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Effect of the interaction between the chemical and the magnetic ordering on the phase equilibria of iron base alloys
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作者 大沼郁雄 KAINUMA Ryosuke ISHIDA Kiyohito 《材料与冶金学报》 CAS 2005年第2期110-110,共1页
It is well known that the magnetic properties such as the Curie temperature Tmag <sub>C and the mean magnetic moment β of ordered compounds have different values from those of the disordered solutions. For inst... It is well known that the magnetic properties such as the Curie temperature Tmag <sub>C and the mean magnetic moment β of ordered compounds have different values from those of the disordered solutions. For instance, both Tmag c and β of the Ni3Pt (L12) and NiPt (L10) and Tmag <sub>c of the CoPt (L10) and CoPt3 (L12) ordered compounds are strongly depressed due to the ordering compared with those of the metastable disordered Ni-Pt and Co-Pt alloys. On the other hand, the γ’-FeNi3 (L12) and the α’-FeCo (B2) ordered compounds have higher Tmag <sub>c and β values comparing with the disordered solution phases, γ (A1) and α (A2), respectively. In consequence, the stability of the ordered phase is depressed or enhanced due to the interaction between the chemical and magnetic ordering caused by the decrease or increase of Tmag <sub>c and β values. The purpose of this study is to investigate the effect of the interaction between the chemical and the magnetic ordering on the phase equilibria in the Fe-X(X=Al, Co, Ni, Rh, Si) binary systems.The Gibbs energy of the α(A2), γ(A1) and liquid phases is described by a sub-regular solution approximation. The ordering contribution to the Gibbs energy ,ΔGorder <sub>m, and deviations of magnetic properties, ΔTmag <sub>c and Δβ, of the ordered compounds, FeAl (B2), Fe3Al (D03), FeCo (B2), FeRh (B2), FeSi (B2), Fe3Si (D03) and FeNi3 (L12) is introduced by the split compound energy formalism. Effect of the interaction between the chemical ordering, B2, D03 and L12 and the magnetic ordering on the phase equilibria will be discussed according to the calculated phase diagrams of the Fe-X binary systems. 展开更多
关键词 化学有序 磁有序 铁基合金 相平衡 交互作用
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Identifying the optimal HVOF spray parameters to attain minimum porosity and maximum hardness in iron based amorphous metallic coatings 被引量:10
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作者 S.Vignesh K.Shanmugam +1 位作者 V.Balasubramanian K.Sridhar 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2017年第2期101-110,共10页
Flow based Erosion e corrosion problems are very common in fluid handling equipments such as propellers, impellers, pumps in warships, submarine. Though there are many coating materials available to combat erosionecor... Flow based Erosion e corrosion problems are very common in fluid handling equipments such as propellers, impellers, pumps in warships, submarine. Though there are many coating materials available to combat erosionecorrosion damage in the above components, iron based amorphous coatings are considered to be more effective to combat erosionecorrosion problems. High velocity oxy-fuel(HVOF)spray process is considered to be a better process to coat the iron based amorphous powders. In this investigation, iron based amorphous metallic coating was developed on 316 stainless steel substrate using HVOF spray technique. Empirical relationships were developed to predict the porosity and micro hardness of iron based amorphous coating incorporating HVOF spray parameters such as oxygen flow rate, fuel flow rate, powder feed rate, carrier gas flow rate, and spray distance. Response surface methodology(RSM) was used to identify the optimal HVOF spray parameters to attain coating with minimum porosity and maximum hardness. 展开更多
关键词 High velocity OXY fuel SPRAY iron baseD AMORPHOUS metallic coating Micro-hardness POROSITY
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Review: Progress in the Preparation of Iron Based Magnetic Nanoparticles for Biomedical Applications 被引量:2
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作者 Yu Mao Yan Li Ning Gu 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2019年第2期1-18,共18页
With unique physical properties, chemical properties, and biological effects, magnetic nanomaterials are important functional materials in many fields. In the past decades, iron based magnetic nanomaterials have attra... With unique physical properties, chemical properties, and biological effects, magnetic nanomaterials are important functional materials in many fields. In the past decades, iron based magnetic nanomaterials have attracted much attention in the biomedicine field due to their superior magnetic properties and great potential in biomedical applications. In particular, magnetic iron oxide nanoparticles(MIONPs) have been playing a crucial role in the biomedicine field because of their diagnostic and therapeutic functions. Meanwhile, MIONPs are benign, low toxic, biocompatible, and biodegradable, so they are the only inorganic magnetic nanomaterials approved by the U.S. Food and Drug Administration(FDA) for clinical use at present. In this review, we mainly introduce the progress in the preparation of iron based magnetic nanomaterials for biomedical applications, including pure iron nanoparticles, iron-based alloy nanoparticles, and MIONPs, with a focus on MIONPs. Also, we summarize the preparation methods of MIONPs and point out the importance of their developments. 展开更多
关键词 iron baseD magnetic NANOMATERIALS BIOMEDICAL applications MIONPs diagnostic and THERAPEUTIC functions preparation methods
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Advancements in biomass gasification research utilizing iron-based oxygen carriers in chemical looping:A review
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作者 Yonghong Niu Zhengyang Chi Ming Li 《Materials Reports(Energy)》 EI 2024年第3期35-48,共14页
Biomass,recognized as renewable green coal,is pivotal for energy conservation,emission reduction,and dualcarbon objectives.Chemical looping gasification,an innovative technology,aims to enhance biomass utilization eff... Biomass,recognized as renewable green coal,is pivotal for energy conservation,emission reduction,and dualcarbon objectives.Chemical looping gasification,an innovative technology,aims to enhance biomass utilization efficiency.Using metal oxides as oxygen carriers regulates the oxygen-to-fuel ratio to optimize synthesis product yields.This review examines various oxygen carriers and their roles in chemical looping biomass gasification,including natural iron ore types,industrial by-products,cerium oxide-based carriers,and core-shell structures.The catalytic,kinetic,and phase transfer properties of iron-based oxygen carriers are analyzed,and their catalytic cracking capabilities are explored.Molecular interactions are elucidated and system performance is optimized by providing insights into chemical looping reaction mechanisms and strategies to improve carrier efficiency,along with discussing advanced techniques such as density functional theory(DFT)and reactive force field(ReaxFF)molecular dynamics(MD).This paper serves as a roadmap for advancing chemical looping gasification towards sustainable energy goals. 展开更多
关键词 Chemical looping gasification iron based oxygen carrier Preparation of oxygen carrier system
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Tribological behaviour of sintered iron based self-lubricating composites 被引量:5
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作者 Jose Daniel Biasoli DE MELLO Cristiano BINDER +2 位作者 Gisele HAMMES Roberto BINDER Aloisio Nelmo KLEIN 《Friction》 CSCD 2017年第3期285-307,共23页
This work is a review of previous works,presenting and discussing the most important results obtained by an ongoing research program towards the development of innovative,low-cost,self-lubricating composites with a lo... This work is a review of previous works,presenting and discussing the most important results obtained by an ongoing research program towards the development of innovative,low-cost,self-lubricating composites with a low friction coefficient and high mechanical strength and wear resistance.Special emphasis is given to uniaxial die pressing of solid lubricant particles mixed with matrix powders and to metal injection moulding associated with in situ generation of solid lubricant particles.Initially,a microstructural model/processing route (powder injection moulding followed by plasma-assisted debinding and sintering) produced a homogeneous dispersion of in situ generated solid lubricant particles.Micrometric nodules of graphite with diameter smaller than 20 μm were formed,constituting a nanostructured stacking of graphite foils with nanometric thickness.Micro Raman analysis indicated that the graphite nodules were composed of turbostratic 2D graphite having highly misaligned graphene planes separated by large interlamellae distance.Large interplanar distance between the graphene foils and misalignment of these foils were confirmed by transmission electron microscopy and were,probably,the origin of the outstandingly low dry friction coefficient (0.04).The effect of sintering temperature,precursor content,metallic matrix composition and surface finish is also reported.Furthermore,the influence of a double-pressing/double-sintering (DPDS) technique on the tribological performance of self-lubricating uniaxially die-pressed hBN + graphite-Fe-Si-C-Mo composite is also investigated.Moreover,the tribological behaviour of die-pressed Fe-Si-C matrix composites containing 5,7.5 and 10 wt% solid lubricants (hBN and graphite) added during the mixing step is analysed in terms of mechanical properties and wear mechanisms.Finally,the synergy between solid lubricant particles dispersed in a metallic matrix and fluid lubricants in a cooperative mixed lubrication regime is presented. 展开更多
关键词 tribological behaviour powder metallurgy iron based SELF-LUBRICATING COMPOSITES turbostratic graphite
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New Iron-based SiC Spherical Composite Magnetic Abrasive for Magnetic Abrasive Finishing 被引量:12
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作者 ZHANG Guixiang ZHAO Yugang +2 位作者 ZHAO Dongbiao ZUO Dunwen YIN Fengshi 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2013年第2期377-383,共7页
SiC magnetic abrasive is used to polish surfaces of precise, complex parts which are hard, brittle and highly corrosion-resistant in magnetic abrasive finishing(MAF). Various techniques are employed to produce this ... SiC magnetic abrasive is used to polish surfaces of precise, complex parts which are hard, brittle and highly corrosion-resistant in magnetic abrasive finishing(MAF). Various techniques are employed to produce this magnetic abrasive, but few can meet production demands because they are usually time-consuming, complex with high cost, and the magnetic abrasives made by these techniques have irregular shape and low bonding strength that result in low processing efficiency and shorter service life. Therefore, an attempt is made by combining gas atomization and rapid solidification to fabricate a new iron-based SiC spherical composite magnetic abrasive. The experimental system to prepare this new magnetic abrasive is constructed according to the characteristics of gas atomization and rapid solidification process and the performance requirements of magnetic abrasive. The new iron-based SiC spherical composite magnetic abrasive is prepared successfully when the machining parameters and the composition proportion of the raw materials are controlled properly. Its morphology, microstructure, phase composition are characterized by scanning electron microscope(SEM) and X-ray diffraction(XRD) analysis. The MAF tests on plate of mold steel S136 are carried out without grinding lubricant to assess the finishing performance and service life of this new SiC magnetic abrasive. The surface roughness(Ra) of the plate worked is rapidly reduced to 0.051 μm from an initial value of 0.372 μm within 5 min. The MAF test is carried on to find that the service life of this new SiC magnetic abrasive reaches to 155 min. The results indicate that this process presented is feasible to prepare the new SiC magnetic abrasive; and compared with previous magnetic abrasives, the new SiC spherical composite magnetic abrasive has excellent finishing performance, high processing efficiency and longer service life. The presented method to fabricate magnetic abrasive through gas atomization and rapid solidification presented can significantly improve the finishing performance and service life of magnetic abrasive, and provide a more practical approach for large-scale industrial production of magnetic abrasive. 展开更多
关键词 iron-based SiC composite powder gas atomization and rapid solidification spherical composite magnetic abrasive magnetic abrasive finishing(MAF)
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Iron-based catalysts encapsulated by nitrogen-doped graphitic carbon for selective synthesis of liquid fuels through the Fischer-Tropsch process 被引量:3
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作者 Lei Tang Xiao‐Ling Dong +2 位作者 Wei Xu Lei He An‐Hui Lu 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2018年第12期1971-1979,共9页
Fischer‐Tropsch synthesis(FTS)has the potential to be a powerful strategy for producing liquid fuels from syngas if highly selective catalysts can be developed.Herein,a series of iron nanoparticle catalysts encapsula... Fischer‐Tropsch synthesis(FTS)has the potential to be a powerful strategy for producing liquid fuels from syngas if highly selective catalysts can be developed.Herein,a series of iron nanoparticle catalysts encapsulated by nitrogen‐doped graphitic carbon were prepared by a one‐step pyrolysis of a ferric L‐glutamic acid complex.The FeC‐800 catalyst pyrolyzed at 800°C showed excellent catalytic activity(239.4μmolCO gFe–1 s–1),high C5–C11 selectivity(49%),and good stability in FTS.The high dispersion of ferric species combined with a well‐encapsulated structure can effectively inhibit the migration of iron nanoparticles during the reaction process,which is beneficial for high activity and good stability.The nitrogen‐doped graphitic carbon shell can act as an electron donor to the iron particles,thus promoting CO activation and expediting the formation of Fe5C2,which is the key factor for obtaining high C5–C11 selectivity. 展开更多
关键词 Nitrogen doping Graphitic carbon ENCAPSULATION ironbased catalyst Fischer‐Tropsch synthesis
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Effect of Al_2O_3 Binder on the Precipitated Iron-Based Catalysts for Fischer-Tropsch Synthesis 被引量:6
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作者 Hai-Jun Wan Bao-Shan Wu +4 位作者 Xia An Ting-Zhen Li Zhi-Chao Tao Hong-Wei Xiang Yong-Wang Li 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2007年第2期130-138,共9页
A series of iron-based Fischer-Tropsch synthesis (FTS) catalysts incorporated with Al2O3 binder were prepared by the combination of co-precipitation and spray drying technology. The catalyst samples were characteriz... A series of iron-based Fischer-Tropsch synthesis (FTS) catalysts incorporated with Al2O3 binder were prepared by the combination of co-precipitation and spray drying technology. The catalyst samples were characterized by using N2 physical adsorption, temperature-programmed reduction/desorption (TPR/TPD) and MSssbauer effect spectroscopy (MES) methods. The characterization results indicated that the BET surface area increases with increasing Al2O3 content and passes through a maximum at the Al2O3/Fe ratio of 10/100 (weight basis). After the point, it decreases with further increase in Al2O3 content. The incorporation of Al2O3 binder was found to weaken the surface basicity and suppress the reduction and carburization of iron-based catalysts probably due to the strong K-Al2O3 and Fe-Al2O3 interactions. Furthermore, the H2 adsorption ability of the catalysts is enhanced with increasing Al2O3 content. The FTS performances of the catalysts were tested in a slurry-phase continuously stirred tank reactor (CSTR) under the reaction conditions of 260 ℃, 1.5 MPa, 1000 h^-1 and molar ratio of H2/CO 0.67 for 200 h. The results showed that the addition of small amounts of Al2O3 affects the activity of iron-based catalysts to a little extent. However, with further increase of Al2O3 content, the FTS activity and water gas shift reaction (WGS) activity are decreased severely. The addition of appropriate Al2O3 do not affect the product selectivity, but the catalysts incorporated with large amounts of Al2O3 have higher selectivity for light hydrocarbons and lower selectivity for heavy hydrocarbons. 展开更多
关键词 Fischer-Tropsch synthesis iron-based catalyst Al2O3 binder Fe-Al2O3 interaction
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Recent advances in application of iron‐based catalysts for CO_(x) hydrogenation to value‐added hydrocarbons 被引量:3
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作者 Junhui Liu Yakun Song +2 位作者 Xuming Guo Chunshan Song Xinwen Guo 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2022年第3期731-754,共24页
The widespread utilization of fossil fuels has caused an associated increase in CO_(2) emissions over the past few decades,which has resulted in global warming and ocean acidification.CO hydrogenation(Fischer‐Tropsch... The widespread utilization of fossil fuels has caused an associated increase in CO_(2) emissions over the past few decades,which has resulted in global warming and ocean acidification.CO hydrogenation(Fischer‐Tropsch synthesis,FTS)is considered a significant route for the production of liquid fuels and chemicals from nonpetroleum sources to meet worldwide demand.Conversion of CO_(2) with renewable H_(2) into valuable hydrocarbons is beneficial for reducing dependence on fossil fuels and mitigating the negative effects of high CO_(2) concentrations in the atmosphere.Iron‐based catalysts exhibit superior catalytic performance in both FTS and CO_(2) hydrogenation to value‐added hydrocarbons.The abundance and low cost of iron‐based catalysts also promote their wide application in CO_(x) hydrogenation.This paper provides a comprehensive overview of the significant developments in the application of iron‐based catalysts in these two fields.The active phases,promoter effect,and support of iron‐based catalysts are discussed in the present paper.Based on understanding of these three essential aspects,we also cover recent advances in the design and preparation of novel iron‐based catalysts for FTS and CO_(2) hydrogenation.Current challenges and future catalytic applications are also outlined. 展开更多
关键词 ironbased catalyst Fischer‐Tropsch synthesis CO_(2)hydrogenation PROMOTER Support Active phase
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Warm compacted NbC particulate reinforced iron-base composite(Ⅰ)--Effect of fabrication parameters 被引量:5
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作者 李元元 肖志瑜 +2 位作者 倪东惠 周照耀 邵明 《中国有色金属学会会刊:英文版》 CSCD 2002年第4期659-663,共5页
NbC was used as reinforced particles in the fabrication of iron base composite. Ball milling was introduced to overcome the problems of agglomeration and powder separation during powder mixing. After ball milling, the... NbC was used as reinforced particles in the fabrication of iron base composite. Ball milling was introduced to overcome the problems of agglomeration and powder separation during powder mixing. After ball milling, the fine NbC particles are embedded on the surface of iron particles and evenly distributed in the mixed powders. Warm compaction was used not only to increase the green density but also to improve the formability of the mixed powder and to improve the compact’s green strength to facilitate handling. The influences of fabrication parameters such as ball milling time, annealing temperature and time, warm compaction temperature, sintering temperature and sintering time were studied. Compacts with a relative sintered density of 97% and a tensile strength of more than 800?MPa can be obtained by using a ball milling time of 5?h, an annealing temperature of 800?℃, a compaction pressure of 600?MPa, warm compaction temperature of 120?℃, sintering temperature of 1?280?℃, and sintering time of 80?min. The shrinkage at this sintering condition was approximately 4.3%. 展开更多
关键词 碳化铌 颗粒增强 铁基复合材料 冶金技术 制备 MMCS
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Warm compacted NbC particulate reinforced iron-base composite(Ⅱ)--Microstructure and properties 被引量:5
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作者 李元元 肖志瑜 +2 位作者 倪东惠 夏伟 陈维平 《中国有色金属学会会刊:英文版》 CSCD 2002年第4期664-668,共5页
Effects of different sintering temperature and sintering time on the relative density of the sintered compacts were studied to obtain the optimal sintering parameters for the fabrication of NbC parti culate reinforced... Effects of different sintering temperature and sintering time on the relative density of the sintered compacts were studied to obtain the optimal sintering parameters for the fabrication of NbC parti culate reinforced iron base composite. With optimal sintering temperature of 1?280?℃ and sintering time of 80?min, wear resisting, high density NbC particulate reinforced iron base composites can be obtained using warm compaction powder metallurgy. The microstructure, relative density, mechanical properties and tribological behaviors of the sintered composites were studied. The results indicate that the mechanical properties of the sintered compacts were closely related to the sintered density. The iron base composite materials with different combinations of mechanical properties and tribological behaviors were developed for different applications. One of the developed composite, which contains 10%NbC, possesses a high strength of 815?MPa with a remarkable friction and wear behaviors. The other developed composite, which contains 15%NbC, possesses a lesser strength of 515?MPa but with excellent friction and wear behaviors. 展开更多
关键词 MMCS 显微组织 碳化铌 颗粒增强 铁基复合材料 性质
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Effect of Manganese Incorporation Manner on an Iron-Based Catalyst for Fischer-Tropsch Synthesis 被引量:5
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作者 Tingzhen Li Yong Yang +5 位作者 Chenghua Zhang Zhichao Tao Haijun Wan Xia An Hongwei Xiang Yongwang Li 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2007年第3期244-251,共8页
A systematic study was undertaken to investigate the effects of the manganese incorporation manner on the textural properties, bulk and surface phase compositions, reduction/carburization behaviors, and surface basici... A systematic study was undertaken to investigate the effects of the manganese incorporation manner on the textural properties, bulk and surface phase compositions, reduction/carburization behaviors, and surface basicity of an iron-based Fischer-Tropsch synthesis (FTS) catalyst. The catalyst samples were characterized by N2 physisorption, X-ray photoelectron spectroscopy (XPS), H2 (or CO) temperature-programmed reduction (TPR), CO2 temperature-programmed desorption (TPD), and M5ssbauer spectroscopy. The FTS performance of the catalysts was studied in a slurry-phase continuously stirred tank reactor (CSTR). The characterization results indicated that the manganese promoter incorporated by using the coprecipitation method could improve the dispersion of iron oxide, and decrease the size of the iron oxide crystallite. The manganese incorporated with the impregnation method is enriched on the catalyst's surface. The manganese promoter added with the impregnation method suppresses the reduction and carburization of the catalyst in H2, CO, and syngas because of the excessive enrichment of manganese on the catalyst surface. The catalyst added manganese using the coprecipitation method has the highest CO conversion (51.9%) and the lowest selectivity for heavy hydrocarbons (C12+). 展开更多
关键词 Fischer-Tropsch synthesis iron-based catalyst manganese promoter incorporation manner
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Fabrication of Iron-base Alloy by Spark Plasma Sintering 被引量:2
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作者 Yuanyuan LI Xiaoqiang LI Yah LONG Wei XIA Min ZHU Weiping CHEN 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2006年第2期257-260,共4页
Fe-2Cu-2Ni-1Mo-0.8C (wt pct) elemental mixed powders were rapidly sintered within 6 min by spark plasma sintering, and the effects of sintering parameters on the densification degree and performance of the assintere... Fe-2Cu-2Ni-1Mo-0.8C (wt pct) elemental mixed powders were rapidly sintered within 6 min by spark plasma sintering, and the effects of sintering parameters on the densification degree and performance of the assintered materials were investigated. Results showed that when a proper combination of pulse electric current and constant electric current was employed for sintering, the density and bend strength of the as-sintered material reached the maxima, being 7.61×10^3 kg/m^3 and 1540 MPa, respectively. Its corresponding fracture morphology was characterized as the mix of ductile, intergranular and cleavage fractures. 展开更多
关键词 Spark plasma sintering iron-base alloy DENSITY Microstructure and performance
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Signal Detection of Carbon in Iron-Based Alloy by Double-Pulse Laser-Induced Breakdown Spectroscopy 被引量:2
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作者 林晓梅 李晗 姚清华 《Plasma Science and Technology》 SCIE EI CAS CSCD 2015年第11期953-957,共5页
Although single-pulse lasers are often used in traditional laser-induced breakdown spectroscopy (LIBS) measurements, their measurement outcomes are generally undesirable because of the low sensitivity of carbon in i... Although single-pulse lasers are often used in traditional laser-induced breakdown spectroscopy (LIBS) measurements, their measurement outcomes are generally undesirable because of the low sensitivity of carbon in iron-based alloys. In this article, a double-pulse laser was applied to improve the signal intensity of carbon. Both the inter-pulse delay and the combination of laser wavelengths in double-pulse laser-induced breakdown spectroscopy (DP-LIBS) were optimized in our experiment. At the optimized inter-pulse delay, the combination of a first laser of 532 nm and a second laser of 1,064 nm achieved the highest signal enhancement. The properties of the target also played a role in determining the mass ablation enhancement in DP-LIBS configuration. 展开更多
关键词 DP-LIBS CARBON signal detection iron-based alloy
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Crystal chemistry and structural design of iron-based superconductors 被引量:2
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作者 蒋好 孙云蕾 +1 位作者 许祝安 曹光旱 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第8期135-145,共11页
The second class of high-temperature superconductors (HTSCs), iron-based pnictides and chalcogenides, necessarily contain Fe2X2 ("X" refers to a pnictogen or a chalcogen element) layers, just like the first clas... The second class of high-temperature superconductors (HTSCs), iron-based pnictides and chalcogenides, necessarily contain Fe2X2 ("X" refers to a pnictogen or a chalcogen element) layers, just like the first class of HTSCs which possess the essential CuO2 sheets. So far, dozens of iron-based HTSCs, classified into nine groups, have been discovered. In this article, the crystal-chemistry aspects of the known iron-based superconductors are reviewed and summarized by employing "hard and soft acids and bases (HSAB)" concept. Based on these understandings, we propose an alternative route to exploring new iron-based superconductors via rational structural design. 展开更多
关键词 iron-based superconductors crystal chemistry structural design
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Angle-resolved photoemission spectroscopy study on iron-based superconductors 被引量:2
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作者 叶子荣 张焱 +1 位作者 谢斌平 封东来 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第8期109-122,共14页
Angle-resolved photoemission spectroscopy (ARPES) has played an important role in determining the band structure and the superconducting gap structure of iron-based superconductors. In this paper, from the ARPES per... Angle-resolved photoemission spectroscopy (ARPES) has played an important role in determining the band structure and the superconducting gap structure of iron-based superconductors. In this paper, from the ARPES perspective, we briefly review the main results from our group in recent years on the iron-based superconductors and their parent compounds, and depict our current understanding on the antiferromagnetism and superconductivity in these materials. 展开更多
关键词 iron-based superconductors angle-resolved photoemission spectroscopy electronic structure
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Die wall lubricated warm compaction of iron-based powder metallurgy material 被引量:2
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作者 倪东惠 陈维平 +2 位作者 肖志瑜 温利平 吴苑标 《中国有色金属学会会刊:英文版》 CSCD 2002年第6期1095-1098,共4页
Lubricant is harmful to the mechanical properties of the sintered materials. Die wall lubrication was applied on warm compaction powder metallurgy in the hope of reducing the concentration level of the admixed lubrica... Lubricant is harmful to the mechanical properties of the sintered materials. Die wall lubrication was applied on warm compaction powder metallurgy in the hope of reducing the concentration level of the admixed lubricant. Iron based samples were prepared by die wall lubricated warm compaction at 175 ℃, using a compacting pressure of 550 MPa. Emulsified polytetrafluoroethylene(PTFE) was used as die wall lubricant. Admixed lubricant concentration ranging from 0 to 0.5% was tested. Extremely low admixed lubricant contents were used. Results show that in addition to the decrease in ejection forces, the green density of the compacts increases with the decrease of admixed lubricant content until it reaches the maximum at 0.06% of lubricant content, then decreases with the decrease of admixed lubricant content. The mechanical properties of the sintered compacts that contain more than 0.06% admixed lubricant are better than those of the samples that contain lesser lubricant. No scoring was observed in all die wall lubricated experiments. 展开更多
关键词 加热压塑 模壁润滑 粉末冶金离子基材料
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Migration behaviors and kinetics of phosphorus during coal-based reduction of high-phosphorus oolitic iron ore 被引量:7
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作者 Yong-sheng Sun Yan-feng Li +1 位作者 Yue-xin Han Yan-jun Li 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2019年第8期938-945,共8页
To understand the migration mechanisms of phosphorus(P)during coal-based reduction,a high-phosphorus oolitic iron ore was reduced by coal under various experimental conditions.The migration characteristics and kinetic... To understand the migration mechanisms of phosphorus(P)during coal-based reduction,a high-phosphorus oolitic iron ore was reduced by coal under various experimental conditions.The migration characteristics and kinetics of P were investigated by a field-emission electron probe microanalyzer(FE-EPMA)and using the basic principle of solid phase mass transfer,respectively.Experimental results showed that the P transferred from the slag to the metallic phase during reduction,and the migration process could be divided into three stages:phosphorus diffusing from the slag to the metallic interface,the formation of Fe P compounds at the slag metal interface and P diffusing from the slag metal interface to the metallic interior.The reduction time and temperature significantly influenced the phosphorus content of the metallic and slag phases.The P content of the metallic phase increased with increasing reduction time and temperature,while that of the slag phase gradually decreased.The P diffusion constant and activation energy were determined and a migration kinetics model of P in coal-based reduction was proposed.P diffusion in the metallic phase was the controlling step of the P migration. 展开更多
关键词 high-phosphorus oolitic iron ORE COAL-baseD REDUCTION PHOSPHORUS migration KINETICS
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Polymerization of Norbornene via an Iron-Based Complex/MAO Catalytic System 被引量:1
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作者 MI Xia MA Zhi +4 位作者 YAN Wei-dong LIU Yuan-xia WANG Hang KE Yu-cai HU You-liang 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2002年第4期462-465,共4页
Polynorbornenes were synthesized in the presence of an iron based catalyst, 2,6-bis[1-(2,6-diisopropyl-phenylimino)ethyl]pyridine iron(Ⅱ) dichloride. The FTIR, 1H NMR and 13C NMR analysis results revealed t... Polynorbornenes were synthesized in the presence of an iron based catalyst, 2,6-bis[1-(2,6-diisopropyl-phenylimino)ethyl]pyridine iron(Ⅱ) dichloride. The FTIR, 1H NMR and 13C NMR analysis results revealed that the structure of the obtained polynorbornenes consisted of vinyl addition polymer substructures without any ring-opening structures. The polymers were amorphous with a short-range order, displayed in the WAXD(wide angle X-ray diffraction) diagrams. The glass transition temperatures ranged from 200 to 400 ℃. The effects of the polymerization reaction conditions, such as Al/Fe molar ratio and toluene/CH_2Cl_2 volume ratio, on the activity, intrinsic viscosity and T_g were also studied. 展开更多
关键词 POLYNORBORNENE iron-based complex Vinyl addition polymer Short-range order Norbornene polymerization
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Review of nuclear magnetic resonance studies on iron-based superconductors 被引量:1
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作者 马龙 于伟强 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第8期181-197,共17页
The newly discovered iron-based superconductors have triggered renewed enormous research interest in the condensed matter physics community. Nuclear magnetic resonance (NMR) is a low-energy local probe for studying ... The newly discovered iron-based superconductors have triggered renewed enormous research interest in the condensed matter physics community. Nuclear magnetic resonance (NMR) is a low-energy local probe for studying strongly correlated electrons, and particularly important for high-Tc superconductors. In this paper, we review NMR studies on the structural transition, antiferromagnetic order, spin fluctuations, and superconducting properties of several iron-based high-Tc superconductors, including LaFeAsOl_xFx, LaFeAsOl_x, BaFe2As2, Bal_xKxFe2As2, Cao.23Nao.67Fe2As2, BaFe2(Asl_xPx)2, Ba(Fel_xRux)2As2, Ba(Fel_xCox)2As2, Lil+xFeAs, LiFel_xCoxAs, NaFeAs, NaFel_xCoxAs, KyFe2_xSe2, and (T1,Rb)yFe2_xSe2. 展开更多
关键词 iron-based superconductors nuclear magnetic resonance (NMR) spin fluctuation superconduc-tivity
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