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Compositional and Hollow Engineering of Silicon Carbide/Carbon Microspheres as High-Performance Microwave Absorbing Materials with Good Environmental Tolerance
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作者 Lixue Gai Yahui Wang +5 位作者 Pan Wan Shuping Yu Yongzheng Chen Xijiang Han Ping Xu Yunchen Du 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第9期128-146,共19页
Microwave absorbing materials(MAMs)characterized by high absorption efficiency and good environmental tolerance are highly desirable in practical applications.Both silicon carbide and carbon are considered as stable M... Microwave absorbing materials(MAMs)characterized by high absorption efficiency and good environmental tolerance are highly desirable in practical applications.Both silicon carbide and carbon are considered as stable MAMs under some rigorous conditions,while their composites still fail to produce satisfactory microwave absorption performance regardless of the improvements as compared with the individuals.Herein,we have successfully implemented compositional and structural engineering to fabricate hollow Si C/C microspheres with controllable composition.The simultaneous modulation on dielectric properties and impedance matching can be easily achieved as the change in the composition of these composites.The formation of hollow structure not only favors lightweight feature,but also generates considerable contribution to microwave attenuation capacity.With the synergistic effect of composition and structure,the optimized SiC/C composite exhibits excellent performance,whose the strongest reflection loss intensity and broadest effective absorption reach-60.8 dB and 5.1 GHz,respectively,and its microwave absorption properties are actually superior to those of most SiC/C composites in previous studies.In addition,the stability tests of microwave absorption capacity after exposure to harsh conditions and Radar Cross Section simulation data demonstrate that hollow SiC/C microspheres from compositional and structural optimization have a bright prospect in practical applications. 展开更多
关键词 SiC/C composites Compositional engineering hollow engineering Microwave absorption Environmental tolerance
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Analysis of strength characteristics of loess before and after freezing using a hollow cylinder torsional shear apparatus
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作者 Peng Shen QingZhi Wang +2 位作者 JianHong Fang ChenWei Wang Kui Zhang 《Research in Cold and Arid Regions》 CSCD 2024年第2期63-72,共10页
This paper aims to comprehensively analyze the influence of the principal stress angle rotation and intermediate principal stress on loess's strength and deformation characteristics. A hollow cylinder torsional sh... This paper aims to comprehensively analyze the influence of the principal stress angle rotation and intermediate principal stress on loess's strength and deformation characteristics. A hollow cylinder torsional shear apparatus was utilized to conduct tests on remolded samples under both normal and frozen conditions to investigate the mechanical properties and deformation behavior of loess under complex stress conditions. The results indicate significant differences in the internal changes of soil particles, unfrozen water, and relative positions in soil samples under normal and frozen conditions, leading to noticeable variations in strength and strain development.In frozen state, loess experiences primarily compressive failure with a slow growth of cracks, while at normal temperature, it predominantly exhibits shear failure. With the increase in the principal stress angle, the deformation patterns of the soil samples under different conditions become essentially consistent, gradually transitioning from compression to extension, accompanied by a reduction in axial strength. The gradual increase in the principal stress axis angle(α) reduces the strength of the generalized shear stress and shear strain curves.Under an increasing α, frozen soil exhibits strain-hardening characteristics, with the maximum shear strength occurring at α = 45°. The intermediate principal stress coefficient(b) also significantly impacts the strength of frozen soil, with an increasing b resulting in a gradual decrease in generalized shear stress strength. This study provides a reference for comprehensively exploring the mechanical properties of soil under traffic load and a reliable theoretical basis for the design and maintenance of roadbeds. 展开更多
关键词 LOESS hollow cylinder torsional shear apparatus Major principal stress angle Intermediate principal stress coefficient
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Topics of Truth,Kindness and Aesthetics in Chinese Education1
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作者 龚丹 《海外英语》 2011年第13期378-380,共3页
The ideal goal to cultivate creative talents who "seek truth","strive for kindness" and "adore aesthetics " and are equipped with "perfect personality" should be achieved,which ... The ideal goal to cultivate creative talents who "seek truth","strive for kindness" and "adore aesthetics " and are equipped with "perfect personality" should be achieved,which is expected to reach brand-new circumstances of "humans development and construction of completeness" and must and should explore "Truth","Kindness" and "Aesthetics" in Chinese education.This article is meant to explore "truth" of Chinese(language,article,literature) in the intellectual education from cognitive science and to promote students to get into quality of exploration;they should explore "kindness" in the moral education in Chinese(language,article,literature) from ethics,which is to urge wakefulness of students' moral consciousness;in addition,"aesthetics" in Chinese(language,article,literature) from aesthetic education is to spur students to construct free soul. 展开更多
关键词 TRUTH kindNESS and AESTHETICS in the CHINESE EDUCATION meaning of truth kindness and AESTHETICS in CHINESE EDUCATION
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N-doped graphene quantum dot-decorated N-TiO2/P-doped porous hollow g-C_(3)N_(4) nanotube composite photocatalysts for antibiotic photodegradation and H2 production 被引量:1
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作者 Jingshu Yuan Yao Zhang +2 位作者 Xiaoyan Zhang Junjie Zhang Shen’gen Zhang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CSCD 2024年第1期165-178,共14页
Exclusive responsiveness to ultraviolet light (~3.2 eV) and high photogenerated charge recombination rate are the two primary drawbacks of pure TiO_(2). We combined N-doped graphene quantum dots (N-GQDs), morphology r... Exclusive responsiveness to ultraviolet light (~3.2 eV) and high photogenerated charge recombination rate are the two primary drawbacks of pure TiO_(2). We combined N-doped graphene quantum dots (N-GQDs), morphology regulation, and heterojunction construction strategies to synthesize N-GQD/N-doped TiO_(2)/P-doped porous hollow g-C_(3)N_(4) nanotube (PCN) composite photocatalysts (denoted as G-TPCN). The optimal sample (G-TPCN doped with 0.1wt% N-GQD, denoted as 0.1% G-TPCN) exhibits significantly enhanced photoabsorption, which is attributed to the change in bandgap caused by elemental doping (P and N), the improved light-harvesting resulting from the tube structure, and the upconversion effect of N-GQDs. In addition, the internal charge separation and transfer capability of0.1% G-TPCN are dramatically boosted, and its carrier concentration is 3.7, 2.3, and 1.9 times that of N-TiO_(2), PCN, and N-TiO_(2)/PCN(TPCN-1), respectively. This phenomenon is attributed to the formation of Z-scheme heterojunction between N-TiO_(2) and PCNs, the excellent electron conduction ability of N-GQDs, and the short transfer distance caused by the porous nanotube structure. Compared with those of N-TiO_(2), PCNs, and TPCN-1, the H2 production activity of 0.1%G-TPCN under visible light is enhanced by 12.4, 2.3, and 1.4times, respectively, and its ciprofloxacin (CIP) degradation rate is increased by 7.9, 5.7, and 2.9 times, respectively. The optimized performance benefits from excellent photoresponsiveness and improved carrier separation and migration efficiencies. Finally, the photocatalytic mechanism of 0.1% G-TPCN and five possible degradation pathways of CIP are proposed. This study clarifies the mechanism of multiple modification strategies to synergistically improve the photocatalytic performance of 0.1% G-TPCN and provides a potential strategy for rationally designing novel photocatalysts for environmental remediation and solar energy conversion. 展开更多
关键词 N-doped TiO_(2) N-doped graphene quantum dots P-doped g-C_(3)N_(4) porous hollow nanotube heterojunction photocatalysis
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Hyperbranched polymer hollow-fiber-composite membranes for pervaporation separation of aromatic/aliphatic hydrocarbon mixtures
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作者 Tong Liu Hao Sun +5 位作者 Xiangqiong Wang Jie Li Zhanquan Zhang Pei Wu Naixin Wang Quanfu An 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第5期13-22,共10页
The separation of aromatic/aliphatic hydrocarbon mixtures is crucial in the petrochemical industry.Pervaporation is regarded as a promising approach for the separation of aromatic compounds from alkanes. Developing me... The separation of aromatic/aliphatic hydrocarbon mixtures is crucial in the petrochemical industry.Pervaporation is regarded as a promising approach for the separation of aromatic compounds from alkanes. Developing membrane materials with efficient separation performance is still the main task since the membrane should provide chemical stability, high permeation flux, and selectivity. In this study, the hyperbranched polymer(HBP) was deposited on the outer surface of a polyvinylidene fluoride(PVDF)hollow-fiber ultrafiltration membrane by a facile dip-coating method. The dip-coating rate, HBP concentration, and thermal cross-linking temperature were regulated to optimize the membrane structure.The obtained HBP/PVDF hollow-fiber-composite membrane had a good separation performance for aromatic/aliphatic hydrocarbon mixtures. For the 50%/50%(mass) toluene/n-heptane mixture, the permeation flux of optimized composite membranes could reach 1766 g·m^(-2)·h^(-1), with a separation factor of 4.1 at 60℃. Therefore, the HBP/PVDF hollow-fiber-composite membrane has great application prospects in the pervaporation separation of aromatic/aliphatic hydrocarbon mixtures. 展开更多
关键词 Aromatic/aliphatic hydrocarbons Hyperbranched polymer PERVAPORATION hollow fiber membrane DIP-COATING
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Controllable fabrication of FeCoS_(4) nanoparticles/S-doped bowl-shaped hollow carbon as efficient lithium storage anode
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作者 Ming Zhou Mengrong Wu +8 位作者 Haiwei Yu Xiangjun Zheng Kuan Shen Xingmei Guo Yuanjun Liu Fu Cao Hongxing Gu Qinghong Kong Junhao Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第3期78-88,共11页
To address the low conductivity and easy agglomeration of transition metal sulfide nanoparticles,FeCoS_(4) nanoparticles embedded in S-doped hollow carbon(FeCoS_(4)@S-HC)composites were successfully fabricated through... To address the low conductivity and easy agglomeration of transition metal sulfide nanoparticles,FeCoS_(4) nanoparticles embedded in S-doped hollow carbon(FeCoS_(4)@S-HC)composites were successfully fabricated through a combination of hydrothermal processes and sulfidation treatment.The unique bowlshaped FeCoS_(4)/S-HC composites exhibit excellent structural stability with a high specific surface area of 303.7 m^(2)·g^(-1) and a pore volume of 0.93 cm^(3)·g^(-1).When applied as anode material for lithium-ion batteries,the FeCoS_(4)@S-HC anode exhibits efficient lithium storage with high reversible specific capacity(970.2 mA·h·g^(-1) at 100 mA·g^(-1))and enhanced cycling stability(574 mA·h·g^(-1) at 0.2 A·g^(-1) after 350 cycles,a capacity retention of 84%).The excellent lithium storage is attributed to the fact that the bimetallic FeCoS_(4) nanoparticles with abundant active sites can accelerate the electrochemical reaction kinetics,and the bowl-shaped S-HC structure can provide a stable mechanical structure to suppress volume expansion. 展开更多
关键词 Bimetallic sulfides Bowl-shaped hollow carbon S doping Buffering volume expand Lithium-ion batteries
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Hollow ZIF-67-derived Co@N-doped carbon nanotubes boosting the hydrogenation of phenolic compounds to alcohols
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作者 Zhihao Guo Jiuxuan Zhang +3 位作者 Lanlan Chen Chaoqun Fan Hong Jiang Rizhi Chen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期157-166,共10页
The selective hydrogenation of highly toxic phenolic compounds to generate alcohols with thermal stability,environmental friendliness,and non-toxicity is of great importance.Herein,a series of Co-based catalysts,named... The selective hydrogenation of highly toxic phenolic compounds to generate alcohols with thermal stability,environmental friendliness,and non-toxicity is of great importance.Herein,a series of Co-based catalysts,named Co@NCNTs,were designed and constructed by direct pyrolysis of hollow ZIF-67(HZIF-67)under H_(2)/Ar atmosphere.The evolution of the catalyst surface from the shell layer assembled by ZIF-67-derived particles to the in situ-grown hollow nitrogen-doped carbon nanotubes(NCNTs)with certain length and density is achieved by adjusting the pyrolysis atmosphere and temperature.Due to the synergistic effects of in situ-formed hollow NCNTs,well-dispersed Co nanoparticles,and intact carbon matrix,the as-prepared Co@NCNTs-0.10-450 catalyst exhibits superior catalytic performance in the hydrogenation of phenolic compounds to alcohols.The turnover frequency value of Co@NCNTs-0.10-450is 3.52 h^(-1),5.9 times higher than that of Co@NCNTs-0.40-450 and 4.5 times higher than that of Co@NCNTs-0.10-550,exceeding most previously reported non-noble metal catalysts.Our findings provide new insights into the development of non-precious metal,efficient,and cost-effective metal-organic framework-derived catalysts for the hydrogenation of phenolic compounds to alcohols. 展开更多
关键词 Phenolic compounds hollow ZIF-67 pyrolysis Nitrogen-doped carbon nanotubes Reduction Multiphase reaction Catalysis
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Functional Outcomes of Adult Tibia Shaft Fractures Treated with Solid Intramedullary Nails versus Hollow Nails: A Systematic Review
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作者 Kwadwo Aning Abu Bernard Hammond +5 位作者 Mohammed Issah Suglo Bukari Kizito Kakra Vormawor Ronald Awoonor-Williams David Anyitey-Kokor Paa Kwesi Baidoo Dominic Konadu-Yeboah 《Open Journal of Orthopedics》 2024年第3期149-172,共24页
Introduction: The management of fractures of the tibia shaft is an important aspect of orthopaedic care, and the selection of the surgical method for fixation can substantially impact patient outcomes. The current rev... Introduction: The management of fractures of the tibia shaft is an important aspect of orthopaedic care, and the selection of the surgical method for fixation can substantially impact patient outcomes. The current review aims to compare the outcomes of adult tibia fractures treated with solid nails to those treated with hollow nails. Methods: A search on Scopus, PubMed, and Cochrane Library, using three keywords (Outcome, Tibia shaft fractures, Nail) was conducted in April 2023. Results were compiled and two independent reviewers screened and selected eligible articles After removing duplicates, titles and abstracts were read to exclude ineligible studies. Full-text articles of the remaining papers were read to select eligible studies which were further critically appraised to ascertain their methodological quality. The data extracted from the selected papers were synthesized using a combination of pooling of results, tests of statistical difference (t-test and chi-square) and narrative synthesis methods. Results: A total of 2295 articles were obtained from the databases and citation searching. A total of 9 papers were identified as eligible and included in the review. Findings revealed that there is no statistical difference in the outcomes of tibia fractures treated with either solid or hollow nail groups such as duration of surgery (p = 0.541), rate of delayed and non-union (p = 0.342), and rate of surgical site infections (p = 0.395). Conclusion: Intramedullary nailing of tibia shaft fractures with either solid or hollow nails have similar functional outcomes. 展开更多
关键词 Tibia Shaft Fractures Functional Outcome SIGN Nail hollow Nail
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Convergence Phenomenon with Fourier Series of tg(x2)and Alike
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作者 Alfred Wünsche 《Advances in Pure Mathematics》 2024年第7期556-595,共40页
The Fourier series of the 2π-periodic functions tg(x2)and 1sin(x)and some of their relatives (first of their integrals) are investigated and illustrated with respect to their convergence. These functions are Generali... The Fourier series of the 2π-periodic functions tg(x2)and 1sin(x)and some of their relatives (first of their integrals) are investigated and illustrated with respect to their convergence. These functions are Generalized functions and the convergence is weak convergence in the sense of the convergence of continuous linear functionals defining them. The figures show that the approximations of the Fourier series possess oscillations around the function which they represent in a broad band embedding them. This is some analogue to the Gibbs phenomenon. A modification of Fourier series by expansion in powers cosn(x)for the symmetric part of functions and sin(x)cosn−1(x)for the antisymmetric part (analogous to Taylor series) is discussed and illustrated by examples. The Fourier series and their convergence behavior are illustrated also for some 2π-periodic delta-function-like sequences connected with the Poisson theorem showing non-vanishing oscillations around the singularities similar to the Gibbs phenomenon in the neighborhood of discontinuities of functions. . 展开更多
关键词 Gibbs Phenomenon Generalized Functions Weak Convergence Chebyshev Polynomials of First and Second kind Even and Odd Generating Functions for Chebyshev Polynomials POLYLOGARITHMS Completeness Relations
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Design of ZnSe-CoSe heterostructure decorated in hollow N-doped carbon nanocage with generous adsorption and catalysis sites for the reversibly fast kinetics of polysulfide conversion 被引量:1
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作者 Junan Feng Chuan Shi +7 位作者 Hanghang Dong Chaoyue Zhang Wendong Liu Yu Liu Tianyi Wang Xiaoxian Zhao Shuangqiang Chen Jianjun Song 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第11期135-145,I0004,共12页
Although lithium-sulfur batteries(Li SBs)are regarded as one of the most promising candidates for the next-generation energy storage system,the actual industrial application is hindered by the sluggish solid–liquid p... Although lithium-sulfur batteries(Li SBs)are regarded as one of the most promising candidates for the next-generation energy storage system,the actual industrial application is hindered by the sluggish solid–liquid phase conversion kinetics,severe shuttle effect,and low sulfur loadings.Herein,a zeolitic imidazolate framework(ZIF)derived heterogeneous ZnSe-CoSe nanoparticles encapsulated in hollow N-doped carbon nanocage(ZnSe-CoSe-HNC)was designed by etching with tannic acid as a multifunctional electrocatalyst to boost the polysulfide conversion kinetics in LiSBs.The hollow structure in ZIF ensures large inner voids for sulfur and buffering volume expansions.Abundant exposed ZnSe-CoSe heterogeneous interfaces serve as bifunctional adsorption-catalytic centers to accelerate the conversion kinetics and alleviate the shuttle effect.Together with the highly conductive framework,the ZnSe-CoSeHNC/S cathode exhibits a high initial reversible capacity of 1305.3 m A h g-1at 0.2 C,high-rate capability,and reliable cycling stability under high sulfur loading and lean electrolyte(maintaining at 745 m A h g-1after 200 cycles with a high sulfur loading of 6.4 mg cm-2and a low electrolyte/sulfur ratio of 6μL mg^(-1)).Theoretical calculations have demonstrated the heterostructures of ZnSe-CoSe offer higher binding energy to lithium polysulfides than that of ZnSe or CoSe,facilitating the electron transfer to lithium polysulfides.This work provides a novel heterostructure with superior catalytic ability and hollow conductive architecture,paving the way for the practical application of functional sulfur electrodes. 展开更多
关键词 Lithium-sulfur batteries HETEROSTRUCTURE Conversion Kinetics hollow structure Bi-directional catalysis
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Fabrication and Characterization of Bamboo—Epoxy Reinforced Composite for Thermal Insulation
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作者 Nandavardhan Reddy Kopparthi Jens Schuster Yousuf Pasha Shaik 《Open Journal of Composite Materials》 2024年第1期15-32,共18页
As global warming intensifies, researchers worldwide strive to develop effective ways to reduce heat transfer. Among the natural fiber composites studied extensively in recent decades, bamboo has emerged as a prime ca... As global warming intensifies, researchers worldwide strive to develop effective ways to reduce heat transfer. Among the natural fiber composites studied extensively in recent decades, bamboo has emerged as a prime candidate for reinforcement. This woody plant offers inherent strengths, biodegradability, and abundant availability. Due to its high cellulose content, its low thermal conductivity establishes bamboo as a thermally resistant material. Its low thermal conductivity, enhanced by a NaOH solution treatment, makes it an excellent thermally resistant material. Researchers incorporated Hollow Glass Microspheres (HGM) and Kaolin fillers into the epoxy matrix to improve the insulating properties of bamboo composites. These fillers substantially enhance thermal resistance, limiting heat transfer. Various compositions, like (30% HGM + 25% Bamboo + 65% Epoxy) and (30% Kaolin + 25% Bamboo + 45% Epoxy), were compared to identify the most efficient thermal insulator. Using Vacuum Assisted Resin Transfer Molding (VARTM) ensures uniform distribution of fillers and resin, creating a structurally sound thermal barrier. These reinforced composites, evaluated using the TOPSIS method, demonstrated their potential as high-performance materials combating heat transfer, offering a promising solution in the battle against climate change. 展开更多
关键词 Thermal Insulator Rooftiles hollow Glass Microspheres BAMBOO KAOLIN EPOXY VARTM Process Thermal Conductivity Mechanical Properties
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Synthesis and Characterization of Hollow Strontium Carbonate Pompons by Composite Soft Template Method
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作者 LI Bibo DONG Xiufang +4 位作者 LI Yu SONG Jian XIE Wuxi ZHANG Wei LIU Yunfei 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第6期1434-1439,共6页
The hollow strontium carbonate pompons was synthesized for the first time by a controlled reaction precipitation method with sodium dodecyl benzene sulfonate(SDBS)and polyvinyl pyrrolidone(PVP)work together as templat... The hollow strontium carbonate pompons was synthesized for the first time by a controlled reaction precipitation method with sodium dodecyl benzene sulfonate(SDBS)and polyvinyl pyrrolidone(PVP)work together as template.The sampled particles were characterized by scanning electron microscopy(SEM),transmission electron microscopy(TEM),nitrogen adsorption-desorption measurement,X-ray diffraction(XRD),Energy dispersive X-Ray spectroscopy(EDX),Fourier transform infrared spectroscopy(FTIR),Thermogravimetric analysis and differential scanning calorimetry(TGA-DSC),etc.It is shown that the assynthesized hollow strontium carbonate pompons with the size of about 2μm consist of flake-like particles under the optimal reaction conditions.The formation mechanism of hollow strontium carbonate pompons was preliminarily explored. 展开更多
关键词 strontium carbonate hollow structure pompons composite soft template method
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The Fabrication and SERS Performance of Multi-layer Hollow Au-Ag Alloy Nano Urchins Structure-based SERS Fiber Probe
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作者 HAO Zhenbang TIAN Qihang +4 位作者 CAO Shiyi HAN Xiaoyu ZHANG Jihong XIE Jun ZHAO Xiujian 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第2期274-279,共6页
Novel hollow Au Ag alloy nano urchins were synthesized via Ag seeds growth method,and self-assembly coated on the wall and end-tip of silica fiber for fiber probe fabrication.The nano urchins homogeneously distributed... Novel hollow Au Ag alloy nano urchins were synthesized via Ag seeds growth method,and self-assembly coated on the wall and end-tip of silica fiber for fiber probe fabrication.The nano urchins homogeneously distributed on fiber surface because of fiber silanization.The sizes and tip sharpness of the nano-urchins could be controlled by Ag seeds.The elements distribution analysis indicated there was high Ag content in tip-top for better surface enhance Raman scattering performance.The detectable concentration could be as low as 10-8 M using crystal violet molecules as analyte.Moreover,the fiber probes were stable in air,due to Au in the alloy.This fiber probe could be used for low content single molecular analysis. 展开更多
关键词 surface enhanced raman spectroscopy hollow Au-Ag alloy nano urchins fiber probe
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Binary molten salt in situ synthesis of sandwich-structure hybrids of hollowβ-Mo2C nanotubes and N-doped carbon nanosheets for hydrogen evolution reaction
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作者 Tianyu Gong Yang Liu +6 位作者 Kai Cui Jiali Xu Linrui Hou Haowen Xu Ruochen Liu Jianlin Deng Changzhou Yuan 《Carbon Energy》 SCIE EI CAS CSCD 2023年第12期111-124,共14页
Focused exploration of earth-abundant and cost-efficient non-noble metal electrocatalysts with superior hydrogen evolution reaction(HER)performance is very important for large-scale and efficient electrolysis of water... Focused exploration of earth-abundant and cost-efficient non-noble metal electrocatalysts with superior hydrogen evolution reaction(HER)performance is very important for large-scale and efficient electrolysis of water.Herein,a sandwich composite structure(designed as MS-Mo2C@NCNS)ofβ-Mo2C hollow nanotubes(HNT)and N-doped carbon nanosheets(NCNS)is designed and prepared using a binary NaCl–KCl molten salt(MS)strategy for HER.The temperature-dominant Kirkendall formation mechanism is tentatively proposed for such a three-dimensional hierarchical framework.Due to its attractive structure and componential synergism,MS-Mo2C@NCNS exposes more effective active sites,confers robust structural stability,and shows significant electrocatalytic activity/stability in HER,with a current density of 10 mA cm-2 and an overpotential of only 98 mV in 1 M KOH.Density functional theory calculations point to the synergistic effect of Mo2C HNT and NCNS,leading to enhanced electronic transport and suitable adsorption free energies of H*(ΔGH*)on the surface of electroactive Mo2C.More significantly,the MS-assisted synthetic methodology here provides an enormous perspective for the commercial development of highly active non-noble metal electrocatalysts toward efficient hydrogen evolution. 展开更多
关键词 binary molten-salt synthesis hydrogen evolution reaction Mo2C hollow nanotubes N-doped carbon nanosheets sandwich structure
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Is Moss Stoichiometry Influenced by Microtopography in a Boreal Peatland of Northeast China?
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作者 ZHANG Xinhou MAO Rong +2 位作者 SONG Changchun LIU Yan REN Zhaojie 《Chinese Geographical Science》 SCIE CSCD 2018年第6期1038-1047,共10页
To examine the effects of microtopography on the stoichiometry of carbon(C), nitrogen(N) and phosphorus(P) in mosses along the hummock-hollow gradient in boreal peatlands, we investigated species-level C?N, C?P and N?... To examine the effects of microtopography on the stoichiometry of carbon(C), nitrogen(N) and phosphorus(P) in mosses along the hummock-hollow gradient in boreal peatlands, we investigated species-level C?N, C?P and N?P ratios of five mosses(Sphagnum magellanicum, S. perichaetiale, S. palustre, S. girgensohnii and Aulacomnium palustre) in the hummocks, hollows and their intermediate zones, and then assessed community-level spatial patterns in a boreal ombrotrophic peatland of north of the Great Xing'an Mountain, Northeast China. The results show that at the species level, C?N, C?P and N?P ratios of the selected Sphagnum mosses remained stable in the hummock-hollow complexes due to unchanged C, N and P concentrations, whereas the non-Sphagnum moss(A. palustre) in the hummocks and intermediate zones had lower P concentrations and thus greater C?P ratios than that in the hollows. At the community level, moss N concentration and C?N ratio remained constant along the hummock-hollow gradient, whereas hummocks and intermediate zones had higher community-level moss C?P and N?P ratios than hollows because of greater C and lower P concentrations. These findings imply that the effects of microtopography on moss C?N?P stoichiometry are scale-dependent and reveal spatial heterogeneity in C and nutrient dynamics. These results provide a more comprehensive understanding of biogeochemical cycles in boreal peatlands. 展开更多
关键词 苔藓 北方 中国 东北 空间模式 调查结果 比率 非水
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Pea-like MoS_(2)@NiS_(1.03)-carbon heterostructured hollow nanofibers for high-performance sodium storage 被引量:3
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作者 Songwei Gao Yixiang He +10 位作者 Guichu Yue Huaike Li Shuai Li Jingchong Liu Beibei Miao Jie Bai Zhimin Cui Nu Wang Qianfan Zhang Lei Jiang Yong Zhao 《Carbon Energy》 SCIE CSCD 2023年第4期42-54,共13页
The rational synergy of chemical composition and spatial nanostructures of electrode materials play important roles in high-performance energy storage devices.Here,we designed pea-like MoS_(2)@NiS_(1.03)-carbon hollow... The rational synergy of chemical composition and spatial nanostructures of electrode materials play important roles in high-performance energy storage devices.Here,we designed pea-like MoS_(2)@NiS_(1.03)-carbon hollow nanofibers using a simple electrospinning and thermal treatment method.The hierarchical hollow nanofiber is composed of a nitrogen-doped carbon-coated NiS_(1.03) tube wall,in which pea-like uniformly discrete MoS_(2) nanoparticles are enclosed.As a sodium-ion battery electrode material,the MoS_(2)@NiS_(1.03)-carbon hollow nanofibers have abundant diphasic heterointerfaces,a conductive network,and appropriate volume variation-buffering spaces,which can facilitate ion diffusion kinetics,shorten the diffusion path of electrons/ion,and buffer volume expansion during Na^(+)insertion/extraction.It shows outstanding rate capacity and long-cycle performance in a sodium-ion battery.This heterogeneous hollow nanoarchitectures designing enlightens an efficacious strategy to boost the capacity and long-life stability of sodium storage performance of electrode materials. 展开更多
关键词 density functional theory electrospinning HETEROSTRUCTURE hollow nanofibers molybdenum disulfide sodium-ion batteries
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Fabrication of ZIF-8 membranes on dual-layer ZnO-PES/PES organic hollow fibers by in-situ crystallization 被引量:2
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作者 Zhengchi Yin Xiaoke Wu +5 位作者 Yanwei Yang Huayu Zhang Wangtao Li Ruimin Zhu Qiancheng Zheng Zhengbao Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第3期101-110,共10页
Compared to inorganic supports, polymeric supports can offer additional benefits, e.g., easier processing and cheaper. However, the organic surface has weak adhesion to the zeolitic imidazolate frameworks(ZIFs) membra... Compared to inorganic supports, polymeric supports can offer additional benefits, e.g., easier processing and cheaper. However, the organic surface has weak adhesion to the zeolitic imidazolate frameworks(ZIFs) membrane layer, which usually requires complex surface modification or seeding. Herein, we demonstrate that a dual-layer asymmetric polymer support prepared by a simple spinning process is a good candidate for the preparation of ZIF-8 membrane. The inner layer of the support is an organic hollow fiber(PES) with finger-like pores, and the outer layer is a ZnO-PES composite layer with finger-like pores also. The ZnO-PES composite layer is expected to contain uniform ZnO crystals in the polymer matrix, i.e., the ZnO particles in the skin layer of the support are not easy to fall off. Under the induction of ZnO particles in the outer layers, continuous ZIF-8 membranes can be prepared by single in-situ crystallization, showing good adhesion to the supports. The obtained ZIF-8 membranes show a H_(2) permeance of 8.7 × 10^(-8)mol·m^(-2)·s^(-1)·Pa^(-1) with a H_(2)/N_(2) ideal separation selectivity of 18.0. The design and preparation of this dual-layer polymer support is expected to promote the large-scale application of MOF membranes on polymer supports. 展开更多
关键词 Dual-layer PES hollow fiber In-situ crystallization ZIF-8 membrane Gas separation ZNO
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Rationally designed hollow carbon nanospheres decorated with S,P co-doped NiSe_(2) nanoparticles for high-performance potassium-ion and lithium-ion batteries 被引量:3
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作者 Jiajia Ye Zizhong Chen +4 位作者 Zhiqiang Zheng Zhanghua Fu Guanghao Gong Guang Xia Cheng Hu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第3期401-411,I0011,共12页
Hollow nanostructures with external shells and inner voids have been proved to greatly shorten the transport distance of ions/electrons and buffer volume change,especially for the large-sized potassium-ions in seconda... Hollow nanostructures with external shells and inner voids have been proved to greatly shorten the transport distance of ions/electrons and buffer volume change,especially for the large-sized potassium-ions in secondary batteries.In this work,hollow carbon(HC) nanospheres embedded with S,P co-doped NiSe_(2)nanoparticles are fabricated by "drop and dry" and "dissolving and precipitation" processes to form Ni(OH)2nanocrystals followed by annealing with S and P dopants to form nanoparticles.The resultant S,P-NiSe_(2)/HC composite exhibits excellent cyclic performance with 131.6 mA h g^(-1)at1000 mA g^(-1)after 3000 cycles for K^(+)storage and a capacity of 417.1 mA h g^(-1)at 1000 mA g^(-1)after1000 cycles for Li^(+)storage.K-ion full cells are assembled and deliver superior cycling stability with a ca pacity of 72.5 mA h g^(-1)at 200 mA g^(-1)after 500 cycles.The hollow carbon shell with excellent electrical conductivity effectively promotes the transporta tion and tolerates large volume variation for both K^(+)and Li^(+).Density functional theory calculations confirm that the S and P co-doping NiSe_(2) enables stronger adsorption of K^(+)ions and higher electrical conductivity that contributes to the improved electrochemical performance. 展开更多
关键词 S P co-doping NiSe_(2)nanoparticles hollow carbon nanospheres Potassium-ion batteries Lithium-ion batteries
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Nano-single-crystal-constructed submicron MnCO_(3) hollow spindles enabled by solid precursor transition combined Ostwald ripening in situ on graphene toward exceptional interfacial and capacitive lithium storage 被引量:1
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作者 Jiamin Fei Shiqiang Zhao +6 位作者 Xiaoxu Bo Furong Xie Guanghui Li Ebrahim-Alkhalil MAAhmed Qingcheng Zhang Huile Jin Zhiqun Lin 《Carbon Energy》 SCIE CSCD 2023年第8期98-113,共16页
Hollow structuring has been identified as an effective strategy to enhance the cycling stability of electrodes for rechargeable batteries due to the outstanding volume expansion buffering efficiency,which motivates ar... Hollow structuring has been identified as an effective strategy to enhance the cycling stability of electrodes for rechargeable batteries due to the outstanding volume expansion buffering efficiency,which motivates ardent pursuing on the synthetic approaches of hollow materials.Herein,an intriguing route,combining solid precursor transition and Ostwald ripening(SPTOR),is developed to craft nano single-crystal(SC)-constructed MnCO_(3) submicron hollow spindles homogeneously encapsulated in a reduced graphene oxide matrix(MnCO_(3) SMHSs/rGO).It is noteworthy that the H-bonding interaction between Mn_(3)O_(4) nanoparticles(NPs)and oxygen-containing groups on GO promotes uniform anchoring of Mn_(3)O_(4) NPs on GO,mild reductant ascorbic acid triggers the progressive solid-to-solid transition from Mn_(3)O_(4) NPs to MnCO_(3) submicron solid spindles(SMSSs)in situ on GO,and the Ostwald ripening process induces the gradual dissolution of interior polycrystals of MnCO_(3) SMSSs and subsequent recrystallization on surface SCs of MnCO_(3) SMHSs.Remarkably,MnCO_(3) SMHSs/rGO delivers a 500th lithium storage capacity of 2023 mAh g^(-1) at 1000 mAg^(-1),which is 10 times higher than that of MnCO_(3) microspheres/rGO fabricated from a conventional Mn^(2+)salt precursor(202 mAh g^(-1)).The ultrahigh capacity and ultralong lifespan of MnCO_(3) SMHSs/rGO can be primarily attributed to the superior reaction kinetics and reversibility combined with exceptional interfacial and capacitive lithium storage capability,enabled by the fast ion/electron transfer,large specific surface area,and robust electrode pulverization inhibition efficacy.Moreover,fascinating in-depth lithium storage reactions of MnCO_(3) are observed such as the oxidation of Mn^(2+)in MnCO_(3) to Mn^(3+)in charge process after long-term cycles and the further lithiation of Li_(2)CO_(3) in discharge process.As such,the Carbon Energy.SPTOR approach may represent a viable strategy for crafting various hollow functional materials with metastable nanomaterials as precursors. 展开更多
关键词 hollow structure interfacial and capacitive lithium storage lithium-ion battery MnCO_(3) Ostwald ripening solid precursor transition
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Experimental study of hollow rectangular bridge column performance under vertical and cyclically bilateral loads 被引量:12
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作者 Han Qiang Du Xiuli +1 位作者 Yihui Zhou George C. Lee 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2013年第3期433-445,共13页
To investigate the seismic performance of hollow reinforced concrete (RC) bridge columns of rectangular cross section under constant axial load and cyclically biaxial bending, five specimens were tested. A parametri... To investigate the seismic performance of hollow reinforced concrete (RC) bridge columns of rectangular cross section under constant axial load and cyclically biaxial bending, five specimens were tested. A parametric study is carried out for different axial load ratios, longitudinal reinforcement ratios and lateral reinforcement ratios. The experimental results showed that all tested specimens failed in the flexural failure mode and their ultimate performance was dominated by flexural capacity, which is represented by the rupture/buckling of tensile longitudinal rebars at the bottom of the bridge columns. Biaxial force and displacement hysteresis loops showed significant stiffness and strength degradations, and the pinching effect and coupling interaction effect of both directions severely decrease the structural seismic resistance. However, the measured ductility coefficient varying from 3.5 to 5.7 and the equivalent viscous damping ratio varying from 0.19 and 0.26 can meet the requirements of the seismic design. The hollow RC rectangular bridge columns with configurations of lateral reinforcement in this study have excellent performance under bidirectional earthquake excitations, and may be considered as a substitute for current hollow RC rectangular section configurations described in the Guideline for Seismic Design of Highway Bridges (JTG/T B02-01-2008). The length of the plastic hinge region was found to approach one sixth of the hollow RC rectangular bridge column height for all specimen columns, and it was much less than those specified in the current JTG/T. Thus, the length of the plastic hinge region is more concentrated for RC rectangular hollow bridge columns. 展开更多
关键词 bridge columns hollow section cyclic loading test biaxial bending seismic performance
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