Intraparticle charge delocalization occurs when metal nanoparticles are functionalized with organic capping ligands through conjugated rnetal-ligand interfacial bonds. In this study, metal nanoparticles of 5d metals ...Intraparticle charge delocalization occurs when metal nanoparticles are functionalized with organic capping ligands through conjugated rnetal-ligand interfacial bonds. In this study, metal nanoparticles of 5d metals （Ir, Pt, and Au） and 4d metals （Ru, Rh, and Pd） were prepared and capped with ethynylphenylacetylene and the impacts of the number of metal d electrons on the nanoparticle optoelectronic properties were examined. Both FTIR and photoluminescence measurements indicate that intraparticle charge delocalization was en- hanced with the increase of the number of d electrons in the same period with palladium being an exception.展开更多
Damping improvement in composite structures via introducing nanofillers generally has remarkable negative effects on the other mechanical properties. Therefore, in the present work, SiC and A1203 nanoparticles＇ infus...Damping improvement in composite structures via introducing nanofillers generally has remarkable negative effects on the other mechanical properties. Therefore, in the present work, SiC and A1203 nanoparticles＇ infusion effects on the flexural, interracial and vibration properties of epoxy matrix and glass fiber reinforced epoxy （GFR/E） laminates were investigated. Unidirectional （UD-GFR/E） and quasi-isotropic （QI-GFR/E） laminates with [0/± 45/90]s and [90/±45/0]s stack- ing sequences were hybridized by the optimum nanoparticles percentages. Results from off-axis flexural strengths of UD-GFR/E demonstrate good fiber/nanophased-matrix interracial bonding. The interlaminar shear stress between the adjacent layers with different orientations/strains of duc- tile QI-GFR/SiC/E laminates results in decreasing the flexural strengths respectively by 24.3% and 9.1% for [0/±45/90]s and [90/± 45/0]s stacking sequences and increasing the dissipated interfacial friction energy and thus the damping by 105.7% and 26.1%. The damping of QI-GFR/E, QI-GFR/SiC/E and QI-GFR/AI203/E laminates with [90/± 45/0]s stacking sequence was increased by 111.4%, 29.7% and 32.9% respectively compared to [0/± 45/90]s stacking sequence.展开更多
基金supported,in part,by the National Science Foundation(DMR-1409396 and CHE-1710408)carried out at the National Center for Electron Microscopy and Molecular Foundry of Lawrence Berkeley National Laboratory,which is supported by the US Department of Energy
文摘Intraparticle charge delocalization occurs when metal nanoparticles are functionalized with organic capping ligands through conjugated rnetal-ligand interfacial bonds. In this study, metal nanoparticles of 5d metals （Ir, Pt, and Au） and 4d metals （Ru, Rh, and Pd） were prepared and capped with ethynylphenylacetylene and the impacts of the number of metal d electrons on the nanoparticle optoelectronic properties were examined. Both FTIR and photoluminescence measurements indicate that intraparticle charge delocalization was en- hanced with the increase of the number of d electrons in the same period with palladium being an exception.
文摘Damping improvement in composite structures via introducing nanofillers generally has remarkable negative effects on the other mechanical properties. Therefore, in the present work, SiC and A1203 nanoparticles＇ infusion effects on the flexural, interracial and vibration properties of epoxy matrix and glass fiber reinforced epoxy （GFR/E） laminates were investigated. Unidirectional （UD-GFR/E） and quasi-isotropic （QI-GFR/E） laminates with [0/± 45/90]s and [90/±45/0]s stack- ing sequences were hybridized by the optimum nanoparticles percentages. Results from off-axis flexural strengths of UD-GFR/E demonstrate good fiber/nanophased-matrix interracial bonding. The interlaminar shear stress between the adjacent layers with different orientations/strains of duc- tile QI-GFR/SiC/E laminates results in decreasing the flexural strengths respectively by 24.3% and 9.1% for [0/±45/90]s and [90/± 45/0]s stacking sequences and increasing the dissipated interfacial friction energy and thus the damping by 105.7% and 26.1%. The damping of QI-GFR/E, QI-GFR/SiC/E and QI-GFR/AI203/E laminates with [90/± 45/0]s stacking sequence was increased by 111.4%, 29.7% and 32.9% respectively compared to [0/± 45/90]s stacking sequence.
