2-Carbonyl propionic acid-4-methyl benzoyl hydrazone （PAMH） has been synthe-sized by using 4-methyl benzoyl hydrazine and pyruvic acid as the chemicals and acetic acid asphase transfer catalyst under microwave radia...2-Carbonyl propionic acid-4-methyl benzoyl hydrazone （PAMH） has been synthe-sized by using 4-methyl benzoyl hydrazine and pyruvic acid as the chemicals and acetic acid asphase transfer catalyst under microwave radiation. Then the PAMH and TbCl3·6H20 are placed inthe methanol/acetone/water （3：2：4） mixture for coordination reaction, getting the Schiff complexTb（PAMH）3. The crystal structure is characterized by elemental analysis, X-ray Diffraction （XRD）and infrared spectrum. The compound crystallizes in the monoclinic space group P21/n, with a =1.4770（4）, b = 1.2864（3）, c = 1.9287（5） nm, β= 92.06（3）°, V= 3.6623（15） nm3 and Z= 4. Tb（Ⅲ） ionis nona-coordinated by three completely deprotonated PAMH ligands in a tricapped trigonal prismgeometry, leaving a zero-dimensional mononuclear configuration. The optical properties and thermalstability are studied by ultraviolet spectrum, fluorescence spectra and thermogravimetric analysis（TGA）. The antibacterial activities of the ligand and rare-earth complex are preliminarily studied,and found they have certain antibacterial activity on fusarium solani, and the complex is obviouslymore effective in suppressing fusarium solani than the ligand.展开更多
基金supported by the National Natural Science Foundation of China(21273171)Natural Science Foundation of Shangluo University(16SKY005)Special Scientific Research Project of Education Department of Shaanxi Province Government(17JK0242)
文摘2-Carbonyl propionic acid-4-methyl benzoyl hydrazone （PAMH） has been synthe-sized by using 4-methyl benzoyl hydrazine and pyruvic acid as the chemicals and acetic acid asphase transfer catalyst under microwave radiation. Then the PAMH and TbCl3·6H20 are placed inthe methanol/acetone/water （3：2：4） mixture for coordination reaction, getting the Schiff complexTb（PAMH）3. The crystal structure is characterized by elemental analysis, X-ray Diffraction （XRD）and infrared spectrum. The compound crystallizes in the monoclinic space group P21/n, with a =1.4770（4）, b = 1.2864（3）, c = 1.9287（5） nm, β= 92.06（3）°, V= 3.6623（15） nm3 and Z= 4. Tb（Ⅲ） ionis nona-coordinated by three completely deprotonated PAMH ligands in a tricapped trigonal prismgeometry, leaving a zero-dimensional mononuclear configuration. The optical properties and thermalstability are studied by ultraviolet spectrum, fluorescence spectra and thermogravimetric analysis（TGA）. The antibacterial activities of the ligand and rare-earth complex are preliminarily studied,and found they have certain antibacterial activity on fusarium solani, and the complex is obviouslymore effective in suppressing fusarium solani than the ligand.
