Ammonia borane(AB)is an excellent candidate for the chemical storage of hydrogen.However,its practical utilization for hydrogen production is hindered by the need for expensive noble-metal-based catalysts.Herein,we re...Ammonia borane(AB)is an excellent candidate for the chemical storage of hydrogen.However,its practical utilization for hydrogen production is hindered by the need for expensive noble-metal-based catalysts.Herein,we report Co-Co3O4 nanoparticles(NPs)facilely deposited on carbon dots(CDs)as a highly efficient,robust,and noble-metal-free catalyst for the hydrolysis of AB.The incorporation of the multiinterfaces between Co,Co3O4 NPs,and CDs endows this hybrid material with excellent catalytic activity(rB=6816 mLH2 min^-1 gCo^-1)exceeding that of previous non-noble-metal NP systems and even that of some noble-metal NP systems.A further mechanistic study suggests that these interfacial interactions can affect the electronic structures of interfacial atoms and provide abundant adsorption sites for AB and water molecules,resulting in a low energy barrier for the activation of reactive molecules and thus substantial improvement of the catalytic rate.展开更多
Seismic traveltime tomographic inversion has played an important role in detecting the internal structure of the solid earth. We use a set of blocks to approximate geologically complex media that cannot be well descri...Seismic traveltime tomographic inversion has played an important role in detecting the internal structure of the solid earth. We use a set of blocks to approximate geologically complex media that cannot be well described by layered models or cells. The geological body is described as an aggregate of arbitrarily shaped blocks,which are separated by triangulated interfaces. We can describe the media as homogenous or heterogeneous in each block. We define the velocities at the given rectangle grid points for each block,and the heterogeneous velocities in each block can be calculated by a linear interpolation algorithm. The parameters of the velocity grid positions are independent of the model parameterization,which is advantageous in the joint inversion of the velocities and the node depths of an interface. We implement a segmentally iterative ray tracer to calculate traveltimes in the 3D heterogeneous block models.The damped least squares method is employed in seismic traveltime inversion,which includes the partial derivatives of traveltime with respect to the depths of nodes in the triangulated interfaces and velocities defined in rectangular grids. The numerical tests indicate that the node depths of a triangulated interface and homogeneous velocity distributions can be well inverted in a stratified model.展开更多
The ripple effect induced by uncontrollable Zn deposition is considered as the Achilles heel for developing high-performance aqueous Zn-ion batteries.For this problem,this work reports a design concept of 3D artificia...The ripple effect induced by uncontrollable Zn deposition is considered as the Achilles heel for developing high-performance aqueous Zn-ion batteries.For this problem,this work reports a design concept of 3D artificial array interface engineering to achieve volume stress elimination,preferred orientation growth and dendrite-free stable Zn metal anode.The mechanism of MXene array interface on modulating the growth kinetics and deposition behavior of Zn atoms were firstly disclosed on the multi-scale level,including the in-situ optical microscopy and transient simulation at the mesoscopic scale,in-situ Raman spectroscopy and in-situ X-ray diffraction at the microscopic scale,as well as density functional theory calculation at the atomic scale.As indicated by the electrochemical performance tests,such engineered electrode exhibits the comprehensive enhancements not only in the resistance of corrosion and hydrogen evolution,but also the rate capability and cyclic stability.High-rate performance(20 mA cm^(-2))and durable cycle lifespan(1350 h at 0.5 mA cm^(-2),1500 h at 1 mA cm^(-2)and 800 h at 5 mA cm^(-2))can be realized.Moreover,the improvement of rate capability(214.1 mAh g^(-1)obtained at 10 A g^(-1))and cyclic stability also can be demonstrated in the case of 3D MXene array@Zn/VO2battery.Beyond the previous 2D closed interface engineering,this research offers a unique 3D open array interface engineering to stabilize Zn metal anode,the controllable Zn deposition mechanism revealed is also expected to deepen the fundamental of rechargeable batteries including but not limited to aqueous Zn metal batteries.展开更多
BP( Back Propagation) neural network and PSO( Particle Swarm Optimization) are two main heuristic optimization methods,and are usually used as nonlinear inversion methods in geophysics. The authors applied BP neural n...BP( Back Propagation) neural network and PSO( Particle Swarm Optimization) are two main heuristic optimization methods,and are usually used as nonlinear inversion methods in geophysics. The authors applied BP neural network and BP neural network optimized with PSO into the inversion of 3D density interface respectively,and a comparison was drawn to demonstrate the inversion results. To start with,a synthetic density interface model was created and we used the proceeding inversion methods to test their effectiveness. And then two methods were applied into the inversion of the depth of Moho interface. According to the results,it is clear to find that the application effect of PSO-BP is better than that of BP network. The BP network structures used in both synthetic and field data are consistent in order to obtain preferable inversion results. The applications in synthetic and field tests demonstrate that PSO-BP is a fast and effective method in the inversion of 3D density interface and the optimization effect is evident compared with BP neural network merely,and thus,this method has practical value.展开更多
Based on the first-principles method, the structural stability and the contribution of point defects such as O, Sr or Ti vacancies on two-dimensional electron gas of n- and p-type LaAlO3/SrTiO3 interfaces are investig...Based on the first-principles method, the structural stability and the contribution of point defects such as O, Sr or Ti vacancies on two-dimensional electron gas of n- and p-type LaAlO3/SrTiO3 interfaces are investigated. The results show that O vacancies at p-type interfaces have much lower formation energies, and Sr or Ti vacancies at n-type interfaces are more stable than the ones at p-type interfaces under O-rich conditions. The calculated densities of states indicate that O vacancies act as donors and give a significant compensation to hole carriers, resulting in insulating behavior at p-type interfaces. In contrast, Sr or Ti vacancies tend to trap electrons and behave as acceptors. Sr vacancies are the most stable defects at high oxygen partial pressures, and the Sr vacancies rather than Ti vacancies are responsible for the insulator-metal transition of n-type interface. The calculated results can be helpful to understand the tuned electronic properties of LaAlO3 /SrTiO3 heterointerfaces.展开更多
The first-principles calculations are employed to investigate the electrical properties of polar MgO/BaTiO3(110)interfaces. Both n-type and p-type polar interfaces show a two-dimensional metallic behavior. For the n...The first-principles calculations are employed to investigate the electrical properties of polar MgO/BaTiO3(110)interfaces. Both n-type and p-type polar interfaces show a two-dimensional metallic behavior. For the n-type polar interface,the interface Ti3d electrons are the origin of the metallic and magnetic properties. Varying the thickness of Ba TiO3 may induce an insulator–metal transition, and the critical thickness is 4 unit cells. For the p-type polar interface, holes preferentially occupy the interface O 2p y state, resulting in a conducting interface. The unbalance of the spin splitting of the O 2p states in the interface Mg O layer leads to a magnetic moment of about 0.25μB per O atom at the interface.These results further demonstrate that other polar interfaces, besides LaAlO3/SrTiO3, can show a two-dimensional metallic behavior. It is helpful to fully understand the role of polar discontinuity on the properties of the interface, which widens the field of polar-nonpolar interfaces.展开更多
Recently, the quasi-two-dimensional electron gas (q2DEG) confined at the interface between LaAlO3 and SrTiO3 has attracted significant attention. In this paper, we briefly review experimental methods that have been ...Recently, the quasi-two-dimensional electron gas (q2DEG) confined at the interface between LaAlO3 and SrTiO3 has attracted significant attention. In this paper, we briefly review experimental methods that have been used to tune the carrier density and mobility of this q2DEG. These methods can be classified into two categories: growth-related tuning (i.e. substrate, growth temperature, oxygen pressure, post-annealing, LaAlO3 thickness, stoichiometry, and capping layers) and post-growth tuning (i.e. electrostatic field gating, conductive atomic force microscopy and surface adsorbates). Taken together, these methods enable the broad tuning of the electronic properties of this interface.展开更多
The distributions of traps and electron density in the interfaces between polyimide (PI) matrix and Al2O3 nanoparticles are researched using the isothermal decay current and the small-angle x-ray scattering (SAXS)...The distributions of traps and electron density in the interfaces between polyimide (PI) matrix and Al2O3 nanoparticles are researched using the isothermal decay current and the small-angle x-ray scattering (SAXS) tests. According to the electron density distribution for quasi two-phase mixture doped by spherical nanoparticles, the electron densities in the interfaces of PI/Al2O3 nanocomposite films are evaluated. The trap level density and carrier mobility in the interface are studied. The experimental results show that the distribution and the change rate of the electron density in the three layers of interface are different, indicating different trap distributions in the interface layers. There is a maximum trap level density in the second layer, where the maximum trap level density for the nanocomposite film doped by 25 wt% is 1.054 × 10^22 eV·m^-3 at 1.324eV, resulting in the carrier mobility reducing. In addition, both the thickness and the electron density of the nanocomposite film interface increase with the addition of the doped Al2O3 contents. Through the study on the trap level distribution in the interface, it is possible to further analyze the insulation mechanism and to improve the performance of nano-dielectric materials.展开更多
By using newly developed CuNi5~25Ti16~28 B rapldly solidifled brazing filler the joining of Si3 N4/1.25Cr-0.5Mo steel has been carried out with interlayer method. If employing the interlayer structure of steel (0.2 mm...By using newly developed CuNi5~25Ti16~28 B rapldly solidifled brazing filler the joining of Si3 N4/1.25Cr-0.5Mo steel has been carried out with interlayer method. If employing the interlayer structure of steel (0.2 mm)/W (2.0 mm)/Ni(0.2 mm), the joint strength can be increased greatly compared with employing that of Ni/W/Ni, and the three point bend strength of the Joint shows the value of 261 MPa. The metallurgical behaviour at the interface between Si3N4 and the interlayer has been studied. It is found that Fe participated in the interfacial reactions between Si3N4 and the brazing filler at the Si3N4/steel (0.2 mm) interface and the compound Fe5Si3 was produced. However, since the reactions of Fe with the active Ti are weaker than those of Ni with Ti, the normal inter facial reactions were still assured at the interface of Si3N4/steel (0.2 mm) instead of Si3N4/Ni (0.2 mm), resulting in the improvement of the joint strength. The mechanism of the formation of Fe5Si3 is also discussed. Finally, some ideas to further ameliorate and simplify the interlayer structure are put forward.展开更多
The first-principles calculations are employed to investigate the stability, magnetic, and electrical properties of the oxide heterostructure of LaAIO3/SrTiO3 (110). By comparing their interface energies, it is obta...The first-principles calculations are employed to investigate the stability, magnetic, and electrical properties of the oxide heterostructure of LaAIO3/SrTiO3 (110). By comparing their interface energies, it is obtained that the buckled interface is more stable than the abrupt interface. This result is consistent with experimental observation. At the interface of LaAIO3/SrTiO3 (110) heterostructure, the Ti-O octahedron distortions cause the Ti tzg orbitals to split into the two- fold degenerate dxz/dyz and nondegenerate dxy orbitals. The former has higher energy than the latter. The partly filled two-fold degenerate t2g orbitals are the origin of two-dimensional electron gas, which is confined at the interface. Lattice mismatch between LaA103 and SrTiO3 leads to ferroelectric-like lattice distortions at the interface, and this is the origin of spin-splitting of Ti 3d electrons. Hence the magnetism appears at the interface of LaAIO3/SrTiO3 (110).展开更多
2022 The paper seeks to demonstrates the likelihood of embedding a 3D gaze point on a 3D visual field,the visual field is inform of a game console where the user has to play from one level to the other by overcoming o...2022 The paper seeks to demonstrates the likelihood of embedding a 3D gaze point on a 3D visual field,the visual field is inform of a game console where the user has to play from one level to the other by overcoming obstacles that will lead them to the next level.Complex game interface is sometimes difficult for the player to progress to next level of the game and the developers also find it difficult to regulate the game for an average player.The model serves as an analytical tool for game adaptations and also players can track their response to the game.Custom eye tracking and 3D object tracking algorithms were developed to enhance the analysis of the procedure.This is a part of the contributions to user interface design in the aspect of visual transparency.The development and testing of human computer interaction uses and application is more easily investigated than ever,part of the contribution to this is the embedding of 3-D gaze point on a 3-D visual field.This could be used in a number of applications,for instance in medical applications that includes long and short sightedness diagnosis and treatment.Experiments and Test were conducted on five different episodes of user attributes,result show that fixation points and pupil changes are the two most likely user attributes that contributes most significantly in the performance of the custom eye tracking algorithm the study.As the advancement in development of eye movement algorithm continues user attributes that showed the least likely appearance will prove to be redundant.展开更多
Mechanochemical reactions of the GaN-Al_(2)O_(3) interface offer a novel principle for scientific and technological merits in the micro-/nano-scale ultra-precision surface machining.In this work,the mechanochemical re...Mechanochemical reactions of the GaN-Al_(2)O_(3) interface offer a novel principle for scientific and technological merits in the micro-/nano-scale ultra-precision surface machining.In this work,the mechanochemical reactions on Ga-and N-faced GaN surfaces rubbed by the Al_(2)O_(3) nanoasperity as a function of the environmental humidity were investigated.Experimental results indicate that the N-face exhibits much stronger mechanochemical removal over the relative humidity range of 20%-80%than the Ga-face.Increasing water molecules in environmental conditions significantly promotes the interfacial mechanochemical reactions and hence accelerates the atomic attrition on N-face.The hypothesized mechanism of the selective water-involved mechanochemical removal is associated with the dangling bond configuration,which affects the mechanically-stimulated chemical reactions via altering the activation energy barrier to form the bonding bridge across the sliding interface.These findings can enrich the understanding of the underlying mechanism of mechanochemical reactions at GaN-Al_(2)O_(3) interface and a broad cognition for regulating the mechanochemical reactions widely existing in scientific and engineering applications.展开更多
Interacting with digital contents in 3 D is an essential task in various applications such as modeling packages, gaming, virtual reality, etc. Traditional interfaces using keyboard and mouse or trackball usually requi...Interacting with digital contents in 3 D is an essential task in various applications such as modeling packages, gaming, virtual reality, etc. Traditional interfaces using keyboard and mouse or trackball usually require a non-trivial amount of working space as well as a learning process. We present the design of EZ-Manipulator, a new 3 D manipulation interface using smartphones that supports mobile, fast, and ambiguity-free interaction with 3 D objects. Our system leverages the built-in multi-touch input and gyroscope sensor of smartphones to achieve 9 degrees-of-freedom axis-constrained manipulation and free-form rotation.Using EZ-Manipulator to manipulate objects in 3 D is easy. The user merely has to perform intuitive singleor two-finger gestures and rotate the hand-held device to perform manipulations at fine-grained and coarse levels respectively. We further investigate the ambiguity in manipulation introduced by indirect manipulations using a multi-touch interface, and propose a dynamic virtual camera adjustment to effectively resolve the ambiguity. A preliminary study shows that our system has significant lower task completion time compared to conventional use of a keyboard–mouse interface, and provides a positive user experience to both novices and experts.展开更多
In this paper,a fairly simple 3D immersed interface method based on the CG-Uzawa type method and the level set representation of the interface is employed for solving three-dimensional Stokes flow with singular forces...In this paper,a fairly simple 3D immersed interface method based on the CG-Uzawa type method and the level set representation of the interface is employed for solving three-dimensional Stokes flow with singular forces along the interface.The method is to apply the Taylor’s expansions only along the normal direction and incorporate the jump conditions up to the second normal derivatives into the finite difference schemes.A second order geometric iteration algorithm is employed for computing orthogonal projections on the surface with third-order accuracy.The Stokes equations are discretized involving the correction terms on staggered grids and then solved by the conjugate gradient Uzawa type method.The major advantages of the present method are the special simplicity,the ability in handling the Dirichlet boundary conditions,and no need of the pressure boundary condition.The method can also preserve the volume conservation and the discrete divergence free condition very well.The numerical results show that the proposed method is second order accurate and efficient.展开更多
光电极通常由半导体吸光层和导电集流体两部分组成,两者间的界面电子结构直接影响导电集流体从半导体光吸收层中收集光生电荷的效率,尤其对于具有3D界面结构的液态金属镶嵌半导体颗粒的光电极.为此,本工作通过改变金属组分改变液态金属...光电极通常由半导体吸光层和导电集流体两部分组成,两者间的界面电子结构直接影响导电集流体从半导体光吸收层中收集光生电荷的效率,尤其对于具有3D界面结构的液态金属镶嵌半导体颗粒的光电极.为此,本工作通过改变金属组分改变液态金属的功函数,从而调节导电集流体与半导体吸光材料间3D界面的电子能带排列和接触类型,促进光生电荷的跨界面转移与收集,提升光电极的光电化学分解水活性.系统研究半导体与液态金属的功函数匹配关系发现,将ZnO颗粒嵌入铟锡(IT)低温液态金属中,会形成欧姆接触;而将其嵌入铋铟锡(BIT)低温液态金属中,则会形成肖特基接触.由于欧姆接触不存在肖特基接触的界面能垒而有利于光生电荷的跨界面转移与收集,因此,与铟锡低温液态金属镶嵌ZnO颗粒的光电极(IT/ZnO)相比铋铟锡低温液态金属镶嵌ZnO颗粒的光电极(BIT/ZnO)具有更为优异的电荷收集和分离能力,其光电化学分解水光电流密度可达0.62 mA cm^(-2),相比BIT/ZnO光电极的光电流密度(0.52 mA cm^(-2))提升了约19%,且在已报道的代表性ZnO光电极中处于前列.而与之相比,WO3、TiO_(2)或Cu2O因分别与IT和BIT形成相同的欧姆或肖特基型接触,两种低温液态金属镶嵌的WO3、TiO_(2)或Cu2O光电极具有几乎相同的光电催化活性.本工作展示了通过选择具有不同功函数的液态金属来改变金属/半导体接触类型以增强低温液态金属镶嵌半导体光电极性能的潜力,为规模化构建高效光电极提供了新的策略.展开更多
In this paper, a vibration motion control is proposed and implemented on a foamed polystyrene machining robot to suppress the generation of undesirable cusp marks, and the basic performance of the controller is verifi...In this paper, a vibration motion control is proposed and implemented on a foamed polystyrene machining robot to suppress the generation of undesirable cusp marks, and the basic performance of the controller is verified through machining experiments of foamed polystyrene. Then, a 3 dimensional (3D) printer-like data interface is proposed for the machining robot. The 3D data inter- face enables to control the machining robot directly using stereolithography (STL) data without conducting any computer-aided man- ufacturing (CAM) process. This is done by developing a robotic preprocessor that helps to remove the need for the conventional CAM process by directly converting the STL data into cutter location source data called cutter location (CL) or cutter location source (CLS) data. The STL is a file format proposed by 3D systems, and recently is supported by many computer aided design (CAD)/CAM soft- waxes. The STL is widely used for rapid prototyping with a 3D printer which is a typical additive manufacturing system. The STL deals with a triangular representation of a curved surface geometry. The developed 3D printer-like data interface allows to directly control the machining robot through a zigzag path, rectangular spiral path and circular spiral path generated according to the information included in STL data. The effectiveness and usefulness of the developed system are demonstrated through actual machining experiments.展开更多
The interfaces between in-situ Al3Ti particles and magnesium(Mg)matrix are crucial role in highperformance titanium(Ti)reinforced AZ31 alloy.Herein,the interfaces between Al3Ti particles and the Mg matrix are fabricat...The interfaces between in-situ Al3Ti particles and magnesium(Mg)matrix are crucial role in highperformance titanium(Ti)reinforced AZ31 alloy.Herein,the interfaces between Al3Ti particles and the Mg matrix are fabricated and investigated using advanced characterization tools and first-principles calculations.The orientation relationship(OR)and atomic interface structure between the Al_(3)Ti particles and matrix are characterized using a high-resolution transmission electron microscope.The OR is determined to be(1010)Mg//(001)Al3Ti;[1213]Mg//[100]Al3Ti.Based on the characterized OR,the interface properties(including atomic structure,work of adhesion,interface energy,and fracture mechanism)are investigated using first-principles calculations.The relaxed interface structure indicates that the TiAl-terminated bridge site configurations(MT1)and hollow site configurations(HCP1)are unstable and would convert into other bridge site configurations(MT).Furthermore,the work of adhesion and interface energy suggests that Al-terminated hollow site configurations(HCP)and bridge site configurations(MT)are more stable than other configurations.In addition,the calculations of work of fracture show that fracture of the interfaces with Al-MT1,Al-HCP,and TiAl-MT configurations may initiate from bulk Mg interior.The findings may help to understand and tailor the deformation mechanisms and mechanical properties of Ti-reinforced Mg alloys.展开更多
A reaction interface between the aluminum and K_2ZrF_6 during molten salt reaction process was frozen by quenching the mold in water, and the interface structure was analyzed to determine the formation process of Al_3...A reaction interface between the aluminum and K_2ZrF_6 during molten salt reaction process was frozen by quenching the mold in water, and the interface structure was analyzed to determine the formation process of Al_3Zr. Results show that a clear conical interface existed between the K_2ZrF_6 and aluminum. A zirconium accumulation layer with the thickness of about 2–3 lm was formed at the aluminum side of the interface. Many initially formed Al_3Zr particles(with the size of 0.4–16 lm) distributed in this layer, most of which located at the interface. The morphology of Al_3Zr particles is closely related with their size. For the size of 0.4–1 lm, the Al_3Zr appeared as globular and ellipsoid shapes. When it grew to the size of 1–2 and 2–16 lm, it exhibited the rule cube shape, and rule cuboids shape, respectively.展开更多
LaON,LaTiO and LaTiON films are deposited as gate dielectrics by incorporating N or/and Ti into La_2O_3 using the sputtering method to fabricate Ge MOS capacitors,and the electrical properties of the devices are caref...LaON,LaTiO and LaTiON films are deposited as gate dielectrics by incorporating N or/and Ti into La_2O_3 using the sputtering method to fabricate Ge MOS capacitors,and the electrical properties of the devices are carefully examined.LaON/Ge capacitors exhibit the best interface quality,gate leakage property and device reliability,but a smaller k value(14.9).LaTiO/Ge capacitors exhibit a higher k value(22.7),but a deteriorated interface quality,gate leakage property and device reliability.LaTiON/Ge capacitors exhibit the highest k value(24.6),and a relatively better interface quality(3.1×10^(11) eV^(-1)cm^(-2)),gate leakage property(3.6 × 10^(-3) A/cm^2 at V_g = 1V+V_(fb)) and device reliability.Therefore,LaTiON is more suitable for high performance Ge MOS devices as a gate dielectric than LaON and LaTiO materials.展开更多
A new scheme is proposed to model 3D angular motion of a revolving regular object with miniature, low-cost micro electro mechanical systems(MEMS) accelerometers(instead of gyroscope),which is employed in 3D mouse syst...A new scheme is proposed to model 3D angular motion of a revolving regular object with miniature, low-cost micro electro mechanical systems(MEMS) accelerometers(instead of gyroscope),which is employed in 3D mouse system.To sense 3D angular motion,the static property of MEMS accelerometer,sensitive to gravity acceleration,is exploited.With the three outputs of configured accelerometers,the proposed model is implemented to get the rotary motion of the rigid object.In order to validate the effectiveness of the proposed model,an input device is developed with the configuration of the scheme.Experimental results show that a simulated 3D cube can accurately track the rotation of the input device.The result indicates the feasibility and effectiveness of the proposed model in the 3D mouse system.展开更多
基金financially supported by the National Natural Science Foundation of China(21774041 and 51433003)the China Postdoctoral Science Foundation(2018M640681 and 2019T120632)。
文摘Ammonia borane(AB)is an excellent candidate for the chemical storage of hydrogen.However,its practical utilization for hydrogen production is hindered by the need for expensive noble-metal-based catalysts.Herein,we report Co-Co3O4 nanoparticles(NPs)facilely deposited on carbon dots(CDs)as a highly efficient,robust,and noble-metal-free catalyst for the hydrolysis of AB.The incorporation of the multiinterfaces between Co,Co3O4 NPs,and CDs endows this hybrid material with excellent catalytic activity(rB=6816 mLH2 min^-1 gCo^-1)exceeding that of previous non-noble-metal NP systems and even that of some noble-metal NP systems.A further mechanistic study suggests that these interfacial interactions can affect the electronic structures of interfacial atoms and provide abundant adsorption sites for AB and water molecules,resulting in a low energy barrier for the activation of reactive molecules and thus substantial improvement of the catalytic rate.
基金supported financially by the Ministry of Science and Technology of China(2011CB808904)the National Natural Science Foundation of China(Nos.41021063,41174075,41004034,41174043,and 41274090)
文摘Seismic traveltime tomographic inversion has played an important role in detecting the internal structure of the solid earth. We use a set of blocks to approximate geologically complex media that cannot be well described by layered models or cells. The geological body is described as an aggregate of arbitrarily shaped blocks,which are separated by triangulated interfaces. We can describe the media as homogenous or heterogeneous in each block. We define the velocities at the given rectangle grid points for each block,and the heterogeneous velocities in each block can be calculated by a linear interpolation algorithm. The parameters of the velocity grid positions are independent of the model parameterization,which is advantageous in the joint inversion of the velocities and the node depths of an interface. We implement a segmentally iterative ray tracer to calculate traveltimes in the 3D heterogeneous block models.The damped least squares method is employed in seismic traveltime inversion,which includes the partial derivatives of traveltime with respect to the depths of nodes in the triangulated interfaces and velocities defined in rectangular grids. The numerical tests indicate that the node depths of a triangulated interface and homogeneous velocity distributions can be well inverted in a stratified model.
基金financially the National Natural Science Foundation of China(Nos.22178221,22208221)Shenzhen Science and Technology Program(Nos.JCYJ20200109105805902)+1 种基金Natural Science Foundation of Guangdong Province(Nos.2021A1515110751)China Postdoctoral Science Foundation(Nos.2021M702255)。
文摘The ripple effect induced by uncontrollable Zn deposition is considered as the Achilles heel for developing high-performance aqueous Zn-ion batteries.For this problem,this work reports a design concept of 3D artificial array interface engineering to achieve volume stress elimination,preferred orientation growth and dendrite-free stable Zn metal anode.The mechanism of MXene array interface on modulating the growth kinetics and deposition behavior of Zn atoms were firstly disclosed on the multi-scale level,including the in-situ optical microscopy and transient simulation at the mesoscopic scale,in-situ Raman spectroscopy and in-situ X-ray diffraction at the microscopic scale,as well as density functional theory calculation at the atomic scale.As indicated by the electrochemical performance tests,such engineered electrode exhibits the comprehensive enhancements not only in the resistance of corrosion and hydrogen evolution,but also the rate capability and cyclic stability.High-rate performance(20 mA cm^(-2))and durable cycle lifespan(1350 h at 0.5 mA cm^(-2),1500 h at 1 mA cm^(-2)and 800 h at 5 mA cm^(-2))can be realized.Moreover,the improvement of rate capability(214.1 mAh g^(-1)obtained at 10 A g^(-1))and cyclic stability also can be demonstrated in the case of 3D MXene array@Zn/VO2battery.Beyond the previous 2D closed interface engineering,this research offers a unique 3D open array interface engineering to stabilize Zn metal anode,the controllable Zn deposition mechanism revealed is also expected to deepen the fundamental of rechargeable batteries including but not limited to aqueous Zn metal batteries.
基金Supported by National High-tech Research&Development Program of China(863 Project)(No.2014AA06A613)
文摘BP( Back Propagation) neural network and PSO( Particle Swarm Optimization) are two main heuristic optimization methods,and are usually used as nonlinear inversion methods in geophysics. The authors applied BP neural network and BP neural network optimized with PSO into the inversion of 3D density interface respectively,and a comparison was drawn to demonstrate the inversion results. To start with,a synthetic density interface model was created and we used the proceeding inversion methods to test their effectiveness. And then two methods were applied into the inversion of the depth of Moho interface. According to the results,it is clear to find that the application effect of PSO-BP is better than that of BP network. The BP network structures used in both synthetic and field data are consistent in order to obtain preferable inversion results. The applications in synthetic and field tests demonstrate that PSO-BP is a fast and effective method in the inversion of 3D density interface and the optimization effect is evident compared with BP neural network merely,and thus,this method has practical value.
基金Supported by the National Natural Science Foundation of China Under Grant No 61205180the Natural Science Foundation of Hebei Province under Grant No E2014201188+1 种基金the Hebei University Science Funds for Distinguished Young Scholars under Grant No 2012JQ01the Program for Top Young Talents of Hebei Province
文摘Based on the first-principles method, the structural stability and the contribution of point defects such as O, Sr or Ti vacancies on two-dimensional electron gas of n- and p-type LaAlO3/SrTiO3 interfaces are investigated. The results show that O vacancies at p-type interfaces have much lower formation energies, and Sr or Ti vacancies at n-type interfaces are more stable than the ones at p-type interfaces under O-rich conditions. The calculated densities of states indicate that O vacancies act as donors and give a significant compensation to hole carriers, resulting in insulating behavior at p-type interfaces. In contrast, Sr or Ti vacancies tend to trap electrons and behave as acceptors. Sr vacancies are the most stable defects at high oxygen partial pressures, and the Sr vacancies rather than Ti vacancies are responsible for the insulator-metal transition of n-type interface. The calculated results can be helpful to understand the tuned electronic properties of LaAlO3 /SrTiO3 heterointerfaces.
基金supported by the National Basic Research Program of China(Grant No.2013CB632506)the National Natural Science Foundation of China(Grant Nos.11374186,51231007,51202132,and 51102153)the Independent Innovation Foundation of Shandong University,China(Grant No.2012TS027)
文摘The first-principles calculations are employed to investigate the electrical properties of polar MgO/BaTiO3(110)interfaces. Both n-type and p-type polar interfaces show a two-dimensional metallic behavior. For the n-type polar interface,the interface Ti3d electrons are the origin of the metallic and magnetic properties. Varying the thickness of Ba TiO3 may induce an insulator–metal transition, and the critical thickness is 4 unit cells. For the p-type polar interface, holes preferentially occupy the interface O 2p y state, resulting in a conducting interface. The unbalance of the spin splitting of the O 2p states in the interface Mg O layer leads to a magnetic moment of about 0.25μB per O atom at the interface.These results further demonstrate that other polar interfaces, besides LaAlO3/SrTiO3, can show a two-dimensional metallic behavior. It is helpful to fully understand the role of polar discontinuity on the properties of the interface, which widens the field of polar-nonpolar interfaces.
基金Project supported by the Department of Energy,Office of Basic Energy Sciences(Grant No.DE-AC02-76SF00515)
文摘Recently, the quasi-two-dimensional electron gas (q2DEG) confined at the interface between LaAlO3 and SrTiO3 has attracted significant attention. In this paper, we briefly review experimental methods that have been used to tune the carrier density and mobility of this q2DEG. These methods can be classified into two categories: growth-related tuning (i.e. substrate, growth temperature, oxygen pressure, post-annealing, LaAlO3 thickness, stoichiometry, and capping layers) and post-growth tuning (i.e. electrostatic field gating, conductive atomic force microscopy and surface adsorbates). Taken together, these methods enable the broad tuning of the electronic properties of this interface.
基金Supported by the National Natural Science Foundation of China under Grant Nos 51337002,51077028,51502063 and 51307046the Foundation of Harbin Science and Technology Bureau of Heilongjiang Province under Grant No RC2014QN017034
文摘The distributions of traps and electron density in the interfaces between polyimide (PI) matrix and Al2O3 nanoparticles are researched using the isothermal decay current and the small-angle x-ray scattering (SAXS) tests. According to the electron density distribution for quasi two-phase mixture doped by spherical nanoparticles, the electron densities in the interfaces of PI/Al2O3 nanocomposite films are evaluated. The trap level density and carrier mobility in the interface are studied. The experimental results show that the distribution and the change rate of the electron density in the three layers of interface are different, indicating different trap distributions in the interface layers. There is a maximum trap level density in the second layer, where the maximum trap level density for the nanocomposite film doped by 25 wt% is 1.054 × 10^22 eV·m^-3 at 1.324eV, resulting in the carrier mobility reducing. In addition, both the thickness and the electron density of the nanocomposite film interface increase with the addition of the doped Al2O3 contents. Through the study on the trap level distribution in the interface, it is possible to further analyze the insulation mechanism and to improve the performance of nano-dielectric materials.
文摘By using newly developed CuNi5~25Ti16~28 B rapldly solidifled brazing filler the joining of Si3 N4/1.25Cr-0.5Mo steel has been carried out with interlayer method. If employing the interlayer structure of steel (0.2 mm)/W (2.0 mm)/Ni(0.2 mm), the joint strength can be increased greatly compared with employing that of Ni/W/Ni, and the three point bend strength of the Joint shows the value of 261 MPa. The metallurgical behaviour at the interface between Si3N4 and the interlayer has been studied. It is found that Fe participated in the interfacial reactions between Si3N4 and the brazing filler at the Si3N4/steel (0.2 mm) interface and the compound Fe5Si3 was produced. However, since the reactions of Fe with the active Ti are weaker than those of Ni with Ti, the normal inter facial reactions were still assured at the interface of Si3N4/steel (0.2 mm) instead of Si3N4/Ni (0.2 mm), resulting in the improvement of the joint strength. The mechanism of the formation of Fe5Si3 is also discussed. Finally, some ideas to further ameliorate and simplify the interlayer structure are put forward.
基金Project supported by the National Basis Research Program of China(Grant No.2013CB632506)the National Natural Science Foundation of China(Grant Nos.11374186,51231007,and 51202132)the Independent Innovation Foundation of Shandong University,China(Grant No.2012TS027)
文摘The first-principles calculations are employed to investigate the stability, magnetic, and electrical properties of the oxide heterostructure of LaAIO3/SrTiO3 (110). By comparing their interface energies, it is obtained that the buckled interface is more stable than the abrupt interface. This result is consistent with experimental observation. At the interface of LaAIO3/SrTiO3 (110) heterostructure, the Ti-O octahedron distortions cause the Ti tzg orbitals to split into the two- fold degenerate dxz/dyz and nondegenerate dxy orbitals. The former has higher energy than the latter. The partly filled two-fold degenerate t2g orbitals are the origin of two-dimensional electron gas, which is confined at the interface. Lattice mismatch between LaA103 and SrTiO3 leads to ferroelectric-like lattice distortions at the interface, and this is the origin of spin-splitting of Ti 3d electrons. Hence the magnetism appears at the interface of LaAIO3/SrTiO3 (110).
文摘2022 The paper seeks to demonstrates the likelihood of embedding a 3D gaze point on a 3D visual field,the visual field is inform of a game console where the user has to play from one level to the other by overcoming obstacles that will lead them to the next level.Complex game interface is sometimes difficult for the player to progress to next level of the game and the developers also find it difficult to regulate the game for an average player.The model serves as an analytical tool for game adaptations and also players can track their response to the game.Custom eye tracking and 3D object tracking algorithms were developed to enhance the analysis of the procedure.This is a part of the contributions to user interface design in the aspect of visual transparency.The development and testing of human computer interaction uses and application is more easily investigated than ever,part of the contribution to this is the embedding of 3-D gaze point on a 3-D visual field.This could be used in a number of applications,for instance in medical applications that includes long and short sightedness diagnosis and treatment.Experiments and Test were conducted on five different episodes of user attributes,result show that fixation points and pupil changes are the two most likely user attributes that contributes most significantly in the performance of the custom eye tracking algorithm the study.As the advancement in development of eye movement algorithm continues user attributes that showed the least likely appearance will prove to be redundant.
基金This work was financially supported by the National Natural Science Foundation of China(Grant Nos.51805240 and 51991373)the Natural Science Foundation of Hunan Province(Grant No.2019JJ50518)The authors are also grateful for the assistance from Shiyanjia Lab(https://www.shiyanjia.com)on XPS analysis.
文摘Mechanochemical reactions of the GaN-Al_(2)O_(3) interface offer a novel principle for scientific and technological merits in the micro-/nano-scale ultra-precision surface machining.In this work,the mechanochemical reactions on Ga-and N-faced GaN surfaces rubbed by the Al_(2)O_(3) nanoasperity as a function of the environmental humidity were investigated.Experimental results indicate that the N-face exhibits much stronger mechanochemical removal over the relative humidity range of 20%-80%than the Ga-face.Increasing water molecules in environmental conditions significantly promotes the interfacial mechanochemical reactions and hence accelerates the atomic attrition on N-face.The hypothesized mechanism of the selective water-involved mechanochemical removal is associated with the dangling bond configuration,which affects the mechanically-stimulated chemical reactions via altering the activation energy barrier to form the bonding bridge across the sliding interface.These findings can enrich the understanding of the underlying mechanism of mechanochemical reactions at GaN-Al_(2)O_(3) interface and a broad cognition for regulating the mechanochemical reactions widely existing in scientific and engineering applications.
文摘Interacting with digital contents in 3 D is an essential task in various applications such as modeling packages, gaming, virtual reality, etc. Traditional interfaces using keyboard and mouse or trackball usually require a non-trivial amount of working space as well as a learning process. We present the design of EZ-Manipulator, a new 3 D manipulation interface using smartphones that supports mobile, fast, and ambiguity-free interaction with 3 D objects. Our system leverages the built-in multi-touch input and gyroscope sensor of smartphones to achieve 9 degrees-of-freedom axis-constrained manipulation and free-form rotation.Using EZ-Manipulator to manipulate objects in 3 D is easy. The user merely has to perform intuitive singleor two-finger gestures and rotate the hand-held device to perform manipulations at fine-grained and coarse levels respectively. We further investigate the ambiguity in manipulation introduced by indirect manipulations using a multi-touch interface, and propose a dynamic virtual camera adjustment to effectively resolve the ambiguity. A preliminary study shows that our system has significant lower task completion time compared to conventional use of a keyboard–mouse interface, and provides a positive user experience to both novices and experts.
基金supported by the Special Project on High-performance Computing under the National Key R&D Program(No.2016YFB0200604)National Natural Science Foundation of China(11971502,11571385)Guangdong Natural Science Foundation(2017A030313017).
文摘In this paper,a fairly simple 3D immersed interface method based on the CG-Uzawa type method and the level set representation of the interface is employed for solving three-dimensional Stokes flow with singular forces along the interface.The method is to apply the Taylor’s expansions only along the normal direction and incorporate the jump conditions up to the second normal derivatives into the finite difference schemes.A second order geometric iteration algorithm is employed for computing orthogonal projections on the surface with third-order accuracy.The Stokes equations are discretized involving the correction terms on staggered grids and then solved by the conjugate gradient Uzawa type method.The major advantages of the present method are the special simplicity,the ability in handling the Dirichlet boundary conditions,and no need of the pressure boundary condition.The method can also preserve the volume conservation and the discrete divergence free condition very well.The numerical results show that the proposed method is second order accurate and efficient.
基金financially supported by the National Key R&D Program of China (2021YFA1500800)the National Natural Science Foundation of China (52072377,and 51825204)+2 种基金the Youth Innovation Promotion Association of the Chinese Academy of Sciences (2020192)the CAS Projects for Young Scientists in Basic Research (YSBR-004)the financial support from the New Cornerstone Science Foundation through the XPLORER PRIZE。
文摘光电极通常由半导体吸光层和导电集流体两部分组成,两者间的界面电子结构直接影响导电集流体从半导体光吸收层中收集光生电荷的效率,尤其对于具有3D界面结构的液态金属镶嵌半导体颗粒的光电极.为此,本工作通过改变金属组分改变液态金属的功函数,从而调节导电集流体与半导体吸光材料间3D界面的电子能带排列和接触类型,促进光生电荷的跨界面转移与收集,提升光电极的光电化学分解水活性.系统研究半导体与液态金属的功函数匹配关系发现,将ZnO颗粒嵌入铟锡(IT)低温液态金属中,会形成欧姆接触;而将其嵌入铋铟锡(BIT)低温液态金属中,则会形成肖特基接触.由于欧姆接触不存在肖特基接触的界面能垒而有利于光生电荷的跨界面转移与收集,因此,与铟锡低温液态金属镶嵌ZnO颗粒的光电极(IT/ZnO)相比铋铟锡低温液态金属镶嵌ZnO颗粒的光电极(BIT/ZnO)具有更为优异的电荷收集和分离能力,其光电化学分解水光电流密度可达0.62 mA cm^(-2),相比BIT/ZnO光电极的光电流密度(0.52 mA cm^(-2))提升了约19%,且在已报道的代表性ZnO光电极中处于前列.而与之相比,WO3、TiO_(2)或Cu2O因分别与IT和BIT形成相同的欧姆或肖特基型接触,两种低温液态金属镶嵌的WO3、TiO_(2)或Cu2O光电极具有几乎相同的光电催化活性.本工作展示了通过选择具有不同功函数的液态金属来改变金属/半导体接触类型以增强低温液态金属镶嵌半导体光电极性能的潜力,为规模化构建高效光电极提供了新的策略.
基金supported by the Japam Society for the Promotion of Science(JSPS)KAKENHI(Nos.25420232 and 16K06203)
文摘In this paper, a vibration motion control is proposed and implemented on a foamed polystyrene machining robot to suppress the generation of undesirable cusp marks, and the basic performance of the controller is verified through machining experiments of foamed polystyrene. Then, a 3 dimensional (3D) printer-like data interface is proposed for the machining robot. The 3D data inter- face enables to control the machining robot directly using stereolithography (STL) data without conducting any computer-aided man- ufacturing (CAM) process. This is done by developing a robotic preprocessor that helps to remove the need for the conventional CAM process by directly converting the STL data into cutter location source data called cutter location (CL) or cutter location source (CLS) data. The STL is a file format proposed by 3D systems, and recently is supported by many computer aided design (CAD)/CAM soft- waxes. The STL is widely used for rapid prototyping with a 3D printer which is a typical additive manufacturing system. The STL deals with a triangular representation of a curved surface geometry. The developed 3D printer-like data interface allows to directly control the machining robot through a zigzag path, rectangular spiral path and circular spiral path generated according to the information included in STL data. The effectiveness and usefulness of the developed system are demonstrated through actual machining experiments.
基金supported by the Guangdong Major Project of Basic and Applied Basic Research(No.2020B0301030006)the financial support from the open research fund of Songshan Lake Materials Laboratory(2021SLABFK06)and start-up funding from Harbin Institute of Technology(Shenzhen).
文摘The interfaces between in-situ Al3Ti particles and magnesium(Mg)matrix are crucial role in highperformance titanium(Ti)reinforced AZ31 alloy.Herein,the interfaces between Al3Ti particles and the Mg matrix are fabricated and investigated using advanced characterization tools and first-principles calculations.The orientation relationship(OR)and atomic interface structure between the Al_(3)Ti particles and matrix are characterized using a high-resolution transmission electron microscope.The OR is determined to be(1010)Mg//(001)Al3Ti;[1213]Mg//[100]Al3Ti.Based on the characterized OR,the interface properties(including atomic structure,work of adhesion,interface energy,and fracture mechanism)are investigated using first-principles calculations.The relaxed interface structure indicates that the TiAl-terminated bridge site configurations(MT1)and hollow site configurations(HCP1)are unstable and would convert into other bridge site configurations(MT).Furthermore,the work of adhesion and interface energy suggests that Al-terminated hollow site configurations(HCP)and bridge site configurations(MT)are more stable than other configurations.In addition,the calculations of work of fracture show that fracture of the interfaces with Al-MT1,Al-HCP,and TiAl-MT configurations may initiate from bulk Mg interior.The findings may help to understand and tailor the deformation mechanisms and mechanical properties of Ti-reinforced Mg alloys.
基金Supported by the National Natural Science Foundation of China(Nos.51204053,51374067&51674078)Central University Basic R&D Operating Expenses(Nos.N130409005,N130709001&N130209001)
文摘A reaction interface between the aluminum and K_2ZrF_6 during molten salt reaction process was frozen by quenching the mold in water, and the interface structure was analyzed to determine the formation process of Al_3Zr. Results show that a clear conical interface existed between the K_2ZrF_6 and aluminum. A zirconium accumulation layer with the thickness of about 2–3 lm was formed at the aluminum side of the interface. Many initially formed Al_3Zr particles(with the size of 0.4–16 lm) distributed in this layer, most of which located at the interface. The morphology of Al_3Zr particles is closely related with their size. For the size of 0.4–1 lm, the Al_3Zr appeared as globular and ellipsoid shapes. When it grew to the size of 1–2 and 2–16 lm, it exhibited the rule cube shape, and rule cuboids shape, respectively.
基金supported by the National Natural Science Foundation of China(No.61274112)the Natural Science Foundation of Hubei Province(No.2011CDB165)the Scientific Research Program of Huanggang Normal University(No.2012028803)
文摘LaON,LaTiO and LaTiON films are deposited as gate dielectrics by incorporating N or/and Ti into La_2O_3 using the sputtering method to fabricate Ge MOS capacitors,and the electrical properties of the devices are carefully examined.LaON/Ge capacitors exhibit the best interface quality,gate leakage property and device reliability,but a smaller k value(14.9).LaTiO/Ge capacitors exhibit a higher k value(22.7),but a deteriorated interface quality,gate leakage property and device reliability.LaTiON/Ge capacitors exhibit the highest k value(24.6),and a relatively better interface quality(3.1×10^(11) eV^(-1)cm^(-2)),gate leakage property(3.6 × 10^(-3) A/cm^2 at V_g = 1V+V_(fb)) and device reliability.Therefore,LaTiON is more suitable for high performance Ge MOS devices as a gate dielectric than LaON and LaTiO materials.
文摘A new scheme is proposed to model 3D angular motion of a revolving regular object with miniature, low-cost micro electro mechanical systems(MEMS) accelerometers(instead of gyroscope),which is employed in 3D mouse system.To sense 3D angular motion,the static property of MEMS accelerometer,sensitive to gravity acceleration,is exploited.With the three outputs of configured accelerometers,the proposed model is implemented to get the rotary motion of the rigid object.In order to validate the effectiveness of the proposed model,an input device is developed with the configuration of the scheme.Experimental results show that a simulated 3D cube can accurately track the rotation of the input device.The result indicates the feasibility and effectiveness of the proposed model in the 3D mouse system.