The coal-rock interface recognition method based on multi-sensor data fusiontechnique is put forward because of the localization of single type sensor recognition method. Themeasuring theory based on multi-sensor data...The coal-rock interface recognition method based on multi-sensor data fusiontechnique is put forward because of the localization of single type sensor recognition method. Themeasuring theory based on multi-sensor data fusion technique is analyzed, and hereby the testplatform of recognition system is manufactured. The advantage of data fusion with the fuzzy neuralnetwork (FNN) technique has been probed. The two-level FNN is constructed and data fusion is carriedout. The experiments show that in various conditions the method can always acquire a much higherrecognition rate than normal ones.展开更多
A microcalorimetric study on molecular recognition of p-sulfonatocalix[4]arene derivatives at selfassembled interface in comparison with in bulk water was performed,inspired by the dramatic change in physicochemical c...A microcalorimetric study on molecular recognition of p-sulfonatocalix[4]arene derivatives at selfassembled interface in comparison with in bulk water was performed,inspired by the dramatic change in physicochemical characteristics from bulk water to interface.A total of six cationic molecules were screened as model guests,including ammonium（NH_4~＋）,guanidinium（Gdm~＋）.N,N＇-dimethyl-1,4-diazabicyclo[2.2.2]octane（DMDABCO^（2＋））,tropylium（Tpm~＋）,N-methyl pyridinium（N-mPY＊） and methyl viologen（MV^（2＋））.The complexation with NH_4~＋.Gdm~＋ and DMDABCO2＊ is pronouncedly enhanced when the recognition process moved from bulk water to interface,whereas the complexation stabilities with Tpm~＋,N-mPY~＋ and MV2＊ increase slightly or even decrease to some extent.A more interesting phenomenon arises from the NH_4~＋/Gdm~＋ pair that the thermodynamic origin at interface differs definitely from each other although with similar association constants.The results were discussed in terms of differential driving forces,electrostatic,hydrogen bond as well as π-stacking interactions,originating from the unique physicochemical features of interfaces,mainly the polarity and dielectric constant.展开更多
基金This project is supported by Provincial Youth Science Foundation of Shanxi China (No.20011020)National Natural Science Foundation of China (No.59975064).
文摘The coal-rock interface recognition method based on multi-sensor data fusiontechnique is put forward because of the localization of single type sensor recognition method. Themeasuring theory based on multi-sensor data fusion technique is analyzed, and hereby the testplatform of recognition system is manufactured. The advantage of data fusion with the fuzzy neuralnetwork (FNN) technique has been probed. The two-level FNN is constructed and data fusion is carriedout. The experiments show that in various conditions the method can always acquire a much higherrecognition rate than normal ones.
基金supported by NSFC(Nos.21322207 and 21672112)the Fundamental Research Funds for the Central Universities and Program of Tianjin Young Talents
文摘A microcalorimetric study on molecular recognition of p-sulfonatocalix[4]arene derivatives at selfassembled interface in comparison with in bulk water was performed,inspired by the dramatic change in physicochemical characteristics from bulk water to interface.A total of six cationic molecules were screened as model guests,including ammonium（NH_4~＋）,guanidinium（Gdm~＋）.N,N＇-dimethyl-1,4-diazabicyclo[2.2.2]octane（DMDABCO^（2＋））,tropylium（Tpm~＋）,N-methyl pyridinium（N-mPY＊） and methyl viologen（MV^（2＋））.The complexation with NH_4~＋.Gdm~＋ and DMDABCO2＊ is pronouncedly enhanced when the recognition process moved from bulk water to interface,whereas the complexation stabilities with Tpm~＋,N-mPY~＋ and MV2＊ increase slightly or even decrease to some extent.A more interesting phenomenon arises from the NH_4~＋/Gdm~＋ pair that the thermodynamic origin at interface differs definitely from each other although with similar association constants.The results were discussed in terms of differential driving forces,electrostatic,hydrogen bond as well as π-stacking interactions,originating from the unique physicochemical features of interfaces,mainly the polarity and dielectric constant.
