Synthesis Characterization Non-isothermal Kinetics of the Thermal Decomposition and Redox Properties Derived from Copper(Ⅱ) Binuclear Coordination Compound of 1,4-Bis-(1'-Phenyl-3'-Methyl-5'-Pyrazolone-4')-1,4-Butanedione

The paper reports the synthetic procedure and character of Copper(II) binuclearcoordination compound of 1,4-bis-(1'-phenyl-3'-methyl-5'-pyrazolone Thenon-isothermal kinetics of thermal decomposition of the complex has been stUdied from the TG-DTGcurves by means of the Achar et al. and Coats-Redfern methods,the most probab1e kinetic equation canbe expressed as dofdtrAe -E / RT * l /(2Q).The corresponding kinetic compensation effect expressions arefound to be lnuA=0. 1794E+0. 1689.The non-isothermal thermal decomposition process of the complex isone-dimensional diffusion.But electrochemical studies of the complex(Cu2L'2)from cyclic voltamrnetriccurves by means of powder microelectrodes technique'',shows one two-electron irreversible process.

Apparent activation energy of mineral in open pit mine based upon the evolution of active functional groups

This study aimed to investigate the mechanism of mineral spontaneous combustion in an open pit. On the study of coal and mineral mixture in open pit mines, as well as through the specifc surface area and Search Engine Marketing (SEM) experiments, the specifc surface area and aperture characteristics of distribution of open pit coal sample and pit mineral mixture samples were analyzed. Thermal analysis experiments were used to divide the oxidation process was divided into three stages, and the thermal behavior characteristics of experimental samples were characterized. On the basis of the stage division, we explored the transfer law of the key active functional groups of the experimental samples. The apparent activation energy calculation of the key active groups, performed by combining the Achar diferential method with the Coats–Redfern integral method, microstructural and oxidation kinetic properties were revealed. The resulted showed that the mixed sample had high ash, the fxed carbon content was reduced, the specifc surface area was far lower than the raw coal, the large aperture distribution was slightly higher than the medium hole, the micropore was exceptionally low, the gas adsorption capacity was weaker than the raw coal, the pit coal sample had the exceedingly more active functional groups, easy to react with oxygen, more likely to occur naturally, and its harm was relatively large. The mixed sample contained the highest C–O–C functional group absorbance. The functional groups were mainly infuenced by the self-OH content, alkyl side chain, and fatty hydrocarbon in the sample. The main functional groups of the four-like mixture had the highest apparent activation energy, and the two reactions were higher in the low-temperature oxidation phase.

Investigation of Physical Properties of Nano Crude Petroleum: Increasing Oil Flow Rate in Reservoirs

The zinc oxide nano-particles have been used in this research. In this work, zinc oxide nanoparticles have been added to light and heavy crude oil. In this research, thermoelectric and physical properties of light and heavy crude petroleum have been measured, experimentally. In addition, dimensionless groups in hydrodynamics and heat transfer calculations are presented. This research illustrates that heat capacity of light and heavy crude petroleum varies from 4256 J/kg·°C to 4457 J/kg·°C and 4476 J/kg·°C to 5002 J/kg·°C, respectively. Moreover, heat capacity of light and heavy nano-crude petroleum is changing from about 4285 J/kg·°C to 4496 J/kg·°C and 4494 J/kg·°C to 5021 J/kg·°C, respectively.

Nanocrystalline High Entropy Alloys with Ultrafast Kinetics and High Storage Capacity for Large-Scale Room-Temperature-Applicable Hydrogen Storage

High-entropy alloys(HEAs)are a promising solution for large-scale hydrogen storage(H-storage)and are therefore receiving increasing attention from the materials science community.In this study,we systematically investigated the microstructures and H-storage properties of V_(35)Ti_(35)Cr_(10) Fe_(10)M_(10)(M=Mn,Co,Sc,or Ni)HEAs prepared by arcmelting.The cast HEAs were found to be nanocrystalline.The crystal lattice parameters and hydrogen absorption energies of the alloys were calculated using density functional theory(DFT)calculations.The alloys can be fully activated in just one cycle of hydrogen absorption/desorption under mild conditions,after which they reach hydrogen absorption saturation in approximately 100 s at ambient temperature.The hydrogenation kinetics of the HEAs are approximately five times higher than that of conventional solid-solution alloys with a body-centered cubic(BCC)structure.By performing in-situ hydriding differential scanning calorimetry in combination with DFT calculations,we revealed that the alloys are more susceptible to hydrogenation than traditional BCC structural alloys.The H-storage capacity of V_(35)Ti_(35)Cr_(10) Fe_(10)M_(10) alloys at ambient temperature was higher than that of HEAs reported in the literature.Quasi-in-situ X-ray diffraction characterization of the HEAs’hydrogenation revealed a phase transition process from a BCC to facecentered cubic,passing through a pseudo-BCC structure.Our work introduces a new perspective for designing alloys with ultrafast hydrogen absorption kinetics and high capacity for large-scale,room-temperature-applicable H-storage.

Influence of TiC catalyst on absorption/desorption behaviors and microstructures of sodium aluminum hydride

TiC-doped NaA1H4 complex hydrides were prepared by hydrogenation of ball-milled Nail/A1 mixture with x TiC powder （x = 0, 5%, 8%, 10%, mole fraction）. The effects of TiC catalyst content on the absorption/desorption behaviors of the samples were investigated. The results show that TiC can improve the hydriding/dehydriding kinetics of sodium aluminum hydride, the hydriding rate of the sample increases with increasing TiC content. It is found that the TiC-doped NaA1H4 composites have a relatively good cyclic stability. The composite doped with 10% TiC maintains steadily about 4.5% （mass fraction） hydrogen absorption capacity as against about 3.8% （mass fraction） hydrogen desorption capacity over 8 cycles. The particle sizes of the TiC-doped NaA1H4 composites can be reduced to 50-100 nm, which may play an important role in improving the hydriding/dehydriding kinetics.

The electrochemical characteristics of AB_(4)-type rare earth-Mg-Ni-based superlattice structure hydrogen storage alloys for nickel metal hydride battery

Rare earth-Mg-Ni-based alloys with superlattice structures are new generation negative electrode materials for the nickel metal hydride batteries.Among them,the novel AB_(4)-type superlattice structure alloy is supposed to have superior cycling stability and rate capability.Yet its preparation is hindered by the crucial requirement of temperature and the special composition which is close to the other superlattice structure.Here,we prepare rare earth-Mg-Ni-based alloy and study the phase transformation of alloys to make clear the formation of AB_(4)-type phase.It is found Pr_(5)Co_(19)-type phase is converted from Ce_(5)Co_(19)-type phase and shows good stability at higher temperature compared to the Ce_(5)Co_(19)-type phase in the range of 930-970℃.Afterwards,with further 5℃increasing,AB_(4)-type superlattice structure forms at a temperature of 975℃by consuming Pr_(5)Co_(19)-type phase.In contrast with A_(5)B_(19)-type alloy,AB_(4)-type alloy has superior rate capability owing to the dominant advantages of charge transfer and hydrogen diffusion.Besides,AB_(4)-type alloy shows long lifespan whose capacity retention rates are 89.2%at the 100;cycle and 82.8%at the 200;cycle,respectively.AB_(4)-type alloy delivers 1.53 wt.%hydrogen storage capacity at room temperature and exhibits higher plateau pressure than Pr_(5)Co_(19)-type alloy.The work provides novel AB_(4)-type alloy with preferable electrochemical performance as negative electrode material to inspire the development of nickel metal hydride batteries.

A THEORETICAL STUDY OF THE THERMODYNAMIC AND KINETIC PROPERTIES FOR THE REACTION OF FORMYL CYANIDE DECOMPOSITION

We compute the thermodynamic and the kinetic properties for the reaction: HCOCN→HCH+CO using the statistical theory and the transition-state theory.The equi- librium constants and the rate coefficients of this reaction are also reported here,and the half lives of formyl cyanide at different temperatures are first estimated in this work.

EFFECTS OF PREPARATOIN CONDITIONS ON THE KINETIC PROPERTIES OF COMPLEX-RESINS

The effects of the reaction temperature, the crosslinking degree of the matrix, the pore-forming agent and the initial concentration of PVA on the kinetic properties of the complex-resins were investigated. The ion-exchange rate of the complex-resin for L-lysine chlorate was three-fold that of 001×8 resin and two-fold that of D61 resin.

Enhancing (de)hydrogenation kinetics properties of the Mg/MgH_(2) system by adding ANi_(5)(A=Ce,Nd,Pr,Sm,and Y) alloys via ball milling

Magnesium(Mg)-based alloys have already been widely studied as the hydrogen storage materials because of their high reversible hydrogen storage capacity,low cost,light weight,etc.However,the poor de/hydrogenation kinetic properties dramatically hinder the practical applications.In this work,the MgH_(2)-ANi_(5)(A=Ce,Nd,Pr,Sm,and Y) composites were prepared by a high-energy ball milling method.which can effectively refine the particle size thus improving the kinetic properties.Experimental results reveal that the MgH_(2)-ANi_(5) composites mainly consist of Mg_(2)NiH_(4),MgH_(2) and rare earth(RE) hydride,which will be dehydrogenated to form Mg_(2)Ni,Mg and stable RE hydride reversibly.Accordingly,the asmilled MgH_(2)-ANi_(5)(A=Ce,Nd,Pr,Sm,and Y) composites with various A-elements can respectively contribute to a reversible hydrogen storage capacity of 6.16 wt%,5.7 wt%,6.21 wt%,6.38 wt%,and 6.5 wt%at a temperature of 300℃,and show much better kinetic properties in comparison to the pure MgH_(2) without any additive.In-situ formed Mg_(2) Ni and stable RE hydride(such as CeH_(2.73) and YH_(2)) might act as effective catalysts to significantly improve the hydrogen storage properties of MgH_(2).The present work provides a guideline on improving the kinetic properties of the Mg-based hydrogen storage alloys.

Spheroidizing Behavior and Spheroidizing Kinetics of W-phase During Solid-Solution Treatment in Mg–Zn–Y–Mn–(B)Alloys

The spheroidizing mechanism of W-phase in the Mg–Zn–Y–Mn–（B） alloys during solid-solution treatment was investigated by using kinetic methodologies. The microstructure and mechanical properties of heat-treated Mg_（94）Zn_（2.5）-Y_（2.5）Mn_1 alloy containing 0.003 wt% B were compared with heat-treated Mg_（94）Zn_（2.5）-Y_（2.5）Mn_1 alloy. The heat-treated Mg_（94）Zn_（2.5）-Y_（2.5）Mn_1 alloy with 0.003 wt% B contained fine and uniform W-phase particles, which exhibited optimal mechanical performance. The ultimate tensile strength, yield strength and elongation were 287.7, 125.5 MPa and 21.1%,respectively.

Synthesis and kinetics of non-isothermal degradation of acetylene terminated silazane

Novel acetylene terminated silazane compounds,with three types of substituent,were synthesized by the aminolysis of dichlorosilane with 3-aminophenylacetylene（3-APA）.Thermal property of the compounds is studied by thermogravimetry analysis （TGA）.It shows that the acetylene terminated silazane has high temperature resistance.The char yield at 1000℃is 77.6,81.9 and 68.7 wt%for methyl,vinyl,and phenyl substituted silazane,respectively.The pyrolysis kinetics of the silazane is investigated by non-isothermal thermogravimetric measurement.The pyrolysis undergoes three stages,which is resolved by PEAKFTT.The kinetic parameters are calculated by the Kissinger method.The role of functionalities on the thermal resistance is discussed.The vinyl-silazane exhibits higher thermal stability because of higher cross-linking density.

Study on electrochemical property of La_(0.75)Mg_(0.25)Ni_(2.85)Co_(0.45–x)(AlSn)_x (x=0.0,0.1,0.2,0.3) alloys

La_（0.75）Mg_（0.25）Ni_（2.85）Co_（0.45–x）（AlSn）_x（AlSn）_x（x=0.0,0.1,0.2,0.3） alloys were prepared by magnetic induction melting method, and the phase composition and electrochemical properties were investigated systematically. The alloys were mainly composed of LaNi5, La2Ni7 and LaNi3 phase, and the cell volume of LaNi5 increased with the Al and Sn contents. For the alloy corresponding to x=0.0, the Cmax and C150 were 348.9 and 185 mA h/g, respectively, then for the alloy electrode with x=0.2, even though the Cmax was only 309.0 mA h/g less than 348.9 mA h/g, the C150 of 231 mA h/g was much higher than 185 mA h/g. And the values of the limit current density, anodic peak current density and hydrogen diffusion coefficient of the La0.75Mg0.25Ni2.85Co0.35（AlS n）0.1（x=0.1） alloy were 1079.5, 1023.8 mA /g and 5.71×10–10 cm2/s, respectively. Which were the highest than that of any other electrodes. These results suggested that the kinetic property of the La_（0.75）Mg_（0.25）Ni_（2.85）Co_（0.45–x）（AlSn）_x（AlSn）_x（x=0.0, 0.1, 0.2, 0.3） electrodes could be improved effectively by adding moderate contents of Al and Sn.

Direct reuse of oxide scrap from retired lithium-ion batteries:advanced cathode materials for sodium-ion batteries

The direct reuse of retired lithium-ion batteries(LIBs)cathode materials is one of the optimum choices for"waste-to-wealth"by virtue of sustainable and high economic efficiency.Considering the harmfulness of retired LIBs and the serious shortage of lithium resources,in this work,the spent oxide cathode materials after simple treatment are directly applied to the sodium-ion batteries(SIBs)and exhibit promising application possibilities in advanced SIBs.The spent oxide cathode shows an appropriate initial discharge capacity of 109 mAh·g^(-1)and exhibits transition and activation processes at a current density of 25 mA·g^(-1).Further,it demonstrates decent cycle performance and comparatively good electrode kinetics performance(the apparent ion diffusion coefficient at steady state is about 1×10^(-12)cm^(2)·s^(-1)).The"waste-towealth"concept of this work provides an economical and sustainable strategy for directly reusing the retired LIBs and supplies a large amount of raw material for the largescale application of SIBs.

Thermal storage properties of Mg-LaNi using as a solar heat storage material

The effect of LaNi on thermal storage properties of MgH2 prepared by ball milling under hydrogen atmosphere was investigated.The thermal storage properties,cyclic property and thermal storage mechanism were studied by pres sure-composition-temperature(PC T),X-ray diffraction(XRD)and transmission electron microscopy(TEM).The Van't Hoff curve indicates that the formation enthalpy of Mg-16 wt%LaNi is 74.62 kJ·mol^(-1),which approaches to the theoretical values of MgH2.The isothermal measurement indicates that Mg-16 wt%LaNi can absorb 6.263 wt%H_(2)within 30 min at 390℃for the first absorption,the absorption reaction fraction within2 min is over 90.00%,and the desorption reaction fraction within 2 min is 72.63%,increasing by 55.36%compared with that of Mg.Mg-16 wt%LaNi has better cyclic stability than that of Mg,only decreasing by 0.609 wt%after 80cycles.The enhancement in thermal storage performances of Mg by adding LaNi is mainly ascribed to the formed Mg_(2)NiH_(4),H_(0.3)Mg_(2)Ni and La_(4)H_(12.19)during the cyclic process which act as catalysts and inhibit the growth of Mg.The above results prove that Mg-16 wt%LaNi is suitable for use as a heat storage material.

A study on turbulence transportation and modification of Spalart–Allmaras model for shock-wave/turbulent boundary layer interaction flow

It is of great significance to improve the accuracy of turbulence models in shock-wave/ boundary layer interaction flow. The relationship between the pressure gradient, as well as the shear layer, and the development of turbulent kinetic energy in impinging shock-wave/turbulent bound- ary layer interaction flow at Mach 2.25 is analyzed based on the data of direct numerical simulation （DNS）. It is found that the turbulent kinetic energy is amplified by strong shear in the separation zone and the adverse pressure gradient near the separation point. The pressure gradient was non-dimensionalised with local density, velocity, and viscosity. Spalart Allmaras （S A） model is modified by introducing the non-dimensional pressure gradient into the production term of the eddy viscosity transportation equation. Simulation results show that the production and dissipation of eddy viscosity are strongly enhanced by the modification of S-A model. Compared with DNS and experimental data, the wall pressure and the wall skin friction coefficient as well as the velocity profile of the modified S-A model are obviously improved. Thus it can be concluded that the mod- ification of S-A model with the pressure gradient can improve the predictive accuracy for simulat- ing the shock-wave/turbulent boundary laver interaction.

Structure and electrochemical characteristics of LaNi_5-Ti_(0.10)Zr_(0.16)V_(0.34)Cr_(0.10)Ni_(0.30) composite alloy electrode

Composite LaNi5+x wt.% Ti0.10Zr0.16V0.34Cr0.10Ni0.30 (x=0, 1, 5, 10) alloys were prepared by two-step re-melting. X-ray diffractometer (XRD), scanning electron microscopy (FESEM), energy dispersive spectrometry (EDS), inductively coupled plasma (ICP) and electrochemical impedance spectroscopy (EIS) analyses showed that the matrix phase of LaNi5 alloy with CaCu5 structure remained unchanged after additive alloy was added, the amount of the second phase increased with increasing x. The synergetic effect withi...

Effects of iron compounds on pyrolysis behavior of coals and metallurgical properties of resultant cokes

The utilization of highly reactive and high-strength coke can enhance the efficiency of blast furnace by promoting indirect reduction of iron oxides.Iron compounds,as the main constituent in iron-bearing minerals,have aroused wide interest in preparation of highly reactive iron coke.However,the effects of iron compounds on pyrolysis behavior of coal and metallurgical properties of resultant cokes are still unclear.Thus,three iron compounds,i.e.,Fe;O;,Fe;O;and FeC;O;·2H;O,were adopted to investigate their effects on coal pyrolysis behavior and metallurgical properties of the resultant cokes.The results show that iron compounds have slight effects on the thermal behavior of coal blend originated from thermogravimetric and differential thermogravimetric curves.The apparent activation energy varies with different iron compounds ranging from 94.85 to 110.11 kJ/mol in the primary pyrolysis process,while lower apparent activation energy is required for the secondary pyrolysis process.Iron compounds have an adverse influence on the mechanical properties and carbon structure of cokes.Strong correlations exist among coke reactivity,coke strength after reaction,and the content of metallic iron in cokes or the values of crystallite stacking height,which reflect the dependency of thermal property on metallic iron content and carbon structure of cokes.

Effect of substitution of Si by Al on the microstructure and mechanical properties of bainitic transformation-induced plasticity steels

The effect of partial or full substitution of Si by Al on the microstructure and mechanical properties has been extensively studied in multi-phase transformation-induced plasticity（TRIP） steels with polygonal ferrite matrix, but rarely studied in bainitic TRIP steels. The aim of the present study is to properly investigate the effect of Al and Si on bainite transformation, microstructure and mechanical properties in bainitic steels in order to provide guidelines for the alloying design as a function of process parameters for the 3 rd generation advanced high strength steels（AHSS）. It is shown from the dilatometry study,microstructural investigations and tensile properties measurements that the Al addition results in an acceleration whereas Si addition leads to a retardation in bainite transformation kinetics. The addition of Al retards the decomposition of austenite into pearlite and carbides at holding temperatures higher than450℃ whereas Si retards the decomposition of austenite into carbides at temperatures lower than 450℃.Consequently, the Al-added bainitic steel has a better strength-elongation combination at bainitic holding temperatures higher than 450℃ while Si-added steel has a better strength-elongation combination at temperatures lower than 450℃. The higher yield strength of Al-added steel is mainly attributed to its finer bainitic lath. The higher tensile strength of Si-added steel is not only related to the stronger contribution of Si on work hardening during deformation, but also due to the higher volume fraction of martensite or martensite/austenite（MA） blocks in all heat treatment conditions, as well as the lower mechanical stability of retained austenite in this steel.

Precipitation Behavior of Cu-1.9Be-0.3Ni-0.15Co Alloy During Aging

In this paper,the evolutions of microstructure and mechanical properties of Cu-l.9Be-0.3Ni-0.15Co alloy were studied.The alloys in the condition of the solution treated（soft state） and 37% cold rolled（hard state） were aged at 320 ℃for different time,respectively.The mechanical properties,electrical conductivity and microstructure of the alloy aged for different time were analyzed.Additionally,the precipitation kinetics of Cu-1.9Be-0.3Ni-0.15Co alloys was investigated.X-ray diffraction and transmission electron microscopy results reveal that both continuous precipitation and discontinuous precipitation existed in the hard-state Cu-l.9Be-0.3Ni-0.15Co alloy during the whole aging process;the sequence of continuous precipitation is G.P.zone →γ″→γ′→γ.Furthermore,the precipitation transformation mechanism of softstate alloy is homogeneous nucleation,while hard-state alloy shows the heterogeneous nucleation（interface nucleation）with the nucleation rate of both states decaying rapidly to zero during aging at 320 ℃.

Effect of LaFeO_3 on hydrogenation/dehydrogenation properties of MgH_2

LaFeO3 was used to improve the hydrogen storage properties of Mg H2. The Mg H2＋20 wt.%La Fe O3 composite was prepared by ball milling method. The composite could absorb 3.417 wt.% of hydrogen within 21 min at 423 K while Mg H2 only uptaked 0.977 wt.% hydrogen under the same conditions. The composite also released 3.894 wt.% of hydrogen at 623 K, which was almost twice more than Mg H2. The TPD measurement showed that the onset dissociation temperature of the composite was 570 K, 80 K lower than the Mg H2. Based on the Kissinger plot analysis of the composite, the activation energy E des was estimated to be 86.69 k J/mol, which was 36 k J/mol lower than Mg H2. The XRD and SEM results demonstrated that highly dispersed La Fe O3 could be presented in Mg H2, benefiting the reduction of particle size and also acting as an inhibitor to keep the particles from clustering during the ball-milled process.