Copper/steel is a typical bimetal functional material,combining the excellent electrical and thermal conductivity of copper alloy and the high strength and hardness of stainless steel.There has been recent interest in...Copper/steel is a typical bimetal functional material,combining the excellent electrical and thermal conductivity of copper alloy and the high strength and hardness of stainless steel.There has been recent interest in manufacturing copper/steel bimetal by directed energy deposition(DED)due to its layer-bylayer method.However,cracks tend to form on the copper/steel interface because of the great difference in thermal expansion coefficient and crystal structure between copper and steel.In this work,interfacial characteristics and mechanical properties of the copper/steel bimetal were studied from one layer to multilayers.The laser power has a great influence on the Cu element distribution of the molten pool,affecting the crack formation dramatically on the solidification stage.Cracks tend to form along columnar grain boundaries because of the Cu-rich liquid films and spherical particles in the cracks.Crack-free and good metallurgical bonding copper/steel interface is formed at a scanning velocity of 800 mm/min and the laser power of 3000 W.The ultimate tensile strength(UTS)and the break elongation(EL)of the vertically combined crack-free copper/steel bimetal are 238.2±4.4 MPa and 20.6±0.7%,respectively.The fracture occurs on the copper side instead of the copper/steel interface,indicating that the bonding strength is higher than that of the Cu-Cr alloy.The UTS of the horizontally combined crack-free copper/steel bimetal is 746.7±22.6 MPa,which is 200%higher than that of the Cu-Cr alloy substrate.The microhardness is 398.6±5.4 HV at the steel side and is 235.3±64.1 HV at the interface,which is400%higher than that of the Cu-Cr alloy substrate.This paper advances the understanding of the interfacial characteristics of heterogeneous materials and provides guidance and reference for the fabrication of multi-material components by DED.展开更多
Laser powder bed fusion(LPBF)is an innovative method for manufacturing multimaterial components with high geometrical resolution.The LPBF-printing sequences of materials may be diverse in the actual design and applica...Laser powder bed fusion(LPBF)is an innovative method for manufacturing multimaterial components with high geometrical resolution.The LPBF-printing sequences of materials may be diverse in the actual design and application of multimaterial components.In this study,multimaterial copper(CuSn10)–steel(316 L)structures are printed using different building strategies(printing 316 L on CuSn10 and printing CuSn10 on 316 L)via LPBF,and the characteristics of two interfaces(the 316 L/CuSn10 or“L/C”and CuSn10/316 L or“C/L”interfaces)are investigated.Subsequently,the interfacial melting mode and formation mechanisms are discussed.At the L/C interface,the keyhole melting mode induced by the high volumetric energy density(EL/C=319.4 J/mm3)results in a large penetration depth in the pre-solidified layer and enhances laser energy absorption,thus promoting the extensive migration of materials and intense intermixing of elements to form a wide diffusion zone(∼400μm).At the C/L interface,the conduction mode induced by the low volumetric energy density(EC/L=74.1 J/mm3)results in a narrow diffusion zone(∼160μm).The interfacial defects observed are primarily cracks and pores.More cracks appeared at the C/L interface,which is attributable to the weak bonding strength of the narrow diffusion zone.This study provides guidance and reference for the design and manufacturing of multimaterial components via LPBF using different building strategies.展开更多
The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully ci...The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully circumvent defects in Ti-6Al-4V deposits for LAAM_(p) and LAAM_(w),respectively.With the optimized process parameters,robust interfaces were achieved between powder/wire deposits and the forged substrate,as well as between powder and wire deposits.Microstructure characterization results revealed the epitaxial prior β grains in the deposited Ti-6Al-4V,wherein the powder deposit was dominated by a finerα′microstructure and the wire deposit was characterized by lamellar α phases.The mechanisms of microstructure formation and correlation with mechanical behavior were analyzed and discussed.The mechanical properties of the interfacial samples can meet the requirements of the relevant Aerospace Material Specifications(AMS 6932)even without post heat treatment.No fracture occurred within the interfacial area,further suggesting the robust interface.The findings of this study highlighted the feasibility of combining LAAM_(p) and LAAM_(w) in the direct manufacturing of Ti-6Al-4V parts in accordance with the required dimensional resolution and deposition rate,together with sound strength and ductility balance in the as-built condition.展开更多
Steel fiber reinforced concrete(SFRC)has drawn extensive attention in recent years for its superior mechanical response to dynamic and impact loadings.Based on the existing test results,the highstrength steel fibers e...Steel fiber reinforced concrete(SFRC)has drawn extensive attention in recent years for its superior mechanical response to dynamic and impact loadings.Based on the existing test results,the highstrength steel fibers embedded in a concrete matrix usually play a strong bridging effect to enhance the bonding force between fiber and the matrix,and directly contribute to the improvement of the post-cracking behavior and residual strength of SFRC.To gain a better understanding of the action behavior of steel fibers in matrix and further capture the failure mechanism of SFRC under dynamic loads,the mesoscopic modeling approach that assumes SFRC to be composed of different mesoscale phases(i.e.,steel fibers,coarse aggregates,mortar matrix,and interfacial transition zone(ITZ))has been widely employed to simulate the dynamic responses of SFRC material and structural members.This paper presents a comprehensive review of the state-of-the-art mesoscopic models and simulations for SFRC under dynamic loading.Generation approaches for the SFRC mesoscale model in the simulation works,including steel fiber,coarse aggregate,and the ITZ between them,are reviewed and compared systematically.The material models for different phases and the interaction relationship between fiber and concrete matrix are summarized comprehensively.Additionally,some example applications for SFRC under dynamic loads(i.e.,compression,tension,and contact blast)simulated using the general mesoscale models are given.Finally,some critical analysis on the current shortcomings of the mesoscale modeling of SFRC is highlighted,which is of great significance for the future investigation and development of SFRC.展开更多
The effect of N_(2)-plasma-treated SiO_(2) interfacial layer on the interfacial and electrical characteristics of HfO_(2)/SiO_(2)/p-Si stacks grown by atomic layer deposition(ALD) was investigated.The microstructure a...The effect of N_(2)-plasma-treated SiO_(2) interfacial layer on the interfacial and electrical characteristics of HfO_(2)/SiO_(2)/p-Si stacks grown by atomic layer deposition(ALD) was investigated.The microstructure and interfacial chemical bonding configuration of the HfO_(2)/SiO_(2)/Si stacks were also examined by high-resolution transmission electron microscopy(HRTEM) and X-ray photoelectron spectroscopy(XPS).Compared with the samples without N2-plasma treatment,it is found that the samples with N2-plasma treatment have less oxygen vacancy density for SiO_(2) interfacial layer and better HfO_(2)/SiO_(2) interface.In agreement with XPS analyses,electrical measurements of the samples with N2-plasma treatment show better interfacial quality,including lower interface-state density(Dit,9.3 × 1011 cm^(-2)·eV^(-1) near midgap) and lower oxidecharge density(Q_(ox),2.5 × 1012 cm^(-2)),than those of the samples without N_(2)-plasma treatment.Additionally,the samples with N_(2)-plasma treatment have better electrical performances,including higher saturation capacitance density(1.49 μF·cm^(-2)) and lower leakage current density(3.2 × 10^(-6) A·cm^(-2) at V_(g)=V_(fb)-1 V).Furthermore,constant voltage stress was applied on the gate electrode to investigate the reliability of these samples.It shows that the samples with N_(2)-plasma treatment have better electrical stability than the samples without N_(2)-plasma treatment.展开更多
By analyzing the grille mechanical property, tensile strength and creep tests, and the fi eld tests, we investigated the characteristics and the reinforcement principle of multidirectional geogrid, and obtained the ef...By analyzing the grille mechanical property, tensile strength and creep tests, and the fi eld tests, we investigated the characteristics and the reinforcement principle of multidirectional geogrid, and obtained the effect factors of grid characteristics, load and time curve and the shear stress of grille and sand interface. The reinforcement effect of geogrid in combination of typical project cases was illustrated and the following conclusions were presented. Firstly, multidirectional geogrid has ability to resist structural deformation, node distortion or soil slippage under stress, and can effectively disperse load. Secondly, with the increase of tensile rate, grille intensity increases and the creep value also increases with the increase of load. Thirdly, the frictional resistance balance between horizontal thrust of damaged zone and reinforced soil in stable region can avoid slope failure due to excessive lateral deformation. Fourthly, the multidirectional geogrid is able to withstand the vertical, horizontal and diagonal forces by combing them well with three-dimensional orientation, realizing the purpose of preventing soil erosion and slope reinforcement, which has a wide range of application and development in engineering fi eld.展开更多
基金supported by the Human Spaceflight Program of China(D050302)the Military Industry Stability Support project(2019KGW.YY4007Tm)。
文摘Copper/steel is a typical bimetal functional material,combining the excellent electrical and thermal conductivity of copper alloy and the high strength and hardness of stainless steel.There has been recent interest in manufacturing copper/steel bimetal by directed energy deposition(DED)due to its layer-bylayer method.However,cracks tend to form on the copper/steel interface because of the great difference in thermal expansion coefficient and crystal structure between copper and steel.In this work,interfacial characteristics and mechanical properties of the copper/steel bimetal were studied from one layer to multilayers.The laser power has a great influence on the Cu element distribution of the molten pool,affecting the crack formation dramatically on the solidification stage.Cracks tend to form along columnar grain boundaries because of the Cu-rich liquid films and spherical particles in the cracks.Crack-free and good metallurgical bonding copper/steel interface is formed at a scanning velocity of 800 mm/min and the laser power of 3000 W.The ultimate tensile strength(UTS)and the break elongation(EL)of the vertically combined crack-free copper/steel bimetal are 238.2±4.4 MPa and 20.6±0.7%,respectively.The fracture occurs on the copper side instead of the copper/steel interface,indicating that the bonding strength is higher than that of the Cu-Cr alloy.The UTS of the horizontally combined crack-free copper/steel bimetal is 746.7±22.6 MPa,which is 200%higher than that of the Cu-Cr alloy substrate.The microhardness is 398.6±5.4 HV at the steel side and is 235.3±64.1 HV at the interface,which is400%higher than that of the Cu-Cr alloy substrate.This paper advances the understanding of the interfacial characteristics of heterogeneous materials and provides guidance and reference for the fabrication of multi-material components by DED.
基金Guangdong Provincial Basic and Applied Basic Research Foundation of China(Grant Nos.2019B1515120094,2022B1515020064)National Natural Science Foundation of China(Grant No.52073105)Guangdong Provincial Key Field Research and Development Program of China(Grant No.2020B090922002).
文摘Laser powder bed fusion(LPBF)is an innovative method for manufacturing multimaterial components with high geometrical resolution.The LPBF-printing sequences of materials may be diverse in the actual design and application of multimaterial components.In this study,multimaterial copper(CuSn10)–steel(316 L)structures are printed using different building strategies(printing 316 L on CuSn10 and printing CuSn10 on 316 L)via LPBF,and the characteristics of two interfaces(the 316 L/CuSn10 or“L/C”and CuSn10/316 L or“C/L”interfaces)are investigated.Subsequently,the interfacial melting mode and formation mechanisms are discussed.At the L/C interface,the keyhole melting mode induced by the high volumetric energy density(EL/C=319.4 J/mm3)results in a large penetration depth in the pre-solidified layer and enhances laser energy absorption,thus promoting the extensive migration of materials and intense intermixing of elements to form a wide diffusion zone(∼400μm).At the C/L interface,the conduction mode induced by the low volumetric energy density(EC/L=74.1 J/mm3)results in a narrow diffusion zone(∼160μm).The interfacial defects observed are primarily cracks and pores.More cracks appeared at the C/L interface,which is attributable to the weak bonding strength of the narrow diffusion zone.This study provides guidance and reference for the design and manufacturing of multimaterial components via LPBF using different building strategies.
基金financially supported by the Agency for Science,Technology and Research(A*Star),Republic of Singapore,under the Aerospace Consortium Cycle 12“Characterization of the Effect of Wire and Powder Deposited Materials”(No.A1815a0078)。
文摘The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully circumvent defects in Ti-6Al-4V deposits for LAAM_(p) and LAAM_(w),respectively.With the optimized process parameters,robust interfaces were achieved between powder/wire deposits and the forged substrate,as well as between powder and wire deposits.Microstructure characterization results revealed the epitaxial prior β grains in the deposited Ti-6Al-4V,wherein the powder deposit was dominated by a finerα′microstructure and the wire deposit was characterized by lamellar α phases.The mechanisms of microstructure formation and correlation with mechanical behavior were analyzed and discussed.The mechanical properties of the interfacial samples can meet the requirements of the relevant Aerospace Material Specifications(AMS 6932)even without post heat treatment.No fracture occurred within the interfacial area,further suggesting the robust interface.The findings of this study highlighted the feasibility of combining LAAM_(p) and LAAM_(w) in the direct manufacturing of Ti-6Al-4V parts in accordance with the required dimensional resolution and deposition rate,together with sound strength and ductility balance in the as-built condition.
基金the financial support from the National Natural Science Foundation of China(52178190 and 52078250)the Science and Technology on Near-Surface Detection Laboratory(6142414200505)+1 种基金the Interdisciplinary Innovation Fundation for Graduates,Nanjing University of Aeronautics and Astronautics(KXKCXJJ202005)The support provided by the China Scholarship Council(202006830096)during a visit of Zhangyu Wu to University College London。
文摘Steel fiber reinforced concrete(SFRC)has drawn extensive attention in recent years for its superior mechanical response to dynamic and impact loadings.Based on the existing test results,the highstrength steel fibers embedded in a concrete matrix usually play a strong bridging effect to enhance the bonding force between fiber and the matrix,and directly contribute to the improvement of the post-cracking behavior and residual strength of SFRC.To gain a better understanding of the action behavior of steel fibers in matrix and further capture the failure mechanism of SFRC under dynamic loads,the mesoscopic modeling approach that assumes SFRC to be composed of different mesoscale phases(i.e.,steel fibers,coarse aggregates,mortar matrix,and interfacial transition zone(ITZ))has been widely employed to simulate the dynamic responses of SFRC material and structural members.This paper presents a comprehensive review of the state-of-the-art mesoscopic models and simulations for SFRC under dynamic loading.Generation approaches for the SFRC mesoscale model in the simulation works,including steel fiber,coarse aggregate,and the ITZ between them,are reviewed and compared systematically.The material models for different phases and the interaction relationship between fiber and concrete matrix are summarized comprehensively.Additionally,some example applications for SFRC under dynamic loads(i.e.,compression,tension,and contact blast)simulated using the general mesoscale models are given.Finally,some critical analysis on the current shortcomings of the mesoscale modeling of SFRC is highlighted,which is of great significance for the future investigation and development of SFRC.
基金financially supported by the National Science and Technology Major Project of China (No. 2013ZX02303-001-002)。
文摘The effect of N_(2)-plasma-treated SiO_(2) interfacial layer on the interfacial and electrical characteristics of HfO_(2)/SiO_(2)/p-Si stacks grown by atomic layer deposition(ALD) was investigated.The microstructure and interfacial chemical bonding configuration of the HfO_(2)/SiO_(2)/Si stacks were also examined by high-resolution transmission electron microscopy(HRTEM) and X-ray photoelectron spectroscopy(XPS).Compared with the samples without N2-plasma treatment,it is found that the samples with N2-plasma treatment have less oxygen vacancy density for SiO_(2) interfacial layer and better HfO_(2)/SiO_(2) interface.In agreement with XPS analyses,electrical measurements of the samples with N2-plasma treatment show better interfacial quality,including lower interface-state density(Dit,9.3 × 1011 cm^(-2)·eV^(-1) near midgap) and lower oxidecharge density(Q_(ox),2.5 × 1012 cm^(-2)),than those of the samples without N_(2)-plasma treatment.Additionally,the samples with N_(2)-plasma treatment have better electrical performances,including higher saturation capacitance density(1.49 μF·cm^(-2)) and lower leakage current density(3.2 × 10^(-6) A·cm^(-2) at V_(g)=V_(fb)-1 V).Furthermore,constant voltage stress was applied on the gate electrode to investigate the reliability of these samples.It shows that the samples with N_(2)-plasma treatment have better electrical stability than the samples without N_(2)-plasma treatment.
基金Funded by the National Natural Science Foundation of China(41372289)the Shandong Province Higher Educational Science and Technology Program(12LH03)+1 种基金the China's Post-doctoral Science Fund(2012M521365)the SDUST Research Fund
文摘By analyzing the grille mechanical property, tensile strength and creep tests, and the fi eld tests, we investigated the characteristics and the reinforcement principle of multidirectional geogrid, and obtained the effect factors of grid characteristics, load and time curve and the shear stress of grille and sand interface. The reinforcement effect of geogrid in combination of typical project cases was illustrated and the following conclusions were presented. Firstly, multidirectional geogrid has ability to resist structural deformation, node distortion or soil slippage under stress, and can effectively disperse load. Secondly, with the increase of tensile rate, grille intensity increases and the creep value also increases with the increase of load. Thirdly, the frictional resistance balance between horizontal thrust of damaged zone and reinforced soil in stable region can avoid slope failure due to excessive lateral deformation. Fourthly, the multidirectional geogrid is able to withstand the vertical, horizontal and diagonal forces by combing them well with three-dimensional orientation, realizing the purpose of preventing soil erosion and slope reinforcement, which has a wide range of application and development in engineering fi eld.