A new flavonoid glucoside with a known one was isolated from the leaves of Cassia angustifolia. Based on the spectral analysis, including MS, ^1H NMR, ^13C NMR, DEPT, ^1H-1HCOSY, HMQC, HMBC and NOSEY, their chemical s...A new flavonoid glucoside with a known one was isolated from the leaves of Cassia angustifolia. Based on the spectral analysis, including MS, ^1H NMR, ^13C NMR, DEPT, ^1H-1HCOSY, HMQC, HMBC and NOSEY, their chemical structures were determined as kaempferol-3-O-[(6'''-O-trans-sinnapoyt)-β-D-glucopyranosyl (1 → 6)]-β-D-glucopyranoside 1 and apigenin-6,8-di-C-glycoside 2.展开更多
Two new flavonol glycosides (1 and 2) together with two known flavonoides (3 and 4), were isolated from the whole plant of Knoxia corymbosa willd. The structures of 1 and 2 were elucidated as kaempferol-7-O-α-L-arabi...Two new flavonol glycosides (1 and 2) together with two known flavonoides (3 and 4), were isolated from the whole plant of Knoxia corymbosa willd. The structures of 1 and 2 were elucidated as kaempferol-7-O-α-L-arabinosyl-3-O-β-D-6'-acetylglucopyranoside and kaempferol -7-O-α-L-arabinosyl-3-O-β-D-3',6'-diacetylglucopyranoside respectively.展开更多
Two new isoflavonoid glucosides, 5-hydroxy-6,7-methylenedioxy-isoflavone-4'-O-D-glucopyranosyl (2→〉l)-L-rhamnoside (irilone-bioside) (compound 1) and 5,4'-methoxy-6,7-methylenedioxyisoflavone-3'-O-β-D-gluc...Two new isoflavonoid glucosides, 5-hydroxy-6,7-methylenedioxy-isoflavone-4'-O-D-glucopyranosyl (2→〉l)-L-rhamnoside (irilone-bioside) (compound 1) and 5,4'-methoxy-6,7-methylenedioxyisoflavone-3'-O-β-D-glucoside (irisleptophyllidin) (compound 2), together with five known compounds, nigricanin- 4'-O-β-D-glucoside (compound 3), irifloside (compound 4), irigenin (compound 5), 5, 3', 4'-trimethoxy-6,7-methylenedioxyisoflavone (compound 6), and nigricanin (compound 7) were isolated from the alcoholic extract of rhizomes of Iris leptophylla Lingelsh. Their structures were elucidated by spectroscopic methods.展开更多
文摘A new flavonoid glucoside with a known one was isolated from the leaves of Cassia angustifolia. Based on the spectral analysis, including MS, ^1H NMR, ^13C NMR, DEPT, ^1H-1HCOSY, HMQC, HMBC and NOSEY, their chemical structures were determined as kaempferol-3-O-[(6'''-O-trans-sinnapoyt)-β-D-glucopyranosyl (1 → 6)]-β-D-glucopyranoside 1 and apigenin-6,8-di-C-glycoside 2.
文摘Two new flavonol glycosides (1 and 2) together with two known flavonoides (3 and 4), were isolated from the whole plant of Knoxia corymbosa willd. The structures of 1 and 2 were elucidated as kaempferol-7-O-α-L-arabinosyl-3-O-β-D-6'-acetylglucopyranoside and kaempferol -7-O-α-L-arabinosyl-3-O-β-D-3',6'-diacetylglucopyranoside respectively.
基金Supported by the National Natural Science Foundation of China (30170103).
文摘Two new isoflavonoid glucosides, 5-hydroxy-6,7-methylenedioxy-isoflavone-4'-O-D-glucopyranosyl (2→〉l)-L-rhamnoside (irilone-bioside) (compound 1) and 5,4'-methoxy-6,7-methylenedioxyisoflavone-3'-O-β-D-glucoside (irisleptophyllidin) (compound 2), together with five known compounds, nigricanin- 4'-O-β-D-glucoside (compound 3), irifloside (compound 4), irigenin (compound 5), 5, 3', 4'-trimethoxy-6,7-methylenedioxyisoflavone (compound 6), and nigricanin (compound 7) were isolated from the alcoholic extract of rhizomes of Iris leptophylla Lingelsh. Their structures were elucidated by spectroscopic methods.