Characteristics of Authigenic Pyrite and its Sulfur Isotopes Influenced by Methane Seep--Taking the Core A at Site 79 of the Middle Okinawa Trough as an Example

Objective Authigenic pyrite often develops extensively in marine sediments,which is an important product of sulfate reduction in an anoxic environment.It has a specific appearance and complicated sulfur isotopic properties,and acts as important evidence of methane seep in marine sediments.Strong AOM（anaerobic oxidation of methane）activity has developed in the Okinawa Trough.

Leaf stable carbon isotope composition in Picea schrenkiana var. tianschanica in relation to leaf physiological and morphological characteristics along an altitudinal gradient

To understand the effects of leaf physiological and morphological characteristics on δ13C of alpine trees, we examined leaf δ13C value, LA, SD, LNC, LPC, LKC, Chla+b, LDMC, LMA and Narea in one-year-old needles of Picea schrenkiana var. tianschanica at ten points along an altitudinal gradient from 1420 m to 2300 m a.s.l. on the northern slopes of the Tianshan Mountains in northwest China. Our results indicated that all the leaf traits differed significantly among sampling sites along the altitudinal gradient(P<0.001). LA, SD, LPC, LKC increased linearly with increasing elevation, whereas leaf δ13C, LNC, Chla+b, LDMC, LMA and Narea varied non-linearly with changes in altitude. Stepwise multiple regression analyses showed that four controlled physiological and morphological characteristics influenced the variation of δ13C. Among these four controlled factors, LKC was the most profound physiological factor that affected δ13C values, LA was the secondary morphological factor, SD was the third morphological factor, LNC was the last physiological factor. This suggested that leaf δ13C was directly controlled by physiological and morphological adjustments with changing environmental conditions due to the elevation.

Zircon U-Pb age, Lu-Hf Isotopic Characteristics and Origin of the Banshanping Granitoid Rocks in East Qinling Orogenic Belt

The Banshanping granitoid rocks distribute in the east of the North Qinling orogenic belt.It is a diorite-quartz diorite-granodiorite-granite series,spreading in a NW-SE direction,and intrudes into the Erlangping Group.The SiO2 content ranges from 57.04% to 76.56%,Na2O from 2.05% to 4.65%,K2O from 0.84% to 3.40%.Major element characteristics indicate that Banshanping granitoid rocks have properties of I type granotoids.SREE ranges from 36.51 ppm to 473.25 ppm,and LREE/ HREE ratios lie between 3.95 and 22.18.Negative Eu anomalies are not obvious in most samples,though there are obvious Nb,P and Ti positive anomalies.The zircon LA-ICP-MS ages of Banshangping granitoid rocks are 496.0±8.1 Ma-486.9±9.3 Ma.Hf isotope shows that 176Hf/177Hf ratios range from 0.282721 to 0.282876,εHf（t） values from 8.5 to 14,all positive,and corresponding modal ages （TDM2） range from 559 Ma to 908 Ma.Based on Hf isotope characteristics and existing SmNd and Rb-Sr isotope data,we consider that the Banshanping granitoid rocks originate from mantlederived material,i.e.the igneous rocks that formed in Neoproterozoic,and there may be a certain amount of crust-derived material during the formation of Banshanping granitoid rocks.

Geochemistry, Zircon U–Pb Dating and Hf Isotopic Characteristics of Neoproterozoic Granitoids in the Yaganbuyang Area, Altyn Tagh, NW China

The South Altyn continental block is an important geological unit of the Altyn Tagh orogenic belt, in which numerous Neoproterozoic granitoids crop out. Granitoids are mainly located in the Paxialayidang-Yaganbuyang area and can provide indispensable information on the dynamics of Rodinia supercontinent aggregation during the Neoproterozoic. Therefore, the study of granitoids can help us understand the formation and evolutionary history of the Altyn Tagh orogenic belt. In this work, we investigated the Yaganbuyang granitic pluton through petrography, geochemistry, zircon U-Pb chronology, and Hf isotope approaches. We obtained the following conclusions： （1） Yaganbuyang granitoids mainly consist of two-mica granite and granodiorite. Geochemical data suggested that these granitoids are peraluminous calc-alkaline or high-K calc-alkaline granite types. Zircon U-Pb data yielded ages of 939~7.1 Ma for granodiorite and ~954 Ma for granitoids, respectively. （2） The ~Hf（t） values of two--mica granite and granodiorite are in the range of-3.93 to ＋5.30 and -8.64 to ＋5.19, respectively. The Hf model ages （TDM2） of two-mica granite and granodiorite range from 1.59-.05 Ga and 1.62-2.35 Ga, respectively, indicating that the parental magma of these materials is derived from ancient crust with a portion of juvenUe crust. （3） Granitoids formed in a collisional orogen setting, which may be a response to Rodinia supercontinent convergence during the Neoproterozoic.

Sr and Nd Isotopic Characteristics and Magma Genesis of Mesozoic Volcanic Rocks Along the Coastal Region of Southeastern China

The Mesozoic volcanic rocks in the coastal region of southeastern China were superimposed on some different basement tectonic elements. The volcanic rocks developed in these different basement tectonic elements have great differences in Sr and Nd isotopic compositions. The rocks in western Zhejiang and northeastern Jiangxi Provinces which belong to the Lower Yangtze subplate have lower initial 87Sr/ 86Sr ratios, but are higher in initial Nd isotopic ratios. The initial 143Nd / 144Nd values of the volcanic rocks developed in the Cathaysian subplate increase clearly from early to late in time, and from the core of the Wuyishan uplift coastwards constantly, but the initial 87Sr/86Sr values tend to decrease. The isotopic characteristics and their spatial variations in Mesozoic volcanic rocks in the study region are, to a great extent, manifestations of the isotopic characteristics in basement metamorphic complexes, and the generation of the Mesozoic acid magma in this region is attributed to the recycling of pre-existing crustal materials.

Zircon U-Pb age, Trace Element, and Hf Isotopic Compositions of Nordmarkite in the Lizhuang Rare Earth Element Deposit in the Western Margin of the Yangtze Block

The Mianning-Dechang （MD） rare earth element （REE） belt, located in the northern Kangdian axis （KDA） in the western margin of the Yangtze platform, is one of the most economically significant REE mineral belts in China. REE mineralization is associated with Himalayan carbonatite- alkaline complexes. The Lizhuang nordmarkite occurred in the northern part of the MD REE belt. The majority of zircons from the Lizhuang nordmarkite are characterized by pronounced positive Ce yet slightly negative Eu anomalies and high U/Yb. Moreover, all zircons have stable Hf isotopic compositions with initial 176Hf/177Hf ratios ranging from 0.282739 to 0.282808 and an average value of 0.282773. The negative Lu/Hf and positive till（t） range from -0.98 to -0.94 （average value of -0.96） and from -0.56 to 1.89 （the majority is positive, with an average of 0.66）, respectively. These characteristics indicate that the rock is derived from an enriched mantle and subducted material. LA-ICP-MS analysis of the zircons from the intrusion yields a weighted mean 2~6pb/23SU age of 28.57~0.61Ma. During this period, the tectonic activity in the KDA is not plate subduction but an intraplate tectonic exhibiting fold-thrust and strike-slip behaviors in the western marginal zone of the Yangtze platform （WMYB）. We suggest the possibility of an existing eastward old slab subduction under WMYB combined with a regional tectonic evolution. The Lizhuang nordmarkite may be derived from an enriched mantle beneath the western part of the Yangtze craton, which originated from the remelting of the Tethys subducting slab, because of the Himalayan strike-slip that formed a special type of REE deposit called strike-slip-type REE deposits.

Isotopic characteristics of shoshonitic rocks in eastern Qinghai-Tibet Plateau: Petrogenesis and its tectonic implication

The Cenozoic magmatic rocks of shoshonitic series in the eastern Qinghai-Tibet Plateau include potassic alkaline plutonic rocks, volcanic rocks, lamprophyres and acidic porphyries. Analytical results show that these different lithological rocks are extremely similar in Sr, Nd and Pb isotopic compositions with the range of 0.705 187-0.707 254 for 87Sr/86Sr, 0.512 305-0.512 630 for 143Nd/144Nd, 18.53-18.97 for 206Pb/204Pb, 15.51-15.72 for 207Pb/204Pb and 38.38-39.24 for 208Pb/204Pb. They are isotopically similar to the EMU end-member. This indicates that mantle metasomatism must have taken place in their source region. The formation of these particular rocks is related to crustal thinning and mantle upwelling in a large-scale strike-slip and pull-apart fault zone at about 40 Ma in northern and eastern Qinghai-Tibet Plateau.