Modified Method for Estimating Organic Carbon Density in Discontinuous Karst Soil Using Ground-Penetrating Radar and Geostatistics

The conventional method which assumes the soil distribution is continuous was unsuitable for estimating soil organic carbon density(SOCD) in Karst areas because of its discontinuous soil distribution. The accurate estimation of SOCD in Karst areas is essential for carbon sequestration assessment in China. In this study, a modified method,which considers the vertical proportion of soil area in the profile when calculating the SOCD, was developed to estimate the SOCD in a typical Karst peak-cluster depression area in southwest China. In the modified method, ground-penetrating radar(GPR) technology was used to detect the distribution and thickness of soil. The accuracy of the method was confirmed through comparison with the data obtained using a validation method, in which the soil thickness was measured by excavation. In comparison with the conventional method and average-soil-depth method,the SOCD estimated using the GPR method showed the minimum relative error with respect to that obtained using the validation method. At a regional scale, the average SOCDs at depths of 0-20 cm and 0-100 cm, which were interpolated by ordinary kriging,were 1.49(ranging from 0.03-5.65) and 2.26(0.09-11.60) kgm-2based on GPR method in our study area(covering 393.6 hm2), respectively. Therefore, the modified method can be applied on the accurate estimation of SOCD in discontinuous soil areas such as Karst regions.

A numerical simulation study on the evolutionary characteristics of the damage process of karst soil cavity under positive pressure effect

Positive pressure effect is the result of rapid urban development in recent years,which leads to over-exploitation of karst groundwater,coupled with the emergence of extreme weather(such as heavy rainfall,the increase in the duration of heavy rainfall),leading to the sharp rise of karst water level,the gas in the karst cavity can not be discharged in time to form a high positive pressure in the soil cavity and promote the destruction of the soil layer,which then induces a series of phenomena,such as karst subsidence.As a new collapse mechanism,the positive pressure effect causes geological disasters that seriously affect the safety of people's lives and properties in karst regions.In order to study the damage characteristics and evolution characteristics of karst soil cavities under positive pressure effect,this study is based on the ASCII text provided by FLAC itself,and the orthotropic simulation computation compilation program,which realizes the finite element analysis in FLAC3D,and focuses on the inhomogeneous change of soil displacement,redistribution of stresses,and plastic damage of karst soil cavities in different evolution stages under the action of positive pressure,and summarizes the characteristics and laws of stress,strain and damage in plastic zone of karst soil cave at different stages of evolution.The results will play a positive role in further investigating the potential mechanical effects,development mechanism and critical warning conditions during the evolution of covered karst soil caves,and also have important scientific research value in deepening the theory of prevention and control of collapse disasters in covered karst soil caves.

Spatial Heterogeneity of Soil Mineral Oxide Components in Depression Between Karst Hills,Southwest China

In karst regions,the spatial heterogeneity of soil mineral oxides and environmental variables is still not clear.We investigated the spatial heterogeneity of SiO2,Al2O3,Fe2O3,CaO,MgO,P2O5,K2O,and MnO contents in the soils of slope land,plantation forest,secondary forest,and primary forest,as well as their relationships with environmental variables in a karst region of Southwest China.Geostatistics,principal component analysis(PCA),and canonical correlation analysis(CCA)were applied to analyze the field data.The results show that SiO2was the predominant mineral in the soils(45.02%–67.33%),followed by Al2O3and Fe2O3.Most soil mineral oxide components had a strong spatial dependence,except for CaO,MgO,and P2O5in the plantation forest,MgO and P2O5in the secondary forest,and CaO in the slope land.Dimensionality reduction in PCA was not appropriate due to the strong spatial heterogeneity in the ecosystems.Soil mineral oxide components,the main factors in all ecosystems,had greater influences on vegetation than those of conventional soil properties.There were close relationships between soil mineral oxide components and vegetation,topography,and conventional soil properties.Mineral oxide components affected species diversity,organic matter and nitrogen levels.

Effects of organic mineral fertiliser on heavy metal migration and potential carbon sink in soils in a karst region

Heavy metal pollution in karst mountainous area of Guizhou has spread due to the long-term exploitation of mineral resources and the improper disposal of environmentally hazardous waste. Heavy metals are characterised by non-degradation, strong toxicity, and constant accumulation, posing a grave threat to karst mountain fragile soil ecosystem. To reduce the harm caused by heavy metal pollution and damage to agricultural products, research was undertaken on the basis of previous work by simulating pot experiments on pak choi cabbage(Brassica rapa chinensis)planted in Cd-contaminated soil: different amounts of organic mineral fertilisers(OMF) compared with chemical fertiliser(CF) were used and by detecting the amount of heavy metal in the mature vegetable, a better fertilisation strategy was developed. The results showed that the Cd content in vegetables grown with CF was 23.70 mg/kg,while that of vegetables grown with OMF and bacterial inoculant was the lowest at 15.13 mg/kg. This suggests that the use of OMF and microbes in karst areas not only promotes plant growth but also hinders plant absorption of heavy metal ions in the soil. In addition, through the collection of pot leachate, the detection of water chemistrycharacteristics, and the calculation of the calcite saturation index, it was found that the OMF method also induces certain carbon sink effects. The results provide a new way in which rationalise the use of OMFs in karst areas to alleviate soil heavy metal pollution and increase soil carbon sequestration.

Interactions between Soil Characteristics, Environmental Factors, and Plant Species Abundance: A Case Study in the Karst Mountains of Longhushan Nature Reserve, Southwest China

The ability to manage and restore plant communities in the face of human-induced landscape change may rely on our ability to predict how species respond to environmental variables.Understanding this response requires examining factors or their interactions that have influence on plant and resource availability.Our objective was to analyze the relationships between changes in plant abundance and the interaction among environmental habitat factors including soil, geological(rock type), and other environmental variables in the Longhushan karst mountains ecosystem.Species density and dominance were examined using ANOVA, ANCOVA,and Generalized Linear Models to establish the single or combined effects of these groups of factors.The results showed that trends in abundance were mainly affected by rock type(related to the percentage content of dolomite and calcite), soil characteristics in association with topography.Both plant indices were higher in dolomite dominated areas and varied positively with moisture, and elevation, but negatively with organic matter, while density also increased with slope degree.The results demonstrate that significant variations in species abundance was produced with the combination of variables from soil, geological, andenvironmental factors, suggesting their interaction influence on plants.We postulate that spatial variations in plant abundance in karst ecosystem depends on the carbonate rock type in addition to water and nutrient availability which are mainly controlled by topography and other factors such as soil texture and temperature.The study suggests that in karst areas carbonate rock type, in addition to local environmental variables, should be taken into account when analyzing the factors that have impact on plant communities.

Effects of Land Cover on Soil Organic Carbon Stock in a Karst Landscape with Discontinuous Soil Distribution

Land cover type is critical for soil organic carbon(SOC) stocks in territorial ecosystems. However, impacts of land cover on SOC stocks in a karst landscape are not fully understood due to discontinuous soil distribution. In this study, considering soil distribution, SOC content and density were investigated along positive successional stages(cropland, plantation, grassland, scrubland, secondary forest, and primary forest) to determine the effects of land cover type on SOC stocks in a subtropical karst area. The proportion of continuous soil on the ground surface under different land cover types ranged between 0.0% and 79.8%. As land cover types changed across the positive successional stages, SOC content in both the 0–20 cm and 20–50 cm soil layers increased significantly. SOC density(SOCD) within 0–100 cm soil depth ranged from 1.45 to 8.72 kg m-2, and increased from secondary forest to primary forest, plantation, grassland, scrubland, and cropland, due to discontinuous soil distribution. Discontinuous soil distribution had a negative effect on SOC stocks, highlighting the necessity for accurate determination of soil distribution in karst areas. Generally, ecological restoration had positive impacts on SOC accumulation in karst areas, but this is a slow process. In the short term, the conversion of croplandto grassland was found to be the most efficient way for SOC sequestration.

Carbon stable isotopic composition of karst soil CO_2 in central Guizhou,China

The δ13 values of soil CO2 are less than that of atmosphere CO2 in the karst area. On the soil-air interface, the δ13 vlaues of soil CO2 decrease with the increase in soil depth; below the soil-air interface, the δ13C values of soil CO2 are invariable. The type of vegetation on the land surface has an influence on the δ13C values of soil CO2 Due to the activity of soil microbes, the δ13C values of soil CO2 are variable with seasonal change in grass. Isotopic tracer indicates that atmosphere CO2 has a great deal of contribution to soil CO2 at the lower parts of soil profile.

Variation of δ^(13)C in karst soil in Yaji Karst Experiment Site, Guilin

This study deals with δ13C variation in karst soil system of Yaji Karst Experiment Site, Guilin, a typical region of humid subtropical karst formations. Samples of near ground air, plant tissue, soil and water (soil solution and karst spring) were respectively collected on site in different seasons during 1996-1999. Considerable variation of δ13C values are not only found with different carbon pools of soil organic carbon, soil air CO2 and soil water HCO3-, but also with the soil depths and with different seasons during a year. The δ13C values of CO2 both of near ground air and soil air are lower in July than those in April by 1‰-4‰ PDB. Our results indicate that the δ13C values of carbon in the water and air are essentially dependent on interface carbon interaction of air-plant-soil-rock-water governed by soilorganic carbon and soil CO2 in the system.

Pool Sizes and Turnover of Soil Organic Carbon of Farmland Soil in Karst Area of Guilin

The three-pool and first-order model separates the mineralizable organic carbon into active,slow,and passive carbon pools.This paper used the model and decomposition curves of the soil organic carbon to fit the active pool and its decomposition rate,slow pool and its decomposition rate.The results showed that the size of the active pool from different profiles accounted for 2.09%-3.08% of the total soil organic carbon and the mean residue time was 3.57-17.21 days.And the size of the slow pool accounted for 3.19%-43.55% and the mean residue time was 1.12-4.94 years.Acid hydrolysis（6M HCl） was used to fractionate the passive organic carbon,which accounted for 50.83%-94.44% of the total soil organic carbon.

Assessment for soil loss by using a scheme of alterative sub-models based on the RUSLE in a Karst Basin of Southwest China

Accurate assessment of soil loss caused by rainfall is essential for natural and agricultural resources management. Soil erosion directly affects the environment and human sustainability. In this work, the empirical and contemporary model of revised universal soil loss equation （RUSLE） was applied for simulating the soil erosion rate in a karst catchment using remote sensing data and geographical information systems. A scheme of alterative sub-models was adopted to calculate the rainfall erosivity （R）, soil erodibility （K）, slope length and steepness （LS）, cover management （C） and conservation practice （P） factors in the geographic information system （GIS） environment. A map showing the potential of soil erosion rate was produced by the RUSLE and it indicated the severe soil erosion in the study area. Six classes of erosion rate are distinguished from the map： 1） minimal, 2） low, 3） medium, 4） high, 5） very high, and 6） extremely high. The RUSLE gave a mean annual erosion rate of 30.24 Mg ha-1 yr-1 from the 1980s to 2000s. The mean annual erosion rate obtained using RUSLE is consistent with the result of previous research based on in situ measurement from 1980 to 2009. The high performance of the RUSLE model indicates the reliability of the sub-models and possibility of applying the RUSLE on quantitative estimation. The result of the RUSLE model is sensitive to the slope steepness, slope length, vegetation factors and digital elevation model （DEM） resolution. The study suggests that attention should be given to the topographic factors and DEM resolution when applying the RUSLE on quantitative estimation of soil loss.

The Heterogeneity and Its Influencing Factors of Soil Nutrients in Peak-Cluster Depression Areas of Karst Region

By selecting a typical peak-cluster depression area of karst region in Southwest China, we evaluated the effect of land use types and topographic factors on soil nutrients. Grid and line sampling methods were used to sample soil in depression and slope lands respectively, and classical statistical tools were applied to analyze the spatial variability character of soil organic carbon （SOC）, total nitrogen （TN）, total phosphorus （TP）, total potassium （TK）, available nitrogen （AN）, available phosphorus （AP）, available potassium （AK）, pH, and C/N. It was found that land use type was the dominant factor that effected the spatial heterogeneity of SOC, TN, TP, TK, AN, and AP. The content of SOC, TN, and AN decreased with the increase of land use intensity. Due to high fertilizer input, TP and AP in tillage fields were higher than those in the other land use types. TK had no obvious change trend among various land use types. Topographic factors had a significant effect on SOC, TN, TP, AN, AP, AK, and pH. Habitat factor was the dominant factor that effected AK. Altitude factor was the dominant factor for pH. However, all of these factors had no significant effect on C/N. Tillage practice had important effect on soil nutrients loss and soil degradation in the fragile karst ecosystem, and the input of organic manure should be increased in this region.

Impact of land cover types on the soil characteristics in karst area of Chongqing

The 26 plots including natural forestland, secondary forestland, shrub-grassland, sloping cropland, artificial forest and abandoned field, were selected to discuss the impact of land cover on the soil characteristics in the three karst districts of Chongqing. The results showed that： （1） After the vegetation turned into secondary vegetation or artificial vegetation, or reclamation, soil physical properties would be degraded. In the surface-layer soil of sloping cropland, the contents of 〉2 mm water-stable aggregates decreased obviously with apparent sandification. （2） The contents of soil organic matter and total nitrogen are controlled completely by vegetation type and land use intensity. The increasing trend is rather slow in the early days when over-reclamation is stopped and the land is converted to forest and pasture. （3） Herbaceous species increase and woody plants species decrease with the increase of land use intensity, therefore, the soil seed banks degrade more seriously. （4） The soil degradation index has been set up to describe the relative soil degradation degree under the conditions of different vegetation types. （5） Land cover has a significant effect on karst soil characteristics, land degradation in the karst ecosystem is essentially characterized by the different degradation of soil functions that serve as water banks, nutrient banks and soil seed banks.

Soil Erosion and Its Basic Characteristics at Karst Rocky-desertified Land Consolidation Area: A Case Study at Muzhe Village of Xichou County in Southeast Yunnan, China

Xichou County of Wenshan Zhuang and Miao Autonomous Prefecture in southeast Yunnan is one of the karst mountainous areas in southwest China showing typical rock desertification. During this study, we set up three soil erosion contrast test spots at Muzhe Village, Benggu Township, Xichou County, which was the birthplace of the Xichou rock-desertified land consolidation mode. The three spots included the terrace land spot (already consolidated land), sloping land spot (unconsolidated sloping land under rock desertification), and standard runoff spot (bare land spot). In 2007, a whole-year complete observation was conducted during the rainy season and "rainfall-erosion" data were obtained for 32 times. Our analysis showed that during the entire observation period, the number of the rainfalls that led to soil erosion accounted for 34.04% of the number of all rainfalls and the amount of the rainfalls that led to soil erosion accounted for 84.17% of the total amount of all rainfalls. The average erosive rainfall standard in the three test spots was 11.0 mm, slightly higher than the 10 mm standard that has been adopted all over China, but lower than the 12.7 mm standard of the US and the 13.0 mm standard of Japan. According to single-factor analysis, the soil loss in the sloping land spot (L2) and that in the bare land spot (L3) are correlated to certain extent to many other factors, including the single precipitation (P), rainfall intensity during the maximum ten minutes (I10), rainfall intensity during the maximum 20 minutes (I20), rainfall intensity during the maximum 30 minutes (I30), rainfall intensity during the maximum 40 minutes (I40), and rainfall intensity during the maximum 60 minutes (I60). Among these factors, they are of the highest relativity with I60. According to double-factor analysis, both L2 and L3 are of good relativity with P and I60. According to multi-factor analysis, L2 and L3 are also of good relativity with seven rainfall indexes, namely, P, Ia (average rainfall intensity), I10, I20, I30, I40, and I60, with their related coefficient R reaching 0.906 and 0.914, respectively. The annual soil losses in the three test spots are widely different: 1030.70 t/km2·a in the terrace land spot, which indicates a low-level erosion; 12913.22 t/km2·a in the sloping land spot (unconsolidated spot), some 12.5 times than that in the terrace land spot, which indicates an ultra-high-level erosion; and 19511.67 t/km2·a in the bare land spot, some 18.9 times than that in terrace land spot, indicating an acute erosion. These figures fully show that the Xichou rock-desertified land consolidation mode plays a significant role in soil conservation.

The features of soil erosion and soil leakage in karst peak-cluster areas of Southwest China

Through utilizing water flow monitoring, rock scratching, soil wood piles and radionuclide ^(137)Cs tracing in the Longhe karst ecological experimental site(hereinafter referred to"Longhe site"), Pingguo County, Guangxi Province, the features and values of soil erosion and soil leakage in different geomorphologic locations and land uses in the karst peak-cluster depressions are showed clearly. There are four kinds of geomorphologic locations in the karst peak-cluster depression, namely peaks, strip, slopes and depression. The soil leakage modulus in the peaks and strips respectively occupy 92.43% and 96.24% of the total mean soil erosion modulus at experimental sites. On the slope, soil leakage accounted for about 75%. At the bottom of depression, surface water was the main factor of soil erosion, and at last most soil leaked into underground rivers from sinkholes. The total soil erosion modulus and the contribution rates of relative surface soil erosion in regard of peaks, slopes and depressions gradually increased. There are also five major types of land use in the karst peak-cluster depressions, farmland, Kudingcha tea plantations, young Lignum Sappan fields, shrub-grassland and pastures. The soil erosion modulus of slope farmland has the highest value with an increasing trend year by year. But soil erosion modulus of other four land use types decreased by year, which shows the "grain for green" will result in better soil protection. By handling with rocky desertification and ecological rehabilitation in Longhe site, the mean soil erosion modulus of the karst peak-cluster depression has decreased about 80% from 2003 to 2015.

The impact of land use on soil properties in a karst agricultural region of Southwest China: a case study of Xiaojiang watershed, Yunnan

Supported by RS and GIS, the land use change from 1982 to 2003 were analyzed and the impacts of land use changes on pH value, organic matter, total N, total P, total K, available N, available P, and available K in soil of Xiaojiang watershed, a typical karst agricultural region of Yunnan Province, Southwest China were assessed. The following aspects are concluded. （1） The total land use converted during the past 20 years in Xiaojiang watershed covers an area of 610.12 km^2, of which 134.29 km^2 of forestland was converted into cultivated land, and 210 km^2 of.unused land was converted into cultivated land. （2） The rapid growth of population and the economic development were the main driving forces of land use change. （3） With the change in land use, the soil properties have been changed significantly. The pH, organic matter, total N, total P, total K, available N, available P and available K in soil in 1982 were 6.3, 38.02 g·kg^-1, 1.86 g·kg^-1, 1.63 g·kg^-1, 10.94 g·kg^-1, 114.42 g·kg^-1, 11.65 mg·kg^-1 and 64.69 mg·kg^-1g, respectively; and those in 2003 were 6.73, 25.26 g·kg^-1, 1.41 g·kg^-1, 0.99 g·kg^-1, 12.6 g·kg^-1, 113.43 mg·kg^-1, 11.11 mg·kg^-1 and 151.59 mg·kg^-1, respectively. Pared samples t-test of the tested indices of soil properties indicate that those indices have changed significantly during the last 20 years. But the soil properties changed differently, due to the differences in land use change. （4） Also, with the change in land use and management measures of soil, the modifications in soil properties which developed from carbonate rocks were more sensitive than those in the soil developed from sandstone.

The Diversity of Soil Fauna Communities in the Karst Cave Wetland of Maolan Nature Reserve

From March 2014 to February 2015, the soil fauna community in the karst cave wetland of Maolan Nature Reserve was investigated. A total of 3,820 soil fauna was obtained, belonging to 31 orders, 11 classes, and 3 phyla. The dominant groups were Araneae, Coleoptera and Hymenoptera, accounting for 48.90% of the total catch. There were 18 common groups and 10 rare groups. The diversity analysis showed that the Banzhai karst cave wetland had the largest soil fauna community diversity index and evenness index and that the Dongsai karst cave wetland had the largest number of groups and individuals. The seasonal variation of the soil fauna in the karst cave wetlands was analyzed: the number of soil fauna individuals showed a downtrend in summer, autumn, spring and winter; there were the highest number of phytophagous soil fauna, followed by predatory soil fauna and saprophagous soil fauna.

Characteristics of heavy metals in soils under different land use in a typical karst area, Southwest China

This study investigated the distribution of six pollutant elements(Cr, Cu, Pb, Zn, Cd, and As), and their relationship to soil organic carbon(SOC) in five soil profiles in the Puding area. Results show SOC content decreased exponentially to the depth of soil profiles; the vertical distribution patterns of SOC in soil profiles were partially controlled by land use. The concentrations of these pollutant elements in most soils were lower than background values, indicating that the local soil was less likely to be contaminated by foreign inputs. Geo-accumulation index values of these elements in most soil samples were less than 1, suggesting that the soil of this area may not be polluted. The concentrations of Cr, Cu, As, and Zn in soils from all land use types were significantly negatively correlated with SOC contents. Geochemical approaches confirmed that the soil of this area was less influenced by pollutant elements.

Soil Ecosystem Degradation of Karst Regions in Southwestern China

Deeply influenced by karst geological environment, the structure of the soil ecosystem in the southwest karst area of China is characterized by strong vertical variation and space variation, structural feature of nonrenewable soil, and functional feature of poor circulation of nutrient elements and limited vegetation growth. On the basis of analyzing vulnerability in structure and function of soil ecosystem in China's southwestern karst regions, we discussed the degradation process and mechanism of soil structure, nutrient, water and microorganism in the course of soil erosion from the perspective of material and energy cycle. Finally, we put forward some recommendations for recovery of degraded soil, transformation and rational utilization of soil.