In cold regions,the creep characteristics of warm frozen silty sand have significant effect on the stability of slope and subgrade.To investigate the creep behavior of warm frozen silty sand under thermo-mechanical co...In cold regions,the creep characteristics of warm frozen silty sand have significant effect on the stability of slope and subgrade.To investigate the creep behavior of warm frozen silty sand under thermo-mechanical coupling loads,a series of triaxial creep tests were carried out under different temperatures and stresses.The test results reveal that the creep strains decrease as the consolidation stress increases,and finally tend to be equal under the same loading stress,regardless of whether the stress is isotropic or deviatoric.Additionally,warm frozen silty sand is highly sensitive to temperature,which greatly influences the creep strain both in the consolidation stage and loading stage.Furthermore,based on the creep test phenomena,a new creep model that considers the influence of the stress level,temperature,hardening,and damage effect was established and experimentally validated.Finally,the sensitivity of the model parameters was analyzed,and it was found that the creep curve transitions from the attenuation creep stage to the non-attenuation creep stage as the temperature coefficient and stress coefficient increases.The hardening effect gradually changes to the damage effect as the coupling coefficient of the hardening and damage increases.展开更多
Step motors, compared to other drive systems, are low-cost and easy to use devices. However, despite these undeniable advantages, they are characterized by some critical running conditions, due to the loss of synchron...Step motors, compared to other drive systems, are low-cost and easy to use devices. However, despite these undeniable advantages, they are characterized by some critical running conditions, due to the loss of synchronization between the stator's magnetic field and the rotor. In order to theoretically investigate such a behavior, several complex mathematical models have been developed, which require several parameters to be defined. For most step motors, such parameters cannot be easily drawn from their data-sheets; on the contrary, in this paper the authors refer to a simplified electro-mechanical model where the most of the parameters are known from data-sheets. The dependence between electrical and mechanical quantities can be investigated by an experimental point of view. At this aim, a specific novel test rig has been designed and developed for either static or dynamic characteristics measurement of small size step motors. In particular, the test rig allow to measure rotor's angular position, motor's torque, currents flowing in the motor's phases. The paper ends with the report of the results of several experimental tests, carried-out on a small-size motor in different running conditions, and with some preliminary remarks on the basis of the measures analysis.展开更多
The development of a powerful numerical model to simulate the fracture behavior of concrete material has long been one of the dominant research areas in earthquake engineering. A reliable model should be able to adequ...The development of a powerful numerical model to simulate the fracture behavior of concrete material has long been one of the dominant research areas in earthquake engineering. A reliable model should be able to adequately represent the discontinuous characteristics of cracks and simulate various failure behaviors under complicated loading conditions. In this paper, a numerical formulation, which incorporates a sophisticated rigid-plastic interface constitutive model coupling cohesion softening, contact, friction and shear dilatation into the XFEM, is proposed to describe various crack behaviors of concrete material. An effective numerical integration scheme for accurately assembling the contribution to the weak form on both sides of the discontinuity is introduced. The effectiveness of the proposed method has been assessed by simulating several well-known experimental tests. It is concluded that the numerical method can successfully capture the crack paths and accurately predict the fracture behavior of concrete structures. The influence ofmode-Ⅱ parameters on the mixed-mode fracture behavior is further investigated to better determine these parameters.展开更多
The hot compression tests of 7Mo super austenitic stainless(SASS)were conducted to obtain flow curves at the temperature of 1000-1200℃and strain rate of 0.001 s^(-1)to 1 s^(-1).To predict the non-linear hot deformati...The hot compression tests of 7Mo super austenitic stainless(SASS)were conducted to obtain flow curves at the temperature of 1000-1200℃and strain rate of 0.001 s^(-1)to 1 s^(-1).To predict the non-linear hot deformation behaviors of the steel,back propagation-artificial neural network(BP-ANN)with 16×8×8 hidden layer neurons was proposed.The predictability of the ANN model is evaluated according to the distribution of mean absolute error(MAE)and relative error.The relative error of 85%data for the BP-ANN model is among±5%while only 42.5%data predicted by the Arrhenius constitutive equation is in this range.Especially,at high strain rate and low temperature,the MAE of the ANN model is 2.49%,which has decreases for 18.78%,compared with conventional Arrhenius constitutive equation.展开更多
In accordance with the memory function of Gaussian chain constraints in entangled polymermelts a set of material functions related to a certain"test flow"are formulated from the O-W-Ftype constitutive equati...In accordance with the memory function of Gaussian chain constraints in entangled polymermelts a set of material functions related to a certain"test flow"are formulated from the O-W-Ftype constitutive equation by the appropriate selection of the Cauchy-Green and Finger tensors.Thedependences of these material functions on the strain rate and the dependences of the linearviscoelastic functions on the primary molecular weight distribution and the entanglement sites sequencedistribution on polymer chain are derived from a multiple-entanglement model and a couple of mech-anisms of relaxation for the loop and terminal entanglement sites.When the primary polymer chainsare modelled with the Lansing-Kraemer molecular distribution function,a set of new relationshipsamong linear viscoelastic functions(η<sub>0</sub>,ψ<sub>10</sub><sup>0</sup>,η<sub>ext</sub><sup>0</sup> and τ<sub>1</sub>)and the molecular weights and their distributionare formulated.These functions and relationships are verified with experimental data.展开更多
The dynamic stress-strain curves of 93% tungsten (W) alloy in the forged state at strain rates up to (5 000 s^(-1)) and in the temperature range from 223 K to 473 K were measured with the split Hopkinson pressure bar ...The dynamic stress-strain curves of 93% tungsten (W) alloy in the forged state at strain rates up to (5 000 s^(-1)) and in the temperature range from 223 K to 473 K were measured with the split Hopkinson pressure bar (SHPB) technique. Based on the above experimental data a dynamic constitutive equation considering the effects of strain rate, temperature and the special microstructure of such a kind of W-alloy was proposed. The numerical simulation for the experimental process with this constitutive equation was also carried out, the results show that the constitutive relationship constructed in this paper is very satisfactory for representing the dynamic responsive behavior of material..展开更多
The electronic structures of Ti_2NbSb with Hg_2CuTi structure and TiZrNbSb with LiMgPdSn structure are investigated using first-principles calculations.The results indicate that Ti_2NbSb is a fully compensated ferrima...The electronic structures of Ti_2NbSb with Hg_2CuTi structure and TiZrNbSb with LiMgPdSn structure are investigated using first-principles calculations.The results indicate that Ti_2NbSb is a fully compensated ferrimagnetic spin-gapless semiconductor with an energy gap of 0.13 e V,and TiZrNbSb is a half-metallic fully compensated ferrimagnet with a half-metallic gap of 0.17 e V.For Ti_2NbSb,the total energy of the Hg_2CuTi structure is0.62 e V/f.u.higher than that of the L2_(1) structure,which is the ground state,and for TiZrNbSb,the total energy of the structure considered in this work is only 0.15 e V/f.u.larger than that of the ground state.Thus both of them may be good candidates for spintronic applications.展开更多
In this study,the texture evolutions of two Mg materials during tension are explored.In-situ X-ray synchrotron and Visco-Plastic SelfConsistent(VPSC) modeling are employed to investigate the different deformation mode...In this study,the texture evolutions of two Mg materials during tension are explored.In-situ X-ray synchrotron and Visco-Plastic SelfConsistent(VPSC) modeling are employed to investigate the different deformation modes between pure Mg and Mg-15Gd(wt.%) alloy.These two materials with a strong extrusion texture show large different slip/twinning activity behaviors during tensile deformation.The basal(a) slip has the highest contribution to the initial stage of plastic deformation for pure Mg.During the subsequent plastic deformation,the prismatic slip is dominant due to the strong ED//(100) fiber texture.In contrast,the deformation behavior of Mg-15Gd alloy is more complex.Twinning and basal slip are dominant at the early stage of plastic deformation,but further deformation results in the increased activation of prismatic and pyramidal slips.In comparison to pure Mg,the ratios of the critical resolved shear stress(CRSS) between non-basal slip and basal slip of the Mg-15Gd alloy are much lower.展开更多
hhen ammonium sulfate-iron oxide is treated below 573 K, ammonium sulfate can spontaneously desperse on the surface of iron oxide. Simultaneously ammonium sulfate decomposes to some extent. During or after the dispers...hhen ammonium sulfate-iron oxide is treated below 573 K, ammonium sulfate can spontaneously desperse on the surface of iron oxide. Simultaneously ammonium sulfate decomposes to some extent. During or after the dispersion, sulfate ion can interact with Fe atom on the surface of iron oxide to form a sort of surface sulfato complex of Fe and thus is transformed from the isolated into the bidentately bound form. Above 573 K the sulfato complex of Fe will gradually decompose with a further increase in temperature.展开更多
The local and global mechanical responses of gas tungsten arc welds(GTAW) of a 2219-T87 aluminum alloy were investigated with experiment and numerical simulation.Digital image correlation(DIC) was used to access t...The local and global mechanical responses of gas tungsten arc welds(GTAW) of a 2219-T87 aluminum alloy were investigated with experiment and numerical simulation.Digital image correlation(DIC) was used to access the local strain fields in transversely loaded welds and to determine the local stress-strain curves of various regions in the joint.The results show that the DIC method is efficient to acquire the local stress-strain curves but the curves of harder regions are incomplete because the stress and strain ranges are limited by the weakest region.With appropriate extrapolation,the complete local stress-strain curves were acquired and proved to be effective to predict the tensile behavior of the welded joint.During the tensile process,the fracture initiates from the weld toes owing to their plastic strain concentrations and then propagates along the fusion line,finally propagates into the partially melted zone(PMZ).展开更多
The deformation behaviors of a new quaternary Mg-6Zn-1.5Cu-0.5Zr alloy at temperatures of 523-673 K and strain rates of 0.001-1 s-1 were studied by compressive tests using a Gleeble 3800 thermal-simulator.The results ...The deformation behaviors of a new quaternary Mg-6Zn-1.5Cu-0.5Zr alloy at temperatures of 523-673 K and strain rates of 0.001-1 s-1 were studied by compressive tests using a Gleeble 3800 thermal-simulator.The results show that the flow stress increases as the deformation temperature decreases or as the strain rate increases.A strain-dependent constitutive equation and a feed-forward back-propagation artificial neural network were used to predict flow stress,which showed good agreement with experimental data.The processing map suggests that the domains of 643-673 K and 0.001-0.01 s-1 are corresponded to optimum conditions for hot working of the T4-treated Mg-6Zn-1.5Cu-0.5Zr alloy.展开更多
Hot deformation behavior ofX20Cr13 martensitic stainless steel was investigated by conducting hot compression tests on Gleeble-1500D thermo-mechanical simulator at the temperature ranging from 1173 to 1423 K and the s...Hot deformation behavior ofX20Cr13 martensitic stainless steel was investigated by conducting hot compression tests on Gleeble-1500D thermo-mechanical simulator at the temperature ranging from 1173 to 1423 K and the strain rate ranging from 0.001 to 10 s^-1. The material constants of a and n, activation energy Q and A were calculated as a function of strain by a fifth-order polynomial fit. Constitutive models incorporating deformation temperature, strain rate and strain were developed to model the hot deformation behavior of X20Cr13 martensitic stainless steel based on the Arrhenius equation. The predictable efficiency of the developed constitutive models of X20Cr13 martensitic stainless steel was analyzed by correlation coefficient and average absolute relative error which are 0.996 and 3.22%, respectively.展开更多
The hot deformation behavior and microstructure evolution of 1460 Al-Li alloy were investigated by isothermal compression test conducted at various strain rates(10-3-10 s-1) and temperatures(573-773 K). The flow s...The hot deformation behavior and microstructure evolution of 1460 Al-Li alloy were investigated by isothermal compression test conducted at various strain rates(10-3-10 s-1) and temperatures(573-773 K). The flow stress curves were corrected by considering the friction at the platen/specimen interface and the temperature change due to the deformation heating. The effects of strain, strain rate and temperature on the deformation behavior were characterized by the Zener-Hollomon parameter in a hyperbolic-sine equation, and the constitutive equations were established according to the peak flow stress associated with dynamic recovery, dynamic recrystallization and the dissolution of T1 phases. In the entire strain rate and temperature range, the prediction capabilities of the developed constitutive equation are proved to be feasible and effective with a linear correlation coefficient and an average absolute relative error coefficient of 0.9909 and 6.72%, respectively.展开更多
Hot compression tests of an extruded Al-1.1Mn-0.3Mg-0.25RE alloy were performed on Gleeble-1500 system in the temperature range of 300-500 ℃ and strain rate range of 0.01-10 s-l. The associated microstructural evolut...Hot compression tests of an extruded Al-1.1Mn-0.3Mg-0.25RE alloy were performed on Gleeble-1500 system in the temperature range of 300-500 ℃ and strain rate range of 0.01-10 s-l. The associated microstructural evolutions were studied by observation of optical and transmission electron microscopes. The results show that the peak stress level decreases with increasing deformation temperature and decreasing strain rate, which can be represented by a Zener-Hollomon parameter in the hyperbolic-sine equation with the hot deformation activation energy of 186.48 kJ/mol. The steady flow behavior results from dynamic recovery whereas flow softening is associated with dynamic recrystallization and dynamic transformation of constituent particles. The main constituent particles are enriched rare earth phases. Positive purifying effects on impurity elements of Fe and Si are shown in the Al-l.lMn-0.3Mg-0.25RE alloy, which increases the workability at high temperature. Processing map was calculated and an optimum processing was determined with deformation temperature of 440-450 ℃ and strain rate of 0.01 s-1.展开更多
The hot deformation behavior and microstructures of Al-7055 commercial alloy were investigated by axisymmetric hot compres- sion at temperatures ranging from 300℃ to 450℃ and strain rates from 10^-2 to 10 s^-1, resp...The hot deformation behavior and microstructures of Al-7055 commercial alloy were investigated by axisymmetric hot compres- sion at temperatures ranging from 300℃ to 450℃ and strain rates from 10^-2 to 10 s^-1, respectively. Microstructures of deformed 7055 alloy were investigated by transmission electron microscopy (TEM). The dependence of peak stress on deformation temperature and strain rate can be expressed by the hyperbolic-sine type equation. The hot deformation activation energy of the alloy is 146 kJ/mol. Moreover, the flow stress curves predicted by the modified constitutive equations are reasonably consistent with the experimental results, which confirms that the proposed deformation constitutive equations can provide evidence for the selection of hot forming parameters. TEM results indicate that dy- namic recovery is the main softening mechanism during hot deformation.展开更多
The dynamic tensile behaviors of a newly developed Ti-6 Al-2 Sn-2 Zr-3 Mo-1 Cr-2 Nb-Si alloy(referred as TC21 in China) over a wide range of strain rates from quasi-static to dynamic regimes(0.001-1 200 s-1) at diff...The dynamic tensile behaviors of a newly developed Ti-6 Al-2 Sn-2 Zr-3 Mo-1 Cr-2 Nb-Si alloy(referred as TC21 in China) over a wide range of strain rates from quasi-static to dynamic regimes(0.001-1 200 s-1) at different temperatures were experimentally investigated. A split Hopkinson tension bar apparatus and a static material testing system were utilized to study the stress-strain responses under uniaxial tension loading condition. The experimental results indicate that the tensile behavior of TC21 titanium alloy is dependent on the strain rate and temperature. The values of initial yield stress increase with increasing strain rate and decreasing temperature. The effects of strain rate and temperature on the initial yield behavior are estimated by introducing two sensitivity parameters. The phenomenological-based constitutive model, Johnson-Cook model, is suitably modified to describe the rate-temperature dependent constitutive behavior of TC21 titanium alloy. It is observed that the modified model is in good agreement with the experimental data subjected to the investigated range of strain rates and temperatures.展开更多
The hot deformation behavior of AA2014forging aluminum alloy was investigated by isothermal compression tests attemperatures of350-480°C and strain rates of0.001-1s-1on a Gleeble-3180simulator.The corresponding m...The hot deformation behavior of AA2014forging aluminum alloy was investigated by isothermal compression tests attemperatures of350-480°C and strain rates of0.001-1s-1on a Gleeble-3180simulator.The corresponding microstructures of thealloys under different deformation conditions were studied using optical microscopy(OM),electron back scattered diffraction(EBSD)and transmission electron microscopy(TEM).The processing maps were constructed with strains of0.1,0.3,0.5and0.7.The results showed that the instability domain was more inclined to occur at strain rates higher than0.1s-1and manifested in theform of local non-uniform deformation.At the strain of0.7,the processing map showed two stability domains:domain I(350-430°C,0.005-0.1s-1)and domain II(450-480°C,0.001-0.05s-1).The predominant softening mechanisms in both of the twodomains were dynamic recovery.Uniform microstructures were obtained in domain I,and an extended recovery occurred in domainII,which would lead to the potential sub-grain boundaries progressively transforming into new high-angle grain boundaries.Theoptimum hot working parameters for the AA2014forging aluminum alloy were determined to be370-420°C and0.008-0.08s-1.展开更多
Extensive testing was carried out to study the effects of rare earth Ce doping on the properties of SnAgCu solder alloys.The addition of 0.03%(mass fraction) rare earth Ce into SnAgCu solder may improve its mechanical...Extensive testing was carried out to study the effects of rare earth Ce doping on the properties of SnAgCu solder alloys.The addition of 0.03%(mass fraction) rare earth Ce into SnAgCu solder may improve its mechanical properties,but slightly lower its melting temperature.The tensile creep behavior of bulk SnAgCuCe solders was reported and compared with SnAgCu solders.It is found that SnAgCuCe solders show higher creep resistance than SnAgCu alloys.Moreover,Dorn model and Garofalo model are successfully used to describe the creep behavior of SnAgCu and SnAgCuCe alloys.The parameters of the two creep constitutive equations for SnAgCu and SnAgCuCe solders are determined from separated constitutive relations and experimental results.Nonlinear least-squares fitting is selected to determine the model constants.The experimental data of the stress-creep strain rate curves are in good agreement with the theoretical ones.展开更多
The hot deformation behaviors of as-solution Mg?xZn?yEr alloys (x/y=6, x=3.0, 4.5 and 6.0; y=0.50, 0.75 and 1.00) wereinvestigated on Gleeble?1500 thermal simulator in a temperature range of 200?450 °C at a strai...The hot deformation behaviors of as-solution Mg?xZn?yEr alloys (x/y=6, x=3.0, 4.5 and 6.0; y=0.50, 0.75 and 1.00) wereinvestigated on Gleeble?1500 thermal simulator in a temperature range of 200?450 °C at a strain rate of 0.001?1 s?1. The truestress?strain curves showed the dynamic competition between the working hardening and working softening mainly due to thedynamic recrystallization (DRX) occurring during hot compression. The constitutive equations were constructed which couldaccurately predict the peak stress of the alloys. The addition of Zn and/or Er resulted in higher deformation activation energy forMg?3Zn?0.5Er (alloy A). The processing maps were constructed as function of the temperature and the strain rate, providing theoptimum hot working conditions (i.e., at strain of 0.3, Mg?3Zn?0.5Er (alloy A): 380?430 ?C, <0.1 s?1; Mg?4.5Zn?0.75Er (alloy B):380?450 ?C, 0.01?0.1 s?1; Mg?6Zn?1Er (alloy C): 390?440 ?C, 0.01?0.1 s?1). The as-solution treated Mg?4.5Zn?0.75Er (alloy B)demonstrated more optimum hot working window comparing with Mg?3Zn?0.5Er (alloy A) and Mg?6Zn?1Er (alloy C).展开更多
Q345E as one of typical low alloy steels is widely used in manufacturing basic components in many fields because of its eminent formability under elevated temperature. In this work, the deformation behavior of Q345E s...Q345E as one of typical low alloy steels is widely used in manufacturing basic components in many fields because of its eminent formability under elevated temperature. In this work, the deformation behavior of Q345E steel was investigated by hot compression experiments on Gleeble-3500 thermo-mechanical simulator with the temperature ranging from 850 ℃ to 1150 ℃ and strain rate ranging from 0.01 s-1 to 10 s-1. The experimental results indicate that dynamic softening of Q345E benefits from increasing deformation temperature and decreasing strain rate. The mathematical relationship between dynamic softening degree and deformation conditions is established to predict the dynamic softening degree quantitatively, which is further proved by some optical microstructures of Q345E. In addition, the experimental results also reveal that the stress level decreases with increasing deformation temperature and decreasing strain rate. The constitutive equation for flow stress of Q345E is formulated by Arrihenius equation and the modified Zener-Hollomon parameter considering the compensation of both strain and strain rate. The flow stress values predicted by the constitutive equation agree well with the experimental values, realizing the accurate prediction of the flow stress of Q345E steel under hot deformation.展开更多
基金supported the National Natural Science Foundation of China (No.41971076)the National Key Research and Development Program of China (No.2016YFE0202400)the State Key Laboratory of Road Engineering Safety and Health in Cold and High-altitude Regions (No.YGY2017KYPT-04)。
文摘In cold regions,the creep characteristics of warm frozen silty sand have significant effect on the stability of slope and subgrade.To investigate the creep behavior of warm frozen silty sand under thermo-mechanical coupling loads,a series of triaxial creep tests were carried out under different temperatures and stresses.The test results reveal that the creep strains decrease as the consolidation stress increases,and finally tend to be equal under the same loading stress,regardless of whether the stress is isotropic or deviatoric.Additionally,warm frozen silty sand is highly sensitive to temperature,which greatly influences the creep strain both in the consolidation stage and loading stage.Furthermore,based on the creep test phenomena,a new creep model that considers the influence of the stress level,temperature,hardening,and damage effect was established and experimentally validated.Finally,the sensitivity of the model parameters was analyzed,and it was found that the creep curve transitions from the attenuation creep stage to the non-attenuation creep stage as the temperature coefficient and stress coefficient increases.The hardening effect gradually changes to the damage effect as the coupling coefficient of the hardening and damage increases.
文摘Step motors, compared to other drive systems, are low-cost and easy to use devices. However, despite these undeniable advantages, they are characterized by some critical running conditions, due to the loss of synchronization between the stator's magnetic field and the rotor. In order to theoretically investigate such a behavior, several complex mathematical models have been developed, which require several parameters to be defined. For most step motors, such parameters cannot be easily drawn from their data-sheets; on the contrary, in this paper the authors refer to a simplified electro-mechanical model where the most of the parameters are known from data-sheets. The dependence between electrical and mechanical quantities can be investigated by an experimental point of view. At this aim, a specific novel test rig has been designed and developed for either static or dynamic characteristics measurement of small size step motors. In particular, the test rig allow to measure rotor's angular position, motor's torque, currents flowing in the motor's phases. The paper ends with the report of the results of several experimental tests, carried-out on a small-size motor in different running conditions, and with some preliminary remarks on the basis of the measures analysis.
基金Scientific Research Fund of Institute of Engineering Mechanics,China Earthquake Administration under Grant No.2016A01the National Key Research and Development Plan under Grant No.2016YFC0701108the National Natural Science Foundation of China under Grant Nos.51238012,51322801)
文摘The development of a powerful numerical model to simulate the fracture behavior of concrete material has long been one of the dominant research areas in earthquake engineering. A reliable model should be able to adequately represent the discontinuous characteristics of cracks and simulate various failure behaviors under complicated loading conditions. In this paper, a numerical formulation, which incorporates a sophisticated rigid-plastic interface constitutive model coupling cohesion softening, contact, friction and shear dilatation into the XFEM, is proposed to describe various crack behaviors of concrete material. An effective numerical integration scheme for accurately assembling the contribution to the weak form on both sides of the discontinuity is introduced. The effectiveness of the proposed method has been assessed by simulating several well-known experimental tests. It is concluded that the numerical method can successfully capture the crack paths and accurately predict the fracture behavior of concrete structures. The influence ofmode-Ⅱ parameters on the mixed-mode fracture behavior is further investigated to better determine these parameters.
文摘The hot compression tests of 7Mo super austenitic stainless(SASS)were conducted to obtain flow curves at the temperature of 1000-1200℃and strain rate of 0.001 s^(-1)to 1 s^(-1).To predict the non-linear hot deformation behaviors of the steel,back propagation-artificial neural network(BP-ANN)with 16×8×8 hidden layer neurons was proposed.The predictability of the ANN model is evaluated according to the distribution of mean absolute error(MAE)and relative error.The relative error of 85%data for the BP-ANN model is among±5%while only 42.5%data predicted by the Arrhenius constitutive equation is in this range.Especially,at high strain rate and low temperature,the MAE of the ANN model is 2.49%,which has decreases for 18.78%,compared with conventional Arrhenius constitutive equation.
文摘In accordance with the memory function of Gaussian chain constraints in entangled polymermelts a set of material functions related to a certain"test flow"are formulated from the O-W-Ftype constitutive equation by the appropriate selection of the Cauchy-Green and Finger tensors.Thedependences of these material functions on the strain rate and the dependences of the linearviscoelastic functions on the primary molecular weight distribution and the entanglement sites sequencedistribution on polymer chain are derived from a multiple-entanglement model and a couple of mech-anisms of relaxation for the loop and terminal entanglement sites.When the primary polymer chainsare modelled with the Lansing-Kraemer molecular distribution function,a set of new relationshipsamong linear viscoelastic functions(η<sub>0</sub>,ψ<sub>10</sub><sup>0</sup>,η<sub>ext</sub><sup>0</sup> and τ<sub>1</sub>)and the molecular weights and their distributionare formulated.These functions and relationships are verified with experimental data.
文摘The dynamic stress-strain curves of 93% tungsten (W) alloy in the forged state at strain rates up to (5 000 s^(-1)) and in the temperature range from 223 K to 473 K were measured with the split Hopkinson pressure bar (SHPB) technique. Based on the above experimental data a dynamic constitutive equation considering the effects of strain rate, temperature and the special microstructure of such a kind of W-alloy was proposed. The numerical simulation for the experimental process with this constitutive equation was also carried out, the results show that the constitutive relationship constructed in this paper is very satisfactory for representing the dynamic responsive behavior of material..
基金Supported by the National Natural Science Foundation of China under Grant No 51301119the Natural Science Foundation for Young Scientists of Shanxi Province under Grant No 2013021010-1the Scientific and Technological Innovation Programs of Higher Education Institutions of Shanxi Province under Grant No 201802023
文摘The electronic structures of Ti_2NbSb with Hg_2CuTi structure and TiZrNbSb with LiMgPdSn structure are investigated using first-principles calculations.The results indicate that Ti_2NbSb is a fully compensated ferrimagnetic spin-gapless semiconductor with an energy gap of 0.13 e V,and TiZrNbSb is a half-metallic fully compensated ferrimagnet with a half-metallic gap of 0.17 e V.For Ti_2NbSb,the total energy of the Hg_2CuTi structure is0.62 e V/f.u.higher than that of the L2_(1) structure,which is the ground state,and for TiZrNbSb,the total energy of the structure considered in this work is only 0.15 e V/f.u.larger than that of the ground state.Thus both of them may be good candidates for spintronic applications.
基金sponsored by the China Postdoctoral Science Foundation (Grant No. 2020M673156)Shanghai Pujiang Program (Grant No. 20PJ1404900)。
文摘In this study,the texture evolutions of two Mg materials during tension are explored.In-situ X-ray synchrotron and Visco-Plastic SelfConsistent(VPSC) modeling are employed to investigate the different deformation modes between pure Mg and Mg-15Gd(wt.%) alloy.These two materials with a strong extrusion texture show large different slip/twinning activity behaviors during tensile deformation.The basal(a) slip has the highest contribution to the initial stage of plastic deformation for pure Mg.During the subsequent plastic deformation,the prismatic slip is dominant due to the strong ED//(100) fiber texture.In contrast,the deformation behavior of Mg-15Gd alloy is more complex.Twinning and basal slip are dominant at the early stage of plastic deformation,but further deformation results in the increased activation of prismatic and pyramidal slips.In comparison to pure Mg,the ratios of the critical resolved shear stress(CRSS) between non-basal slip and basal slip of the Mg-15Gd alloy are much lower.
文摘hhen ammonium sulfate-iron oxide is treated below 573 K, ammonium sulfate can spontaneously desperse on the surface of iron oxide. Simultaneously ammonium sulfate decomposes to some extent. During or after the dispersion, sulfate ion can interact with Fe atom on the surface of iron oxide to form a sort of surface sulfato complex of Fe and thus is transformed from the isolated into the bidentately bound form. Above 573 K the sulfato complex of Fe will gradually decompose with a further increase in temperature.
基金Project(2012 2X04012-011)supported by the Innovation Platform for Process Modeling and Simulation of Advanced Materials Processing Technologies,China
文摘The local and global mechanical responses of gas tungsten arc welds(GTAW) of a 2219-T87 aluminum alloy were investigated with experiment and numerical simulation.Digital image correlation(DIC) was used to access the local strain fields in transversely loaded welds and to determine the local stress-strain curves of various regions in the joint.The results show that the DIC method is efficient to acquire the local stress-strain curves but the curves of harder regions are incomplete because the stress and strain ranges are limited by the weakest region.With appropriate extrapolation,the complete local stress-strain curves were acquired and proved to be effective to predict the tensile behavior of the welded joint.During the tensile process,the fracture initiates from the weld toes owing to their plastic strain concentrations and then propagates along the fusion line,finally propagates into the partially melted zone(PMZ).
基金supported by the R&D Program of Korea Institute of Materials Sciencethe World Premier Materials Program funded by The Ministry of Knowledge Economy,Koreasupport from China Scholarship Council(CSC)
文摘The deformation behaviors of a new quaternary Mg-6Zn-1.5Cu-0.5Zr alloy at temperatures of 523-673 K and strain rates of 0.001-1 s-1 were studied by compressive tests using a Gleeble 3800 thermal-simulator.The results show that the flow stress increases as the deformation temperature decreases or as the strain rate increases.A strain-dependent constitutive equation and a feed-forward back-propagation artificial neural network were used to predict flow stress,which showed good agreement with experimental data.The processing map suggests that the domains of 643-673 K and 0.001-0.01 s-1 are corresponded to optimum conditions for hot working of the T4-treated Mg-6Zn-1.5Cu-0.5Zr alloy.
基金Project(51005150)supported by the National Natural Science Foundation of ChinaProject(2011CB012903)supported by the National Basic Research Program of China
文摘Hot deformation behavior ofX20Cr13 martensitic stainless steel was investigated by conducting hot compression tests on Gleeble-1500D thermo-mechanical simulator at the temperature ranging from 1173 to 1423 K and the strain rate ranging from 0.001 to 10 s^-1. The material constants of a and n, activation energy Q and A were calculated as a function of strain by a fifth-order polynomial fit. Constitutive models incorporating deformation temperature, strain rate and strain were developed to model the hot deformation behavior of X20Cr13 martensitic stainless steel based on the Arrhenius equation. The predictable efficiency of the developed constitutive models of X20Cr13 martensitic stainless steel was analyzed by correlation coefficient and average absolute relative error which are 0.996 and 3.22%, respectively.
基金Project supported by the Nonferrous Metal Oriented Advanced Structural Materials and Manufacturing Cooperative Innovation CenterProject(2013JSJJ0001)supported by the Teachers’Research Foundation of Central South UniversityChina
文摘The hot deformation behavior and microstructure evolution of 1460 Al-Li alloy were investigated by isothermal compression test conducted at various strain rates(10-3-10 s-1) and temperatures(573-773 K). The flow stress curves were corrected by considering the friction at the platen/specimen interface and the temperature change due to the deformation heating. The effects of strain, strain rate and temperature on the deformation behavior were characterized by the Zener-Hollomon parameter in a hyperbolic-sine equation, and the constitutive equations were established according to the peak flow stress associated with dynamic recovery, dynamic recrystallization and the dissolution of T1 phases. In the entire strain rate and temperature range, the prediction capabilities of the developed constitutive equation are proved to be feasible and effective with a linear correlation coefficient and an average absolute relative error coefficient of 0.9909 and 6.72%, respectively.
基金Project(31115014)supported by the of Open Research Fund Program of State Key Laboratory of Advanced Design and Manufacture forVehicle Body(Hunan University)Project(12JJ9017)supported by the Natural Science Foundation of Hunan Province,China
文摘Hot compression tests of an extruded Al-1.1Mn-0.3Mg-0.25RE alloy were performed on Gleeble-1500 system in the temperature range of 300-500 ℃ and strain rate range of 0.01-10 s-l. The associated microstructural evolutions were studied by observation of optical and transmission electron microscopes. The results show that the peak stress level decreases with increasing deformation temperature and decreasing strain rate, which can be represented by a Zener-Hollomon parameter in the hyperbolic-sine equation with the hot deformation activation energy of 186.48 kJ/mol. The steady flow behavior results from dynamic recovery whereas flow softening is associated with dynamic recrystallization and dynamic transformation of constituent particles. The main constituent particles are enriched rare earth phases. Positive purifying effects on impurity elements of Fe and Si are shown in the Al-l.lMn-0.3Mg-0.25RE alloy, which increases the workability at high temperature. Processing map was calculated and an optimum processing was determined with deformation temperature of 440-450 ℃ and strain rate of 0.01 s-1.
文摘The hot deformation behavior and microstructures of Al-7055 commercial alloy were investigated by axisymmetric hot compres- sion at temperatures ranging from 300℃ to 450℃ and strain rates from 10^-2 to 10 s^-1, respectively. Microstructures of deformed 7055 alloy were investigated by transmission electron microscopy (TEM). The dependence of peak stress on deformation temperature and strain rate can be expressed by the hyperbolic-sine type equation. The hot deformation activation energy of the alloy is 146 kJ/mol. Moreover, the flow stress curves predicted by the modified constitutive equations are reasonably consistent with the experimental results, which confirms that the proposed deformation constitutive equations can provide evidence for the selection of hot forming parameters. TEM results indicate that dy- namic recovery is the main softening mechanism during hot deformation.
基金Funded by the National Natural Science Foundation of China Academy of Engineering Physics and Jointly Set up “NSAF” Joint Fund(No.U1430119)
文摘The dynamic tensile behaviors of a newly developed Ti-6 Al-2 Sn-2 Zr-3 Mo-1 Cr-2 Nb-Si alloy(referred as TC21 in China) over a wide range of strain rates from quasi-static to dynamic regimes(0.001-1 200 s-1) at different temperatures were experimentally investigated. A split Hopkinson tension bar apparatus and a static material testing system were utilized to study the stress-strain responses under uniaxial tension loading condition. The experimental results indicate that the tensile behavior of TC21 titanium alloy is dependent on the strain rate and temperature. The values of initial yield stress increase with increasing strain rate and decreasing temperature. The effects of strain rate and temperature on the initial yield behavior are estimated by introducing two sensitivity parameters. The phenomenological-based constitutive model, Johnson-Cook model, is suitably modified to describe the rate-temperature dependent constitutive behavior of TC21 titanium alloy. It is observed that the modified model is in good agreement with the experimental data subjected to the investigated range of strain rates and temperatures.
基金Project(51301209) supported by the National Natural Science Foundation of China
文摘The hot deformation behavior of AA2014forging aluminum alloy was investigated by isothermal compression tests attemperatures of350-480°C and strain rates of0.001-1s-1on a Gleeble-3180simulator.The corresponding microstructures of thealloys under different deformation conditions were studied using optical microscopy(OM),electron back scattered diffraction(EBSD)and transmission electron microscopy(TEM).The processing maps were constructed with strains of0.1,0.3,0.5and0.7.The results showed that the instability domain was more inclined to occur at strain rates higher than0.1s-1and manifested in theform of local non-uniform deformation.At the strain of0.7,the processing map showed two stability domains:domain I(350-430°C,0.005-0.1s-1)and domain II(450-480°C,0.001-0.05s-1).The predominant softening mechanisms in both of the twodomains were dynamic recovery.Uniform microstructures were obtained in domain I,and an extended recovery occurred in domainII,which would lead to the potential sub-grain boundaries progressively transforming into new high-angle grain boundaries.Theoptimum hot working parameters for the AA2014forging aluminum alloy were determined to be370-420°C and0.008-0.08s-1.
基金Project(BCXJ09-07) supported by Doctoral Dissertation Innovation and Excellence Producing Foundation of Nanjing University of Aeronautics and Astronautics,ChinaProject(CX07B_087z) supported by the Jiangsu General Colleges and Universities Postgraduate Scientific Research Innovative Plan,China
文摘Extensive testing was carried out to study the effects of rare earth Ce doping on the properties of SnAgCu solder alloys.The addition of 0.03%(mass fraction) rare earth Ce into SnAgCu solder may improve its mechanical properties,but slightly lower its melting temperature.The tensile creep behavior of bulk SnAgCuCe solders was reported and compared with SnAgCu solders.It is found that SnAgCuCe solders show higher creep resistance than SnAgCu alloys.Moreover,Dorn model and Garofalo model are successfully used to describe the creep behavior of SnAgCu and SnAgCuCe alloys.The parameters of the two creep constitutive equations for SnAgCu and SnAgCuCe solders are determined from separated constitutive relations and experimental results.Nonlinear least-squares fitting is selected to determine the model constants.The experimental data of the stress-creep strain rate curves are in good agreement with the theoretical ones.
基金Project(2142005)supported by Beijing Natural Science Foundation,ChinaProject(51401005)supported by the National Natural Science Foundation of China+2 种基金Project(KM201410005014)supported by the Beijing Municipal Commission of Education,ChinaProject(2015-RX-L11)supported by the Ri Xin Talents Plan of Beijing University of Technology,ChinaProject(009000514316007)supported by the Advanced Medical Instruments of Beijing University of Technology,China
文摘The hot deformation behaviors of as-solution Mg?xZn?yEr alloys (x/y=6, x=3.0, 4.5 and 6.0; y=0.50, 0.75 and 1.00) wereinvestigated on Gleeble?1500 thermal simulator in a temperature range of 200?450 °C at a strain rate of 0.001?1 s?1. The truestress?strain curves showed the dynamic competition between the working hardening and working softening mainly due to thedynamic recrystallization (DRX) occurring during hot compression. The constitutive equations were constructed which couldaccurately predict the peak stress of the alloys. The addition of Zn and/or Er resulted in higher deformation activation energy forMg?3Zn?0.5Er (alloy A). The processing maps were constructed as function of the temperature and the strain rate, providing theoptimum hot working conditions (i.e., at strain of 0.3, Mg?3Zn?0.5Er (alloy A): 380?430 ?C, <0.1 s?1; Mg?4.5Zn?0.75Er (alloy B):380?450 ?C, 0.01?0.1 s?1; Mg?6Zn?1Er (alloy C): 390?440 ?C, 0.01?0.1 s?1). The as-solution treated Mg?4.5Zn?0.75Er (alloy B)demonstrated more optimum hot working window comparing with Mg?3Zn?0.5Er (alloy A) and Mg?6Zn?1Er (alloy C).
基金Project(51135007)supported by the National Natural Science Foundation of ChinaProject(IRT13087)supported by the Innovative Research Team Development Program of Ministry of Education of China+1 种基金Project(2012-86)supported by the High-end Talent Leading Program of Hubei Province,ChinaProject(2012-P08)supported by State Key Laboratory of Materials Processing and Die&Mould Technology,China
文摘Q345E as one of typical low alloy steels is widely used in manufacturing basic components in many fields because of its eminent formability under elevated temperature. In this work, the deformation behavior of Q345E steel was investigated by hot compression experiments on Gleeble-3500 thermo-mechanical simulator with the temperature ranging from 850 ℃ to 1150 ℃ and strain rate ranging from 0.01 s-1 to 10 s-1. The experimental results indicate that dynamic softening of Q345E benefits from increasing deformation temperature and decreasing strain rate. The mathematical relationship between dynamic softening degree and deformation conditions is established to predict the dynamic softening degree quantitatively, which is further proved by some optical microstructures of Q345E. In addition, the experimental results also reveal that the stress level decreases with increasing deformation temperature and decreasing strain rate. The constitutive equation for flow stress of Q345E is formulated by Arrihenius equation and the modified Zener-Hollomon parameter considering the compensation of both strain and strain rate. The flow stress values predicted by the constitutive equation agree well with the experimental values, realizing the accurate prediction of the flow stress of Q345E steel under hot deformation.