For the development of high-strength Mg alloys,active use of Laves phases such as C14-type Mg_(2)Yb and Mg_(2)Ca is strongly expected.However,the brittleness of the Laves phases is the biggest obstacle to it.We first ...For the development of high-strength Mg alloys,active use of Laves phases such as C14-type Mg_(2)Yb and Mg_(2)Ca is strongly expected.However,the brittleness of the Laves phases is the biggest obstacle to it.We first found that kink-band formation can be induced in directionally solidified Mg/Mg_(2)Yb and Mg/Mg_(2)Ca eutectic lamellar alloys when a stress is applied parallel to the lamellar interface,leading to a high yield stress accompanied with ductility.That is,microstructural control can induce a new deformation mode that is not activated in the constituent phases,thereby inducing ductility.It was clarified that the geometric relationship between the operative slip plane in the constituent phases and the lamellar interface,and the microstructural features that provide kink-band nucleation sites are important factors for controlling kink-band formation.The obtained results show a possibility to open the new door for the development of novel high-strength structural material using the kink bands.展开更多
Two TiAl alloys,Ti-47.5Al-3.7(Cr,V,Zr)and Ti-47.5Al-3.7(Cr,V,Zr)-0.1C(at.%),were prepared by cold crucible levitation melting to couple the hard-oriented directional lamellar microstructure with carbon microalloying s...Two TiAl alloys,Ti-47.5Al-3.7(Cr,V,Zr)and Ti-47.5Al-3.7(Cr,V,Zr)-0.1C(at.%),were prepared by cold crucible levitation melting to couple the hard-oriented directional lamellar microstructure with carbon microalloying strengthening.The creep behavior and mechanism for the improvement in creep properties by carbon addition were investigated by mechanical tests and electron microscopy characterizations.The results show that obvious improvements on the creep properties at 760°C and 276 MPa are achieved by 0.1 at.%C addition into TiAl alloy with directional lamellar microstructure,which promotes the creep strain and minimum creep rate decreasing with a large content.The minimum creep rate is reduced from 4.37×10^(-8) to 3.97×10^(-9) s^(-1),and the duration entering into creep acceleration is prolonged for more than 10 times.The mechanism for creep property improvement by 0.1%C addition is attributed to two aspects.The first one is that Ti_(2) AlC is found to be strong obstacles of 1/2[110]dislocations when moving across the lamellar interface in the carbon containing alloy.The other one is that the in terfacial dislocatio ns are effectively impeded and the release process is hindered by dynamic precipitation of Ti_(3) AlC,which is proposed to be the special mechanism for creep resistance improvement of this hard-oriented directional lamellar microstructure.展开更多
Improving the plasticity of TiAl alloys at room temperature has been a longstanding challenge for the de-velopment of next-generation aerospace engines.By adopting the nacre-like architecture design strategy,we have o...Improving the plasticity of TiAl alloys at room temperature has been a longstanding challenge for the de-velopment of next-generation aerospace engines.By adopting the nacre-like architecture design strategy,we have obtained a novel heterogeneous lamellar Ti_(2)AlC/TiAl composite with superior strength-plasticity synergy,i.e.,compressive strength of∼2065 MPa and fracture strain of∼27%.A combination of micropil-lar compression and large-scale atomistic simulation has revealed that the superior strength-plasticity synergy is attributed to the collaboration of Ti_(2)AlC reinforcement,lamellar architecture and heteroge-neous interface.More specifically,multiple deformation modes in Ti_(2)AlC,i.e.,basal-plane dislocations,atomic-scale ripples and kink bands,could be activated during the compression,thus promoting the plas-tic deformation capability of composite.Meanwhile,the lamellar architecture could not only induce sig-nificant stress redistribution and crack deflection between Ti_(2)AlC and TiAl,but also generate high-density SFs and DTs interactions in TiAl,leading to an improved strength and strain hardening ability.In addi-tion,profuse unique Ti_(2)AlC(1¯10¯3)/TiAl(111)interfaces in the composite could dramatically contribute to the strength and plasticity due to the interface-mediated dislocation nucleation and obstruction mecha-nisms.These findings offer a promising paradigm for tailoring microstructure of TiAl matrix composites with extraordinary strength and plasticity at ambient temperature.展开更多
The specimens cut from the cold-rolled pure titanium sheet at 0°,45°and 90°to the rolling direction were treated by high density electropulsing(maximum current density J=(7.22-7.96)×10^(3)A/mm^(2),...The specimens cut from the cold-rolled pure titanium sheet at 0°,45°and 90°to the rolling direction were treated by high density electropulsing(maximum current density J=(7.22-7.96)×10^(3)A/mm^(2),pulse period t_(p)=110μs).The mechanical properties and microstructures of the cold-rolled,electropulsed and conventional annealed commercially pure titanium sheet were examined by using uniaxial tension test machine and optical microscope(OM),respectively.The results show that the deformation behavior of the electropulsed pure titanium sheet is significantly different from that of conventional annealed pure titanium sheet.The difference of the mechanical properties between the 0°,45°and 90°direction specimens is almost diminished.It is mainly due to the increase in dislocation mobility and formation of lamellar microstructure after the electropulsing.展开更多
基金supported by Japan Society for the Promotion of Science (JSPS) KAKENHI for Scientific Research on Innovative Areas "MFS Materials Science" (Grant Numbers: JP18H05478 and JP18H05475)partly supported by the Light Metals Educational Foundation of Japan。
文摘For the development of high-strength Mg alloys,active use of Laves phases such as C14-type Mg_(2)Yb and Mg_(2)Ca is strongly expected.However,the brittleness of the Laves phases is the biggest obstacle to it.We first found that kink-band formation can be induced in directionally solidified Mg/Mg_(2)Yb and Mg/Mg_(2)Ca eutectic lamellar alloys when a stress is applied parallel to the lamellar interface,leading to a high yield stress accompanied with ductility.That is,microstructural control can induce a new deformation mode that is not activated in the constituent phases,thereby inducing ductility.It was clarified that the geometric relationship between the operative slip plane in the constituent phases and the lamellar interface,and the microstructural features that provide kink-band nucleation sites are important factors for controlling kink-band formation.The obtained results show a possibility to open the new door for the development of novel high-strength structural material using the kink bands.
基金National Natural Science Foundation of China(51788104,51390471,51527803 and 51761135131)National 973 Project of China(2015CB654902)National Key Research and Development Pro gram(2016YFB0700402)。
文摘Two TiAl alloys,Ti-47.5Al-3.7(Cr,V,Zr)and Ti-47.5Al-3.7(Cr,V,Zr)-0.1C(at.%),were prepared by cold crucible levitation melting to couple the hard-oriented directional lamellar microstructure with carbon microalloying strengthening.The creep behavior and mechanism for the improvement in creep properties by carbon addition were investigated by mechanical tests and electron microscopy characterizations.The results show that obvious improvements on the creep properties at 760°C and 276 MPa are achieved by 0.1 at.%C addition into TiAl alloy with directional lamellar microstructure,which promotes the creep strain and minimum creep rate decreasing with a large content.The minimum creep rate is reduced from 4.37×10^(-8) to 3.97×10^(-9) s^(-1),and the duration entering into creep acceleration is prolonged for more than 10 times.The mechanism for creep property improvement by 0.1%C addition is attributed to two aspects.The first one is that Ti_(2) AlC is found to be strong obstacles of 1/2[110]dislocations when moving across the lamellar interface in the carbon containing alloy.The other one is that the in terfacial dislocatio ns are effectively impeded and the release process is hindered by dynamic precipitation of Ti_(3) AlC,which is proposed to be the special mechanism for creep resistance improvement of this hard-oriented directional lamellar microstructure.
基金the National Natural Science Foundation of China(Grant No.52101174)the State Key Lab of Advanced Metals and Materials(No.2022-Z15).
文摘Improving the plasticity of TiAl alloys at room temperature has been a longstanding challenge for the de-velopment of next-generation aerospace engines.By adopting the nacre-like architecture design strategy,we have obtained a novel heterogeneous lamellar Ti_(2)AlC/TiAl composite with superior strength-plasticity synergy,i.e.,compressive strength of∼2065 MPa and fracture strain of∼27%.A combination of micropil-lar compression and large-scale atomistic simulation has revealed that the superior strength-plasticity synergy is attributed to the collaboration of Ti_(2)AlC reinforcement,lamellar architecture and heteroge-neous interface.More specifically,multiple deformation modes in Ti_(2)AlC,i.e.,basal-plane dislocations,atomic-scale ripples and kink bands,could be activated during the compression,thus promoting the plas-tic deformation capability of composite.Meanwhile,the lamellar architecture could not only induce sig-nificant stress redistribution and crack deflection between Ti_(2)AlC and TiAl,but also generate high-density SFs and DTs interactions in TiAl,leading to an improved strength and strain hardening ability.In addi-tion,profuse unique Ti_(2)AlC(1¯10¯3)/TiAl(111)interfaces in the composite could dramatically contribute to the strength and plasticity due to the interface-mediated dislocation nucleation and obstruction mecha-nisms.These findings offer a promising paradigm for tailoring microstructure of TiAl matrix composites with extraordinary strength and plasticity at ambient temperature.
文摘The specimens cut from the cold-rolled pure titanium sheet at 0°,45°and 90°to the rolling direction were treated by high density electropulsing(maximum current density J=(7.22-7.96)×10^(3)A/mm^(2),pulse period t_(p)=110μs).The mechanical properties and microstructures of the cold-rolled,electropulsed and conventional annealed commercially pure titanium sheet were examined by using uniaxial tension test machine and optical microscope(OM),respectively.The results show that the deformation behavior of the electropulsed pure titanium sheet is significantly different from that of conventional annealed pure titanium sheet.The difference of the mechanical properties between the 0°,45°and 90°direction specimens is almost diminished.It is mainly due to the increase in dislocation mobility and formation of lamellar microstructure after the electropulsing.