aging and improve their livelihood and well-being.Based on China’s national conditions and combined with the actual development needs of the cities,it is of great significance to explore the coupling and coordination characteristics and influencing factors within the livable environment system for the elderly for the coordination and stable development.This article was based on the three subsystems of’living service environment,socioeconomic environment and ecological livable environment’,following the research framework of’process-pattern-trend-impact’,constructs an evaluation index system for the livable environment for the elderly.Entropy weight-TOPSIS evaluation model,coupling coordination degree model,center of gravity and standard deviation ellipse model and the geographic detector model were used starting from the evolution of coupling coordination types to study the spatial and temporal pattern and dynamic trend characteristics and influencing factors of internal coupling coordination types in the livable environment system for the elderly from2010 to 2019.The results showed that:1)The coordinated development of life service environment system and ecological livable environment system(LE)and socioeconomic environment system and ecological livable environment system(SE)in the livable environment for the elderly decreased from the intermediate coordination level coordination areas to the low-level quality improvement and optimization areas:coordinated transition type.The overall development level of life service environment system and socioeconomic environment system(LS)was low,and it was always at a low level.2)The coupling degree of livable environment system for the elderly was high,the coupling coordination type shown a gradually decreasing layer structure with Zhejiang,Beijing and Guangdong high-level leading demonstration areas as the axis belt.3)The coupling coordination center of the elderly livable environment system was located in Henan,and the standard deviation ellipse was distributed in the northeast-southwest direction.The development center and the ellipse of the high-level leading demonstration areas and the intermediate coordination level areas were concentrated in the central and eastern regions,while the low-level coordination areas for improving quality and efficiency are mainly located in the western region.4)Urban development,green facilities,infrastructure,government macroscopic regulation and control,economic stimulus,and housing construction were all important factors affecting the coordinated development of the livable environment system for the elderly,exerting a varying degree of effect on the level of coordinated development of various types of systems.

An Analysis of Influencers of Energy Security for SMEs in the Greater Accra Region of Ghana

Investments in the exploitation of the continent’s raw material reserves have resulted in little (positive) impact on the energy security situation within Africa. This paper attempts to explore factors influencing the level of energy security of Small Medium Enterprises (SMEs) in the Greater Accra Region of Ghana, and from the dimension of availability, affordability, economic efficiency and environmental stewardship or sustainability of energy. The cross-sectional survey design was employed as the design for the collection and analysis of data. The study applied a quantitative research method in examining the indicators of energy security for SMEs in Accra Metropolis in the Greater Accra Region of Ghana. The population covered about 500 SMEs who have about 100 employees and total revenue of $1 million or the equivalence in Ghana Cedis. A sample of 246 was selected through a cluster and simple random sampling. The analysis adopted statistical techniques to conduct descriptive, exploratory and inferential analysis of the data collected. Factors that influence the level of energy security of SMEs are broadly categorized into the environment and economic change, political factors, physical disruptions and market conditions. Ge- nerally, the level of energy security under the availability dimension is medium among the SMEs. Issues of affordability, economic efficiency and environmental stewardship provide high medium interventions on energy security for SMEs. It is recommended that managers of Ghana’s energy sector should ensure prudent management of the country’s energy resources since the disruption of supply lines or sources form the key conditions that influence the energy security level of SMEs. SMEs should adopt energy efficiency measures to ensure that energy is conserved for future use.

Non-Specific Factors Involved in the Treatment： Its Influence on Treatment Adherence

Introduction： The effectiveness of treatment depends on the efficacy of the therapy and the level of compliance of the patient. NF （non-specific factors） involved in treatment are all those effects that do not depend on the pharmacological properties of the drug. Materials and Methods： The job lasted a year. The sample consisted of patients with mental health disorders and was divided into two groups. Treatment compliance was measured with the Morisky-Green Test. Results were compared using the chi square test and relative risk. Results and Discussion： Group A had 23 patients ending 91.3% of them and group B of 22 patients, ending the 77.27%. At the beginning of the study, we found in the group A 0.86 NF/patients while in the group B 0.82 NF/patient. At the end of the study there was a 54.65% decrease in group A while in group B the proportion remained. At the beginning of the study both groups had approximately 40% of compliant patients. Data that remained in the control group rose to 80.95% in group A at the end of the study. Conclusions： The work demonstrates the negative influence of these factors on adherence to treatment.