Recently,lipid nanoparticles(LNPs)have been extensively investigated as non-viral carriers of nucleic acid vaccines due to their high transport efficiency,safety,and straightforward production and scalability.However,...Recently,lipid nanoparticles(LNPs)have been extensively investigated as non-viral carriers of nucleic acid vaccines due to their high transport efficiency,safety,and straightforward production and scalability.However,the molecular mechanism underlying the interactions between nucleic acids and phospholipid bilayers within LNPs remains elusive.In this study,we employed the all-atom molecular dynamics simulation to investigate the interactions between single-stranded nucleic acids and a phospholipid bilayer.Our findings revealed that hydrophilic bases,specifically G in single-stranded RNA(ssRNA)and single-stranded DNA(ssDNA),displayed a higher propensity to form hydrogen bonds with phospholipid head groups.Notably,ssRNA exhibited stronger binding energy than ssDNA.Furthermore,divalent ions,particularly Ca2+,facilitated the binding of ssRNA to phospholipids due to their higher binding energy and lower dissociation rate from phospholipids.Overall,our study provides valuable insights into the molecular mechanisms underlying nucleic acidphospholipid interactions,with potential implications for the nucleic acids in biotherapies,particularly in the context of lipid carriers.展开更多
Today’s product creative design has rendered many fe atures and has brought a great change in our everyday life, there are many new c hallenges in its traditional theory and principle. According to the traditional de...Today’s product creative design has rendered many fe atures and has brought a great change in our everyday life, there are many new c hallenges in its traditional theory and principle. According to the traditional design theory, the FBS design model pays more attention to the function and stru cture of the product. But this model still couldn’t strengthen the relation bet ween product appearance design and human-machine design effectively. This paper adopt converse design thinking and presents an improved design thinking methodo logy based on C: FBS for product appearance design and give a general summarizat ion for the features, methods and technology based on human-machine interaction and interface. Meanwhile it also combines with the behavior design of product r elated IT fields and constructs a new outline to improve the design of product a ppearance supported by the technology of computer aided design. So the new metho d about design thinking for computer aided design, the new abstract product design model and the key problem of design thinking based on human-machine inte raction and interface are addressed in this paper. This kind of creative design theory that is driven by human-machine interaction and interface will help the development of CAD software system and the research of product design and manufa cture. Additionally, this paper gives some beneficial characters to address the theory based on human-machine interaction and interface. Meanwhile, combining with the developing of computer technology, the trends of design thinking based on t he technology of human-machine interaction and interface are also analyzed and discussed at the end of this paper.展开更多
Two-dimensional(2D) semiconductors have captured broad interest as light emitters, due to their unique excitonic effects. These layer-blocks can be integrated through van der Waals assembly, i.e., fabricating homo-or ...Two-dimensional(2D) semiconductors have captured broad interest as light emitters, due to their unique excitonic effects. These layer-blocks can be integrated through van der Waals assembly, i.e., fabricating homo-or heterojunctions, which show novel emission properties caused by interface engineering. In this review, we will first give an overview of the basic strategies that have been employed in interface engineering, including changing components, adjusting interlayer gap, and tuning twist angle. By modifying the interfacial factors, novel emission properties of emerging excitons are unveiled and discussed. Generally, well-tailored interfacial energy transfer and charge transfer within a 2D heterostructure cause static modulation of the brightness of intralayer excitons. As a special case, dynamically correlated dual-color emission in weakly-coupled bilayers will be introduced, which originates from intermittent interlayer charge transfer. For homobilayers and type Ⅱ heterobilayers, interlayer excitons with electrons and holes residing in neighboring layers are another important topic in this review. Moreover, the overlap of two crystal lattices forms moiré patterns with a relatively large period, taking effect on intralayer and interlayer excitons. Particularly, theoretical and experimental progresses on spatially modulated moiré excitons with ultra-sharp linewidth and quantum emission properties will be highlighted. Moiré quantum emitter provides uniform and integratable arrays of single photon emitters that are previously inaccessible, which is essential in quantum many-body simulation and quantum information processing. Benefiting from the optically addressable spin and valley indices, 2D heterostructures have become an indispensable platform for investigating exciton physics, designing and integrating novel concept emitters.展开更多
The interaction of particles with a solid-liquid interface during solidification of metal matrix composites has been investigated theoretically in this paper.Owing to the presence of particles in the melt,the shape of...The interaction of particles with a solid-liquid interface during solidification of metal matrix composites has been investigated theoretically in this paper.Owing to the presence of particles in the melt,the shape of the solidification front and solute concentration field in front of solidification interface have been disturbed The thermodynamic method was employed,and a mathematical expression of the shape of the solidification interface and solute concentration field were deduced.Meanwhile,a theory is developed for evaluation of critical velocities of particles pushed by the solidification interface.A numerical simulation is done in which the critical velocity is evaluated as a function of particle size,thermal conductivity,diffusion coefficient,temperature gradient at the solidification front,the solid-liquid interfacial energy and the melt viscosity.The critical velocity is shown to be closely linked to the shape of the solidification interface and solute concentration field, and hence all the parameters also affect the shape of the solidification interface and solute concentration field of the front.展开更多
Interface dislocations may dramatically change the electric properties, such as polarization, of the piezoelectric crystals. In this paper, we study the linear interactions of two interface dislocation loops with arbi...Interface dislocations may dramatically change the electric properties, such as polarization, of the piezoelectric crystals. In this paper, we study the linear interactions of two interface dislocation loops with arbitrary shape in generally anisotropic piezoelectric bi-crystals. A simple formula for calculating the interaction energy of the interface dislocation loops is derived and given by a double line integral along two closed dislocation curves. Particularly, interactions between two straight segments of the interface dislocations are solved analytically, which can be applied to approximate any curved loop so that an analytical solution can be also achieved. Numerical results show the influence of the bi-crystal interface as well as the material orientation on the interaction of interface dislocation loops.展开更多
The membrane method based on adaptive wettability shows great advantages in oil-water separation.At present,researches focus on the excellent application performance of the membrane material,while the quantitative ana...The membrane method based on adaptive wettability shows great advantages in oil-water separation.At present,researches focus on the excellent application performance of the membrane material,while the quantitative analysis of interactions in oil-water separation is rarely recognized.Herein,we constructed an adaptable wettability membrane with multiple polymer networks by polydopamine(PDA)and mussel-inspired amphiphilic polymer.Based on the Owens three-probe liquid method,the surface energy of the modified membrane was verified to meet the adaptive wettability conditions,with surface energies(γ-8)of 147.6 mJ m^(−2)(superhydrophilic/underwater superoleophobic)and 49.87 mJ m^(−2)(superhydrophobic/superoleophobic),respectively.The adhesion or repulsion of the membrane to the oil phase under different conditions during the separation process was quantified by the chemical probe AFM technique.In addition,the oil-water selective separation mechanism was further analyzed in a simplified membrane microchannel model.The results show that the different wetting produces capillary additional pressure in opposite directions,resulting in different energies to be overcome when the oil or water passes through the microchannels,thus achieving selective separation.展开更多
In order to find a parameter as the evaluation index that can capture the effect of the interaction between asphalt and aggregate, the rheological properties of asphalt mastics using two kinds of asphalts and four kin...In order to find a parameter as the evaluation index that can capture the effect of the interaction between asphalt and aggregate, the rheological properties of asphalt mastics using two kinds of asphalts and four kinds of aggregates under different filler-asphalt ratios were measured by a dynamic shear rheometer (DSR). Moreover, four rheological parameters of K.Ziegel-B, Luis Ibrarra-A, complex shear modulus ΔG*and complex viscosity Δη* for evaluating the interaction ability were studied. Results indicate that all the four parameters can characterize the interaction ability of asphalt and aggregate correctly and feasibly. Through the comparison of sensitivities and physical meanings of the four parameters, K.Ziegel-B with high sensitivity and exact physical meaning is finally selected as the evaluation index for interaction ability of asphalt and aggregate.展开更多
Heterojunction photocatalysts have shown considerable activities for organic pollutants degradation.However,the faint connection interface and inferior charge shift efficiency critically block the property of heteroju...Heterojunction photocatalysts have shown considerable activities for organic pollutants degradation.However,the faint connection interface and inferior charge shift efficiency critically block the property of heterojunction photocatalysis.Herein,Bi_(2)O_(2)S/NiFe_(2)O_(4) nanosheets heterojunction with ultrastrong inter-face interaction and high internal electric field are designed by an in-situ growth method.Tentative and theoretical consequences prove that the interfacial interaction and internal electric field not only act as the electron flow bridge but also decrease the electrons shift energy obstacle,thus speeding up electrons transfer and achieving effective spatial electron-hole separation.Therefore,a large amount of·O_(2)^(-)and holes as active species were generated.Remarkably,Bi_(2)O_(2) S/NiFe_(2)O_(4) establishes a considerably boosted photocatalytic performance for tetracycline degradation(0.032 min^(-1)),which is about 14.2-fold and 7.8-fold of the pristine BOS and NFO,respectively.This work provides a promising motivation for modulating charge transfer by interface control and internal electric field to boost photocatalytic performance.展开更多
A novel process for synthesizing nano-ceramics powders, named mechanical & therm al activation processing, is discussed in the present paper. It is a processing based on thermal activation in liquid phase (molten ...A novel process for synthesizing nano-ceramics powders, named mechanical & therm al activation processing, is discussed in the present paper. It is a processing based on thermal activation in liquid phase (molten salt) after mechanical activ ation. The nanometer-sized TiC particles (15-20nm) have been synthesized by the method, and analyzed by X-ray diffraction (XRD), transmission electron microscop e (TEM), scanning electron microscopy (SEM) and energy dispersion X-ray (EDX) sp ectroscopy. An interface interaction between liquid (molten salt) and solid (fin al product particles) phases plays a dominating role for the control of product particles size. The mechanism for the formation of nanometer-sized TiC particles has been discussed.展开更多
The corrosion of steels in liquid metal lead (Pb) and bismuth (Bi) is a critical challenge in the development of accel-erator driven systems (ADS). Using a first-principles method with a slab model, we theoretic...The corrosion of steels in liquid metal lead (Pb) and bismuth (Bi) is a critical challenge in the development of accel-erator driven systems (ADS). Using a first-principles method with a slab model, we theoretically investigate the interaction between the Pb (Bi) atom and the iron (Fe) (100) surface to assess the fundamental corrosion properties. Our investigation demonstrates that both Pb and Bi atoms favorably adsorb on the (100) surface. Such an adsorption decreases the energy required for the dissociation of an Fe atom from the surface, enhancing the dissolution tendency significantly. The seg- regation of six common alloying elements (Cr, A1, Mn, Ni, Nb, and Si) to the surface and their impacts on the corrosion properties are also considered. The present results reveal that Si seems to have a relatively good performance to stabilize the surface and alleviate the dissolving trend caused by Pb and Bi.展开更多
In order to prevent smearing the discontinuity, a modified term is added to the third order Upwind Compact Difference scheme to lower the dissipation error. Moreover, the dispersion error is controled to hold back the...In order to prevent smearing the discontinuity, a modified term is added to the third order Upwind Compact Difference scheme to lower the dissipation error. Moreover, the dispersion error is controled to hold back the non physical oscillation by means of the group velocity control. The scheme is used to simulate the interactions of shock density stratified interface and the disturbed interface developing to vortex rollers. Numerical results are satisfactory.展开更多
Purpose: Fully integrating its e-reserves service into the university's course management system has become the primary design goal of the innovative e-reserves service system at Shanghai Jiao Tong University(SJTU...Purpose: Fully integrating its e-reserves service into the university's course management system has become the primary design goal of the innovative e-reserves service system at Shanghai Jiao Tong University(SJTU) Library.Design/methodology/approach: Through blending library and information service into the teaching and learning process, SJTU Library has effectively combined its reserves service into the user learning environment. The main metadata model and the design of various interfaces of the e-reserves service system are introduced.Findings: E-reserves has been integrated into the course management system. Users can directly access relevant resources when they browse the customized course page. It is more convenient for teachers to add reserves items, and the added items can be made available simultaneously on SJTU Library's resource discovery platform automatically.Research limitations: At present, e-reserves items are mainly books, and more other types of reserves materials are needed to be provided. Some relevant copyright issues should be addressed.Practical implications: Using a series of interface interactions, the e-reserves service has been integrated into the university's course management system. It is convenient for students to access customized e-reserves service during their learning process.Originality/value: We achieved interconnection between the e-reserves and the university's course management system. Information on the e-reserves Web page is automatically updated.SJTU Library provides customized e-reserves service in the course management system.展开更多
Background Free-viewpoint video(FVV)is processed video content in which viewers can freely select the viewing position and angle.FVV delivers an improved visual experience and can also help synthesize special effects ...Background Free-viewpoint video(FVV)is processed video content in which viewers can freely select the viewing position and angle.FVV delivers an improved visual experience and can also help synthesize special effects and virtual reality content.In this paper,a complete FVV system is proposed to interactively control the viewpoints of video relay programs through multimedia terminals such as computers and tablets.Methods The hardware of the FVV generation system is a set of synchronously controlled cameras,and the software generates videos in novel viewpoints from the captured video using view interpolation.The interactive interface is designed to visualize the generated video in novel viewpoints and enable the viewpoint to be changed interactively.Results Experiments show that our system can synthesize plausible videos in intermediate viewpoints with a view range of up to 180°.展开更多
Recent advances in the study of exchange couplings in magnetic films are introduced.To provide a comprehensive understanding of exchange coupling,we have designed different bilayers,trilayers and multilayers,such as a...Recent advances in the study of exchange couplings in magnetic films are introduced.To provide a comprehensive understanding of exchange coupling,we have designed different bilayers,trilayers and multilayers,such as anisotropic hard/soft-magnetic multilayer films,ferromagnetic/antiferromagnetic/ferromagnetic trilayers,[Pt/Co]/NiFe/NiO heterostructures,Co/NiO and Co/NiO/Fe trilayers on an anodic aluminum oxide(AAO) template.The exchange-coupling interaction between soft-and hard-magnetic phases,interlayer and interfacial exchange couplings and magnetic and magnetotransport properties in these magnetic films have been investigated in detail by adjusting the magnetic anisotropy of ferromagnetic layers and by changing the thickness of the spacer layer,ferromagnetic layer,and antiferromagnetic layer.Some particular physical phenomena have been observed and explained.展开更多
The paper analyzes the principles and applications of CGI for collaborative design. The utility model possessing broad reference values is set up and its implementation techniques are presented in detail.
It is difficult to achieve selective separation and enrichment of different rare earths from high abundance yttrium ores efficiently only dependent on their discrepancy in thermodynamic properties.The present work sug...It is difficult to achieve selective separation and enrichment of different rare earths from high abundance yttrium ores efficiently only dependent on their discrepancy in thermodynamic properties.The present work suggests a new strategy based on non-equilibrium kinetic separation of Er and Tm on the surface of freely rising oil droplets to control the separation order of Y.It is revealed that the mutual separation of Er/Tm is significantly promoted with the separation coefficient of 2.89 during the non-equilibrium extraction with the addition of diethylenetriaminepentaacetic acid(DTPA).The extraction sequence of Tm,Er and Y can be controlled as Tm>Y>Er,thus Y can be selectively enriched during the process of separation of Er and Tm,Such a sequence is subject to the controllable dissociation rates of RE(Ⅲ)-DTPA complexes and extraction abilities of P507 with the three RE(Ⅲ)ions.The dissociation rate is dependent on the stabilities of RE(Ⅲ)-DTPA complexes and follows the sequence ofY(Ⅲ)—DTPA Er>Y to Tm>Y>Er.展开更多
A valid strategy to tailor the properties of polylactic acid for more extensive applications was introducing filler.In this work,basalt fiber assembled with in-situ SiO_(2) nanoparticles on the surface was successfull...A valid strategy to tailor the properties of polylactic acid for more extensive applications was introducing filler.In this work,basalt fiber assembled with in-situ SiO_(2) nanoparticles on the surface was successfully prepared via hydrothermal method and it was further treated with coupling agent KH-550 to improve interfacial interaction between polylactic acid(PLA)and basalt fibers(BF).It was demonstrated that the introduction of BFS could increase the crystallization of PLA and resulted in forming trans-crystallization based on TG and DSC results.The tensile strength of PLA/BF composites raised from 39 MPa to 62.5 MPa with increasing the fiber loading from 1 wt%to 10 wt%.Furthermore,the interfacial interaction could be effectively improved by assembling SiO_(2)(especially with 250 nm in diameter)on BF surface to build mechanical locking,which could keep the PLA matrix in place during the mechanical deformation with the tensile strength value raised from 62.5 MPa to 74.0 MPa.It is noticeable that the impact and flexural properties were effectively increased with the incorporation of in-situ SiO_(2) nanoparticles.The further KH-550 treatment made a positive impact as well.For instance,the impact strength and flexural strength of the sample with SiO_(2) and KH-550 modification were improved to 22.49 k J/m^(2) and 146.83 MPa and it enhanced about 42.16%and 41.04%than those of neat PLA,respectively.Therefore,an efficient enhancement of mechanical performance was achieved and this concept of assembling in-situ SiO_(2) on silica-based fiber as a modifier was a novel and simple path to design the interfacial construction and properties of the polymer composites.展开更多
DNA-functionalized gold nanoparticles are one of the most versatile bionanomaterials for biomedical and clinical diagnosis. Herein, we discovered that the performance of DNAzyme cleaving the substrate is highly relate...DNA-functionalized gold nanoparticles are one of the most versatile bionanomaterials for biomedical and clinical diagnosis. Herein, we discovered that the performance of DNAzyme cleaving the substrate is highly related to its length. This intriguing phenomenon only appears at the interfaces of DNAfunctionalized gold nanoparticles. We systematically investigated the causes of this phenomenon. We conjectured that the DNAzyme with extended nucleotides that do not match its substrate strand is vulnerable to non-specific adsorption, electrostatic repulsion, and steric hindrance. Based on our improved understanding of this phenomenon, we have successfully developed a highly sensitive and specific amplifiable biosensor to detect human apurinic/apyrimidinic endonuclease 1.展开更多
The heterostructure of transition metal nanocrystal on two-dimensional(2D)materials exhibits unique physical and chemical properties through various interfacial interactions.It has been established that the atomic str...The heterostructure of transition metal nanocrystal on two-dimensional(2D)materials exhibits unique physical and chemical properties through various interfacial interactions.It has been established that the atomic structure and strain in the vicinity of the interface determine the band structure and phonon modes of the nanocrystal,regulating the optical and electrical properties of such heterostructures.Hence,metal–support interfacial engineering is a demonstrated approach to acquiring desired properties of the nanocrystals.However,a fundamental understanding of the interfacial structures remains elusive and precise control of the interactions has yet achieved.Herein,we explore the regulation of interface on MoS_(2)supported Pt nanocrystals which were prepared by reducing ultrasonic dispersed potassium chloroplatinate.The Pt-MoS_(2)heterostructure interface was systematically studied by aberration corrected transmission electron microscopy.Three types of Pt-MoS_(2)interfaces with distinct atomic configurations were identified.The strain within the Pt nanocrystals is sensitive to the atomic configuration of the supporting MoS_(2),which regulates the size of the Pt nanocrystals.These results provide insights on tuning of nanocrystal strain,paving the way for precise control of 2D semiconductor heterostructures.展开更多
Forests are highly productive ecosystems that contribute to biogeochemical cycles of carbon and nitrogen,through which it regulates climate and global change.Forests are also spatially highly heterogeneous ecosystems ...Forests are highly productive ecosystems that contribute to biogeochemical cycles of carbon and nitrogen,through which it regulates climate and global change.Forests are also spatially highly heterogeneous ecosystems that comprise a multitude of microbial-mediated reactive interfaces.These are mainly the root-soil interface,litter-soil interface,root-root interface,and plant-atmosphere interface.Each of these interfaces has its own unique characteristics,e.g.,specific drivers that affect the microbial abundance,nutrient availability,microbial community,and the dominance of certain microbial taxa.Here,we review the microbial-mediated reactive interfaces in forests,focusing on interrelation and dynamics of fungi and bacteria on a broad temporal scale with ecosystem processes ranging from short-term events(e.g.,seasonal changes)to long-term stand development suffering a global climate change(e.g.,global warming or nitrogen deposition).We argue that in-depth knowledge of forest microbiology can only be obtained by exploring the complex forest microbiome and its ecosystem functions.Underpinning the basis for individual forest variation would ultimately facilitate the formulation of microbiome-based strategies in the future.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.12222506,12347102,and 12174184).
文摘Recently,lipid nanoparticles(LNPs)have been extensively investigated as non-viral carriers of nucleic acid vaccines due to their high transport efficiency,safety,and straightforward production and scalability.However,the molecular mechanism underlying the interactions between nucleic acids and phospholipid bilayers within LNPs remains elusive.In this study,we employed the all-atom molecular dynamics simulation to investigate the interactions between single-stranded nucleic acids and a phospholipid bilayer.Our findings revealed that hydrophilic bases,specifically G in single-stranded RNA(ssRNA)and single-stranded DNA(ssDNA),displayed a higher propensity to form hydrogen bonds with phospholipid head groups.Notably,ssRNA exhibited stronger binding energy than ssDNA.Furthermore,divalent ions,particularly Ca2+,facilitated the binding of ssRNA to phospholipids due to their higher binding energy and lower dissociation rate from phospholipids.Overall,our study provides valuable insights into the molecular mechanisms underlying nucleic acidphospholipid interactions,with potential implications for the nucleic acids in biotherapies,particularly in the context of lipid carriers.
文摘Today’s product creative design has rendered many fe atures and has brought a great change in our everyday life, there are many new c hallenges in its traditional theory and principle. According to the traditional design theory, the FBS design model pays more attention to the function and stru cture of the product. But this model still couldn’t strengthen the relation bet ween product appearance design and human-machine design effectively. This paper adopt converse design thinking and presents an improved design thinking methodo logy based on C: FBS for product appearance design and give a general summarizat ion for the features, methods and technology based on human-machine interaction and interface. Meanwhile it also combines with the behavior design of product r elated IT fields and constructs a new outline to improve the design of product a ppearance supported by the technology of computer aided design. So the new metho d about design thinking for computer aided design, the new abstract product design model and the key problem of design thinking based on human-machine inte raction and interface are addressed in this paper. This kind of creative design theory that is driven by human-machine interaction and interface will help the development of CAD software system and the research of product design and manufa cture. Additionally, this paper gives some beneficial characters to address the theory based on human-machine interaction and interface. Meanwhile, combining with the developing of computer technology, the trends of design thinking based on t he technology of human-machine interaction and interface are also analyzed and discussed at the end of this paper.
基金supported by the Natural Science Foundation of China(22203042,21873048 and 22173044)。
文摘Two-dimensional(2D) semiconductors have captured broad interest as light emitters, due to their unique excitonic effects. These layer-blocks can be integrated through van der Waals assembly, i.e., fabricating homo-or heterojunctions, which show novel emission properties caused by interface engineering. In this review, we will first give an overview of the basic strategies that have been employed in interface engineering, including changing components, adjusting interlayer gap, and tuning twist angle. By modifying the interfacial factors, novel emission properties of emerging excitons are unveiled and discussed. Generally, well-tailored interfacial energy transfer and charge transfer within a 2D heterostructure cause static modulation of the brightness of intralayer excitons. As a special case, dynamically correlated dual-color emission in weakly-coupled bilayers will be introduced, which originates from intermittent interlayer charge transfer. For homobilayers and type Ⅱ heterobilayers, interlayer excitons with electrons and holes residing in neighboring layers are another important topic in this review. Moreover, the overlap of two crystal lattices forms moiré patterns with a relatively large period, taking effect on intralayer and interlayer excitons. Particularly, theoretical and experimental progresses on spatially modulated moiré excitons with ultra-sharp linewidth and quantum emission properties will be highlighted. Moiré quantum emitter provides uniform and integratable arrays of single photon emitters that are previously inaccessible, which is essential in quantum many-body simulation and quantum information processing. Benefiting from the optically addressable spin and valley indices, 2D heterostructures have become an indispensable platform for investigating exciton physics, designing and integrating novel concept emitters.
文摘The interaction of particles with a solid-liquid interface during solidification of metal matrix composites has been investigated theoretically in this paper.Owing to the presence of particles in the melt,the shape of the solidification front and solute concentration field in front of solidification interface have been disturbed The thermodynamic method was employed,and a mathematical expression of the shape of the solidification interface and solute concentration field were deduced.Meanwhile,a theory is developed for evaluation of critical velocities of particles pushed by the solidification interface.A numerical simulation is done in which the critical velocity is evaluated as a function of particle size,thermal conductivity,diffusion coefficient,temperature gradient at the solidification front,the solid-liquid interfacial energy and the melt viscosity.The critical velocity is shown to be closely linked to the shape of the solidification interface and solute concentration field, and hence all the parameters also affect the shape of the solidification interface and solute concentration field of the front.
基金supports from the National Natural Science Foundation of China(11402133 and 11502128)
文摘Interface dislocations may dramatically change the electric properties, such as polarization, of the piezoelectric crystals. In this paper, we study the linear interactions of two interface dislocation loops with arbitrary shape in generally anisotropic piezoelectric bi-crystals. A simple formula for calculating the interaction energy of the interface dislocation loops is derived and given by a double line integral along two closed dislocation curves. Particularly, interactions between two straight segments of the interface dislocations are solved analytically, which can be applied to approximate any curved loop so that an analytical solution can be also achieved. Numerical results show the influence of the bi-crystal interface as well as the material orientation on the interaction of interface dislocation loops.
基金We gratefully acknowledge the financial support from National Key Research and Development Project,China(2019YFA0708700)the National Natural Science Foundation of China(52222403,52074333)the Innovation Fund Project for graduate students of China University of Petroleum(East China)(22CX04049A).
文摘The membrane method based on adaptive wettability shows great advantages in oil-water separation.At present,researches focus on the excellent application performance of the membrane material,while the quantitative analysis of interactions in oil-water separation is rarely recognized.Herein,we constructed an adaptable wettability membrane with multiple polymer networks by polydopamine(PDA)and mussel-inspired amphiphilic polymer.Based on the Owens three-probe liquid method,the surface energy of the modified membrane was verified to meet the adaptive wettability conditions,with surface energies(γ-8)of 147.6 mJ m^(−2)(superhydrophilic/underwater superoleophobic)and 49.87 mJ m^(−2)(superhydrophobic/superoleophobic),respectively.The adhesion or repulsion of the membrane to the oil phase under different conditions during the separation process was quantified by the chemical probe AFM technique.In addition,the oil-water selective separation mechanism was further analyzed in a simplified membrane microchannel model.The results show that the different wetting produces capillary additional pressure in opposite directions,resulting in different energies to be overcome when the oil or water passes through the microchannels,thus achieving selective separation.
基金the National Natural Science Foundation of China(Nos.51108138,51008099)the Program for New Century Excellent Talents in University by Ministry of Education(No.NCET-06–0340)
文摘In order to find a parameter as the evaluation index that can capture the effect of the interaction between asphalt and aggregate, the rheological properties of asphalt mastics using two kinds of asphalts and four kinds of aggregates under different filler-asphalt ratios were measured by a dynamic shear rheometer (DSR). Moreover, four rheological parameters of K.Ziegel-B, Luis Ibrarra-A, complex shear modulus ΔG*and complex viscosity Δη* for evaluating the interaction ability were studied. Results indicate that all the four parameters can characterize the interaction ability of asphalt and aggregate correctly and feasibly. Through the comparison of sensitivities and physical meanings of the four parameters, K.Ziegel-B with high sensitivity and exact physical meaning is finally selected as the evaluation index for interaction ability of asphalt and aggregate.
基金the financial support by the National Natural Science Foundation of China as general projects(Grant Nos.51779068,52070066,52211530084,42277059,and 22006029)Tianjin Commission of Science and Technology as key technologies R&D projects(No.21YFSNSN00250)+1 种基金Doctoral Inno-vation Project of Hebei Province(CXZZBS2023031)the Royal Society/International Exchanges 2021 Cost Share/NSFC(Grant No.IEC\NSFC\211142).
文摘Heterojunction photocatalysts have shown considerable activities for organic pollutants degradation.However,the faint connection interface and inferior charge shift efficiency critically block the property of heterojunction photocatalysis.Herein,Bi_(2)O_(2)S/NiFe_(2)O_(4) nanosheets heterojunction with ultrastrong inter-face interaction and high internal electric field are designed by an in-situ growth method.Tentative and theoretical consequences prove that the interfacial interaction and internal electric field not only act as the electron flow bridge but also decrease the electrons shift energy obstacle,thus speeding up electrons transfer and achieving effective spatial electron-hole separation.Therefore,a large amount of·O_(2)^(-)and holes as active species were generated.Remarkably,Bi_(2)O_(2) S/NiFe_(2)O_(4) establishes a considerably boosted photocatalytic performance for tetracycline degradation(0.032 min^(-1)),which is about 14.2-fold and 7.8-fold of the pristine BOS and NFO,respectively.This work provides a promising motivation for modulating charge transfer by interface control and internal electric field to boost photocatalytic performance.
基金The project was supported by China Postdoctoral Science Foundation(No.2003034452)National Natural Science Foundation of China(No.50371027).
文摘A novel process for synthesizing nano-ceramics powders, named mechanical & therm al activation processing, is discussed in the present paper. It is a processing based on thermal activation in liquid phase (molten salt) after mechanical activ ation. The nanometer-sized TiC particles (15-20nm) have been synthesized by the method, and analyzed by X-ray diffraction (XRD), transmission electron microscop e (TEM), scanning electron microscopy (SEM) and energy dispersion X-ray (EDX) sp ectroscopy. An interface interaction between liquid (molten salt) and solid (fin al product particles) phases plays a dominating role for the control of product particles size. The mechanism for the formation of nanometer-sized TiC particles has been discussed.
基金Project supported by the Strategic Priority Research Program of Chinese Academy of Sciences(Grant Nos.KJCX2-YW-N35 and XDA03010303)the National Natural Science Foundation of China(Grant Nos.91026002 and 91126002)the National Magnetic Confinement Fusion Program,China(Grant No.2011GB108004)
文摘The corrosion of steels in liquid metal lead (Pb) and bismuth (Bi) is a critical challenge in the development of accel-erator driven systems (ADS). Using a first-principles method with a slab model, we theoretically investigate the interaction between the Pb (Bi) atom and the iron (Fe) (100) surface to assess the fundamental corrosion properties. Our investigation demonstrates that both Pb and Bi atoms favorably adsorb on the (100) surface. Such an adsorption decreases the energy required for the dissociation of an Fe atom from the surface, enhancing the dissolution tendency significantly. The seg- regation of six common alloying elements (Cr, A1, Mn, Ni, Nb, and Si) to the surface and their impacts on the corrosion properties are also considered. The present results reveal that Si seems to have a relatively good performance to stabilize the surface and alleviate the dissolving trend caused by Pb and Bi.
基金NKBRSF CG 1990 3 2 80 5 National Natural Science F oundation of China !( No.5 98760 0 2 )
文摘In order to prevent smearing the discontinuity, a modified term is added to the third order Upwind Compact Difference scheme to lower the dissipation error. Moreover, the dispersion error is controled to hold back the non physical oscillation by means of the group velocity control. The scheme is used to simulate the interactions of shock density stratified interface and the disturbed interface developing to vortex rollers. Numerical results are satisfactory.
基金supported by the Scientific and Research Innovation Project of Shanghai Municipal Education Commission
文摘Purpose: Fully integrating its e-reserves service into the university's course management system has become the primary design goal of the innovative e-reserves service system at Shanghai Jiao Tong University(SJTU) Library.Design/methodology/approach: Through blending library and information service into the teaching and learning process, SJTU Library has effectively combined its reserves service into the user learning environment. The main metadata model and the design of various interfaces of the e-reserves service system are introduced.Findings: E-reserves has been integrated into the course management system. Users can directly access relevant resources when they browse the customized course page. It is more convenient for teachers to add reserves items, and the added items can be made available simultaneously on SJTU Library's resource discovery platform automatically.Research limitations: At present, e-reserves items are mainly books, and more other types of reserves materials are needed to be provided. Some relevant copyright issues should be addressed.Practical implications: Using a series of interface interactions, the e-reserves service has been integrated into the university's course management system. It is convenient for students to access customized e-reserves service during their learning process.Originality/value: We achieved interconnection between the e-reserves and the university's course management system. Information on the e-reserves Web page is automatically updated.SJTU Library provides customized e-reserves service in the course management system.
基金Supported by USDA 2018-67021-27416NSFJS BK20190292.
文摘Background Free-viewpoint video(FVV)is processed video content in which viewers can freely select the viewing position and angle.FVV delivers an improved visual experience and can also help synthesize special effects and virtual reality content.In this paper,a complete FVV system is proposed to interactively control the viewpoints of video relay programs through multimedia terminals such as computers and tablets.Methods The hardware of the FVV generation system is a set of synchronously controlled cameras,and the software generates videos in novel viewpoints from the captured video using view interpolation.The interactive interface is designed to visualize the generated video in novel viewpoints and enable the viewpoint to be changed interactively.Results Experiments show that our system can synthesize plausible videos in intermediate viewpoints with a view range of up to 180°.
基金Project supported by the National Basic Research Program of China (Grant No. 2010CB934603)Ministry of Science and Technology of China and the National Natural Science Foundation of China (Grant Nos. 50931006,50971123,and 51271177)
文摘Recent advances in the study of exchange couplings in magnetic films are introduced.To provide a comprehensive understanding of exchange coupling,we have designed different bilayers,trilayers and multilayers,such as anisotropic hard/soft-magnetic multilayer films,ferromagnetic/antiferromagnetic/ferromagnetic trilayers,[Pt/Co]/NiFe/NiO heterostructures,Co/NiO and Co/NiO/Fe trilayers on an anodic aluminum oxide(AAO) template.The exchange-coupling interaction between soft-and hard-magnetic phases,interlayer and interfacial exchange couplings and magnetic and magnetotransport properties in these magnetic films have been investigated in detail by adjusting the magnetic anisotropy of ferromagnetic layers and by changing the thickness of the spacer layer,ferromagnetic layer,and antiferromagnetic layer.Some particular physical phenomena have been observed and explained.
文摘The paper analyzes the principles and applications of CGI for collaborative design. The utility model possessing broad reference values is set up and its implementation techniques are presented in detail.
基金Project supported by the National Natural Science Foundation of China(51904027,52074031,51574213)。
文摘It is difficult to achieve selective separation and enrichment of different rare earths from high abundance yttrium ores efficiently only dependent on their discrepancy in thermodynamic properties.The present work suggests a new strategy based on non-equilibrium kinetic separation of Er and Tm on the surface of freely rising oil droplets to control the separation order of Y.It is revealed that the mutual separation of Er/Tm is significantly promoted with the separation coefficient of 2.89 during the non-equilibrium extraction with the addition of diethylenetriaminepentaacetic acid(DTPA).The extraction sequence of Tm,Er and Y can be controlled as Tm>Y>Er,thus Y can be selectively enriched during the process of separation of Er and Tm,Such a sequence is subject to the controllable dissociation rates of RE(Ⅲ)-DTPA complexes and extraction abilities of P507 with the three RE(Ⅲ)ions.The dissociation rate is dependent on the stabilities of RE(Ⅲ)-DTPA complexes and follows the sequence ofY(Ⅲ)—DTPA Er>Y to Tm>Y>Er.
基金funded by China Postdoctoral Science Foundation(No.2018M643699)the Xi’an Science and Technology Bureau Innovation Leading Projects(No.201805037YD15CG21(23))+2 种基金the Natural Science Foundation of Shaanxi Province(No.2019JQ741)the Science and Technology Bureau of Beilin District,Xi’an(No.GX2035)the Postdoctoral Science Foundation of Shaanxi Province(No.2018BSHEDZZ101)。
文摘A valid strategy to tailor the properties of polylactic acid for more extensive applications was introducing filler.In this work,basalt fiber assembled with in-situ SiO_(2) nanoparticles on the surface was successfully prepared via hydrothermal method and it was further treated with coupling agent KH-550 to improve interfacial interaction between polylactic acid(PLA)and basalt fibers(BF).It was demonstrated that the introduction of BFS could increase the crystallization of PLA and resulted in forming trans-crystallization based on TG and DSC results.The tensile strength of PLA/BF composites raised from 39 MPa to 62.5 MPa with increasing the fiber loading from 1 wt%to 10 wt%.Furthermore,the interfacial interaction could be effectively improved by assembling SiO_(2)(especially with 250 nm in diameter)on BF surface to build mechanical locking,which could keep the PLA matrix in place during the mechanical deformation with the tensile strength value raised from 62.5 MPa to 74.0 MPa.It is noticeable that the impact and flexural properties were effectively increased with the incorporation of in-situ SiO_(2) nanoparticles.The further KH-550 treatment made a positive impact as well.For instance,the impact strength and flexural strength of the sample with SiO_(2) and KH-550 modification were improved to 22.49 k J/m^(2) and 146.83 MPa and it enhanced about 42.16%and 41.04%than those of neat PLA,respectively.Therefore,an efficient enhancement of mechanical performance was achieved and this concept of assembling in-situ SiO_(2) on silica-based fiber as a modifier was a novel and simple path to design the interfacial construction and properties of the polymer composites.
基金the National Natural Science Foundation of China (Nos. 82172372 and 21904045)COVID-19 Pneumonia Emergency Scientific Research Special Fund of Wuhan (No. EX20D03)the Fundamental Research Funds for the Central Universities (Nos. 2019kfy XJJS169 and 2021yjs CXCY127)。
文摘DNA-functionalized gold nanoparticles are one of the most versatile bionanomaterials for biomedical and clinical diagnosis. Herein, we discovered that the performance of DNAzyme cleaving the substrate is highly related to its length. This intriguing phenomenon only appears at the interfaces of DNAfunctionalized gold nanoparticles. We systematically investigated the causes of this phenomenon. We conjectured that the DNAzyme with extended nucleotides that do not match its substrate strand is vulnerable to non-specific adsorption, electrostatic repulsion, and steric hindrance. Based on our improved understanding of this phenomenon, we have successfully developed a highly sensitive and specific amplifiable biosensor to detect human apurinic/apyrimidinic endonuclease 1.
基金the National Key Research and Development Program of China(No.2018YFA0703700)the National Natural Science Foundation of China(Nos.12034002,51971025,11974041,51901012,and 52071022)+1 种基金Natural Science Foundation of Beijing,China(No.2212034)the Fundamental Research Funds for the Central Universities(No.FRF-TP-18-075A1).
文摘The heterostructure of transition metal nanocrystal on two-dimensional(2D)materials exhibits unique physical and chemical properties through various interfacial interactions.It has been established that the atomic structure and strain in the vicinity of the interface determine the band structure and phonon modes of the nanocrystal,regulating the optical and electrical properties of such heterostructures.Hence,metal–support interfacial engineering is a demonstrated approach to acquiring desired properties of the nanocrystals.However,a fundamental understanding of the interfacial structures remains elusive and precise control of the interactions has yet achieved.Herein,we explore the regulation of interface on MoS_(2)supported Pt nanocrystals which were prepared by reducing ultrasonic dispersed potassium chloroplatinate.The Pt-MoS_(2)heterostructure interface was systematically studied by aberration corrected transmission electron microscopy.Three types of Pt-MoS_(2)interfaces with distinct atomic configurations were identified.The strain within the Pt nanocrystals is sensitive to the atomic configuration of the supporting MoS_(2),which regulates the size of the Pt nanocrystals.These results provide insights on tuning of nanocrystal strain,paving the way for precise control of 2D semiconductor heterostructures.
基金This work was supported by the National Key Research and Development Program of China(2021YFD2201202,2022YFD2201900)Jiangsu Special Fund on Technology Innovation of Carbon Dioxide Peaking and Carbon Neutrality(BE2022420)the National Natural Science Foundation of China(42011045,42007211,32122056).
文摘Forests are highly productive ecosystems that contribute to biogeochemical cycles of carbon and nitrogen,through which it regulates climate and global change.Forests are also spatially highly heterogeneous ecosystems that comprise a multitude of microbial-mediated reactive interfaces.These are mainly the root-soil interface,litter-soil interface,root-root interface,and plant-atmosphere interface.Each of these interfaces has its own unique characteristics,e.g.,specific drivers that affect the microbial abundance,nutrient availability,microbial community,and the dominance of certain microbial taxa.Here,we review the microbial-mediated reactive interfaces in forests,focusing on interrelation and dynamics of fungi and bacteria on a broad temporal scale with ecosystem processes ranging from short-term events(e.g.,seasonal changes)to long-term stand development suffering a global climate change(e.g.,global warming or nitrogen deposition).We argue that in-depth knowledge of forest microbiology can only be obtained by exploring the complex forest microbiome and its ecosystem functions.Underpinning the basis for individual forest variation would ultimately facilitate the formulation of microbiome-based strategies in the future.