Adsorption of Cr(Ⅵ) and p-chloroaniline on three typical soil colloids and pH influence were studied using batch equilibrium method. Both of Cr(Ⅵ) and p-chloroaniline adsorption on the colloids could be well describ...Adsorption of Cr(Ⅵ) and p-chloroaniline on three typical soil colloids and pH influence were studied using batch equilibrium method. Both of Cr(Ⅵ) and p-chloroaniline adsorption on the colloids could be well described by general adsorption simulation equations. The adsorption processes changed with media pH. When Cr(Ⅵ) and p-chloroaniline coexisted on soil colloids, their interactions could be observed in a certain pH range to be accompanied with Cr(Ⅵ) reduction, which clearly suggested that a surface catalytic reaction occurred in this system. Soil colloid acted as an efficient catalyst for the interaction of Cr(Ⅵ) and p-chloroaniline. The pH values at which no interaction was observed were 4.0, 4.5 and 5.0 for the colloids of indigotic black soil, yellow-brown soil and latosol, respectively. Capillary electrophoresis used to analyze p-chloroaniline provided a high separation efficiency and short separation time, and needed no more extensive pretreatment of samples.展开更多
In Glacier Bay National Park, about 95% of the visitors come on board of cruise ships. The National Park Service has the mandate to manage park resources like air quality and visibility, while ensuring visitation. To ...In Glacier Bay National Park, about 95% of the visitors come on board of cruise ships. The National Park Service has the mandate to manage park resources like air quality and visibility, while ensuring visitation. To understand the impact of cruise-ship emissions on the overall concentrations in Glacier Bay, emission-source contribution ratios (ESCR) and the interaction of pollutant from local and/or distant sources were determined using results from four WRF/Chem simulations of the 2008 tourist season (May 15 to September 15). These simulations only differed by the emissions considered: Biogenic emissions only (CLN), biogenic plus activity-based cruise-ship emissions (REF), biogenic plus all anthropogenic emissions except cruise-ship emissions (RETRO), and all aforementioned emissions (ALL). In general, ESCRs differed among pollutants. Interaction between pollutants from cruise-ship emissions and species from other sources including those advected into the bay decreased towards the top of the atmospheric boundary layer. Pollutants from different sources interacted strongest (lowest) in the west arm of the fjord where ships berthed for glacier viewing (in areas of the bay without cruise-ship travel). Pollutant interaction both enhanced/reduced NO<sub>2</sub> concentrations by 10% (4 - 8 ppt absolute). Except for ozone, cruise-ship emissions on average governed air quality in the bay. On days with cruise-ship visits, they contributed between 60% and 80% of the bay-wide daily mean SO<sub>2</sub> and NO<sub>2</sub> concentrations below 1 km height. On days without visits, cruise-ship contributions still reached 40% due to previous visits. Highest cruise-ship ESCRs occurred during stagnant weather conditions. Despite the fact that all coarse particulate matter was due to anthropogenic sources, worst visibility conditions were due to meteorology. The results suggest limits as well as windows for managing air quality and visibility in Glacier Bay.展开更多
文摘Adsorption of Cr(Ⅵ) and p-chloroaniline on three typical soil colloids and pH influence were studied using batch equilibrium method. Both of Cr(Ⅵ) and p-chloroaniline adsorption on the colloids could be well described by general adsorption simulation equations. The adsorption processes changed with media pH. When Cr(Ⅵ) and p-chloroaniline coexisted on soil colloids, their interactions could be observed in a certain pH range to be accompanied with Cr(Ⅵ) reduction, which clearly suggested that a surface catalytic reaction occurred in this system. Soil colloid acted as an efficient catalyst for the interaction of Cr(Ⅵ) and p-chloroaniline. The pH values at which no interaction was observed were 4.0, 4.5 and 5.0 for the colloids of indigotic black soil, yellow-brown soil and latosol, respectively. Capillary electrophoresis used to analyze p-chloroaniline provided a high separation efficiency and short separation time, and needed no more extensive pretreatment of samples.
文摘In Glacier Bay National Park, about 95% of the visitors come on board of cruise ships. The National Park Service has the mandate to manage park resources like air quality and visibility, while ensuring visitation. To understand the impact of cruise-ship emissions on the overall concentrations in Glacier Bay, emission-source contribution ratios (ESCR) and the interaction of pollutant from local and/or distant sources were determined using results from four WRF/Chem simulations of the 2008 tourist season (May 15 to September 15). These simulations only differed by the emissions considered: Biogenic emissions only (CLN), biogenic plus activity-based cruise-ship emissions (REF), biogenic plus all anthropogenic emissions except cruise-ship emissions (RETRO), and all aforementioned emissions (ALL). In general, ESCRs differed among pollutants. Interaction between pollutants from cruise-ship emissions and species from other sources including those advected into the bay decreased towards the top of the atmospheric boundary layer. Pollutants from different sources interacted strongest (lowest) in the west arm of the fjord where ships berthed for glacier viewing (in areas of the bay without cruise-ship travel). Pollutant interaction both enhanced/reduced NO<sub>2</sub> concentrations by 10% (4 - 8 ppt absolute). Except for ozone, cruise-ship emissions on average governed air quality in the bay. On days with cruise-ship visits, they contributed between 60% and 80% of the bay-wide daily mean SO<sub>2</sub> and NO<sub>2</sub> concentrations below 1 km height. On days without visits, cruise-ship contributions still reached 40% due to previous visits. Highest cruise-ship ESCRs occurred during stagnant weather conditions. Despite the fact that all coarse particulate matter was due to anthropogenic sources, worst visibility conditions were due to meteorology. The results suggest limits as well as windows for managing air quality and visibility in Glacier Bay.
