Effect of bipolar-plates design on corrosion,mass and heat transfer in proton-exchange membrane fuel cells and water electrolyzers:A review

Attaining a decarbonized and sustainable energy system,which is the core solution to global energy issues,is accessible through the development of hydrogen energy.Proton-exchange membrane water electrolyzers(PEMWEs)are promising devices for hydrogen production,given their high efficiency,rapid responsiveness,and compactness.Bipolar plates account for a relatively high percentage of the total cost and weight compared with other components of PEMWEs.Thus,optimization of their design may accelerate the promotion of PEMWEs.This paper reviews the advances in materials and flow-field design for bipolar plates.First,the working conditions of proton-exchange membrane fuel cells(PEMFCs)and PEMWEs are compared,including reaction direction,operating temperature,pressure,input/output,and potential.Then,the current research status of bipolar-plate substrates and surface coatings is summarized,and some typical channel-rib flow fields and porous flow fields are presented.Furthermore,the effects of materials on mass and heat transfer and the possibility of reducing corrosion by improving the flow field structure are explored.Finally,this review discusses the potential directions of the development of bipolar-plate design,including material fabrication,flow-field geometry optimization using threedimensional printing,and surface-coating composition optimization based on computational materials science.

Transient Heat Transfer Study of Direct Contact Condensation of Steam in Spray Cooling Water

We conducted a transient experimental investigation of steam–water direct contact condensation in the absence of noncondensible gas in a laboratory-scale column with the inner diameter of 325 mm and the height of 1045 mm. We applied a new analysis method for the steam state equation to analyze the molar quantity change in steam over the course of the experiment and determined the transient steam variation. We also investigated the influence of flow rates and temperatures ofcooling water on the efficiency ofsteam condensation. Our experimental results show that appropriate increasing of the cooling water flow rate can significantly accelerate the steam condensation. We achieved a rapid increase in the total volumetric heat transfer coefficient by increasing the flow rate of cooling water, which indicated a higher thermal convection between the steam and the cooling water with higher flow rates. We found that the temperature ofcooling water did not play an important role on steam condensation. This method was confirmed to be effective for rapid recovering ofsteam.

Coupled Transfer of Water and Heat in Red Soil: Experiment and Numerical Modelling

Coupled transfer of soil water and heat in closed columns of homogeneous red soil was studied under laboratory conditions. A coupled model was constructed using soil physical theory, empirical equations and experimental data to predict the coupled transfer. The results show that transport of soil water was affected by temperature gradient, and the largest net water transport was found in the soil column with initial water content of 0.148 m3 m-3. At the same time, temperature changes with the transport of soil water was in a nonlinear shape as heat parameters were function of water content, and the changes of temperature were positively correlated with the net amount of water transported. Numerical modelling results show that the predicted values of temperature distribution were close to the observed values, while the predicted values of water content exhibited limited deviation at both ends of the soil column due to the slight temperature changes at both ends. It was indicated that the model proposed here was applicable.

Simulation on flow, heat transfer and stress characteristics of large-diameter thick-walled gas cylinders in quenching process under different water spray volumes

Cooling strength is one of the important factors affecting microstructure and properties of gas cylinders during quenching process,and reasonable water spray volume can effectively improve the quality of gas cylinders and reduce production costs.To find the optimal water spray parameters,a fluid-solid coupling model with three-phase flow was established in consideration of water-vapor conversion.The inner and outer walls of gas cylinder with the dimensions of d914 mm×38 mm×12000 mm were quenched using multi-nozzle water spray system.The internal pressure,average heat transfer coefficient(have)and stress of the gas cylinder under different water spray volumes during quenching process were studied.Finally,the mathematical model was experimentally verified.The results show that both the internal pressure and have increase along with the increase of spray volume.The internal pressure increases slowly first and then rapidly,but have increases rapidly first and then slowly.To satisfy hardenability of gas cylinders,the minimum spray volume should not be less than 40 m^3/(h·m).The results of stress indicate that water spray quenching will not cause deformation of bottle body in the range of water volume from 40 to 290 m^3/(h·m).

Pool Boiling Heat Transfer in Dilute Water/Triethyleneglycol Solutions

Boiling of water/triethyleneglycol(TEG)binary solution has a wide-ranging application in the gas processing engineering.Design,operation and optimization of the involved boilers require accurate prediction of boiling heat transfer coefficient between surface and solution.In this investigation,nucleate pool boiling heat transfer coefficient has been experimentally measured on a horizontal rod heater in water/TEG binary solutions in a wide range of concentrations and heat fluxes under ambient condition.The present experimental data are correlated using major existing correlations.In addition a correlation is presented for prediction of pool boiling heat transfer for the system in which the vapour pressure of one component is negligible.This model is based on the mass transfer rate equation for prediction of the concentration at the bubble vapor/liquid interface.Based on this prediction,the temperature of the interface and accordingly,the boiling heat transfer coefficient could be straightforwardly calculated from the known concentration at the interface.It is shown that this simple model has sufficient accuracy and is acceptable below the medium concentrations of TEG when the vapor equilibrium concentration of TEG is almost zero.The presented model excludes any tuning parameter and requires very few physical properties to apply.

Simulation of heat transfer of supercritical water in obstacle-bearing vertical tube

The heat transfer coefficient is very low at bulk temperatures higher than the pseudo-critical point,because the supercritical pressure leads to a vapor-like fluid.In this paper,the heat transfer downstream an obstacle-bearing vertical tube is simulated by the CFD code of Fluent 6.1,using an adaptive grid in the supercritical condition.The reliable results are obtained by the RNG k-ε model using the enhanced wall treatment.The blockage ratio and local temperature of obstacle affect greatly the heat transfer enhancement,and the resultant influence region and decay trend are compared with the existing equations.

The Effect of Water Flow Velocity on Heat Collection Performance of Active Heat Storage and Release System for Solar Greenhouses

In order to explore the influence of water velocity on the heat collection performance of the active heat storage and release system for solar greenhouses,six different flow rates were selected for treatment in this experiment.The comprehensive heat transfer coefficient of the active heat storage and release system at the heat collection stage was calculated by measuring the indoor solar radiation intensity,indoor air temperature and measured water tank temperature.The prediction model of water temperature in the heat collection stage was established,and the initial value of water temperature and the comprehensive heat transfer coefficient were input through MATLAB software.The simulated value of water temperature was compared with the measured value and the results showed that the best heat transfer effect could be achieved when the water flow speed was 1.0 m3h-1.The average relative error between the simulated water tank temperature and the measured value is 2.70-6.91%.The results indicate that the model is established correctly,and the variation trend of water temperature can be predicted according to the model in the heat collection stage.

STUDY OF THE HEAT AND HUMIDITY TRANSFER PROCESSES BETWEEN AIR AND WATER IN THE AIR WASHER

The processes of heat and humidity transfer between air and water are what to be studied mainly in the paper, we put forward some main factors which influence the processes of heat and humidity transfer in the air washer. We come to the conclusion that we can change these main factors to achieve different heat and humidity transfer processes and decide processes of heat and humidity transfer of air and water with the initial temperature of spraying water in the air washer. All these results can make things convenient for the air conditioning management.

Forced Convective Heat Transfer Experiment of Supercritical Water in Different Diameter of Tubes

Forced convective experiment of supercritical water was performed in Inconel-625 tubes of 4.62 mm, 7.98 mm and 10.89 mm in diameter. The water flowed upward, covering the ranges of pressure of 23.4 MPa to 25.8 MPa, mass flux of 90 kg/m^2s to 3,281 kg/m^2s, local bulk temperature of 102-384 ℃, inner wall temperature of 167-669℃ and heat flux of up to 2.41 MW/m^2. The results exhibited severe deteriorated and enhancement heat transfer. The experimental results can be calculated by the Jackson＇s correlation and the Bishop＇s correlation mostly. But some data with strong effects of the buoyancy force and the variations of flow regimes can not be predicted properly.

Mathematical model on heat transfer of water-cooling steel-stick bottom electrode of DC electric arc furnace

For predicting and controlling the melted depth of bottomelectrode during the process of steelmaking, the water-cooling steel-stick electrode is taken as an example, to analyze the process ofheat transfer, then 3D mathematical model by control capacity methodis built. At the same time, the measurement on the melted depth ofbottom electrode is conducted which verified the correctness of thebuilt mathematical model. On the base of verification, all kinds ofkey parameters are calculated through the application and a series ofresults are simulated. Finally, the optimum parameters are found andthe service life of bottom electrode is prolonged.

Numerical Simulation on Subcooled Boiling Heat Transfer Characteristics of Water-Cooled W/Cu Divertors

In order to realize safe and stable operation of a water-cooled W/Cu divertor under high heating condition,the exact knowledge of its subcooled boiling heat transfer characteristics under different design parameters is crucial.In this paper,subcooled boiling heat transfer in a water-cooled W/Cu divertor was numerically investigated based on computational fluid dynamic（CFD）.The boiling heat transfer was simulated based on the Euler homogeneous phase model,and local differences of liquid physical properties were considered under one-sided high heating conditions.The calculated wall temperature was in good agreement with experimental results,with the maximum error of 5%only.On this basis,the void fraction distribution,flow field and heat transfer coefficient（HTC）distribution were obtained.The effects of heat flux,inlet velocity and inlet temperature on temperature distribution and pressure drop of a water-cooled W/Cu divertor were also investigated.These results provide a valuable reference for the thermal-hydraulic design of a water-cooled W/Cu divertor.

he Design of Efficient Heat Transfer Based on Flat Plate Solar Water Heater

This is an improved design based on the existing plate type solar water heaters. It aims at making full use of solar energy. To fully absorb radiation, it absorbs coating selectively by adopting the magnetron sputtering technology AL-N/AL. this design conduct heat through aluminum material which can reduce the cost meanwhile conduct heat effectively. To ensure the quality of the water at the same time improve the utilization rate of solar energy, this design use phase change for second heat exchange. Take Shanghai for example, where this design and heat transfer model are applied, the average efficiency of water heaters can achieve 68%, which has proven the feasibility of the design. In a word, this design can achieve the goal of energy conservation and emissions reduction and has broad market prospects.

Analysis of surface cracking in water-cooled rolls and heat transfer between furnace chamber and rolls in a direct flame furnace

In the direct fired furnace of a continuous annealing line, seal rolls are susceptible to deformation that leads to surface defects of steel strips. According to failure analysis, the reasons include improper structural design and heat imbalance. An improved design has been proposed to reduce stress concentration and thermal radiation. A heat transfer model has been employed to determine the proper water flow rate for roll cooling. Industrial application proves that seal rolls with the new design has less deformation and longer service life.

Forced Convection Boiling Heat Transfer and Dryout Characteristics in Helical Coiled Tubes with Various Axial Angles

对水和水蒸汽汽液两相流体在螺旋轴呈各种倾角放置的螺旋管内强制对流沸腾传热与烧毁特性进行了系统地试验研究，试验中系统及结构参数范围如下：压力：Ｐ＝０．４～３．０ＭＰａ质量流速：Ｇ＝１００～２４００ｋｇ／ｍ２·ｓ进口水温：Ｔ＝３０～８０℃出口干度：ｘ＝－０．０５～１．２管内壁面热负荷：ｑ＝０～５４０ｋＥ／ｍ２试验段结构参数：总长Ｌ＝６４４８ｍｍ，管内径ｄ＝１１ｍｍ，螺旋直径Ｄ＝２５６ｍｍ，螺旋升角β＝４．２７°螺旋管轴向放置倾角：水平位置（０°）、向上倾斜４５°（＋４５°）、垂直向上（＋９０°）、向下倾斜４５°（－４５°）．共进行了１０５０个工况的试验．试验结果表明，螺旋管内汽液两相流强制对流沸腾传热可以划分为核态沸腾区、两相流强制对流区、烧毁及烧毁后传热区等３种区域．通过数据处理和分析总结，给出了３区域间转变的边界方程，和３个区域内两相流传热系数的计算公式．根据试验观察和数据结果，对烧毁现象及烧毁点或区域发生的条件及机理进行了深入的分析研究，发现一系列有关现象的规律和特点，指出了其主要影响因素，并给出了烧毁点临界质量干度的预报公式．

Water and heat transport in hilly red soil of southern China:I. Experiment and analysis

Studies on coupled transfer of soil moisture and heat have been widely carried out for decades. However, little work has been done on red soils, widespread in southern China. The simultaneous transfer of soil moisture and heat depends on soil physical properties and the climate conditions. Red soil is heavy clay and high content of free iron and aluminum oxide. The climate conditions are characterized by the clear four seasons and the serious seasonal drought. The great annual and diurnal air temperature differences result in significant fluctuation in soil temperature in top layer. The closed and evaporating columns experiments with red soil were conducted to simulate the coupled transfer of soil water and heat under the overlaying and opening fields’ conditions, and to analyze the effects of soil temperature gradient on the water transfer and the effects of initial soil water contents on the transfer of soil water and heat. The closed and evaporating columns were designed similarly with about 18 °C temperatures differences between the top and bottom boundary, except of the upper end closed or exposed to the air, respectively. Results showed that in the closed column, water moved towards the cold end driven by temperature gradient, while the transported water decreased with the increasing initial soil water content until the initial soil water content reached to field capacity equivalent, when almost no changes for the soil moisture profile. In the evaporating column, the net transport of soil water was simultaneously driven by evaporation and temperature gradients, and the drier soil was more influenced by temperature gradient than by evapo- ration. In drier soil, it took a longer time for the temperature to reach equilibrium, because of more net amount of transported water.

Water and heat transport in hilly red soil of southern China:II. Modeling and simulation

Simulation models of heat and water transport have not been rigorously tested for the red soils of southern China. Based on the theory of nonisothermal water-heat coupled transfer, a simulation model, programmed in Visual Basic 6.0, was developed to predict the coupled transfer of water and heat in hilly red soil. A series of soil column experiments for soil water and heat transfer, including soil columns with closed and evaporating top ends, were used to test the simulation model. Results showed that in the closed columns, the temporal and spatial distribution of moisture and heat could be very well predicted by the model, while in the evaporating columns, the simulated soil water contents were somewhat different from the observed ones. In the heat flow equation by Taylor and Lary (1964), the effect of soil water evaporation on the heat flow is not involved, which may be the main reason for the differences between simulated and observed results. The predicted temperatures were not in agreement with the observed one with thermal conductivities calculated by de Vries and Wierenga equations, so that it is suggested that Kh, soil heat conductivity, be multiplied by 8.0 for the first 6.5 h and by 1.2 later on. Sensitivity analysis of soil water and heat coefficients showed that the saturated hydraulic conductivity, KS, and the water diffusivity, D(θ), had great effects on soil water transport; the variation of soil porosity led to the difference of soil thermal properties, and accordingly changed temperature redistribution, which would affect water redistribution.

Performance enhancement of water bath heater at natural gas city gate station using twisted tubes

Natural gas is transported from producing regions to consumption regions by using transmission pipelines at high pressures. At consumption regions, the pressure of natural gas is reduced in city gate stations(CGSs). Before the pressure reduction process, the temperature of natural gas is increased usually by using a water bath heater,which burns natural gas as fuel, to protect against freezing of natural gas. These types of heat exchangers have a low efficiency and consume a lot of fuel to generate the required heat. In the current study, the twisted configuration of the heating coil is proposed and investigated to enhance the heat transfer through a water bath heater with a nominal capacity of 1000 m^3·h^-1. Firstly, the implementation procedure is validated with data collected from the CGS of Qaleh-Jiq(located in Golestan province of Iran). A very good agreement is achieved between the obtained results and the real data. Then, three different twist ratios are considered to examine the twisting effects. The proposed technique is evaluated in the terms of velocity, temperature, and pressure variations, and the results are compared with the conventional case, i.e. straight configuration. It is found that both the heat transfer rate and the pressure drop augment as the twist ratio is raised. Finally, it is concluded that the twisted tubes can reduce the length of the gas coil by about 12.5% for the model with low twist ratio, 18.75% for the model with medium twist ratio, and 25% for the model with high twist ratio as compared to the straight configuration.

Effect of SEN structure on the mold level fluctuation and heat transfer for a medium thin slab caster

It is important to select suitable parameters of a submerged entry nozzle （SEN） for optimizing the flow and temperature patterns in a mold. The effect of SEN design on the mould level stability, meniscus steel flow velocity, and heat transfer of the mold of a medium thin slab caster was studied by means of 1：1 water modeling and industrial testing. The advantages of a 2-port SEN compared with a 3-port SEN are the following： more optimal flow patterns with a lower mold level fluctuation and a lower meniscus steel flow velocity; proper powder consumption without slag bears due to a reasonable liquid powder thickness. The argon flow rate can be reduced and the mold average heat flux and temperature near the edges of the copper plate are reduced. At a casting speed of 2.5 m·min^-1, the mold level fluctuation lies within ＋5 mm. In addition, soft cooling of the steel shell in the mold is realized, which is suitable for casting crack susceptible steel grades.

Performance of Heat Transfer Correlations Adopted at Supercritical Pressures: A Review

Research activities involving heat transfer at supercritical pressures have attracted attention in recent years because of possibility of increase in thermal output of heat transfer and industrial equipment. Because of high pressure and temperature conditions associated with heat transfer at supercritical pressures, only few experimental heat transfer studies are being carried out at supercritical conditions. The use of numerical tools for heat transfer and other related studies at supercritical pressures is increasing because of the high-pressure-temperature limitation of experimental studies at supercritical conditions. Heat transfer correlations implemented in these numerical tools are used to obtain numerical heat transfer data to complement experimental heat transfer data provided through experimental studies. In order to further broaden the understanding of fluid flow and heat transfer, this review examines the performance of heat transfer correlations adopted at supercritical pressures. It is found from the review that most of the correlations could predict heat transfer quite well in the low enthalpy region and few of the correlations could predict heat transfer in the high enthalpy region near critical and pseudo-critical conditions (heat transfer deteriorated conditions). However, no single heat transfer correlation is able to accurately predict all the experimental results presented in this work.

On the Effect of Mist Flow on the Heat Transfer Performances of a Three-Copper- Sphere Configuration

The cooling of a(pebble bed)spent fuel in a high-temperature gas-cooled reactor(HTGR)is adversely affected by an increase in the temperature of the used gas(air).To investigate this problem,a configuration consisting of three copper spheres arranged in tandem subjected to a forced mistflow inside a cylindrical channel is considered.The heat transfer coefficients and related variations as a function of Reynolds number are investigated accord-ingly.The experimental results show that when compared to those with only airflow,the heat transfer coefficient of the spherical elements with mistflow(j=112 kg/m2 hr,Re=55000)increases by 180%,75%,and 20%,respec-tively for thefirst,second,and third spherical element(the corresponding heat transfer enhancement ratio being 2.3,1.4,and 1.1).Additional numerical simulations reveal that the presence of stagnant zones with intense vortex formation around each spherical element contributes significantly to determine the heat transfer behavior.