In November 2018, scientists from 60 countries voted unanimously to redefine the kilogram and three other standard units of measure: the ampere, for electrical current;the kelvin, for temperature;and the mole, which d...In November 2018, scientists from 60 countries voted unanimously to redefine the kilogram and three other standard units of measure: the ampere, for electrical current;the kelvin, for temperature;and the mole, which describes the amount of a chemical substance [1].展开更多
The development of large-scale synthetic methods for high quality carbon quantum dots(CQDs) is fundamental to their applications.However,the macroscopic preparation and scale up synthetic of CQDs is still in its infan...The development of large-scale synthetic methods for high quality carbon quantum dots(CQDs) is fundamental to their applications.However,the macroscopic preparation and scale up synthetic of CQDs is still in its infancy.Here,we report a facile,green,kilogram-scale synthesis of high quality fluorescent CQDs derived from poplar leaves via a one-step hydrothermal method.Notably,the throughput of CQDs can reach a level up to as high as 1.4975 kg in one pot.The structure and properties of the as-prepared CQDs were assessed through TEM,XRD,XPS and various spectroscopic methods.The obtained high quality CQD s with a photoluminescent quantum yield of 10.64% showed remarkable stability in aqueous media,rich functional groups,high photostability,consistent photoluminescence within biological pH range and low cytotoxicity.On account of these good properties,we demonstrated the multifunctional application to electrocatalytic water splitting,Fe^3+ sensing and bioimaging.It showed remarkable electrocatalytic activity,Fe^3+ sensitivity and good biocompatibility.This study provides a green,facile,inexpensive and large-scale method for producing high quality CQDs,which provides application value for large-scale production of CQDs.展开更多
【目的】定量中国不同农业生态区和不同产量水平条件下的玉米百千克籽粒地上部吸氮量(N_(100)),分析气候、土壤、品种和施肥因素对玉米N_(100)的影响,为确定合理施氮量提供科学依据。【方法】将中国分为东北、西北、华北平原、长江中下...【目的】定量中国不同农业生态区和不同产量水平条件下的玉米百千克籽粒地上部吸氮量(N_(100)),分析气候、土壤、品种和施肥因素对玉米N_(100)的影响,为确定合理施氮量提供科学依据。【方法】将中国分为东北、西北、华北平原、长江中下游平原、西南和东南6大农作区,搜集1980—2022年发表的349篇符合要求的文献,通过数据统计分析不同区域和不同产量水平条件下的玉米N_(100),并分析采用统一和区域化的N_(100)计算出的理论施氮量差异,采用皮尔逊相关系数(pearson correlation coefficient)、随机森林(random forest)模型和整合分析(Meta-analysis)方法分析气候、土壤和施肥因素对玉米N_(100)的影响,揭示导致中国玉米N_(100)空间差异的原因。【结果】优化处理条件下,中国春玉米N_(100)显著低于夏玉米,分别为2.21和2.46;不同农业生态区玉米N_(100)存在显著差异,分别为2.19(东北春玉米)、2.12(西北春玉米)、2.54(西北夏玉米)、2.45(华北夏玉米)、2.77(长江中下游春玉米)、2.38(长江中下游夏玉米)和2.39(西南玉米区)。依据本研究全国玉米平均N_(100)(2.34)计算的理论施氮量与采用区域化的N_(100)计算得到的理论施氮量相差-22—31 kg N·hm^(-2)。地上部吸氮量、产量、年均气温是影响玉米N_(100)的最重要因素;N_(100)随产量增加呈显著二次曲线降低的趋势(P<0.01),籽粒产量可以很好地预测N_(100);品种显著影响玉米N_(100),中国常见的玉米品种郑单958、先玉335和登海605的N_(100)分别为2.42、2.12和2.39,新品种玉米N_(100)显著低于老品种。施用氮肥显著增加了玉米N_(100),且在施氮量200—300 kg N·hm^(-2)时,施氮肥引起的N_(100)增加效应最大。单施缓控释肥、深施氮肥、减少氮肥基施比例以及增加施氮次数均显著增加了玉米N_(100)。【结论】在利用N_(100)进行合理施氮量计算时,需要考虑不同农业生态区N_(100)的显著差异,以得到更加准确的推荐施氮量,玉米N_(100)的驱动因素主要为作物地上部吸氮量、产量和年均气温的变异。展开更多
文摘In November 2018, scientists from 60 countries voted unanimously to redefine the kilogram and three other standard units of measure: the ampere, for electrical current;the kelvin, for temperature;and the mole, which describes the amount of a chemical substance [1].
基金financial support from Project funded by China postdoctoral Science Foundation (No. 2018M640681)
文摘The development of large-scale synthetic methods for high quality carbon quantum dots(CQDs) is fundamental to their applications.However,the macroscopic preparation and scale up synthetic of CQDs is still in its infancy.Here,we report a facile,green,kilogram-scale synthesis of high quality fluorescent CQDs derived from poplar leaves via a one-step hydrothermal method.Notably,the throughput of CQDs can reach a level up to as high as 1.4975 kg in one pot.The structure and properties of the as-prepared CQDs were assessed through TEM,XRD,XPS and various spectroscopic methods.The obtained high quality CQD s with a photoluminescent quantum yield of 10.64% showed remarkable stability in aqueous media,rich functional groups,high photostability,consistent photoluminescence within biological pH range and low cytotoxicity.On account of these good properties,we demonstrated the multifunctional application to electrocatalytic water splitting,Fe^3+ sensing and bioimaging.It showed remarkable electrocatalytic activity,Fe^3+ sensitivity and good biocompatibility.This study provides a green,facile,inexpensive and large-scale method for producing high quality CQDs,which provides application value for large-scale production of CQDs.
文摘【目的】定量中国不同农业生态区和不同产量水平条件下的玉米百千克籽粒地上部吸氮量(N_(100)),分析气候、土壤、品种和施肥因素对玉米N_(100)的影响,为确定合理施氮量提供科学依据。【方法】将中国分为东北、西北、华北平原、长江中下游平原、西南和东南6大农作区,搜集1980—2022年发表的349篇符合要求的文献,通过数据统计分析不同区域和不同产量水平条件下的玉米N_(100),并分析采用统一和区域化的N_(100)计算出的理论施氮量差异,采用皮尔逊相关系数(pearson correlation coefficient)、随机森林(random forest)模型和整合分析(Meta-analysis)方法分析气候、土壤和施肥因素对玉米N_(100)的影响,揭示导致中国玉米N_(100)空间差异的原因。【结果】优化处理条件下,中国春玉米N_(100)显著低于夏玉米,分别为2.21和2.46;不同农业生态区玉米N_(100)存在显著差异,分别为2.19(东北春玉米)、2.12(西北春玉米)、2.54(西北夏玉米)、2.45(华北夏玉米)、2.77(长江中下游春玉米)、2.38(长江中下游夏玉米)和2.39(西南玉米区)。依据本研究全国玉米平均N_(100)(2.34)计算的理论施氮量与采用区域化的N_(100)计算得到的理论施氮量相差-22—31 kg N·hm^(-2)。地上部吸氮量、产量、年均气温是影响玉米N_(100)的最重要因素;N_(100)随产量增加呈显著二次曲线降低的趋势(P<0.01),籽粒产量可以很好地预测N_(100);品种显著影响玉米N_(100),中国常见的玉米品种郑单958、先玉335和登海605的N_(100)分别为2.42、2.12和2.39,新品种玉米N_(100)显著低于老品种。施用氮肥显著增加了玉米N_(100),且在施氮量200—300 kg N·hm^(-2)时,施氮肥引起的N_(100)增加效应最大。单施缓控释肥、深施氮肥、减少氮肥基施比例以及增加施氮次数均显著增加了玉米N_(100)。【结论】在利用N_(100)进行合理施氮量计算时,需要考虑不同农业生态区N_(100)的显著差异,以得到更加准确的推荐施氮量,玉米N_(100)的驱动因素主要为作物地上部吸氮量、产量和年均气温的变异。
