Only two macroscopic parameters are needed to describe the mechanical properties of linear elastic solids, i.e. the Poisson＇s ratio and Young＇s modulus. Correspondingly, there should be two microscopic parameters to...Only two macroscopic parameters are needed to describe the mechanical properties of linear elastic solids, i.e. the Poisson＇s ratio and Young＇s modulus. Correspondingly, there should be two microscopic parameters to determine the mechanical properties of material if the macroscopic mechanical properties of linear elastic solids are derived from the microscopic level. Enlightened by this idea, a multiscale mechanical model for material, the virtual multi-dimensional internal bonds （VMIB） model, is proposed by incorporating a shear bond into the virtual internal bond （VIB） model. By this modification, the VMIB model associates the macro mechanical properties of material with the microscopic mechanical properties of discrete structure and the corresponding relationship between micro and macro parameters is derived. The tensor quality of the energy density function, which contains coordinate vector, is mathematically proved. From the point of view of VMIB, the macroscopic nonlinear behaviors of material could be attributed to the evolution of virtual bond distribution density induced by the imposed deformation. With this theoretical hypothesis, as an application example, a uniaxial compressive failure of brittle material is simulated. Good agreement between the experimental results and the simulated ones is found.展开更多
In last time,the series of virtual internal bond model was proposed for solving rock mechanics problems.In these models,the rock continuum is considered as a structure of discrete particles connected by normal and she...In last time,the series of virtual internal bond model was proposed for solving rock mechanics problems.In these models,the rock continuum is considered as a structure of discrete particles connected by normal and shear springs(bonds).It is well announced that the normal springs structure corresponds to a linear elastic solid with a fixed Poisson ratio,namely,0.25 for threedimensional cases.So the shear springs used to represent the diversity of the Poisson ratio.However,the shearing force calculation is not rotationally invariant and it produce difficulties in application of these models for rock mechanics problems with sufficient displacements.In this letter,we proposed the approach to support the diversity of the Poisson ratio that based on usage of deformable Voronoi cells as set of particles.The edges of dual Delaunay tetrahedralization are considered as structure of normal springs(bonds).The movements of particle’s centers lead to deformation of tetrahedrals and as result to deformation of Voronoi cells.For each bond,there are the corresponded dual face of some Voronoi cell.We can consider the normal bond as some beam and in this case,the appropriate face of Voronoi cell will be a cross section of this beam.If during deformation the Voronoi face was expand,then,according Poisson effect,the length of bond should be decrees.The above mechanism was numerically investigated and we shown that it is acceptable for simulation of elastic behavior in 0.1–0.3 interval of Poisson ratio.Unexpected surprise is that proposed approach give possibility to simulate auxetic materials with negative Poisson’s ratio in interval from–0.5 to–0.1.展开更多
The rock fragmentation involves the inter-block and the intra-block fracture.A simulation method for rock fragmentation is developed by coupling Voronoi diagram(VD)and discretized virtual internal bond(DVIB).The DVIB ...The rock fragmentation involves the inter-block and the intra-block fracture.A simulation method for rock fragmentation is developed by coupling Voronoi diagram(VD)and discretized virtual internal bond(DVIB).The DVIB is a lattice model that consists of bonds.The VD is used to generate the potential block structure in the DVIB mesh.Each potential block may contain any number of bond cells.To characterize the inter-block fracture,a hyperelastic bond potential is employed for the bond cells that are cut by the VD edges.While to characterize the intra-block fracture,an elastobrittle bond potential is adopted for the bonds in a block.By this method,both the inter-block and intra-block fracture can be well simulated.The simulation results suggest that this method is a simple and efficient approach to rock fragmentation simulation with block smash.展开更多
To effectively simulate the fracture propagation in shale,the bedding plane(BP)effect is incorporated into the augmented virtual internal bond(AVIB)constitutive relation through BP tensor.Comparing the BP-embedded AVI...To effectively simulate the fracture propagation in shale,the bedding plane(BP)effect is incorporated into the augmented virtual internal bond(AVIB)constitutive relation through BP tensor.Comparing the BP-embedded AVIB with the theory of transverse isotropy,it is found the approach can represent the anisotropic properties induced by parallel BPs.Through the simulation example,it is found that this method can simulate the stiffness anisotropy of shale and can represent the effect of BPs on hydraulic fracture propagation direction.Compared with the BP-embedded virtual internal bond(VIB),this method can account for the various Poisson’s ratio.It provides a feasible approach to simulate the fracture propagation in shale.展开更多
Imine bonds are among the most explored building motifs in dynamic chemistry,polymers,and materials,and yet,their acid-resistance remains a longstanding issue.Herein we demonstrate a concept of internal protecting gro...Imine bonds are among the most explored building motifs in dynamic chemistry,polymers,and materials,and yet,their acid-resistance remains a longstanding issue.Herein we demonstrate a concept of internal protecting groups for improving the kinetic stability of dynamic imine bonds and polymers.Systematic examination of structure-reactivity relationship of a series of aldehydes/imines bearing a neighboring carboxyl allowed uncovering of required structural features for dynamically masking imine bonds with cyclic structures.Mechanistic studies indicated that noncovalent interactions along with sterics control the ringchain equilibrium and the stability of imine bonds.The incorporation of internal protecting groups into imine polymers further enabled their controlled stability in acidic media.Moreover,a combination of dynamic covalent network and coordination supramolecular network provided a facile means for the modulation of luminescent and mechanical properties of polymers.The strategies and results reported should be beneficial to molecular assemblies,dynamic polymers,biological delivery,and intelligent materials.展开更多
The coating substrate bonding strengths under different intermixing processes were evaluated by scratch and spherical rolling contact fatigue methods. The results show that for low bombarding energy of N ions dynamic ...The coating substrate bonding strengths under different intermixing processes were evaluated by scratch and spherical rolling contact fatigue methods. The results show that for low bombarding energy of N ions dynamic recoiling at 10 keV and 20 keV, the coating layers are of excellent bonding strengths. The bonding strength of CrN coating with 40 keV static recoiling is higher than that of low energy(20 keV). On the other hand, the bonding strength of coating with 40 keV dynamic recoiling is much lower than that of static recoiling at the same energy and even less than that of dynamic recoiling intermixings at 10 keV and 20 keV energy. The results of scratch and spherical rolling contact fatigue methods exhibit the same trend for each group of recoiling methods, yet the results of the scratch and fatigue tests for two groups do not agree with each other.展开更多
I B课程和AP课程是很优秀的国际课程,被全球教育界认可为具有较高学业水准的教育项目,在全球范围内迅速发展壮大,成为国际学生考取国外大学的最理想选择。它们的课程理念先进,强化学生学习领域的拓展,崇尚实践和创新;它们的课程体系完备...I B课程和AP课程是很优秀的国际课程,被全球教育界认可为具有较高学业水准的教育项目,在全球范围内迅速发展壮大,成为国际学生考取国外大学的最理想选择。它们的课程理念先进,强化学生学习领域的拓展,崇尚实践和创新;它们的课程体系完备,基础课程、拓展课程、选修课程,满足学生发展的真实需要。述评这两种课程,研究学习这两种课程,对于思考完善当今国内的高中课程改革很有意义。展开更多
Covalent organic frameworks(COFs)are promising materials for converting solar energy into green hydrogen.However,limited charge separation and transport in COFs impede their application in the photocatalytic hydrogen ...Covalent organic frameworks(COFs)are promising materials for converting solar energy into green hydrogen.However,limited charge separation and transport in COFs impede their application in the photocatalytic hydrogen evolution reaction(HER).In this study,the intrinsically tunable internal bond electric field(IBEF)at the imine bonds of COFs was manipulated to cooperate with the internal molecular electric field(IMEF)induced by the donor-acceptor(D-A)structure for an efficient HER.The aligned orientation of IBEF and IMEF resulted in a remarkable H_(2) evolution rate of 57.3 mmol·g^(-1)·h^(-1)on TNCA,which was approximately 520 times higher than that of TCNA(0.11 mmol·g^(-1)·h^(-1))with the opposing electric field orientation.The superposition of the dual electric fields enables the IBEF to function as an accelerating field for electron transfer,kinetically facilitat-ing the migration of photogenerated electrons from D to A.Furthermore,theoretical calculations indicate that the inhomogeneous charge distribution at the C and N atoms in TNCA not only pro-vides a strong driving force for carrier transfer but also effectively hinders the return of free elec-trons to the valence band,improving the utilization of photoelectrons.This strategy of fabricating dual electric fields in COFs offers a novel approach to designing photocatalysts for clean energy synthesis.展开更多
基金Project supported by the National Basic Research Program of China (973 Project) (No. 2002CB412704).
文摘Only two macroscopic parameters are needed to describe the mechanical properties of linear elastic solids, i.e. the Poisson＇s ratio and Young＇s modulus. Correspondingly, there should be two microscopic parameters to determine the mechanical properties of material if the macroscopic mechanical properties of linear elastic solids are derived from the microscopic level. Enlightened by this idea, a multiscale mechanical model for material, the virtual multi-dimensional internal bonds （VMIB） model, is proposed by incorporating a shear bond into the virtual internal bond （VIB） model. By this modification, the VMIB model associates the macro mechanical properties of material with the microscopic mechanical properties of discrete structure and the corresponding relationship between micro and macro parameters is derived. The tensor quality of the energy density function, which contains coordinate vector, is mathematically proved. From the point of view of VMIB, the macroscopic nonlinear behaviors of material could be attributed to the evolution of virtual bond distribution density induced by the imposed deformation. With this theoretical hypothesis, as an application example, a uniaxial compressive failure of brittle material is simulated. Good agreement between the experimental results and the simulated ones is found.
文摘In last time,the series of virtual internal bond model was proposed for solving rock mechanics problems.In these models,the rock continuum is considered as a structure of discrete particles connected by normal and shear springs(bonds).It is well announced that the normal springs structure corresponds to a linear elastic solid with a fixed Poisson ratio,namely,0.25 for threedimensional cases.So the shear springs used to represent the diversity of the Poisson ratio.However,the shearing force calculation is not rotationally invariant and it produce difficulties in application of these models for rock mechanics problems with sufficient displacements.In this letter,we proposed the approach to support the diversity of the Poisson ratio that based on usage of deformable Voronoi cells as set of particles.The edges of dual Delaunay tetrahedralization are considered as structure of normal springs(bonds).The movements of particle’s centers lead to deformation of tetrahedrals and as result to deformation of Voronoi cells.For each bond,there are the corresponded dual face of some Voronoi cell.We can consider the normal bond as some beam and in this case,the appropriate face of Voronoi cell will be a cross section of this beam.If during deformation the Voronoi face was expand,then,according Poisson effect,the length of bond should be decrees.The above mechanism was numerically investigated and we shown that it is acceptable for simulation of elastic behavior in 0.1–0.3 interval of Poisson ratio.Unexpected surprise is that proposed approach give possibility to simulate auxetic materials with negative Poisson’s ratio in interval from–0.5 to–0.1.
基金the National Natural ScienceFoundation of China(Grant 11772190),which is gratefully acknowledged.
文摘The rock fragmentation involves the inter-block and the intra-block fracture.A simulation method for rock fragmentation is developed by coupling Voronoi diagram(VD)and discretized virtual internal bond(DVIB).The DVIB is a lattice model that consists of bonds.The VD is used to generate the potential block structure in the DVIB mesh.Each potential block may contain any number of bond cells.To characterize the inter-block fracture,a hyperelastic bond potential is employed for the bond cells that are cut by the VD edges.While to characterize the intra-block fracture,an elastobrittle bond potential is adopted for the bonds in a block.By this method,both the inter-block and intra-block fracture can be well simulated.The simulation results suggest that this method is a simple and efficient approach to rock fragmentation simulation with block smash.
基金This work is supported by the National Natural Science Foundation of China(Grant 11772190),which is gratefully acknowledged.
文摘To effectively simulate the fracture propagation in shale,the bedding plane(BP)effect is incorporated into the augmented virtual internal bond(AVIB)constitutive relation through BP tensor.Comparing the BP-embedded AVIB with the theory of transverse isotropy,it is found the approach can represent the anisotropic properties induced by parallel BPs.Through the simulation example,it is found that this method can simulate the stiffness anisotropy of shale and can represent the effect of BPs on hydraulic fracture propagation direction.Compared with the BP-embedded virtual internal bond(VIB),this method can account for the various Poisson’s ratio.It provides a feasible approach to simulate the fracture propagation in shale.
基金the National Natural Science Foundation of China(NSFC,Nos.22071247,92156010,22101283,and 22101284)the Key Research Program of Frontier Sciences(No.QYZDBSSW-SLH030)of the CAS+1 种基金Natural Science Foundation of Fujian Province(Nos.2020J06035 and 2022J05085)Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China(No.2021ZR112)for support.
文摘Imine bonds are among the most explored building motifs in dynamic chemistry,polymers,and materials,and yet,their acid-resistance remains a longstanding issue.Herein we demonstrate a concept of internal protecting groups for improving the kinetic stability of dynamic imine bonds and polymers.Systematic examination of structure-reactivity relationship of a series of aldehydes/imines bearing a neighboring carboxyl allowed uncovering of required structural features for dynamically masking imine bonds with cyclic structures.Mechanistic studies indicated that noncovalent interactions along with sterics control the ringchain equilibrium and the stability of imine bonds.The incorporation of internal protecting groups into imine polymers further enabled their controlled stability in acidic media.Moreover,a combination of dynamic covalent network and coordination supramolecular network provided a facile means for the modulation of luminescent and mechanical properties of polymers.The strategies and results reported should be beneficial to molecular assemblies,dynamic polymers,biological delivery,and intelligent materials.
文摘The coating substrate bonding strengths under different intermixing processes were evaluated by scratch and spherical rolling contact fatigue methods. The results show that for low bombarding energy of N ions dynamic recoiling at 10 keV and 20 keV, the coating layers are of excellent bonding strengths. The bonding strength of CrN coating with 40 keV static recoiling is higher than that of low energy(20 keV). On the other hand, the bonding strength of coating with 40 keV dynamic recoiling is much lower than that of static recoiling at the same energy and even less than that of dynamic recoiling intermixings at 10 keV and 20 keV energy. The results of scratch and spherical rolling contact fatigue methods exhibit the same trend for each group of recoiling methods, yet the results of the scratch and fatigue tests for two groups do not agree with each other.
文摘Covalent organic frameworks(COFs)are promising materials for converting solar energy into green hydrogen.However,limited charge separation and transport in COFs impede their application in the photocatalytic hydrogen evolution reaction(HER).In this study,the intrinsically tunable internal bond electric field(IBEF)at the imine bonds of COFs was manipulated to cooperate with the internal molecular electric field(IMEF)induced by the donor-acceptor(D-A)structure for an efficient HER.The aligned orientation of IBEF and IMEF resulted in a remarkable H_(2) evolution rate of 57.3 mmol·g^(-1)·h^(-1)on TNCA,which was approximately 520 times higher than that of TCNA(0.11 mmol·g^(-1)·h^(-1))with the opposing electric field orientation.The superposition of the dual electric fields enables the IBEF to function as an accelerating field for electron transfer,kinetically facilitat-ing the migration of photogenerated electrons from D to A.Furthermore,theoretical calculations indicate that the inhomogeneous charge distribution at the C and N atoms in TNCA not only pro-vides a strong driving force for carrier transfer but also effectively hinders the return of free elec-trons to the valence band,improving the utilization of photoelectrons.This strategy of fabricating dual electric fields in COFs offers a novel approach to designing photocatalysts for clean energy synthesis.
