In this paper the authors classify saline lake sediments into the cold, warm and eurythermal phases, reveal the consistency between the zoning of hydrochemical types of modern saline lake water and climatic zoning and...In this paper the authors classify saline lake sediments into the cold, warm and eurythermal phases, reveal the consistency between the zoning of hydrochemical types of modern saline lake water and climatic zoning and give climatic parameters under the conditions of typical cold phase (mirabilite and natron), warm phase (thenar-dite) and slightly warm phase (bloedite) saline lake deposition.展开更多
Since the ban on the use of organochlorine pesticides (OCPs) such as dichloro-diphenyl-trichloroethane (DDT) and hexachlorocyclohexane(HCH) in agriculture, their levels have generally dropped. In a number of cas...Since the ban on the use of organochlorine pesticides (OCPs) such as dichloro-diphenyl-trichloroethane (DDT) and hexachlorocyclohexane(HCH) in agriculture, their levels have generally dropped. In a number of cases, however, the levels of these OCPs were found to be unchanging or even increasing after the ban. With the aim to unveil the possible causes of these exceptions, we collected two lake cores from King George Island, West Antarctica, and determined their accumulation flux profiles and temporal trends of these OCPs. In the lake core sediments with glacier meltwater input, the accumulation flux of DDT shows an abnormal peak around 1980s in addition to the expected one in 1960s. In the lake core sediments without glacier meltwater input, the accumulation flux of DDT shows a gradual decline trend after the peak in 1960s. This striking difference in the DDT flux profiles between the two lake cores is most likely caused by the regional climate warming and the resulted discharge of the DDT stored in the Antarctic ice cap into the lakes in the Antarctic glacier frontier. Furthermore, to investigate the change of OCPs loadings in the Antarctic coastal ecosystem, we reconstructed the HCH and DDT concentration profiles in penguin droppings and observed a gradual increase for the former and a continuous decrease for the latter during the past 50 years. The increase of HCH seems to be due to the regional warming from the early 1970s and the resulted HCH discharge to the coastal ecosystem by glaciers' meltwater and the illegal use of HCH in the Southern Hemisphere in the recent decade. The different temporal trends of HCH and DDT accumulation rate in the lake core with glacier meltwater input and the aged penguin droppings can be explained by their different water-soluble property.展开更多
Based on analysis of parameters of cores taken from Gaoyou Lake, including magnetic susceptibility, grain-size characteristics and sedimentary rate, environmental changes during the modern period were examined with th...Based on analysis of parameters of cores taken from Gaoyou Lake, including magnetic susceptibility, grain-size characteristics and sedimentary rate, environmental changes during the modern period were examined with the assistance of historical records and Gaoyou Lake water level materials. It is concluded that during the modern period a higher value of magnetic susceptibility and a lower sediment grain size coincided with a wet climate, while a lower value of magnetic susceptibility and a higher grain size were related with a dry climate. The results indicate that the climate in the 123 years period from 1880 to 2003AD can be divided into four stages: two low water level stages (1880-1915AD, 1948-1981AD) and two high water level stages (1915-1948AD, 1981-2003AD). It appears that the regional climate generally underwent a dry-wet-dry-wet pattern in 30-year cycles. At present, it is at the end of a wet period, so the regional climate is expected to become dry in the near future. This conclusion corresponds with the climate records in the historical literature of the Gaoyou area, and it also matches with the climatic changes in North Jiangsu area.展开更多
According to palaeoclimatic and modern instrumental data,numerous studies have indicated that the Arctic climate has undergone a significant warming during the past 100 years,and this may lead to significant impact on...According to palaeoclimatic and modern instrumental data,numerous studies have indicated that the Arctic climate has undergone a significant warming during the past 100 years,and this may lead to significant impact on the fragile lake ecosystem.In this study,we collected a lake sediment core from the Nylesund of Svalbard and determined the concentrations of four pigments including chlorophyll derivatives,total carotenoids,oscillaxanthin and myxoxanthophyll in the sediments.Combined with other physical and chemical proxies such as calcium carbonate,total organic carbon,biogenic silicon etc.,we have reconstructed the historical changes of lacustrine primary productivity in Ny-lesund,especially for the past 100 years.The results showed that during the period of Little Ice Age(LIA),the climate was unfavorable for the growth of the lake algae,and thus the lacustrine productivity declined.This result was supported by the relatively low contents of pigment and biogenic silica in the sediments.In contrast,the contents of total organic carbon(TOC) and sediment pigments increased significantly in the upper 5 cm(-1890AD),reflecting the rapid growth of the lake algae,thus the great increase of lacustrine primary productivity,corresponding to the warming climate after LIA.However,the biogenic silica in the upper sediments still had a relatively low level,and this might be related to the growth competition with other algae species.Over the past 100 years,the ratio of Osc/Myx in the sediments decreased continuously,indicative of durative increase of myxoxanthophyll in blue-green algal pigments,and this might imply that the human activity had enhanced the nutrition level of the lake in the Arctic region.展开更多
The Huguangyan Maar Lake(HML)(21°9'N,110°17'E),situated on the Leizhou Peninsula in the southernmost of China's Mainland,is the deepest recent crater lake among the identified volcanic structures i...The Huguangyan Maar Lake(HML)(21°9'N,110°17'E),situated on the Leizhou Peninsula in the southernmost of China's Mainland,is the deepest recent crater lake among the identified volcanic structures in the Leiqiong Volcanic Field.The bi-lobate lake.展开更多
Objective Despite the fact that the bioavailability of trace metals indicated by their speciation has been an indispensable parameter in the assessment and treatment of the environmental pollution of trace metals, ma...Objective Despite the fact that the bioavailability of trace metals indicated by their speciation has been an indispensable parameter in the assessment and treatment of the environmental pollution of trace metals, many studies have suggested that the bioavailability of trace metals may change according to the conditions of the environment, and the speciation of trace metals can also transform between some fractions. These transformations are related with these factors such as the compositions, microorganism, time, and other physical-chemical conditions of the system. Our work aims to systematically investigate and probe the factors to affect the transformation aside from analysis at certain time-place. The results of these understanding and investigations can be used for reasonably determining the allocation of financial and technical resources in natural and engineered processes, with bringing about inspirations from the evolution of the speciation of the trace metals on environmental impacts.展开更多
The quantitative calculation of the volume of large earthquake-triggered landslides and related dammed lake sediments is of great significance in the study of secondary disasters and focal parameters of strong histori...The quantitative calculation of the volume of large earthquake-triggered landslides and related dammed lake sediments is of great significance in the study of secondary disasters and focal parameters of strong historical earthquakes.In this study,the dammed lake induced by Qishan M7 earthquake(Lingtai County,Gansu Province,Northwest China)is selected as the research object.Based on the information collected from the 4 boreholes in the dammed lake area,we further take advantage of the lowlevel Unmanned Aerial Vehicle(UAV)photogrammetry and the morphology recovery method,to calculate the volume of the dammed lake and landslides,respectively.Finally,major conclusions are obtained as follows:①the AMS-14C age at the bottom of the Qiuzigou Dammed Lake sediments is 2890±30 BP,which coincides with the 780 BC Qishan earthquake;furthermore,the Qiuzigou Landslides seem to have been triggered by the earthquake,forming an enclosed dammed lake deposition environment after the upstream sediments accumulate;②the Qiuzigou landslides are opposite-sliding landslides that have blocked the river valley;in detail,landslide volumes at the right and left banks are 235×104 m3 and 229×104 m3,respectively.The length of the dammed lake is 2.6 km,with a thickness of approximately 43 m near the landslides,and the total sedimentary volume is 573×104 m3;③the erosion rate of Qiuzigou Landslide Dammed Lake is 0.44 mm/a,the accumulation rate is 15.05 mm/a,and the soil erosion modulus is 593 t/(km2/a),characterized as slight erosion.Quantitative research on the formation of landslides and dammed lakes from strong historical earthquakes is vital for increasing our understanding of the vibrational characteristics and surface action processes of these types of earthquakes.展开更多
A 107cm piston-core (SHC-2) was drilled at the site with water depth of 5m in South Hongshan Lake, northwest Tibet in 1998. Based upon the 0.72cm/a of modern sedimentary rate that was tested by 210Pb method and also c...A 107cm piston-core (SHC-2) was drilled at the site with water depth of 5m in South Hongshan Lake, northwest Tibet in 1998. Based upon the 0.72cm/a of modern sedimentary rate that was tested by 210Pb method and also calibrated by 137Cs method as well as the 1cm interval sample cutting level, a lake sedimentary record of 150-yr old and with a resolution of 1.4 yrs was obtained. Ratio of geochemistry contents (TOC, TN, CaCO3) and concentrations of trace elements such as B, Sr, Ba, Ca, Mg, K, Na, Al, Ti, Cu, Zn, Fe, Mn, Ni, Cr, V, Pb, etc were analyzed. The values of TOC, TN, C/N, CaCO3, Sr/Ba and Fe/Mn had clear environmental significance and well reflected the environmental changes. Geochemical multi-proxies of lacustrine sediments from SHC-2 core showed that the environmental changes in this area during the past 150 years could be reconstructed as follows: Stage 1 (1850s-1880s) was a cold period; Stage 2 (1880s-1920s) was a warm period. But the variation of lake water volume was stable in the two periods. Stage 3 (1920s-1950s) was a fluctuant and transitional period in temperature, but there were a short cold period in the 1920s and a warm period in the 1930s. Stage 4 (1950s-) showed a warming tendency, though there existed a cold period from the mid 1970s to the end of the 1980s. In the view of general trend in the past 150 years, South Hongshan Lake was shrinking gradually. It showed that, from the comparison with the Guliya ice core and meteorological records of adjacent weather stations, there is difference in the variations of temperature and precipitation among different regions and altitudes in Tibetan Plateau. It is necessary to search multi-scale and high-resolution records for environmental reconstruction and comparison.展开更多
Thirteen sediment core samples(0-10 cm) were taken from the seven lakes in the middle and lower reaches of the Yangtze River to determine the contents and distributions of organic phosphorus(P) fractions in the sedime...Thirteen sediment core samples(0-10 cm) were taken from the seven lakes in the middle and lower reaches of the Yangtze River to determine the contents and distributions of organic phosphorus(P) fractions in the sediments of the shallow lakes in the area.The organic P fractions in the sediments were in the order of moderately labile organic P(MLOP) > moderately resistant organic P(MROP) > highly resistant organic P(HROP) > labile organic P(LOP),with average proportional ratios of 13.2:2.8:1.3:1.0.LOP,MLOP,and MROP were significantly related to the contents of total organic carbon(TOC),water-soluble P(WSP),algal-available P(AAP),NaHCO3-extractable P(Olsen-P),total P(TP),organic P(OP),and inorganic P(IP).However,HROP was significantly related to OP and weakly correlated with TOC,WSP,AAP,Olsen-P,TP or IP.This suggested that organic P,especially LOP and MLOP in sediments,deserved even greater attention than IP in regards to lake eutrophication.In terms of organic P,sediments were more hazardous than soils in lake eutrophication.Although OP concentrations were higher in moderately polluted sediment than those in heavily polluted sediment,LOP and MLOP were higher in the heavily polluted sediment,which indicated that heavily polluted sediment was more hazardous than moderately polluted sediment in lake eutrophication.展开更多
Based on the analyses of environmental proxy data in lake sediments and instrumental records of Xinjiang in northwest China, the Holocene climate and hydrological variability and its environmental responses were studi...Based on the analyses of environmental proxy data in lake sediments and instrumental records of Xinjiang in northwest China, the Holocene climate and hydrological variability and its environmental responses were studied in different time scales and regions. The results showed that the Holocene climate variability had obvious differences between the north and south of Xinjiang. In northern Xinjiang, the Holocene climate was dry in the early period, humid in the middle period, and then changed to dry in the late period. However, the climate transition times were not consistent in different regions. In southern Xin- jiang, although there were many different types of climate change patterns inferred from different catch- ments, the warm and wet climate was recorded in most lake sediments in the middle Holocene. According to comparisons of some millennium scale records in lake sediments, the climate was warm and dry in the past 100 years. It can be concluded the climate showed a trend of aridity in Holocene. Especially in recent 50 years, the lake area has been shrinking rapidly because of the population growth and social economic development, which brings some environmental problems. Lake level and area changes were sensitively affected by the climate variation in geological history of Xinjiang and the lake level will continue to shrink because of the drought climate and strengthened human activities.展开更多
Radionuclide dating techniques characterized by137Cs and210Pbex have recently been applied in the study of lake sediments around the world.In this study,a chronological series of sediment cores was established based o...Radionuclide dating techniques characterized by137Cs and210Pbex have recently been applied in the study of lake sediments around the world.In this study,a chronological series of sediment cores was established based on137Cs and210Pbex analyses along with the evaluation of sediment properties,such as particle size distribution,total organic carbon(TOC),carbonate content,and acid-insoluble residue,to study sediment accumulation rates,sediment sources,and responses to human activities in the Jiuzhaigou National Nature Reserve in southwestern China.In terms of the particle size distribution of sediments,silt content was the highest,and clay and sand contents were relatively low.The sediments displayed high TOC contents because of the significant amounts of vegetation grown in the lakes.The carbonate content was also high due to the overall geological background of carbonates in Jiuzhaigou.Carbonate content tended to decline from top to bottom in the sediment cores,whereas the acid-insoluble residue tended to increase.These results suggested that the depth variation of the environmental parameters of the sediments in two lakes in Jiuzhaigou would correspond to each other.The results indicated that the sediment rate of Jiuzhaigou was generally high with strong siltation,indicating that serious soil loss was induced by intensive human activities in the basin over the past decades.The increases in the mass accumulation rate,contents of acid-insoluble residue,and mean particle size during the periods of 1840–1900s,late 1930s–early 1950s,1966–1978,and2003–2006 revealed the occurrence of severe soil and water loss as a result of extensive agricultural expansion,large-scale deforestation,and road construction in Jiuzhaigou.The deposition rate and the properties of lacustrine sediments could reflect the significant impact of human activities on lake sedimentation during Jiuzhaigou′s history.展开更多
Black Carbon(BC),as a driver of environmental change,could significantly impact the snow by accelerating melting and decreasing albedo.Systematic documentation of BC studies is crucial for a better understanding of it...Black Carbon(BC),as a driver of environmental change,could significantly impact the snow by accelerating melting and decreasing albedo.Systematic documentation of BC studies is crucial for a better understanding of its spatial and temporal trends.This study reviewed the BC studies in the ice core and remote lake sediments and their sources in the northern hemisphere.The literature surveyed points to around 2.9 to 3.7 times increase of BC in the European Alps and up to a three-fold increase of BC in the Himalayan-Tibetan Plateau(HTP)after the onset of industrialization in Europe and Asia,respectively.BC concentration from Greenland ice core showed seven times increase with an interrupted trend after 1950's.South Asian emissions were dominant in the HTP along with a contribution from the Middle East,whereas Western European and local emissions were responsible for the change in BC concentration in the European Alps.In the Arctic,contributions from North America,Europe and Asia persisted.Similarly,a historical reconstruction of lake sediments records demonstrates the effects of emissions from long-range transport,sediment focusing,local anthropogenic activities,precipitation and total input of flux on the BC concentration.展开更多
Polycyclic aromatic hydrocarbons(PAHs)are ubiquitous environmental contaminants of growing concern due to their potential ecological and human health risks.This study presents a comprehensive assessment of PAHs contam...Polycyclic aromatic hydrocarbons(PAHs)are ubiquitous environmental contaminants of growing concern due to their potential ecological and human health risks.This study presents a comprehensive assessment of PAHs contamination in the surface sediments of Burullus Lake,a vital and second largest delta lake in Egypt.The aim was to evaluate the eco-toxicity and potential health risks associated with the presence of these compounds.Surface seven sediment samples were collected from various drains in the southern part of Burullus Lake.Soxhlet extraction method was employed to extract PAHs(16PAHs)from the sediment sample.Analytically,target compounds were located using HPLC.The results showed that samples contained PAHs levels ranging from 0.038×10^(-6)to 0.459×10^(-6),which is considered heavily polluted by the European standard for PAHs pollution.Additionally,there was no apparent source of PAHs in the ElKhashah drain or the Brinbal Canal,as HPLC found none of the compounds.The most prevalent compound in sediment samples along the study area was fluoranthene.The diagnostic indices in the present study indicated that the hydrocarbons in the region originated from pyrolytic and man-made sources along the drains of Burullus Lake.The principal component analysis(PCA)and diagnostic ratios revealed that coal combustion and pyrolytic sources were responsible for the PAHs contamination in the surface sediments.The non-carcinogenic risk(HI),which is the product of the HQs for the adult and child populations,respectively,was calculated.HI values under 1,therefore,demonstrated that they had no carcinogenic effects on human health.TEQs and MEQs in the sediments of Burullus Lake do not have a cancer-causing impact on people.For the safety of nearby wildlife,aquatic life,and people,all activities that raise petroleum hydrocarbon levels in Burullus Lake must be adequately regulated and controlled.According to the ecological risk assessment,there is little chance that PAHs will be found in the sediments of Burullus Lake.This study underscores the urgent need for effective pollution control measures and regular monitoring of PAHs levels in Burullus Lake sediments to protect the aquatic ecosystem and public health.It also highlights the importance of considering eco-toxicity and human health risks in integrated risk assessments of PAHs-contaminated environments.展开更多
Transported by wind and water,the relatively old sediments can deposit in the terminal lake of an inland drainage basin.The reworking effect can affect the lake sediments 14 C dating and explanations for proxies.The Z...Transported by wind and water,the relatively old sediments can deposit in the terminal lake of an inland drainage basin.The reworking effect can affect the lake sediments 14 C dating and explanations for proxies.The Zhuye Lake is the terminal lake of the Shiyang River Basin.Previous studies indicated that sediments in different locations of the lake basin showed different climatic change patterns.And then,some radiocarbon dates were inverted for some Late Pleistocene sections.Whether this phenomenon is related with the reworking effect? The pollen concentrates 14 C dating can avoid the reservoir effect,which is an ideal method for studying the reworking effect.In this study,we used the pollen concentrates as dating materials and dated five Holocene sections in the Zhuye Lake Basin.Based on the 14 C dates comparison between the pollen concentrates,organic matter,and shells,the pollen concentrates dates are relatively older than other dating materials.Based on the result,the reworking effect worked in the Zhuye Lake Basin during the Holocene;however,in different locations of the lake basin the reworking effects were in different levels.Furthermore,the Holocene lacustrine deposits were formed mostly during the early and middle Holocene.This study provided clues for reworking effect studies of other lakes in arid China.展开更多
This study was conducted to evaluate the distribution characteristics of phosphorus and its species in 14 sediments samples collected from Lake Hongfeng based on sequential extraction. Lake Hongfeng, a major drinking-...This study was conducted to evaluate the distribution characteristics of phosphorus and its species in 14 sediments samples collected from Lake Hongfeng based on sequential extraction. Lake Hongfeng, a major drinking-water source for Guiyang City in southwestern China, is one of the largest artificial reservoirs located in a typical karstic area of the Yunnan-Guizhou Plateau. The results of this study indicate that the average percentages of DP, Al-P, Fe-P, Ca-P and OP in the lake sediments were 0.52, 6.59, 6.09, 42.85 and 40.27, respectively. The concentrations of organic phosphorus (OP) were lower than those of inorganic phosphorus (IP), which consisted mainly of calcium-bound phosphorus (Ca-P). The high concentrations of Ca-P may temporarily control the release of phosphorus from the sediments because it is a relatively stable, inert, and non-bioavailable phosphorus fraction. However, a large number of phosphate solubilizing bacteria can transform insoluble phosphate into bioavailable forms. Moreover, the concentrations of total phosphorus (TP) in the lake sediments were high; thus, the potential for the release of phosphorus from the sediments to the water column and phosphorus bioavailability were still significant. Further statistical analyses of the results revealed significant correlations between phosphorus species in sediments from the lake with two extractable principal component species (PCs) and five selectable cluster levels allowing interpretation of possible origins of phosphorus loading and the release of phosphorus. Furthermore, available remediation measures were briefly assessed for the lake with consideration of its distinctive environmental features.展开更多
Pollen analyses of 85 samples from the San-jiaocheng section well along the margin of a palaeolake at the end of the Shiyang River, NW China, show that Picea and Sabina dominate the pollen assemblage. Together they re...Pollen analyses of 85 samples from the San-jiaocheng section well along the margin of a palaeolake at the end of the Shiyang River, NW China, show that Picea and Sabina dominate the pollen assemblage. Together they reach as high as 40%-60%, with the percentage of Picea varying inversely with that of Sabina. Similar results were obtained from another section in the Shiyang River drainage. Using modern ecological habitat relationship analogues, pol-len transport characteristics, and the overall pollen assem-blage, we propose that both Picea and Sabina pollen were transported by the river from the mountains at the upper reaches of the Shiyang River, and that the assemblage is more indicative of changes in upland vegetation than of local conditions near the section. This interpretation is supported by pollen data derived from surface samples, water samples, and riverbed samples. Using a moisture indicator (the Picea to Sabina ratio) and calculated pollen concentrations, we identify a series of展开更多
Modern climate research has shown that the Asian summer monsoon water vapor transport is limited to the eastern part of the Qilian Mountains. On the Holocene millennial-scale, whether the northwest boundary of the sum...Modern climate research has shown that the Asian summer monsoon water vapor transport is limited to the eastern part of the Qilian Mountains. On the Holocene millennial-scale, whether the northwest boundary of the summer monsoon varies according to climate change is a key scientific issue. Yanchi Lake is located in the northern Qilian Mountains and the middle of the Hexi Corridor, where the modern climate is less affected by the Asian summer monsoon. It is a key research area for examining the long-term variations of the Asian summer monsoon. Paleoclimatic data, including AMS ^14C dates of pollen concentrates and bulk organic carbon, lithology, grain-size, mineral composition and geochemical proxies were acquired from sediments of Yanchi Lake. The chronological results show that the lower part of the lacustrine section is formed mainly in the Late Glacial and early Holocene period, while the proxies' data indicate the lake expansion is associated with high content of mineral salts. The middle part of this section is formed during the transitional period of the early and middle Holocene. Affected by the reworking effect, the pollen concentrates AMS^14C dates from the middle part of the section are generally older than those from the lower part. Since the mid-Holocene, Yanchi Lake retreated significantly and the deposition rate dropped obvi- ously. The Yanchi Lake record is consistent with the Late Glacial and Holocene lake records in the Qinghai-Tibet Plateau and the climatic records in typical monsoon domain, which indicate the lake expansion and the strong Asian summer monsoon during the Late Glacial and early Holocene. The long-term monsoonal pattern is different from the lake evolution in Central Asia on the Holocene millennial-scale. This study proves the monsoon impacts on the northwestern margin of the summer monsoon, and also proves the fact that the northern boundary of the summer monsoon moves according to millennial-scale climate change.展开更多
Effects of pH,temperature,and oxygen on the production and release of phosphine in eutrophic lake sedi-ments were investigated under laboratory tests.Results indi-cated that the elimination of matrix-bound phosphine w...Effects of pH,temperature,and oxygen on the production and release of phosphine in eutrophic lake sedi-ments were investigated under laboratory tests.Results indi-cated that the elimination of matrix-bound phosphine was accelerated under initial pH 1 or 12.Phosphine levels could reach maximum under initial pH 10.The contents of phos-phine increased with the addition of alkali under pH 4-12.The rates of phosphine production and release from lake sed-iments varied with temperature.20°C was the most favorable temperature for the production of matrix-bound phosphine.Oxygen showed little effect on matrix-bound phosphine.Matrix-bound phosphine concentrations in lake sediments were concluded to be dependent on a balance of natural generation and depletion processes.展开更多
Fractionation of heavy metals in sediments can help in understanding potential hazards of heavy metals. The present study analyzed total concentrations and fractions of selected heavy metals (Cd, Cr, Cu, Pb, and Zn)...Fractionation of heavy metals in sediments can help in understanding potential hazards of heavy metals. The present study analyzed total concentrations and fractions of selected heavy metals (Cd, Cr, Cu, Pb, and Zn) in surface sediments from Dianchi Lake, Yunnan Province, China, as well as factors that may affect distributions of the various heavy metal fractions. Total concentrations of the heavy metals decreased in the order Zn 〉 Cu 〉 Pb 〉 Cr 〉 Cd. These heavy metals, except Cr, were much higher than their background levels, indicating that Dianchi Lake was polluted by Cd, Zn, Pb, and Cu. Cadmium occurred mainly as the non-residual fraction (sum of the HOAc-soluble, reducible, and oxidizable fractions) (97.6%), and Zn (55.7%) was also predominantly found in the non-residual fraction. In contrast, most of the Cr (88.5%), Pb (81.8%), and Cu (59.2%) occurred in the residual fraction. Correlation analysis showed that total heavy metal concentrations, organic matter and reducible Fe were the main factors affecting the distributions of the various heavy metal fractions. In the Walhai section of Dianchi Lake (comprising 97% of the lake area), the concentrations of Cd, Zn, Pb, and Cu in the non-residual fraction were significantly lower (P ≤ 0.01 or 0.05) than those of the Caohal section (3% of the lake area). This indicated that potential heavy metal hazards in the Caohai section were greater than the Waihai section.展开更多
The modern pollen assemblages of surface lake sediments and topsoils in northwestern China were studied to understand the relationship of modem pollen data with contemporary vegetation and climate, and the differences...The modern pollen assemblages of surface lake sediments and topsoils in northwestern China were studied to understand the relationship of modem pollen data with contemporary vegetation and climate, and the differences between the pollen assem- blages of surface lake sediments and topsoils. The results show that Chenopodiaceae and Artemisia are dominant elements in the pollen assemblages of northwestern China. Additionally, Ephedra, Cyperaceae, Asteraceae, Poaceae, Picea, Pinus, and Betula are also important pollen taxa. Both pollen assemblages and principal component analysis indicate that pollen data from surface lake sediments and topsoils can be used to differentiate the main vegetation types of this region (desert, steppe, mead- ow and forest). However, differences exist between modern pollen assemblages of the two types of sediments due to the dif- ferent relevant source areas of pollen and degrees of pollen preservation. For example, the larger relevant source area of sur- face lake sediment results in a higher abundance of Betula in pollen assemblage from surface lake sediment, whereas the ten- dency to disintegrate thin-walled pollen types in topsoil leads to a higher proportion of resistant pollen, such as Asteraceae. Linear regression analysis indicates that the Artemisia/Chenopodiaceae (A/C) ratio in pollen assemblages of surface lake sedi- ments can be used to indicate humidity changes in the study area. However, the A/C ratio in topsoils should be used carefully. Our results suggest that pollen data from surface lake sediments would be better references for interpreting the fossil pollen assemblages of lake cores or lacustrine profiles.展开更多
文摘In this paper the authors classify saline lake sediments into the cold, warm and eurythermal phases, reveal the consistency between the zoning of hydrochemical types of modern saline lake water and climatic zoning and give climatic parameters under the conditions of typical cold phase (mirabilite and natron), warm phase (thenar-dite) and slightly warm phase (bloedite) saline lake deposition.
文摘Since the ban on the use of organochlorine pesticides (OCPs) such as dichloro-diphenyl-trichloroethane (DDT) and hexachlorocyclohexane(HCH) in agriculture, their levels have generally dropped. In a number of cases, however, the levels of these OCPs were found to be unchanging or even increasing after the ban. With the aim to unveil the possible causes of these exceptions, we collected two lake cores from King George Island, West Antarctica, and determined their accumulation flux profiles and temporal trends of these OCPs. In the lake core sediments with glacier meltwater input, the accumulation flux of DDT shows an abnormal peak around 1980s in addition to the expected one in 1960s. In the lake core sediments without glacier meltwater input, the accumulation flux of DDT shows a gradual decline trend after the peak in 1960s. This striking difference in the DDT flux profiles between the two lake cores is most likely caused by the regional climate warming and the resulted discharge of the DDT stored in the Antarctic ice cap into the lakes in the Antarctic glacier frontier. Furthermore, to investigate the change of OCPs loadings in the Antarctic coastal ecosystem, we reconstructed the HCH and DDT concentration profiles in penguin droppings and observed a gradual increase for the former and a continuous decrease for the latter during the past 50 years. The increase of HCH seems to be due to the regional warming from the early 1970s and the resulted HCH discharge to the coastal ecosystem by glaciers' meltwater and the illegal use of HCH in the Southern Hemisphere in the recent decade. The different temporal trends of HCH and DDT accumulation rate in the lake core with glacier meltwater input and the aged penguin droppings can be explained by their different water-soluble property.
基金Foundation: National Natural Science Foundation of China, No.40271004Acknowledgements: We wish to thank Professor Wang Ying for her supervision during fieldwork and paper writing, Professor Bruce Mitchell, Associate Provost of University of Waterloo, for reviewing the paper, Shi Xiaodong and Luo Weiwei for making ^210pb dating measurements, and Ding Haiyan for participating in grain size and magnetic susceptibility measurements.
文摘Based on analysis of parameters of cores taken from Gaoyou Lake, including magnetic susceptibility, grain-size characteristics and sedimentary rate, environmental changes during the modern period were examined with the assistance of historical records and Gaoyou Lake water level materials. It is concluded that during the modern period a higher value of magnetic susceptibility and a lower sediment grain size coincided with a wet climate, while a lower value of magnetic susceptibility and a higher grain size were related with a dry climate. The results indicate that the climate in the 123 years period from 1880 to 2003AD can be divided into four stages: two low water level stages (1880-1915AD, 1948-1981AD) and two high water level stages (1915-1948AD, 1981-2003AD). It appears that the regional climate generally underwent a dry-wet-dry-wet pattern in 30-year cycles. At present, it is at the end of a wet period, so the regional climate is expected to become dry in the near future. This conclusion corresponds with the climate records in the historical literature of the Gaoyou area, and it also matches with the climatic changes in North Jiangsu area.
基金supported by the National Natural Science Foundation(Grant Nos.40876096,40606003and 40676004)the young fund for strategetic research of Chinese polar sciences fromCAAA(No.20070202)+1 种基金open research fund from SOA Key Laboratory for Polar Science(KP2007002)special fund for excellent PhD thesis of CAS
文摘According to palaeoclimatic and modern instrumental data,numerous studies have indicated that the Arctic climate has undergone a significant warming during the past 100 years,and this may lead to significant impact on the fragile lake ecosystem.In this study,we collected a lake sediment core from the Nylesund of Svalbard and determined the concentrations of four pigments including chlorophyll derivatives,total carotenoids,oscillaxanthin and myxoxanthophyll in the sediments.Combined with other physical and chemical proxies such as calcium carbonate,total organic carbon,biogenic silicon etc.,we have reconstructed the historical changes of lacustrine primary productivity in Ny-lesund,especially for the past 100 years.The results showed that during the period of Little Ice Age(LIA),the climate was unfavorable for the growth of the lake algae,and thus the lacustrine productivity declined.This result was supported by the relatively low contents of pigment and biogenic silica in the sediments.In contrast,the contents of total organic carbon(TOC) and sediment pigments increased significantly in the upper 5 cm(-1890AD),reflecting the rapid growth of the lake algae,thus the great increase of lacustrine primary productivity,corresponding to the warming climate after LIA.However,the biogenic silica in the upper sediments still had a relatively low level,and this might be related to the growth competition with other algae species.Over the past 100 years,the ratio of Osc/Myx in the sediments decreased continuously,indicative of durative increase of myxoxanthophyll in blue-green algal pigments,and this might imply that the human activity had enhanced the nutrition level of the lake in the Arctic region.
基金financially supported by the China Geological Survey(grant no.1212011120045)the NSFC(grant no.41274074)
文摘The Huguangyan Maar Lake(HML)(21°9'N,110°17'E),situated on the Leizhou Peninsula in the southernmost of China's Mainland,is the deepest recent crater lake among the identified volcanic structures in the Leiqiong Volcanic Field.The bi-lobate lake.
基金funded by the National Natural Science Foundation of China(grant No.41572329)
文摘Objective Despite the fact that the bioavailability of trace metals indicated by their speciation has been an indispensable parameter in the assessment and treatment of the environmental pollution of trace metals, many studies have suggested that the bioavailability of trace metals may change according to the conditions of the environment, and the speciation of trace metals can also transform between some fractions. These transformations are related with these factors such as the compositions, microorganism, time, and other physical-chemical conditions of the system. Our work aims to systematically investigate and probe the factors to affect the transformation aside from analysis at certain time-place. The results of these understanding and investigations can be used for reasonably determining the allocation of financial and technical resources in natural and engineered processes, with bringing about inspirations from the evolution of the speciation of the trace metals on environmental impacts.
基金Received on April 20th,2020revised on July 30th,2020.This project is sponsored by the National Natural Science Foundation of China(42072248)+1 种基金the Seismic Active Fault Exploration Project based on High-Resolution Remote Sensing Interpretation Technology by the Department of Earthquake Damage Defense,CEA(15230003)the Basic Science Research Plan of Institute of Earthquake Forecasting,CEA(2019IEF0201).
文摘The quantitative calculation of the volume of large earthquake-triggered landslides and related dammed lake sediments is of great significance in the study of secondary disasters and focal parameters of strong historical earthquakes.In this study,the dammed lake induced by Qishan M7 earthquake(Lingtai County,Gansu Province,Northwest China)is selected as the research object.Based on the information collected from the 4 boreholes in the dammed lake area,we further take advantage of the lowlevel Unmanned Aerial Vehicle(UAV)photogrammetry and the morphology recovery method,to calculate the volume of the dammed lake and landslides,respectively.Finally,major conclusions are obtained as follows:①the AMS-14C age at the bottom of the Qiuzigou Dammed Lake sediments is 2890±30 BP,which coincides with the 780 BC Qishan earthquake;furthermore,the Qiuzigou Landslides seem to have been triggered by the earthquake,forming an enclosed dammed lake deposition environment after the upstream sediments accumulate;②the Qiuzigou landslides are opposite-sliding landslides that have blocked the river valley;in detail,landslide volumes at the right and left banks are 235×104 m3 and 229×104 m3,respectively.The length of the dammed lake is 2.6 km,with a thickness of approximately 43 m near the landslides,and the total sedimentary volume is 573×104 m3;③the erosion rate of Qiuzigou Landslide Dammed Lake is 0.44 mm/a,the accumulation rate is 15.05 mm/a,and the soil erosion modulus is 593 t/(km2/a),characterized as slight erosion.Quantitative research on the formation of landslides and dammed lakes from strong historical earthquakes is vital for increasing our understanding of the vibrational characteristics and surface action processes of these types of earthquakes.
基金Under the auspices of the National (G19980408) and CAS(s Key Project for Basic Research on Tibetan Plateau (KZ951-A1-204, KZ95T-
文摘A 107cm piston-core (SHC-2) was drilled at the site with water depth of 5m in South Hongshan Lake, northwest Tibet in 1998. Based upon the 0.72cm/a of modern sedimentary rate that was tested by 210Pb method and also calibrated by 137Cs method as well as the 1cm interval sample cutting level, a lake sedimentary record of 150-yr old and with a resolution of 1.4 yrs was obtained. Ratio of geochemistry contents (TOC, TN, CaCO3) and concentrations of trace elements such as B, Sr, Ba, Ca, Mg, K, Na, Al, Ti, Cu, Zn, Fe, Mn, Ni, Cr, V, Pb, etc were analyzed. The values of TOC, TN, C/N, CaCO3, Sr/Ba and Fe/Mn had clear environmental significance and well reflected the environmental changes. Geochemical multi-proxies of lacustrine sediments from SHC-2 core showed that the environmental changes in this area during the past 150 years could be reconstructed as follows: Stage 1 (1850s-1880s) was a cold period; Stage 2 (1880s-1920s) was a warm period. But the variation of lake water volume was stable in the two periods. Stage 3 (1920s-1950s) was a fluctuant and transitional period in temperature, but there were a short cold period in the 1920s and a warm period in the 1930s. Stage 4 (1950s-) showed a warming tendency, though there existed a cold period from the mid 1970s to the end of the 1980s. In the view of general trend in the past 150 years, South Hongshan Lake was shrinking gradually. It showed that, from the comparison with the Guliya ice core and meteorological records of adjacent weather stations, there is difference in the variations of temperature and precipitation among different regions and altitudes in Tibetan Plateau. It is necessary to search multi-scale and high-resolution records for environmental reconstruction and comparison.
基金the China’s National Basic Research Program:"Studies on the Process of Eutrophication of Lakesand the Mechanism of the Blooming of Blue Green Alga" (No2002CB412304)
文摘Thirteen sediment core samples(0-10 cm) were taken from the seven lakes in the middle and lower reaches of the Yangtze River to determine the contents and distributions of organic phosphorus(P) fractions in the sediments of the shallow lakes in the area.The organic P fractions in the sediments were in the order of moderately labile organic P(MLOP) > moderately resistant organic P(MROP) > highly resistant organic P(HROP) > labile organic P(LOP),with average proportional ratios of 13.2:2.8:1.3:1.0.LOP,MLOP,and MROP were significantly related to the contents of total organic carbon(TOC),water-soluble P(WSP),algal-available P(AAP),NaHCO3-extractable P(Olsen-P),total P(TP),organic P(OP),and inorganic P(IP).However,HROP was significantly related to OP and weakly correlated with TOC,WSP,AAP,Olsen-P,TP or IP.This suggested that organic P,especially LOP and MLOP in sediments,deserved even greater attention than IP in regards to lake eutrophication.In terms of organic P,sediments were more hazardous than soils in lake eutrophication.Although OP concentrations were higher in moderately polluted sediment than those in heavily polluted sediment,LOP and MLOP were higher in the heavily polluted sediment,which indicated that heavily polluted sediment was more hazardous than moderately polluted sediment in lake eutrophication.
基金supported by the Knowledge Innovation Program of the Chinese Academy of Sciences (KZCX2-EW-308)the National Basic Research Program of China (2006FY110600)the National Natural Science Foundation of China (41071139 and 40971117)
文摘Based on the analyses of environmental proxy data in lake sediments and instrumental records of Xinjiang in northwest China, the Holocene climate and hydrological variability and its environmental responses were studied in different time scales and regions. The results showed that the Holocene climate variability had obvious differences between the north and south of Xinjiang. In northern Xinjiang, the Holocene climate was dry in the early period, humid in the middle period, and then changed to dry in the late period. However, the climate transition times were not consistent in different regions. In southern Xin- jiang, although there were many different types of climate change patterns inferred from different catch- ments, the warm and wet climate was recorded in most lake sediments in the middle Holocene. According to comparisons of some millennium scale records in lake sediments, the climate was warm and dry in the past 100 years. It can be concluded the climate showed a trend of aridity in Holocene. Especially in recent 50 years, the lake area has been shrinking rapidly because of the population growth and social economic development, which brings some environmental problems. Lake level and area changes were sensitively affected by the climate variation in geological history of Xinjiang and the lake level will continue to shrink because of the drought climate and strengthened human activities.
基金Under the auspices of Programme of Introducing Talents of Discipline to Universities(the 111 Project)(No.B08037)National Key Technology R&D Program of China(No.2012BAC06B02)
文摘Radionuclide dating techniques characterized by137Cs and210Pbex have recently been applied in the study of lake sediments around the world.In this study,a chronological series of sediment cores was established based on137Cs and210Pbex analyses along with the evaluation of sediment properties,such as particle size distribution,total organic carbon(TOC),carbonate content,and acid-insoluble residue,to study sediment accumulation rates,sediment sources,and responses to human activities in the Jiuzhaigou National Nature Reserve in southwestern China.In terms of the particle size distribution of sediments,silt content was the highest,and clay and sand contents were relatively low.The sediments displayed high TOC contents because of the significant amounts of vegetation grown in the lakes.The carbonate content was also high due to the overall geological background of carbonates in Jiuzhaigou.Carbonate content tended to decline from top to bottom in the sediment cores,whereas the acid-insoluble residue tended to increase.These results suggested that the depth variation of the environmental parameters of the sediments in two lakes in Jiuzhaigou would correspond to each other.The results indicated that the sediment rate of Jiuzhaigou was generally high with strong siltation,indicating that serious soil loss was induced by intensive human activities in the basin over the past decades.The increases in the mass accumulation rate,contents of acid-insoluble residue,and mean particle size during the periods of 1840–1900s,late 1930s–early 1950s,1966–1978,and2003–2006 revealed the occurrence of severe soil and water loss as a result of extensive agricultural expansion,large-scale deforestation,and road construction in Jiuzhaigou.The deposition rate and the properties of lacustrine sediments could reflect the significant impact of human activities on lake sedimentation during Jiuzhaigou′s history.
基金the National Natural Science Foundation of China(41771079,41805106)the Strategic Priority Research Program of the Chinese Academy of Sciences-The Pan-Third Pole Environment Study for a Green Silk Road(Pan-TPE)(XDA20040501)the Key Laboratory of Cryospheric Sciences Scientific Research Foundation(SKLCS-ZZ-2019)。
文摘Black Carbon(BC),as a driver of environmental change,could significantly impact the snow by accelerating melting and decreasing albedo.Systematic documentation of BC studies is crucial for a better understanding of its spatial and temporal trends.This study reviewed the BC studies in the ice core and remote lake sediments and their sources in the northern hemisphere.The literature surveyed points to around 2.9 to 3.7 times increase of BC in the European Alps and up to a three-fold increase of BC in the Himalayan-Tibetan Plateau(HTP)after the onset of industrialization in Europe and Asia,respectively.BC concentration from Greenland ice core showed seven times increase with an interrupted trend after 1950's.South Asian emissions were dominant in the HTP along with a contribution from the Middle East,whereas Western European and local emissions were responsible for the change in BC concentration in the European Alps.In the Arctic,contributions from North America,Europe and Asia persisted.Similarly,a historical reconstruction of lake sediments records demonstrates the effects of emissions from long-range transport,sediment focusing,local anthropogenic activities,precipitation and total input of flux on the BC concentration.
文摘Polycyclic aromatic hydrocarbons(PAHs)are ubiquitous environmental contaminants of growing concern due to their potential ecological and human health risks.This study presents a comprehensive assessment of PAHs contamination in the surface sediments of Burullus Lake,a vital and second largest delta lake in Egypt.The aim was to evaluate the eco-toxicity and potential health risks associated with the presence of these compounds.Surface seven sediment samples were collected from various drains in the southern part of Burullus Lake.Soxhlet extraction method was employed to extract PAHs(16PAHs)from the sediment sample.Analytically,target compounds were located using HPLC.The results showed that samples contained PAHs levels ranging from 0.038×10^(-6)to 0.459×10^(-6),which is considered heavily polluted by the European standard for PAHs pollution.Additionally,there was no apparent source of PAHs in the ElKhashah drain or the Brinbal Canal,as HPLC found none of the compounds.The most prevalent compound in sediment samples along the study area was fluoranthene.The diagnostic indices in the present study indicated that the hydrocarbons in the region originated from pyrolytic and man-made sources along the drains of Burullus Lake.The principal component analysis(PCA)and diagnostic ratios revealed that coal combustion and pyrolytic sources were responsible for the PAHs contamination in the surface sediments.The non-carcinogenic risk(HI),which is the product of the HQs for the adult and child populations,respectively,was calculated.HI values under 1,therefore,demonstrated that they had no carcinogenic effects on human health.TEQs and MEQs in the sediments of Burullus Lake do not have a cancer-causing impact on people.For the safety of nearby wildlife,aquatic life,and people,all activities that raise petroleum hydrocarbon levels in Burullus Lake must be adequately regulated and controlled.According to the ecological risk assessment,there is little chance that PAHs will be found in the sediments of Burullus Lake.This study underscores the urgent need for effective pollution control measures and regular monitoring of PAHs levels in Burullus Lake sediments to protect the aquatic ecosystem and public health.It also highlights the importance of considering eco-toxicity and human health risks in integrated risk assessments of PAHs-contaminated environments.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41001116 and J1030519)the Fundamental Research Fund for the Central Universities (Grant No. LZUJBKY-2010-99)
文摘Transported by wind and water,the relatively old sediments can deposit in the terminal lake of an inland drainage basin.The reworking effect can affect the lake sediments 14 C dating and explanations for proxies.The Zhuye Lake is the terminal lake of the Shiyang River Basin.Previous studies indicated that sediments in different locations of the lake basin showed different climatic change patterns.And then,some radiocarbon dates were inverted for some Late Pleistocene sections.Whether this phenomenon is related with the reworking effect? The pollen concentrates 14 C dating can avoid the reservoir effect,which is an ideal method for studying the reworking effect.In this study,we used the pollen concentrates as dating materials and dated five Holocene sections in the Zhuye Lake Basin.Based on the 14 C dates comparison between the pollen concentrates,organic matter,and shells,the pollen concentrates dates are relatively older than other dating materials.Based on the result,the reworking effect worked in the Zhuye Lake Basin during the Holocene;however,in different locations of the lake basin the reworking effects were in different levels.Furthermore,the Holocene lacustrine deposits were formed mostly during the early and middle Holocene.This study provided clues for reworking effect studies of other lakes in arid China.
基金Supported by the National Natural Science Foundation of China (No.20967003)
文摘This study was conducted to evaluate the distribution characteristics of phosphorus and its species in 14 sediments samples collected from Lake Hongfeng based on sequential extraction. Lake Hongfeng, a major drinking-water source for Guiyang City in southwestern China, is one of the largest artificial reservoirs located in a typical karstic area of the Yunnan-Guizhou Plateau. The results of this study indicate that the average percentages of DP, Al-P, Fe-P, Ca-P and OP in the lake sediments were 0.52, 6.59, 6.09, 42.85 and 40.27, respectively. The concentrations of organic phosphorus (OP) were lower than those of inorganic phosphorus (IP), which consisted mainly of calcium-bound phosphorus (Ca-P). The high concentrations of Ca-P may temporarily control the release of phosphorus from the sediments because it is a relatively stable, inert, and non-bioavailable phosphorus fraction. However, a large number of phosphate solubilizing bacteria can transform insoluble phosphate into bioavailable forms. Moreover, the concentrations of total phosphorus (TP) in the lake sediments were high; thus, the potential for the release of phosphorus from the sediments to the water column and phosphorus bioavailability were still significant. Further statistical analyses of the results revealed significant correlations between phosphorus species in sediments from the lake with two extractable principal component species (PCs) and five selectable cluster levels allowing interpretation of possible origins of phosphorus loading and the release of phosphorus. Furthermore, available remediation measures were briefly assessed for the lake with consideration of its distinctive environmental features.
基金. This work was supported by the National Natural Science Foundation of China (Grant Nos. 49731010 and 49871072).
文摘Pollen analyses of 85 samples from the San-jiaocheng section well along the margin of a palaeolake at the end of the Shiyang River, NW China, show that Picea and Sabina dominate the pollen assemblage. Together they reach as high as 40%-60%, with the percentage of Picea varying inversely with that of Sabina. Similar results were obtained from another section in the Shiyang River drainage. Using modern ecological habitat relationship analogues, pol-len transport characteristics, and the overall pollen assem-blage, we propose that both Picea and Sabina pollen were transported by the river from the mountains at the upper reaches of the Shiyang River, and that the assemblage is more indicative of changes in upland vegetation than of local conditions near the section. This interpretation is supported by pollen data derived from surface samples, water samples, and riverbed samples. Using a moisture indicator (the Picea to Sabina ratio) and calculated pollen concentrations, we identify a series of
基金National Natural Science Foundation of China, No.41001116 The Fundamental Research Fund for the Central Universities, No.lzuj bky-2013 - 127 No.lzuj bky-2013 - 129
文摘Modern climate research has shown that the Asian summer monsoon water vapor transport is limited to the eastern part of the Qilian Mountains. On the Holocene millennial-scale, whether the northwest boundary of the summer monsoon varies according to climate change is a key scientific issue. Yanchi Lake is located in the northern Qilian Mountains and the middle of the Hexi Corridor, where the modern climate is less affected by the Asian summer monsoon. It is a key research area for examining the long-term variations of the Asian summer monsoon. Paleoclimatic data, including AMS ^14C dates of pollen concentrates and bulk organic carbon, lithology, grain-size, mineral composition and geochemical proxies were acquired from sediments of Yanchi Lake. The chronological results show that the lower part of the lacustrine section is formed mainly in the Late Glacial and early Holocene period, while the proxies' data indicate the lake expansion is associated with high content of mineral salts. The middle part of this section is formed during the transitional period of the early and middle Holocene. Affected by the reworking effect, the pollen concentrates AMS^14C dates from the middle part of the section are generally older than those from the lower part. Since the mid-Holocene, Yanchi Lake retreated significantly and the deposition rate dropped obvi- ously. The Yanchi Lake record is consistent with the Late Glacial and Holocene lake records in the Qinghai-Tibet Plateau and the climatic records in typical monsoon domain, which indicate the lake expansion and the strong Asian summer monsoon during the Late Glacial and early Holocene. The long-term monsoonal pattern is different from the lake evolution in Central Asia on the Holocene millennial-scale. This study proves the monsoon impacts on the northwestern margin of the summer monsoon, and also proves the fact that the northern boundary of the summer monsoon moves according to millennial-scale climate change.
基金This work was supported by the Science&Technol-ogy Key Project of the Ministry of Education(Grant No.03079)the National Natural Science Foundation of China(Grant No.20177007)the National Key Basic Research and Development(973)Program of China(Grant No.2002CB412304).
文摘Effects of pH,temperature,and oxygen on the production and release of phosphine in eutrophic lake sedi-ments were investigated under laboratory tests.Results indi-cated that the elimination of matrix-bound phosphine was accelerated under initial pH 1 or 12.Phosphine levels could reach maximum under initial pH 10.The contents of phos-phine increased with the addition of alkali under pH 4-12.The rates of phosphine production and release from lake sed-iments varied with temperature.20°C was the most favorable temperature for the production of matrix-bound phosphine.Oxygen showed little effect on matrix-bound phosphine.Matrix-bound phosphine concentrations in lake sediments were concluded to be dependent on a balance of natural generation and depletion processes.
基金Project supported by the Science and Technology Program for Social Development of Jiangsu Province,China (No.BS2006060)Startup Fund of Nanjing University of Information Science & Technology, the State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering, Hohai University (No. 2005406711)the Jiangsu Key Laboratory of Environmental Change and Ecological Construction, Nanjing Normal University.
文摘Fractionation of heavy metals in sediments can help in understanding potential hazards of heavy metals. The present study analyzed total concentrations and fractions of selected heavy metals (Cd, Cr, Cu, Pb, and Zn) in surface sediments from Dianchi Lake, Yunnan Province, China, as well as factors that may affect distributions of the various heavy metal fractions. Total concentrations of the heavy metals decreased in the order Zn 〉 Cu 〉 Pb 〉 Cr 〉 Cd. These heavy metals, except Cr, were much higher than their background levels, indicating that Dianchi Lake was polluted by Cd, Zn, Pb, and Cu. Cadmium occurred mainly as the non-residual fraction (sum of the HOAc-soluble, reducible, and oxidizable fractions) (97.6%), and Zn (55.7%) was also predominantly found in the non-residual fraction. In contrast, most of the Cr (88.5%), Pb (81.8%), and Cu (59.2%) occurred in the residual fraction. Correlation analysis showed that total heavy metal concentrations, organic matter and reducible Fe were the main factors affecting the distributions of the various heavy metal fractions. In the Walhai section of Dianchi Lake (comprising 97% of the lake area), the concentrations of Cd, Zn, Pb, and Cu in the non-residual fraction were significantly lower (P ≤ 0.01 or 0.05) than those of the Caohal section (3% of the lake area). This indicated that potential heavy metal hazards in the Caohai section were greater than the Waihai section.
基金supported by the National Basic Research Program of China(Grant No.2012CB956102)the National Natural Science Foundation of China(Grant Nos.41071126,41125006,41401227)the China Postdoctoral Science Foundation(Grant No.2014M550822)
文摘The modern pollen assemblages of surface lake sediments and topsoils in northwestern China were studied to understand the relationship of modem pollen data with contemporary vegetation and climate, and the differences between the pollen assem- blages of surface lake sediments and topsoils. The results show that Chenopodiaceae and Artemisia are dominant elements in the pollen assemblages of northwestern China. Additionally, Ephedra, Cyperaceae, Asteraceae, Poaceae, Picea, Pinus, and Betula are also important pollen taxa. Both pollen assemblages and principal component analysis indicate that pollen data from surface lake sediments and topsoils can be used to differentiate the main vegetation types of this region (desert, steppe, mead- ow and forest). However, differences exist between modern pollen assemblages of the two types of sediments due to the dif- ferent relevant source areas of pollen and degrees of pollen preservation. For example, the larger relevant source area of sur- face lake sediment results in a higher abundance of Betula in pollen assemblage from surface lake sediment, whereas the ten- dency to disintegrate thin-walled pollen types in topsoil leads to a higher proportion of resistant pollen, such as Asteraceae. Linear regression analysis indicates that the Artemisia/Chenopodiaceae (A/C) ratio in pollen assemblages of surface lake sedi- ments can be used to indicate humidity changes in the study area. However, the A/C ratio in topsoils should be used carefully. Our results suggest that pollen data from surface lake sediments would be better references for interpreting the fossil pollen assemblages of lake cores or lacustrine profiles.