The Factors for Transformation between the Fractions of Speciation of Trace Metals in Lake Sediments

Objective Despite the fact that the bioavailability of trace metals indicated by their speciation has been an indispensable parameter in the assessment and treatment of the environmental pollution of trace metals,many studies have suggested that the bioavailability of trace metals may change according to the conditions of the environment,

The Calculation Method for the Volume of Landslides and Dammed Lake Sediments Triggered by a Strong Historical Earthquake in the Loess Plateau:A Case Study of Qiuzigou, Gansu Province, Northwest China

The quantitative calculation of the volume of large earthquake-triggered landslides and related dammed lake sediments is of great significance in the study of secondary disasters and focal parameters of strong historical earthquakes.In this study,the dammed lake induced by Qishan M7 earthquake(Lingtai County,Gansu Province,Northwest China)is selected as the research object.Based on the information collected from the 4 boreholes in the dammed lake area,we further take advantage of the lowlevel Unmanned Aerial Vehicle(UAV)photogrammetry and the morphology recovery method,to calculate the volume of the dammed lake and landslides,respectively.Finally,major conclusions are obtained as follows:①the AMS-14C age at the bottom of the Qiuzigou Dammed Lake sediments is 2890±30 BP,which coincides with the 780 BC Qishan earthquake;furthermore,the Qiuzigou Landslides seem to have been triggered by the earthquake,forming an enclosed dammed lake deposition environment after the upstream sediments accumulate;②the Qiuzigou landslides are opposite-sliding landslides that have blocked the river valley;in detail,landslide volumes at the right and left banks are 235×104 m3 and 229×104 m3,respectively.The length of the dammed lake is 2.6 km,with a thickness of approximately 43 m near the landslides,and the total sedimentary volume is 573×104 m3;③the erosion rate of Qiuzigou Landslide Dammed Lake is 0.44 mm/a,the accumulation rate is 15.05 mm/a,and the soil erosion modulus is 593 t/(km2/a),characterized as slight erosion.Quantitative research on the formation of landslides and dammed lakes from strong historical earthquakes is vital for increasing our understanding of the vibrational characteristics and surface action processes of these types of earthquakes.

A concise overview on historical black carbon in ice cores and remote lake sediments in the northern hemisphere

Black Carbon(BC),as a driver of environmental change,could significantly impact the snow by accelerating melting and decreasing albedo.Systematic documentation of BC studies is crucial for a better understanding of its spatial and temporal trends.This study reviewed the BC studies in the ice core and remote lake sediments and their sources in the northern hemisphere.The literature surveyed points to around 2.9 to 3.7 times increase of BC in the European Alps and up to a three-fold increase of BC in the Himalayan-Tibetan Plateau(HTP)after the onset of industrialization in Europe and Asia,respectively.BC concentration from Greenland ice core showed seven times increase with an interrupted trend after 1950's.South Asian emissions were dominant in the HTP along with a contribution from the Middle East,whereas Western European and local emissions were responsible for the change in BC concentration in the European Alps.In the Arctic,contributions from North America,Europe and Asia persisted.Similarly,a historical reconstruction of lake sediments records demonstrates the effects of emissions from long-range transport,sediment focusing,local anthropogenic activities,precipitation and total input of flux on the BC concentration.

The environmental signal of an early Holocene pollen record from the Shiyang River basin lake sediments, NW China

Pollen analyses of 85 samples from the San-jiaocheng section well along the margin of a palaeolake at the end of the Shiyang River, NW China, show that Picea and Sabina dominate the pollen assemblage. Together they reach as high as 40%-60%, with the percentage of Picea varying inversely with that of Sabina. Similar results were obtained from another section in the Shiyang River drainage. Using modern ecological habitat relationship analogues, pol-len transport characteristics, and the overall pollen assem-blage, we propose that both Picea and Sabina pollen were transported by the river from the mountains at the upper reaches of the Shiyang River, and that the assemblage is more indicative of changes in upland vegetation than of local conditions near the section. This interpretation is supported by pollen data derived from surface samples, water samples, and riverbed samples. Using a moisture indicator (the Picea to Sabina ratio) and calculated pollen concentrations, we identify a series of

Effects of environmental factors on the production and release of matrix-bound phosphine from lake sediments

Effects of pH,temperature,and oxygen on the production and release of phosphine in eutrophic lake sedi-ments were investigated under laboratory tests.Results indi-cated that the elimination of matrix-bound phosphine was accelerated under initial pH 1 or 12.Phosphine levels could reach maximum under initial pH 10.The contents of phos-phine increased with the addition of alkali under pH 4-12.The rates of phosphine production and release from lake sed-iments varied with temperature.20°C was the most favorable temperature for the production of matrix-bound phosphine.Oxygen showed little effect on matrix-bound phosphine.Matrix-bound phosphine concentrations in lake sediments were concluded to be dependent on a balance of natural generation and depletion processes.

Modern pollen assemblages of the surface lake sediments from the steppe and desert zones of the Tibetan Plateau

Modern pollen analysis is the basis for revealing the palaeovegetation and palaeoclimate changes from fossil pollen spectra.Many studies pertaining to the modern pollen assemblages on the Tibetan Plateau have been conducted,but little attention has been paid to pollen assemblages of surface lake sediments.In this study,modern pollen assemblages of surface lake sediments from 34 lakes in the steppe and desert zones of the Tibetan Plateau are investigated and results indicate that the two vegetation zones are dominated by non-arboreal pollen taxa and show distinctive characteristics.The pollen assemblages from the desert zone contain substantially high relative abundance of Chenopodiaceae while those from the steppe zone are dominated by Cyperaceae.Pollen ratios show great potential in terms of separating different vegetation zones and to indicate climate changes on the Tibetan Plateau.The Artemisia/Chenopodiaceae ratio and arboreal/non-arboreal pollen ratio could be used as proxies for winter precipitation.Artemisia/Cyperaceae ratio and the sum of relative abundance of xerophilous elements increase with enhanced warming and aridity.When considering the vegetation coverage around the lakes,hierarchical cluster analysis suggests that the studied sites can be divided into four clusters:meadow,steppe,desert-steppe,and desert.The pollen-based vegetation classification models are established using a random forest algorithm.The random forest model can effectively separate the modern pollen assemblages of the steppe zone from those of the desert zone on the Tibetan Plateau.The model for distinguishing the four vegetation clusters shows a weaker but still valid classifying power.It is expected that the random forest model can provide a powerful tool to reconstruct the palaeovegetation succession on the Tibetan Plateau when more pollen data from surface lake sediments are included.

Composition and Evolution of Hydrogen Isotopes of n-Akanes Generated from Anhydrous Pyrolysis of Sediments from Lake Gahai,Gannan,China

To understand the thermal evolution of lacustrine sedimentary n-alkane hydrogen isotopic composition(δD),especially bacterially derived n-alkanes,anhydrous thermal simulation experiments were performed with sediments from Lake Gahai(Gannan,China).We analyzed the original and pyrolysis-generated n-alkanes and theirδD values.The results showed that thermal maturity and n-alkane origins significantly affected the distribution of pyrolysis-generated n-alkanes.In immature to post-mature sediments,the bacterial-derived medium-chain n-alkanes generally had depletedδD values.The maximum difference in averageδD values between the bacterial-and herbaceous plant-derived medium-chain n-alkanes was 32‰,and the maximum difference in δD values among individual n-alkanes was 59‰.We found that the averageδD value of pyrolysis-generated n-alkanes from different latitude was significantly different in immature to highly mature sediments,but similar in post-mature ssediments.The hydrogen isotopes of sedimentary n-alkanes can be used as indicators for paleoclimate/paleo-environment conditions only when sediments are immature to highly mature.During thermal evolution,the δD value of generated individual n-alkanes and the averageδD value increased with thermal maturity,indicating that hydrogen isotopes of sedimentary n-alkanes can be used as an index of organic matter maturity.We established mathematical models of average δD values of generated n-alkanes from immature to post-mature sediments using n C_(21)^(-)/nC_(21)^(+)and average chain lengths.These results improve our understanding of the distribution andδD value of sedimentary n-alkanes derived from herbaceous plants in mid-latitude plateau cold regions.

Variations in rare earth elements with environmental factors in lake surface sediments from 17 lakes in western China

Numerous lakes in western China are excellent sites for understanding environmental change.However,what dominates rare earth element(REE) variations are still under debate in the lake environmental research.In this study,we selected 28 surface sediment samples from 17 lakes(i.e.largescale lakes,small water bodies,etc.) in the QinghaiTibet Plateau and Xinjiang area.These samples were analyzed to reveal the behavior of the REEs and major elements.These REE patterns are characterized by light rare earth element(LREE) enrichment,weak Ce anomaly(0.84-0.98,0.94 on average) and negative Eu anomaly(0.53-1.00,0.67 on average).The homogeneous REE patterns may reflect similar REE of the source lithologys.However,the REE abundances showed some significant differences.In this study,water chemistry data analyses inferred that the highly REE values appear possibly in the saltwater lake,and also related to carbonate mineral,whereas p H played a minor role in REE concentrations.In large-scale lakes(e.g.Lake Bosten and Lake Ulungur),the results showed that the relatively larger REE values are in the margins of lakes.Moreover,lower REE contents are towards the central region.Comprehensive study suggested that five major factors control the REE contents:(1) The REE tends to increase with the increase of the weathering intensity.(2) Likewise,heavy mineral(i.e.rutile,anatase,zircon,etc.) are probably primary in these sediments because they are highly enriched in the REE.(3) The contribution of Fe-Mn oxides is significant in sediments because their concentrations highly correlate with the REE.(4) The carbonate mineral(mainly calcite) played a significant role on the REE values in the lakes because the REEs are incorporated into the carbonate minerals generating the low REE concentrations.(5) Major element analysis,mineral analysis,and grain-size data analysis showed that the REE distribution is chiefly influenced by finer grain-size component of lake sediments due to the decreasing proportion of quartz and feldspar than coarser one.Moreover,the clay minerals in finer grain-size sediments can highly absorb the REE.

Influences of environmental factors on the modern 14C reservoir effects in Qinghai-Tibet Plateau lakes

The establishment of reliable age in the lake sediment profile mainly depends on the AMS 14C dating technique.However,the presence of the 14C lake reservoir effects(LREs)restricted for using radiocarbon dating in lake sediment,especially in dry and cold areas with a scarce plant cover in the Qinghai-Tibet Plateau.Hence,the discussion of influence factors of LREs is crucial.This paper selected 15 lakes(17 sediment and 3 plant samples)in the Qinghai-Tibet Plateau to examine the distribution characteristics of the modern LREs and their main influencing factors.In our study area,14 lakes were all affected by the LREs.The minimum 14C year is 5900 a BP towards the deep water area,whereas the maximum 14C year is up to 7185 a BP in the margins of Lake Heihai.The maximum 14C year is up to 7750 a BP,and the minimum 14C year is present-day carbon in the 15 lakes.One further study indicated that the LRE differences in individual lake are mostly owing to the contribution of exogenous carbonate.The results displayed that the LREs tended to increase with the increase of the salinity,moreover,the LREs of saltwater lakes or salt lakes were significantly larger than freshwater lakes due to the possible supply of old total dissolved inorganic carbon with a long residence time in the lakes.Moreover,the contribution of calcite played a significant role on the LREs.Additionally,the LREs differences are affected by the source of organic matter.The lake with groundwater supply shows large LRE due to likely being influenced by crustal and ancient CO_(2) uprising.

Late Holocene brGDGTs-based quantitative paleotemperature reconstruction from lacustrine sediments on the western Tibetan Plateau

We present a quantitative mean annual air temperature(MAAT)record spanning the past 4700 years based on the analysis of branched glycerol dialkyl glycerol tetraethers(brGDGTs)from a sediment core from Xiada Co,an alpine lake on the western Tibetan Plateau(TP).The record indicates a relatively stable and warm MAAT until 2200 cal yr BP;subsequently,the MAAT decreased by~4.4℃ at~2100 cal yr BP and maintained a cooling trend until the present day,with centennial-scale oscillations centered at~800 cal yr BP,~600 cal yr BP,and~190-170 cal yr BP.MAAT decreased abruptly at~500-300 cal yr BP and reached its minimum for the past 4700 years.We assessed the representativeness of our record by comparing it with 15 published paleotemperature records from the TP spanning the past~5000 years.The results show divergent temperature variations,including a gradual cooling trend,a warming trend,and no clear trend.We suggest that these discrepancies could be caused by factors such as the seasonality of the temperature proxies,the length of the freezing season of the lakes,the choice of proxy-temperature calibrations,and chronological errors.Our results highlight the need for more high-quality paleotemperature reconstructions with unambiguous climatic significance,clear seasonality,site-specific calibration,and robust dating,to better understand the processes,trends,and mechanisms of Holocene temperature changes on the TP.

Grain-size Age Model in Reconstructing Orbital-and Suborbital-scale Climate Changes on the Northeastern Tibetan Plateau Since the Late Glacial

Reconstructions of past climatic changes on the northeastern Tibetan Plateau(NETP) can provide insights into the Asian summer monsoon(ASM) variability. However, the regional climate changes on both orbital and suborbital time scales since the late Glacial remain controversial. Here we present the results of high-resolution geochemical and grain-size analyses of a sediment core from Genggahai Lake, a small, shallow lake in this area. Changes of the accumulation rate of the core sediments show a similar trend with variations of the coarse fraction. Accordingly, the chronological framework is constructed using a grain-size age model. In addition, the histories of chemical weathering and aeolian activity since the late Glacial are reconstructed based on the Al/Ti ratios and coarse fractions, respectively. The results suggest that an enhanced chemical weathering and a weakened aeolian activity occurred on the NETP under a warmer, wetter climate during the early to mid-Holocene(11.3–6.3 ka cal BP), compared with the late Glacial(17.1–11.3 ka cal BP) and the late Holocene(6.3 ka cal BP to present), which responded mainly to the strengthened ASM on orbital time scale. In addition, the synchronous occurrences of weakened chemical weathering, low lake level and intense aeolian activity on suborbital time scale reflect several episodes of weakened ASM. Furthermore, these episodes largely coincide with the centennial-to millennial-scale cold events in the North Atlantic, which demonstrates the close connection between the ASM and the cooling at high latitudes.

贝加尔湖沉积物记录的第四纪大陆气候对轨道驱动的响应（英文）

The long sediment core BDP98 obtained from Lake Baikal was analyzed in order to discuss the periodicity of glacial cycles in the terrestrial climatic record of the past 2.6 Ma.Spectral analysis shows that the Baikal grain size record has been dominated by orbit-related cycles with periods of about100 ka,41 ka,and 23 ka,similar to those in the marine isotope record.However,there are some notable differences between the Baikal and oceanic records.In the marine isotope record,the 41 ka cycle was dominant before 1 Ma and the 100 ka cycle became significant only afterward.Conversely,in the Baikal record,the 100 ka period has appeared continuously throughout the past 2.6 Ma,and no appreciable shift in period is detected.These results suggest that the terrestrial climatic response to orbital forcing,as imprinted in the Baikal sediment,is different from the oceanic response.The 100 ka cycle detected in the Baikal record from before 1 Ma may be attributable to relatively long interglacials with skipping of two or three 41 ka obliquity cycles.This result may support the hypothesis that the 100 ka cycle is paced by the obliquity cycle.

Historical record of effects of human activities on absolute and relative concentrations of Polycyclic aromatic hydrocarbons(PAHs) in Lake Chao,China

Polycyclic aromatic hydrocarbons(PAHs)are attracting concern because of their potential toxicity,posing serious threats to health of humans and ecosystems(Kim et al.,2013;Zhao et al.,2016).Generally,similar to other contaminants’behaviors(Wu et al.,2001;Zhang et al.,2007,2008;Lu et al.,2009),PAHs result from natural organic matter and activities of humans,the latter’s contribution usually outweighing the inputs from other sources(Fernández et al.,2000;Srogi,2007).

Distribution of aromatic amines,phenols,chlorobenzenes,and naphthalenes in the surface sediment of the Dianchi Lake,China

Organic pollutants are widespread environmental pollutants with high toxicity,persistence,and bioaccumulation.Our aim was to investigate the distribution of aromatic amines,phenols,chlorobenzenes,and naphthalenes in the surface sediment of the Dianchi Lake,China.Nineteen surface sediment samples were collected from the Dianchi Lake,and 40 types of organic pollutants were analyzed via gas chromatography-mass spectrometry.The total organic pollutant concentrations in the surface sediment of the Dianchi Lake varied from 27.4 to 1.62×10^3 ng/g.The concentrations of phenols were much higher than those in other water bodies but still within a controllable range,whereas the concentrations of the other organic pollutant classes were similar or even lower.The detection ratio of 3-or 4-methylphenol was the highest(100.00%)among the pollutants.The average total organic pollutant concentrations decreased in the following order:Caohai(540 ng/g)>the middle of Waihai(488 ng/g)>the edge of Waihai(351 ng/g)>Haigeng Dam(90.4 ng/g).Pearson analysis showed a strong correlation among 1-methylnaphthalene,2-methylnaphthalene,1,3-dinitronaphthalene,and 1,4-dinitronaphthalene(P<0.01).Caohai,the north lakeshore of Waihai and the south of Waihai showed higher risk because of high concentration;meanwhile,1,4-dichlorobenzene,3-or 4-methylphenol and 1,2,4-trichlorobenzene were mor e likely to cause risks.

A re-evaluation of the average chain length of lacustrine sedimentary n-alkanes as a paleoproxy on the Qinghai-Tibet Plateau

Long-chain n-alkanes are one of the most common organic compounds in terrestrial plants and they are well-preserved in various geological archives.n-alkanes are relatively resistant to degradation and thus they can provide high-fidelity records of past vegetation and climate changes.Nevertheless,previous studies have shown that the interpretation of n-alkane proxies,such as the average chain length(ACL),is often ambiguous since this proxy depends on more than one variable.Both vegetation and climate could exert controls on the n-alkane ACL,and hence its interpretation requires careful consideration,especially in regions like the Qinghai-Tibet Plateau(QTP)where topography,biome type and moisture source are highly variable.To further evaluate the influences of vegetation and climate on the ACL in high-elevation lakes,we examined the n-alkane distributions of the surface sediments of 55 lakes across the QTP.Our results show that the ACL across a climatic gradient is significantly affected by precipitation,rather than by temperature.The positive correlation between ACL and precipitation may be because of the effect of microbial degradation during deposition.Finally,we suggest that more caution is needed in the interpretation of ACL data in different regions.

Middle-late Holocene environment change induced by climate and human based on multi-proxy records from the middle and lower reaches of Yangtze River,eastern China

Our knowledge about the interaction between human activities and the environment in the middle-late Holocene remains incomplete.Core C1 in Lake Chaohu from the middle and lower reaches of Yangtze River (MLYR),eastern China,provides an opportunity to investigate vegetation and climate changes,human activities,and East Asian summer monsoon(EASM) evolution since 5100 cal.yr BP.These variables are assessed based on radiocarbon dating,pollen and charcoal records,and magnetic susceptibility (χ_(lf)),median grain size and TP.Results reveal a hiatus in sedimentation between 2080 and 730 cal.yr BP in the western part of Lake Chaohu,which is common in most lakes in the MLYR.Evergreen and deciduous broadleaved mixed forest retreated gradually after 3650 cal.yr BP,and was replaced by secondary Pinus forest after at least 730 cal.yr BP.Intense agricultural activities and vegetation clearance are first detected at 2520 cal.yr BP.Human settlements expanded from the lake front wetlands (during the period 2520–2080 cal.yr BP) to remote high-altitude areas(2080–400 cal.yr BP),and then returned to the lake front to reclaim the wetlands and lake (after 400 cal.yr BP).A gradual trend of recessional EASM strength from 4300 cal.yr BP and centennial-scale variations of EASM during the period5100–3650 cal.yr BP are revealed.The reduction of summer insolation,southward shift of the ITCZ,and El Ni?o Southern Oscillation may control the intensity of EASM and climate on a large regional scale.

Complementarity of lacustrine pollen and sedimentary DNA in representing vegetation on the central-eastern Tibetan Plateau

Plant environmental DNA extracted from lacustrine sediments(sedimentary DNA,sedDNA)has been increasingly used to investigate past vegetation changes and human impacts at a high taxonomic resolution.However,the representation of vegetation communities surrounding the lake is still unclear.In this study,we compared plant sedDNA metabarcoding and pollen assemblages from 27 lake surface-sediment samples collected from alpine meadow on the central-eastern Tibetan Plateau to investigate the representation of sedDNA data.In general,the identified components of sedDNA are consistent with the counted pollen taxa and local plant communities.Relative to pollen identification,sedDNA data have higher taxonomic resolution,thus providing a potential approach for reconstructing past plant diversity.The sedDNA signal is strongly influenced by local plants while rarely affected by exogenous plants.Because of the overrepresentation of local plants and PCR bias,the abundance of sedDNA sequence types is very variable among sites,and should be treated with caution when investigating past vegetation cover and climate based on sedDNA data.Our finding suggests that sedDNA analysis can be a complementary approach for investigating the presence/absence of past plants and history of human land-use with higher taxonomic resolution.

Indication of paleoecological evidence on the evolution of alpine vegetation productivity and soil erosion in central China since the mid-Holocene

Although alpine ecosystems have been commonly recognized as sensitive to recent climate change,few studies have examined its impact on the long-term productivity of vegetation and soil erosion.Using paleoecological records,these two aspects were examined in the alpine zone of the Taibai Mountains(elevation,3767 m)in monsoon-dominated East Asia since the middle Holocene.Proxies for the productivity of vegetation and severity of soil erosion from high-resolution alpine lacustrine records show that the productivity and soil erosion were closely related to mean annual temperature and summer precipitation from the East Asian Summer Monsoon(EASM),respectively.Specifically,when the mean annual temperature was low and precipitation was abundant,during 5800–4000 calendar years before the present(cal.yr BP),the alpine ecosystem was characterized by low vegetation productivity and severe soil erosion.However,the productivity increased and soil erosion decreased from 4000 cal.yr BP onwards.These results highlight the role of paleoecological evidence in studying ecosystem services on longer time scales,which is significant in making policies for sustainable development under climate change in regions for which such long-term monitoring data are not available.

Variations in monsoon precipitation over southwest China during the last 1500 years and possible driving forces

Understanding hydroclimatic patterns and their possible driving mechanisms during distinct climate periods over the last 1500 years—such as the Medieval Warm Period(MWP),the Little Ice Age(LIA),and the Current Warm Period—is crucial for predicting future changes to monsoon precipitation in southwest China under global warming scenarios.In this study,based on ^(210)Pb and ^(137)Cs dating of surface sediments and AMS ^(14)C dating of terrestrial plant residues,we establish a robust age model that covers the last~1500 years(AD 439–2012)at Lake Yihai in southwest China.We use analyses of multiple geochemical proxy indices,including loss on ignition at 550℃,total organic carbon,total nitrogen,C/N ratios,and stable carbon isotopes of organic matter to reconstruct changes in summer monsoon precipitation at Lake Yihai during the last~1500 years.The results show that,over southwest China,warm and dry climate conditions prevailed during the MWP(AD 1000–1400)and the past 200 years,whereas conditions during the LIA(AD 1400–1800)were cold and wet.This is consistent with evidence from other geological records over southwest China,such as stalagmite and lake sediment data.Similar hydroclimatic patterns have occurred over the last 1500 years in adjacent tropical/subtropical monsoon regions where the climate is similarly dominated by the Indian summer monsoon(e.g.,South China,the South China Sea,Southeast Asia,Northeast India).We suggest that the meridional migration of the mean position of the Inter-tropical Convergence Zone,and El Niño/Southern Oscillation conditions which are linked to tropical Pacific sea surface temperature,are responsible for centennial-scale hydroclimatic patterns over southwest China and adjacent areas during the last 1500 years.

Paleoclimatic indication of X-ray fluorescence core-scanned Rb/Sr ratios: A case study in the Zoige Basin in the eastern Tibetan Plateau

The X-ray fluorescence(XRF)core-scanned Rb/Sr ratios of lake sediments have been widely used as a proxy for chemical weathering intensity and past climate change.However,some factors could affect Rb/Sr ratios,causing misinterpretation and limiting its application.In this study,we present a high-resolution XRF core-scanned Rb/Sr record of core ZB13-C1 from the Zoige Basin in the eastern Tibetan Plateau.To validate its application,we correlated this record with the chemical index of alteration(CIA)and other paleoclimatic proxies.Our results showed that(1)the core-scanned Rb/Sr ratios and CIA were reliable proxies of chemical weathering intensity in fine-grained sedimentary sequences;(2)the low values of corescanned Rb/Sr ratios and CIA were significantly correlated with high total organic carbon content,arboreal pollen content,carbonate content,and C/N ratios,confirming its reliability as a proxy for the Asian summer monsoon intensity;(3)the corescanned Rb/Sr ratios at core depths of 25–0.3 and 56–47 m were unable to reliably reflect chemical weathering intensity due to both the grain-size effect and the low test accuracy.Our study highlights the need for mutual verification of multiple indicators before accurately applying Rb/Sr as a paleoclimatic proxy in other similar study areas.