Freshening of the Intermediate Waters in the Northern South China Sea over the Past Six Decades

The properties of salinity in the South China Sea(SCS),a significant marginal sea connecting the Pacific and Indian Oceans,are greatly influenced by the transport of fresh water flux between the two oceans.However,the long-term changes in the intermediate water in the SCS have not been thoroughly studied due to limited data,particularly in relation to its thermodynamic variations.This study utilized reanalysis data products to identify a 60-year trend of freshening in the intermediate waters of the northern South China Sea(NSCS),accompanied by an expansion of low-salinity water.The study also constructed salinity budget terms,including advection and entrainment processes,and conducted an analysis of the salinity budget to understand the impacts of external and internal dynamic processes on the freshening trend of the intermediate water in the NSCS.The analysis revealed that the freshening in the northwest Pacific Ocean and the intensification of intrusion through the Luzon Strait at intermediate levels are the primary drivers of the salinity changes in the NSCS.Additionally,a weakened trend in the intensity of vertical entrainment also contributes to the freshening in the NSCS.This study offers new insights into the understanding of regional deep sea changes in response to variations in both thermodynamics and oceanic dynamic processes.

Origins and pathways of the subsurface and intermediate water masses of the Indonesian Throughflow derived from historical and Argo data

On the basis of Argo data and historic temperature/salinity data from the World Ocean Database 2001 （ WOD01 ）, origins and spreading pathways of the subsurface and intermediate water masses in the Indonesian Throughflow （ITF） region were discussed by analyzing distributions of salinity on representative isopyenal layers. Results were shown that, subsurface water mostly comes from the North Pacific Ocean while the intermediate water originates from both the North and South Pacific Ocean, even possibly from the Indian Ocean. Spreading through the Sulawesi Sea, the Makassar Strait, and file Flores Sea, the North Pacific subsurface water and the North Pacific Intermediate water dominate the western part of the Indonesian Archipelago. Furthermore as the depth increases, the features of the North Pacific sourced water masses become more obvious. In the eastern part of the waters, high sa- linity South Pacific subsurface water is blocked by a strong salinity front between Halmahera and New Guinea. Intermediate water in the eastern interior region owns salinity higher than the North Pacific intermediate water and the antarctic intermediate water （ AAIW）, possibly coming from the vertical mixing between subsurface water and the AAIW from the Pacific Ocean, and possibly coming from the northward extending of the AAIW from the Indian Ocean as well.

Warming and depth convergence of the Arctic Intermediate Water in the Canada Basin during 1985–2006

The warming of the Arctic Intermediate Water （AIW） is studied based on the analyses of hydro- graphic observations in the Canada Basin of the Arctic Ocean during 1985-2006. It is shown that how the anomalously warm AIW spreads in the Canada Basin during the observation time through the analysis of the AIW temperature spatial distribution in different periods. The results indicate that by 2006, the entire Canada Basin has almost been covered by the warming AIW. In order to study interannual variability of the AIW in the Canada Basin, the Canada Basin is divided into five regions according to the bottom topography. From the interannual variation of AIW temperature in each region, it is shown that a cooling period follows after the warming event in upstream regions. At the Chukchi Abyssal Plain and Chukchi Plateau, upstream of the Arctic Circumpolar Boundary Current （ACBC） in the Canada Basin, the AIW temperature reached maximum and then started to fall respectively in 2000 and 2002. However, the AIW in the Canada Abyssal Plain and Beaufort Sea continues to warm monotonically until the year 2006. Furthermore, it is revealed that there is convergence of the AIW depth in the five different regions of the Canada Basin when the AIW warming occurs during observation time. The difference of AIW depth between the five regions of the Canada Basin is getting smaller and smaller, all approaching 410 m in recent years. The results show that depth convergence is related to the variation of AIW potential density in the Canada Basin.

The intermediate water in the Philippine Sea

The dimensional and temporal distribution of Antarctic Intermediate Water(AAIW)and North Pacifi c Intermediate Water(NPIW)in the Philippine Sea were explored using Argo profi les and gridded Argo data.As the salinity minimum of intermediate water from mid-high latitude of the southern and northern hemisphere of the Pacifi c Ocean,the properties of AAIW and NPIW merge at about 10°N with diff erent properties in the Philippine Sea.The core of AAIW is located below 600 dbar with potential density of 27≤σθ≤27.3 kg/m 3 and salinity of 34.5≤S≤34.55.The core of NPIW is located between 300–700 dbar with potential density of 26.2≤σθ≤27 kg/m 3 and salinity of 34≤S≤34.4.The volume of AAIW and NPIW during January 2004 to December 2017 is negatively correlated.The time series of AAIW and NPIW is dominated by signifi cant periods of 6 and 8 months,respectively.The variations of AAIW and NPIW are mainly aff ected by volume transport through a 130°E section by the North Equatorial Current(NEC)and North Equatorial Undercurrent(NEUC).

Freshening of the intermediate water of the South China Sea between the 1960s and the 1980s

Variation in intermediate water salinity in the South China Sea (SCS) between the 1960s and 1980s was studied using historical hydrographic data. The results demonstrate that the water was significantly fresher in the 1980s than in the 1960s, indicating that vertical mixing at intermediate water depth was reduced in the 1980s. This was partially because of the change of the SCS meridional overturning circulation (MOC) connecting local intermediate water with deep water. Data assimilation showed a 0.5Sv (1 Sv=10 6m 3/s) reduction in the strength of the MOC, which is about one third of the mean SCS MOC. Because the SCS MOC is linked to the Pacific Ocean, such an interdecadal variation in the intermediate water SCS may reflect anthropogenic climate change in the world ocean.

The destiny of the North Pacific Intermediate Water in the South China Sea

The previous studies show that the spreading path of the subtropical salinity minimum of the North Pacific Intermediate Water （NPIW） is southwestward pointing to the Luzon Strait. Based on the P -vector method and generalized digital environmental model （GDEM） data, the volume transport of NPIW through Luzon Strait and the upward transport on the NPIW lower and upper boundaries are calculated to examine the destiny of NPIW in the South China Sea （SCS）. On the annual mean, the estimation of NPIW transport into the SCS through the Luzon Strait is 1.72 Sv （1Sv=10 6 m 3 /s）. The upward transport over the SCS is 0.31 Sv on the NPIW upper boundary and 1.31 Sv on the NPIW lower boundary. There is no strait or passage deeper than the surface for the NPIW to extend, except for the Luzon Strait. For the volume balance in the SCS NPIW, the volume transport of 2.72 Sv has to flow out of the SCS NPIW layer through the Luzon Strait.

Modeling Arctic Intermediate Water: The effects of Neptune parameterization and horizontal resolution

Arctic Intermediate Water （AIW）, advected from the North Atlantic Ocean, has a potential influence on climate in the Arctic region, but is poorly simulated in coarse resolution models. In this study, a coupled ice-ocean model is used to investigate features of AIW by conducting two sensitivity experiments based on Neptune parameterization and horizontal resolution. The re- suits show that both experiments improve the modeling of temperature profiles in the western Eurasian Basin, mainly as a result of more realistic volume and heat transport through the Fram Strait. Topographical flows are well reproduced using Neptune parame- terization or a finer horizontal resolution. In the eddy-permitting model with relatively higher resolution, the velocity field is more realistic than in the Neptune parameterization model, and complex inflow and outflow belts of barotropic structure are well repro- duced. The findings of this study suggest that increased model resolution, as provided by an eddy-resolving model, is needed to reproduce realistic circulation and thermohaline structure in the Arctic, since the Rossby radius of deformation is only several kilometers in the Arctic Ocean. This paper focuses on the external heat input rather than internal mixing process, and obtains a conclusion that the heat input from the Fram Strait is a main factor to reproduce AIW in the Eurasian Basin successfully, at least for the western part.

An evaluation of the simulations of the Arctic Intermediate Water in climate models and reanalyses

The simulations of the Arctic Intermediate Water in four datasets of climate models and reanalyses, CCSM3, CCSM4, SODA and GLORYS, are analyzed and evaluated. The climatological core temperatures and depths in both CCSM models exhibit deviations over 0.5°C and 200 m from the PHC. SODA reanalysis reproduces relatively reasonable spatial patterns of core temperature and depth, while GLORYS, another reanalysis, shows a remarkable cooling and deepening drift compared with the result at the beginning of the dataset especially in the Eurasian Basin （about 2°C）. The heat contents at the depth of intermediate water in the CCSM models are overestimated with large positive errors nearly twice of that in the PHC. To the contrary, the GLORYS in 2009 show a negative error with a similar magnitude, which means the characteristic of the water mass is totally lost. The circulations in the two reanalyses at the depth of intermediate water are more energetic and realistic than those in the CCSMs, which is attributed to the horizontal eddy-permitting reso-lution. The velocity fields and the transports in the Fram Strait are also investigated. The necessity of finer horizontal resolution is concluded again. The northward volume transports are much larger in the two re-analyses, although they are still weak comparing with mooring observations. Finally, an investigation of the impact of assimilation is done with an evidence of the heat input from assimilation. It is thought to be a reason for the good performance in the SODA, while the GLORYS drifts dramatically without assimilation data in the Arctic Ocean.

Monte Carlo Simulation-based Decision-making Model for the Water Conservation and Intermediate Water Recycling of Conservationminded Buildings

Through analyzing the life cycle cost of the water conservation and intermediate water application project of conservation-minded buildings,net present value(NPV) was applied as the index to establish the life cycle economic decision-making model.Monte Carlo simulation was used in demonstration cases,modeling analysis of water-saving projects in conservation-minded and traditional buildings verified rationality and practicability of this model and simulation method.It was to provide a referential and operable method for the decision-making of conservation-minded construction projects,as well as a scientific approach and theoretic basis for the precise decision-making of government organs,decision-making departments and developers.

Manipulating the spin configuration by topochemical transformation for optimized intermediates adsorption ability in oxygen evolution reaction

The underlying spin-related mechanism remains unclear,and the rational manipulation of spin states is challenging due to various spin configurations under different coordination conditions.Therefore,it is urgent to study spin-dependent oxygen evolution reaction(OER)performance through a controllable method.Herein,we adopt a topochemical reaction method to synthesize a series of selenides with eg occupancies ranging from 1.67 to 1.37.The process begins with monoclinic-CoSeO_(3),featuring a distinct laminar structure and Co-O6 coordination.The topochemical reaction induces significant changes in the crystal field's intensity,leading to spin state transitions.These transitions are driven by topological changes from a Co-O-Se-O-Co to a Co-Se-Co configuration,strengthening the crystalline field and reducing eg orbital occupancy.This reconfiguration of spin states shifts the rate-determining step from desorption to adsorption for both OER and the hydrogen evolution reaction(HER),reducing the potential-determined step barrier and enhancing overall catalytic efficiency.As a result,the synthesized cobalt selenide exhibits significantly enhanced adsorption capabilities.The material demonstrates impressive overpotentials of 35 mV for HER,250 mV for OER,and 270 mV for overall water splitting,indicating superior catalytic activity and efficiency.Additionally,a negative relation between eg filling and OER catalytic performance confirms the spin-dependent nature of OER.Our findings provide crucial insights into the role of spin state transitions in catalytic performance.

A preliminary study on the intermediate water masses in the tropical West Pacific

Based on the CTD data of China's first WOCE cruise in winter of 1991, and those of the first and second Chinese TOGA cruises in the winters of 1985 and 1986, we apply the classical method of T-S diagram analysis to identify intermediate water masses in the tropical West Pacific and study their distribution feature. Results of these analyses show that there are mainly two kinds of intermediate water masses, namely, the mouth Pacific intermediate Water (SPIW) and the North Pacific intermediate Water (NPIW) in the tropical West Pacific. The NPIW extends from north to south with its southern boundary generally at about 8° N. However, it is westwards intensified near the coast of Mindanao Island where it extends further south to about 5° N with more distinctive characteristics of low salinity and low temperature. The SPIW extends from south to north with its northern boundary at about 12° N. In the zonal area between 0° and 4° N various intermediate waters interact. The analysis also shows the existence of interannual variations of NPIW in the tropical West Pacific.

Formation and transport of intermediate water masses in a model of the Pacific Ocean

A basin-wide ocean general circulation model of the Pacific Ocean was used to investigate how the interior restoration in the Okhotsk Sea and the isopycnal diffusion affect the circulation and intermediate water masses. Four numerical experiments were conducted, including a run with the same isopycnal and thickness diffusivity of 1.0×10^3 m2/s, a run employing the interior restoration of temperature and salinity in the Okhotsk Sea with a time scale of 3 months, a run that is the same as the first run except for the enhanced isopycnal mixing, and a final run with the combination of the restoration in the Okhotsk Sea and large isopycnal diffusivity. Simulated results show that the intermediate water masses reproduced in the first run are relatively weak. An increase in isopycnal diffusivity can improve the simulation of both Antarctic and North Pacific intermediate waters, mainly increasing the transport in the interior ocean, but inhibiting the outflow from the Okhotsk Sea. The interior restoration generates the reverse current from the observation in the Okhotsk Sea, whereas the simulation of the temperature and salinity is improved in the high latitude region of the Northern Hemisphere because of the reasonable source of the North Pacific Intermediate Water. A comparison of vertical profiles of temperature and salinity along 50°N between the simulation and observations demonstrates that the vertical mixing in the source region of intermediate water masses is very important.

Mesoscale characteristics of Antarctic Intermediate Water in the South Pacific

The Argo float observations are used to investigate the mesoscale characteristics of the Antarctic Intermediate Water （AAIW） in the South Pacific in this paper. It is shown that a subsurface mesoscale phenomenon is probably touched by an Argo float during the float＇s ascent-descent cycles and is identified by the horizontal salinity gradient between the vertical temperature-salinity profiles. This shows that the transportation of the AAIW may be accompanied with the rich mesoscale characteristics. To derive the spatial length, time, and propagation characteristics of the mesoscale variability of the AAIW, the gridded temperature-salinity dataset ENACT/ENSEMBLE Version 3 constructed on the in-situ observations in the South Pacific since 2005 is used. The Empirical Mode Decomposition method is applied to decompose the isopycnal-averaged salinity anomaly from 26.8 cr0-27.4 ao, where the AAIW mainly resides, into the basin scale and two mesoscale modes. It is found that the first mesoscale mode with the length scale on the order of 1 000 km explains nearly 50% variability of the mesoscale characteristics of the AAIW. Its westward-propagation speeds are slower in the mid-latitude （around 1 cm/s） and faster in the low latitude （around 6 cm/s）, but with an increasing in the latitude band on 25^-30~S. The second mesoscale mode is of the length scale on the order of 500 km, explaining about 30% variability of the mesoscale characteristics of the AAIW. Its westward-propagation speed keeps nearly unchanged （around 0.5 cm/s）. These results presented the stronger turbulent motion of the subsurface ocean on the spatial scale, and also described the significant role of Argo program for the better understanding of the deep ocean.

The Preparation of 2-O-Acetonyl-β-cyclodextrin as One Key Intermediate for Water Soluble β-Cyclodextrin Derivatives

O-Acetonyl-b-cyclodextrin with a suitable average substitution degree of about 5.8, which could be used as a key intermediate for water soluble functional b-cyclodextrin derivatives, was prepared based on the proper oxidation of heptakis (6-O-dimethyl-tert-butylsilyl)-2-O -hydroxypropyl-b-cyclodextrin.

Pacific-Indian interocean circulation of the Antarctic Intermediate Water around South Australia

On the basis of the salinity distribution of isopycnal（σ_0=27.2 kg/m^3） surface and in salinity minimum, the Antarctic Intermediate Water（AAIW） around South Australia can be classified into five types corresponding to five regions by using in situ CTD observations. Type 1 is the Tasman AAIW, which has consistent hydrographic properties in the South Coral Sea and the North Tasman Sea. Type 2 is the Southern Ocean（SO） AAIW, parallel to and extending from the Subantarctic Front with the freshest and coldest AAIW in the study area. Type 3 is a transition between Type 1 and Type 2. The AAIW transforms from fresh to saline with the latitude declining（equatorward）. Type 4, the South Australia AAIW, has relatively uniform AAIW properties due to the semienclosed South Australia Basin. Type 5, the Southeast Indian AAIW, progressively becomes more saline through mixing with the subtropical Indian intermediate water from south to north. In addition to the above hydrographic analysis of AAIW, the newest trajectories of Argo（Array for real-time Geostrophic Oceanography） floats were used to constructed the intermediate（1 000 m water depth） current field, which show the major interocean circulation of AAIW in the study area. Finally, a refined schematic of intermediate circulation shows that several currents get together to complete the connection between the Pacific Ocean and the Indian Ocean. They include the South Equatorial Current and the East Australia Current in the Southwest Pacific Ocean, the Tasman Leakage and the Flinders Current in the South Australia Basin, and the extension of Flinders Current in the southeast Indian Ocean.

On Physical and Mechanical Behavior of Natural Marine Intermediate Deposits

Coastal structures may be built on natural sedimentary intermediate grounds, which mainly consist of silty soils and fine sandy soils. In this study, extensive field and laboratory tests were performed on the natural marine intermediate deposits to demonstrate the difference in behavior between natural marine clayey soils and natural marine intermediate deposits. The natural intermediate deposits have almost the same ratios of natural water content to liquid limit as those of the soft natural marine clays, but the former have much higher in-situ strength and sensitivity than the latter. The research results indicate that grain size distributions of soils affect significantly tip resistance obtained in field cone penetration tests. The mechanical parameters of natural marine intermediate deposits are also significantly affected by sample disturbance due to their high sensitivity and relatively large permeability. Unconfined compression shear tests largely underestimate the strength of natural marine intermediate soils. The triaxial consolidated compression shear tests with simulated in-situ confined pressure give results much better than those of uncomfined compression shear tests.

Mechanistic insights into the active intermediates of 2,6-diaminopyridine dinitration

Mechanistic understanding of the active intermediates of 2,6-diaminopyridine(DAP) dinitration in the concentrated nitric-sulfuric acid system is of crucial importance for the selectivity control of target product, i.e., 2,6-diamino-3,5-dinitropyridine(DADNP). The active intermediates determining the product selectivity are theoretically studied. The HSO_(4)^(-)-NO_(2)^(+) complex is proposed as the dominant active nitrating intermediate for the first time, which shows low energy barrier(i.e., 10.19 kcal·mol^(-1),1 kcal = 4.186 k J) for direct dinitration of DAP to DADNP. The formed water during the reaction results in not only the formation of less active SO_(4)^(2-)-NO_(2)^(+) complex, but also the occurance of DAP sulfonation(DAP-SO_(3)H intermediate)to facilitate the formation of mononitration byproduct. Meanwhile, the accompanied thermal effects cause the generation of undesirable pyridine-NHNO_(2) intermediate, which is difficult to be rearranged to yield DADNP, inhibiting the reaction and thus giving low DAP conversion. The insights reported here elucidates the importance of thermal effects elimination and water content control, confirmed experimentally in the batch-and micro-reaction systems.

A quasi-synoptic interpretation of water mass distribution and circulation in the western North Pacific:I.Water mass distribution

With high-resolution conductivity-temperature-depth （CTD） observations conducted in Oct.-Nov. 2005, this study provides a detailed quasi-synoptic description of the North Pacific Tropic Water （NPTW）, North Pacific Intermediate Water （NPIW） and Antarctic Intermediate Water （AAIW） in the western North Pacific. Some novel features are found. NPTW enters the western ocean with highest-salinity core off shore at 15°-18°N, and then splits to flow northward and southward along the western boundary. Its salinity decreases and density increases outside the core region. NPIW spreads westward north of 15°N with lowest salinity off shore at 21°N, but mainly hugs the Mindanao coast south of 12°N. It shoals and thins toward the south, with salinity increasing and density decreasing. AAIW extends to higher latitude off shore than that in shore, and it is traced as a salinity minimum to only 10°N at 130°E. Most of the South Pacific waters turn northeastward rather than directly flow northward upon reaching to the Mindanao coast, indicating the eastward shift of the Mindanao Undercurrent （MUC）.

The westward intrusion of south Pacific water at the western tip of the New Guinea Island

From the eastern Indonesian cruise from November 14 to 23, 2007, CTD （conductivity, temperature, depth profiler）/ADCP （acoustic Doppler current profiler）casting and seawater sampling were done at 25 stations around Waigeo Island near New Guinea Island. It was found overall westward intrusion of the south Pacific waters into the Seram Sea and southward spreading of the north and south Pacific waters into the Seram Sea. There is westward residual flow along the channel between Waigeo and New Guinea within upper 200 m with the maximum speed up to 50 cm/s, and much weaker eastward flow in the lower layer （〈 10 cm/s） due to blocking by the shallow sill at the west of the Dampier Strait. The abrupt change of bottom topography induces active horizontal and vertical mixing which results in a three-layered current system with a major through-flow of-0.99 Sv （Sv = 106 ma/s） into the Seram Sea; the transports in the upper and the lower layers are -1.14 Sv and -0.24 Sv （westward）, respectively, and in the middle there is a return flow with the transoort of ＋0.39 Sv （eastward）.

稻田上覆水中光致活性组分形成过程及其环境效应研究进展

稻田上覆水中富含有机质、亚硝酸盐和硝酸盐等光敏活性物质,在太阳光作用下会产生三重激发态有机质(^(3)CDOM^(*))、单线态氧(^(1)O_(2))和羟基自由基(•OH)等活性组分,其对稻田污染物转化和碳氮等元素循环具有重要意义。基于此,综述了稻田上覆水中光致活性组分产生过程和机制,重点介绍了水稻不同生长周期内光活性组分的类型、通量变化趋势;探讨了不同环境因素对自由基产生的影响;阐述了上覆水光致活性组分对稻田中砷和不同有机污染物的非生物转化贡献与机制,并展望了稻田上覆水光化学过程的未来研究方向。