The different confinement shapes can induce the formation of various interesting and novel morphologies, which might inspire potential applications of materials. In this paper, we study the directed self-assembly of d...The different confinement shapes can induce the formation of various interesting and novel morphologies, which might inspire potential applications of materials. In this paper, we study the directed self-assembly of diblock copolymer confined in irregular geometries with a soft surface by using self-consistent field theory. Two types of confinement geometries are considered, namely, one is the concave pore with one groove and the other is the concave pore with two grooves. We obtain more novel and different structures which could not be produced in other two-dimensional（2D） confinements. Comparing these new structures with those obtained in regular square confinement, we find that the range of ordered lamellae is enlarged and the range of disordered structure is narrowed down under the concave pore confinement.We also compare the different structures obtained under the two types of confinement geometries, the results show that the effect of confinement would increase, which might induce the diblock copolymer to form novel structures. We construct the phase diagram as a function of the fraction of B block and the ratio of h/L of the groove. The simulation reveals that the wetting effect of brushes and the shape of confinement geometries play important roles in determining the morphologies of the system. Our results improve the applications in the directed self-assembly of diblock copolymer for fabricating the irregular structures.展开更多
SAR弧的磁层源区对应环电流与等离子体层顶重叠区域,而等离子体层顶常常观测到密度不规则结构.之前还没有暴时等离子体层顶密度不规则结构对SAR弧调制的观测报道.本文报道了地基成像和磁层、电离层卫星对2013年10月9日磁暴恢复相期间发...SAR弧的磁层源区对应环电流与等离子体层顶重叠区域,而等离子体层顶常常观测到密度不规则结构.之前还没有暴时等离子体层顶密度不规则结构对SAR弧调制的观测报道.本文报道了地基成像和磁层、电离层卫星对2013年10月9日磁暴恢复相期间发生的SAR弧的联合观测事件.在SAR弧的磁层源区,Van Allen Probe B卫星观测到了密度不规则结构,其中存在EMIC波、环电流离子分布和非线性电场结构.联合观测表明:该区域中的环电流离子分布通过库伦碰撞产生的热流通量足以驱动SAR弧,热流通量受到密度不规则结构的调制,形成空间上的小尺度分布,环电流离子中几keV的质子和几十keV的氧离子对这个过程起主导作用;此外,位于等离子体层顶密度不规则结构的低密度区的非线性结构电场引起的低能电子沉降可能是造成这次SAR弧非常明亮的原因.展开更多
目的考察Fe_(3)O_(4)纳米颗粒在低频振动磁场(low-frequency vibrating magnetic field,VMF)驱动下通过磁场机械力杀伤肿瘤细胞的效果。方法通过共沉淀法合成一种磁性强、具有不规则形貌的立方相Fe_(3)O_(4)纳米颗粒。将其置于本课题组...目的考察Fe_(3)O_(4)纳米颗粒在低频振动磁场(low-frequency vibrating magnetic field,VMF)驱动下通过磁场机械力杀伤肿瘤细胞的效果。方法通过共沉淀法合成一种磁性强、具有不规则形貌的立方相Fe_(3)O_(4)纳米颗粒。将其置于本课题组自制的VMF中,研究其介导的磁场机械力对肿瘤细胞的杀伤效果。结果单纯施加VMF对细胞活力无影响;加入Fe_(3)O_(4)纳米颗粒后,细胞活力随VMF处理时间和Fe_(3)O_(4)纳米颗粒浓度的增加而降低,受损细胞释放的乳酸脱氢酶也随磁场处理时间延长而增加。结论不规则形貌Fe_(3)O_(4)纳米颗粒在VMF下可将机械力转移到肿瘤细胞,破坏细胞结构,导致细胞死亡;所采用的VMF装置结构简单、使用安全、操作方便。所采用的磁性粒子及其杀伤肿瘤细胞的方法,有临床转化潜力。展开更多
基金Project supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China(Grant No.20121404110004)the Research Foundation for Excellent Talents of Shanxi Provincial Department of Human Resources and Social Security+2 种基金Chinathe Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi ProvinceChina
文摘The different confinement shapes can induce the formation of various interesting and novel morphologies, which might inspire potential applications of materials. In this paper, we study the directed self-assembly of diblock copolymer confined in irregular geometries with a soft surface by using self-consistent field theory. Two types of confinement geometries are considered, namely, one is the concave pore with one groove and the other is the concave pore with two grooves. We obtain more novel and different structures which could not be produced in other two-dimensional（2D） confinements. Comparing these new structures with those obtained in regular square confinement, we find that the range of ordered lamellae is enlarged and the range of disordered structure is narrowed down under the concave pore confinement.We also compare the different structures obtained under the two types of confinement geometries, the results show that the effect of confinement would increase, which might induce the diblock copolymer to form novel structures. We construct the phase diagram as a function of the fraction of B block and the ratio of h/L of the groove. The simulation reveals that the wetting effect of brushes and the shape of confinement geometries play important roles in determining the morphologies of the system. Our results improve the applications in the directed self-assembly of diblock copolymer for fabricating the irregular structures.
文摘SAR弧的磁层源区对应环电流与等离子体层顶重叠区域,而等离子体层顶常常观测到密度不规则结构.之前还没有暴时等离子体层顶密度不规则结构对SAR弧调制的观测报道.本文报道了地基成像和磁层、电离层卫星对2013年10月9日磁暴恢复相期间发生的SAR弧的联合观测事件.在SAR弧的磁层源区,Van Allen Probe B卫星观测到了密度不规则结构,其中存在EMIC波、环电流离子分布和非线性电场结构.联合观测表明:该区域中的环电流离子分布通过库伦碰撞产生的热流通量足以驱动SAR弧,热流通量受到密度不规则结构的调制,形成空间上的小尺度分布,环电流离子中几keV的质子和几十keV的氧离子对这个过程起主导作用;此外,位于等离子体层顶密度不规则结构的低密度区的非线性结构电场引起的低能电子沉降可能是造成这次SAR弧非常明亮的原因.
文摘目的考察Fe_(3)O_(4)纳米颗粒在低频振动磁场(low-frequency vibrating magnetic field,VMF)驱动下通过磁场机械力杀伤肿瘤细胞的效果。方法通过共沉淀法合成一种磁性强、具有不规则形貌的立方相Fe_(3)O_(4)纳米颗粒。将其置于本课题组自制的VMF中,研究其介导的磁场机械力对肿瘤细胞的杀伤效果。结果单纯施加VMF对细胞活力无影响;加入Fe_(3)O_(4)纳米颗粒后,细胞活力随VMF处理时间和Fe_(3)O_(4)纳米颗粒浓度的增加而降低,受损细胞释放的乳酸脱氢酶也随磁场处理时间延长而增加。结论不规则形貌Fe_(3)O_(4)纳米颗粒在VMF下可将机械力转移到肿瘤细胞,破坏细胞结构,导致细胞死亡;所采用的VMF装置结构简单、使用安全、操作方便。所采用的磁性粒子及其杀伤肿瘤细胞的方法,有临床转化潜力。
