The disposal of filtered tailings in high dry stacks can induce particle breakage,changing the material's behaviour during the structure's lifetime.The grading changes influence material properties at the crit...The disposal of filtered tailings in high dry stacks can induce particle breakage,changing the material's behaviour during the structure's lifetime.The grading changes influence material properties at the critical state,and this is not mature for intermediate artificial soils(tailings)in a broad range of confining pressures.In this paper,it aims to describe the behaviour of iron ore tailings in a spectrum of confining pressures broader than the reported in previous studies.A series of consolidated drained(CD)triaxial tests was carried out with confining pressures ranging from 0.075 MPa to 120 MPa.These results show that the amount of breakage plays an essential role in the response of iron ore tailings.The existence of curved critical state line(CSL)in both specific volume(ν)-logarithm of mean effective stress(p′)and deviatoric stress(q)-mean effective stress(p′)planes,and different responses in the deviatoric stress-axial strain-volumetric strain curves were verified.An inverse S-shaped equation was proposed to represent the silty-sandy tailings'behaviour up to high pressures onν-lnp′plane.The proposed equation provides a basis for enhancing constitutive models and considers the evolution of the grading up to severe loading conditions.The adjustment considered three regions with different responses associated with particle breakage at different pressure levels.展开更多
The disposal of mining tailings has increasingly focused on the use of dry stacks.These structures offer more security since they use filtered and compacted material.Because of the construction method and the heights ...The disposal of mining tailings has increasingly focused on the use of dry stacks.These structures offer more security since they use filtered and compacted material.Because of the construction method and the heights achieved,the material that compounds the structure can be subjected to different stress paths along the failure plane.The theoretical framework considered in the design of these structures generally is the critical state soil mechanics(CSSM).However,the data in the literature concerning the uniqueness of critical state line(CSL)is still controversial as the soil is subjected to different stress paths.With respect to tailings,this question is even more restricted.This paper studies two tailings with different gradings due to the beneficial processes over extension and compression paths.A series of drained and undrained triaxial tests was conducted over a range of initial densities and stress levels.In the q-p'plane,different critical stress ratio(M)values were obtained for compression and extension stress paths.However,the critical state friction angle is very similar with a slightly higher critical state friction angle for extension tests.Curved stress path dependent CSLs were obtained in the n-lnp0 plane with the extension tests below the CSL defined in compression.Regarding the fines content,the studied tailings presented very similar M and critical state friction angle values.However,the fines content af-fects the volumetric behavior of the studied tailings and the CSLs on the n-lnp0 plane shift downwards with the increasing fines content for compression and extension tests.In relation to dilatancy analysis,the fines content did not present an evident influence on the dilatancy of the materials.However,different values of mean stress ratio N were obtained between compression and extension tests and can corroborate the existence of non-unique CSLs for these materials.展开更多
In the background of little reuse and large stockpile for iron ore tailings, iron ore tailing from Chinese Tonghua were used as raw material to prepare cementitious materials. Cementitious properties of the iron ore t...In the background of little reuse and large stockpile for iron ore tailings, iron ore tailing from Chinese Tonghua were used as raw material to prepare cementitious materials. Cementitious properties of the iron ore tailings activated by compound thermal activation were studied. Testing methods, such as XRD, TG-DTA, and IR were used for researching the phase and structure variety of the iron ore railings in the process of compound thermal activation. The results reveal that a new cementitious material that contains 30wt% of the iron ore tailings can be obtained by compounded thermal activation, whose mortar strength can come up to the standard of 42.5 cement of China.展开更多
In order to develop the applications of ore tailings, the glass ceramics were prepared by using a conventional melting-quenching-sintering process. The phase component, microstructures, magnetic properties and thermal...In order to develop the applications of ore tailings, the glass ceramics were prepared by using a conventional melting-quenching-sintering process. The phase component, microstructures, magnetic properties and thermal conductivities of the prepared glass ceramics were investigated by using X-ray diffractometer, scanning electron microscopy, vibrating sample magnetometer and thermophysical properties tester, respectively. The results show that orthorhombic olivine-type phase and triclinic sunstone-type phase formed when the glass was annealed at 700 oC, the concentration of olivine-type and sunstone-type phases decreased, the spinel-type cubic phase occurred and the amount increased when the annealing temperatures increased. The magnetic properties from the cubic spinel ferrites were detected in the glass ceramics, and the related saturation magnetization increased with the annealing temperature increasing. The porous glass ceramics with magnetic property showed much lower thermal conductivity, compared with the non-magnetic porous glass-ceramic and the dense glass-ceramics.展开更多
Improving the activity of Iron Ore Tailings(IOTs)to utilize them as a mineral admixture in cement-based minerals is still challenging.In this paper,the wet grinding technology was employed to stimulate the activity of...Improving the activity of Iron Ore Tailings(IOTs)to utilize them as a mineral admixture in cement-based minerals is still challenging.In this paper,the wet grinding technology was employed to stimulate the activity of IOTs,and the traditional dry grinding method was used as a reference.The effect of wet grinding on the activation of IOTs was evaluated through ion leaching from an alkaline solution and the reactivity index.Additionally,a detailed comparison between Dry-grinding Iron Ore Tailings(DIOTs)and Wet-grinding Iron Ore Tailings(WIOTs)was made.This comparison was based on particle characteristics,crystal structures,chemical structure,and surface properties.The results showed that the particle size of IOTs reduced rapidly during wet grinding.In addition,WIOTs had a higher activity index compared to DIOTs.The storage of lattice distortions in the quartz crystal structure was also more significant during the wet grinding process than during the dry grinding process.Moreover,both prolonged dry and wet grinding could destabilize the Si-O bond and decrease the surface binding energy.展开更多
The aim of this study is to understand the relationship between the polymerization degree and cememitious activity of iron ore tailings. In light of the poor usage of iron ore tailings, stockpile samples from Tangshan...The aim of this study is to understand the relationship between the polymerization degree and cememitious activity of iron ore tailings. In light of the poor usage of iron ore tailings, stockpile samples from Tangshan were studied in terms of their ability to become cementitious materials. Compound thermal activation was used to improve the cementitious properties of the tailings, while analyzing methods, such as X-ray diffraction (XRD), infrared spectroscopy (IR), nuclear magnetic resonance (NMR), and X-ray photoelectron spectrometer (XPS), were employed to study the changes in phase and structure under different activation conditions. The results reveal clear relationships between the binding energies of Si2p and O 1 s, polymerization degree, and cementitious activity of iron ore tailings.展开更多
In order to distinguish the filling effect and volcanic activity and explore the ways motivating the activity of rich-silicon iron ore tailing(IOT), inert quartz was brought in as the correction standard, the influe...In order to distinguish the filling effect and volcanic activity and explore the ways motivating the activity of rich-silicon iron ore tailing(IOT), inert quartz was brought in as the correction standard, the influences of fineness, calcination, thermal curing system and some other factors were investigated by IR, XRD, MIP, and so on microscopic methods. The experimental results show grinding and calcination can only change the amorphous state of SiO2, and IOT do not have volcanic activity in concrete cured under room temperature condition. Thermal curing systems can stimulate the activity of IOT, especially mortar cured by autoclave curing system can consume a large amount of Ca(OH)2 and hard calcium silicate and has a closer structure. When the specific surface area of IOT powder is 800 m^2/kg, and 30% cement is replaced by IOT powder, the mortar strength with IOT powder is even higher than that with cementonly.展开更多
Herein,micro iron ore tailings(micro-IOTs)were prepared by wet-grinding and applied to improve sulphoaluminate cement(SAC)performance.The physicochemical properties of micro-IOTs were investigated by particle size ana...Herein,micro iron ore tailings(micro-IOTs)were prepared by wet-grinding and applied to improve sulphoaluminate cement(SAC)performance.The physicochemical properties of micro-IOTs were investigated by particle size analysis,XRD,and XPS.The hydrates trait and the hydration mechanism of micro-IOTs-SAC composite were studied by XRD,TGA,MIP,and SEM.The results demonstrated that micro-IOTs with an average grain diameter of 517 nm could be obtained by wet-grinding.The setting time of SAC gradually decreased with increasing micro-IOTs content.By adding 2%micro-IOTs,the compressive strengths of SAC pastes were enhanced about 22%and 10%at 4 h and 28 d,respectively.Moreover,the addition of micro-IOTs accelerated ettringite precipitation and changed its morphology,resulting in early strength improvement of the binary system.And increased later strength by micro-IOTs was closely related to the high content of AH_(3),fine pore structure,and high hydration degree of SAC.The findings suggested one new approach to utilize iron ore tailings in cementbased materials.展开更多
In order to solve the problems caused by the storage of iron ore tailings (IOTs), many researchers conducted a series of experimental studies on the reuse of IOTs. The results of many studies showed that it was feasib...In order to solve the problems caused by the storage of iron ore tailings (IOTs), many researchers conducted a series of experimental studies on the reuse of IOTs. The results of many studies showed that it was feasible to use IOTs for road engineering. This paper summarized the composition, gradation and particle characteristics of IOTs from chemical and physical aspects, and proved the feasibility of IOTs replacing traditional aggregate for asphalt concrete. Then, the research on the road performance of asphalt concrete incorporating IOTs were summarized and reviewed, including the evaluation of high-temperature stability, low-temperature crack resistance, fatigue resistance and water stability. The water stability and the improvement of adhesion between asphalt and IOTs aggregate were discussed in detail. Finally, the performance of IOTs as asphalt concrete aggregate and the existing defects were evaluated, and future research directions were proposed.展开更多
The aim of this study was to investigate the synthesis of iron oxide pigments from IOT. The sample of IOT was obtained through mining activity of the Quadrilátero Ferrífero in the state of Minas Gerais, Braz...The aim of this study was to investigate the synthesis of iron oxide pigments from IOT. The sample of IOT was obtained through mining activity of the Quadrilátero Ferrífero in the state of Minas Gerais, Brazil. The procedure was carried out by hot acid leaching with hydrochloric acid (HCl) which allowed the recovery of about 95% of the iron in a liquor. The iron-based pigments—red (IBP_R), black (IBP_B), and yellow (IBP_Y)—were synthetised from the liquor by selective precipitation, crystallisation, and thermal procedures. The pigments were characterised by particle size distribution, mineral and chemical compositions, as well as colourimetric properties. The process of synthesis was successful and the procedure was shown to maximise the utilisation of mineral resources and minimise the environmental, social, and economic impacts associated with IOT disposal.展开更多
This study presents a laboratory investigation of load-settlement behaviour of a strip footing resting on iron ore tailings used as a structural fill.The footing was placed at various depths in the tailings bed.The re...This study presents a laboratory investigation of load-settlement behaviour of a strip footing resting on iron ore tailings used as a structural fill.The footing was placed at various depths in the tailings bed.The relative density of the tailings was varied as D_r = 50%,70%and 90%.An incremental load was applied on the footing while observing the settlement until the failure took place.The results obtained for tailings were compared with those for the sandy soil.It is observed that the load-bearing capacity and stiffness increase with an increase in footing embedment depth and relative density.Compared to load-settlement behaviour of Perth sandy soil,the tailings fill could have as high as 22 times and 13.5 times the load-bearing capacity and stiffness,respectively.Therefore,the replacement of sandy soil with iron ore tailings for structural fills is cost-effective,and moreover,this application contributes to environmental sustainability in construction.展开更多
文摘The disposal of filtered tailings in high dry stacks can induce particle breakage,changing the material's behaviour during the structure's lifetime.The grading changes influence material properties at the critical state,and this is not mature for intermediate artificial soils(tailings)in a broad range of confining pressures.In this paper,it aims to describe the behaviour of iron ore tailings in a spectrum of confining pressures broader than the reported in previous studies.A series of consolidated drained(CD)triaxial tests was carried out with confining pressures ranging from 0.075 MPa to 120 MPa.These results show that the amount of breakage plays an essential role in the response of iron ore tailings.The existence of curved critical state line(CSL)in both specific volume(ν)-logarithm of mean effective stress(p′)and deviatoric stress(q)-mean effective stress(p′)planes,and different responses in the deviatoric stress-axial strain-volumetric strain curves were verified.An inverse S-shaped equation was proposed to represent the silty-sandy tailings'behaviour up to high pressures onν-lnp′plane.The proposed equation provides a basis for enhancing constitutive models and considers the evolution of the grading up to severe loading conditions.The adjustment considered three regions with different responses associated with particle breakage at different pressure levels.
基金wish to express their appreciation to Vale S.A.and Brazilian Research Council(CNPq)for the support to the research group.
文摘The disposal of mining tailings has increasingly focused on the use of dry stacks.These structures offer more security since they use filtered and compacted material.Because of the construction method and the heights achieved,the material that compounds the structure can be subjected to different stress paths along the failure plane.The theoretical framework considered in the design of these structures generally is the critical state soil mechanics(CSSM).However,the data in the literature concerning the uniqueness of critical state line(CSL)is still controversial as the soil is subjected to different stress paths.With respect to tailings,this question is even more restricted.This paper studies two tailings with different gradings due to the beneficial processes over extension and compression paths.A series of drained and undrained triaxial tests was conducted over a range of initial densities and stress levels.In the q-p'plane,different critical stress ratio(M)values were obtained for compression and extension stress paths.However,the critical state friction angle is very similar with a slightly higher critical state friction angle for extension tests.Curved stress path dependent CSLs were obtained in the n-lnp0 plane with the extension tests below the CSL defined in compression.Regarding the fines content,the studied tailings presented very similar M and critical state friction angle values.However,the fines content af-fects the volumetric behavior of the studied tailings and the CSLs on the n-lnp0 plane shift downwards with the increasing fines content for compression and extension tests.In relation to dilatancy analysis,the fines content did not present an evident influence on the dilatancy of the materials.However,different values of mean stress ratio N were obtained between compression and extension tests and can corroborate the existence of non-unique CSLs for these materials.
基金supported by the National Nature Science Foundation of China (No.50674062)the National Key Technologies R&D Program of China (No.2006BAC21B03)the Post doctoral Science Foundation (No.20070420354)
文摘In the background of little reuse and large stockpile for iron ore tailings, iron ore tailing from Chinese Tonghua were used as raw material to prepare cementitious materials. Cementitious properties of the iron ore tailings activated by compound thermal activation were studied. Testing methods, such as XRD, TG-DTA, and IR were used for researching the phase and structure variety of the iron ore railings in the process of compound thermal activation. The results reveal that a new cementitious material that contains 30wt% of the iron ore tailings can be obtained by compounded thermal activation, whose mortar strength can come up to the standard of 42.5 cement of China.
基金Project(51172287)supported by the National Natural Science Foundation of ChinaProject(2012-2013)supported by the Laboratory Research Fund of the State Key Laboratory of Powder Metallurgy,China
文摘In order to develop the applications of ore tailings, the glass ceramics were prepared by using a conventional melting-quenching-sintering process. The phase component, microstructures, magnetic properties and thermal conductivities of the prepared glass ceramics were investigated by using X-ray diffractometer, scanning electron microscopy, vibrating sample magnetometer and thermophysical properties tester, respectively. The results show that orthorhombic olivine-type phase and triclinic sunstone-type phase formed when the glass was annealed at 700 oC, the concentration of olivine-type and sunstone-type phases decreased, the spinel-type cubic phase occurred and the amount increased when the annealing temperatures increased. The magnetic properties from the cubic spinel ferrites were detected in the glass ceramics, and the related saturation magnetization increased with the annealing temperature increasing. The porous glass ceramics with magnetic property showed much lower thermal conductivity, compared with the non-magnetic porous glass-ceramic and the dense glass-ceramics.
基金This work was supported by University Natural Science Research Project of Anhui Province(KJ2019A0171).
文摘Improving the activity of Iron Ore Tailings(IOTs)to utilize them as a mineral admixture in cement-based minerals is still challenging.In this paper,the wet grinding technology was employed to stimulate the activity of IOTs,and the traditional dry grinding method was used as a reference.The effect of wet grinding on the activation of IOTs was evaluated through ion leaching from an alkaline solution and the reactivity index.Additionally,a detailed comparison between Dry-grinding Iron Ore Tailings(DIOTs)and Wet-grinding Iron Ore Tailings(WIOTs)was made.This comparison was based on particle characteristics,crystal structures,chemical structure,and surface properties.The results showed that the particle size of IOTs reduced rapidly during wet grinding.In addition,WIOTs had a higher activity index compared to DIOTs.The storage of lattice distortions in the quartz crystal structure was also more significant during the wet grinding process than during the dry grinding process.Moreover,both prolonged dry and wet grinding could destabilize the Si-O bond and decrease the surface binding energy.
基金supported by the National Natural Science Foundation of China (No.50674062)the Key Project of the Ministry of Railway of China (No.2008G031-N)the Postdoctoral Science Foundation (No.20070420354)
文摘The aim of this study is to understand the relationship between the polymerization degree and cememitious activity of iron ore tailings. In light of the poor usage of iron ore tailings, stockpile samples from Tangshan were studied in terms of their ability to become cementitious materials. Compound thermal activation was used to improve the cementitious properties of the tailings, while analyzing methods, such as X-ray diffraction (XRD), infrared spectroscopy (IR), nuclear magnetic resonance (NMR), and X-ray photoelectron spectrometer (XPS), were employed to study the changes in phase and structure under different activation conditions. The results reveal clear relationships between the binding energies of Si2p and O 1 s, polymerization degree, and cementitious activity of iron ore tailings.
基金Funded by the National Natural Science Foundation of China(51372185)
文摘In order to distinguish the filling effect and volcanic activity and explore the ways motivating the activity of rich-silicon iron ore tailing(IOT), inert quartz was brought in as the correction standard, the influences of fineness, calcination, thermal curing system and some other factors were investigated by IR, XRD, MIP, and so on microscopic methods. The experimental results show grinding and calcination can only change the amorphous state of SiO2, and IOT do not have volcanic activity in concrete cured under room temperature condition. Thermal curing systems can stimulate the activity of IOT, especially mortar cured by autoclave curing system can consume a large amount of Ca(OH)2 and hard calcium silicate and has a closer structure. When the specific surface area of IOT powder is 800 m^2/kg, and 30% cement is replaced by IOT powder, the mortar strength with IOT powder is even higher than that with cementonly.
基金This work was supported by University Natural Science Research Project of Anhui Province(KJ2019A0171)National Natural Science Foundation of China(Grant No.52005009)+1 种基金Anhui Province Natural Science Funds for Youth Fund Project(2008085QE273)Anhui Province Key Research and Development Project(202004e11020003).
文摘Herein,micro iron ore tailings(micro-IOTs)were prepared by wet-grinding and applied to improve sulphoaluminate cement(SAC)performance.The physicochemical properties of micro-IOTs were investigated by particle size analysis,XRD,and XPS.The hydrates trait and the hydration mechanism of micro-IOTs-SAC composite were studied by XRD,TGA,MIP,and SEM.The results demonstrated that micro-IOTs with an average grain diameter of 517 nm could be obtained by wet-grinding.The setting time of SAC gradually decreased with increasing micro-IOTs content.By adding 2%micro-IOTs,the compressive strengths of SAC pastes were enhanced about 22%and 10%at 4 h and 28 d,respectively.Moreover,the addition of micro-IOTs accelerated ettringite precipitation and changed its morphology,resulting in early strength improvement of the binary system.And increased later strength by micro-IOTs was closely related to the high content of AH_(3),fine pore structure,and high hydration degree of SAC.The findings suggested one new approach to utilize iron ore tailings in cementbased materials.
文摘In order to solve the problems caused by the storage of iron ore tailings (IOTs), many researchers conducted a series of experimental studies on the reuse of IOTs. The results of many studies showed that it was feasible to use IOTs for road engineering. This paper summarized the composition, gradation and particle characteristics of IOTs from chemical and physical aspects, and proved the feasibility of IOTs replacing traditional aggregate for asphalt concrete. Then, the research on the road performance of asphalt concrete incorporating IOTs were summarized and reviewed, including the evaluation of high-temperature stability, low-temperature crack resistance, fatigue resistance and water stability. The water stability and the improvement of adhesion between asphalt and IOTs aggregate were discussed in detail. Finally, the performance of IOTs as asphalt concrete aggregate and the existing defects were evaluated, and future research directions were proposed.
文摘The aim of this study was to investigate the synthesis of iron oxide pigments from IOT. The sample of IOT was obtained through mining activity of the Quadrilátero Ferrífero in the state of Minas Gerais, Brazil. The procedure was carried out by hot acid leaching with hydrochloric acid (HCl) which allowed the recovery of about 95% of the iron in a liquor. The iron-based pigments—red (IBP_R), black (IBP_B), and yellow (IBP_Y)—were synthetised from the liquor by selective precipitation, crystallisation, and thermal procedures. The pigments were characterised by particle size distribution, mineral and chemical compositions, as well as colourimetric properties. The process of synthesis was successful and the procedure was shown to maximise the utilisation of mineral resources and minimise the environmental, social, and economic impacts associated with IOT disposal.
文摘This study presents a laboratory investigation of load-settlement behaviour of a strip footing resting on iron ore tailings used as a structural fill.The footing was placed at various depths in the tailings bed.The relative density of the tailings was varied as D_r = 50%,70%and 90%.An incremental load was applied on the footing while observing the settlement until the failure took place.The results obtained for tailings were compared with those for the sandy soil.It is observed that the load-bearing capacity and stiffness increase with an increase in footing embedment depth and relative density.Compared to load-settlement behaviour of Perth sandy soil,the tailings fill could have as high as 22 times and 13.5 times the load-bearing capacity and stiffness,respectively.Therefore,the replacement of sandy soil with iron ore tailings for structural fills is cost-effective,and moreover,this application contributes to environmental sustainability in construction.