This paper discusses the two-block large-scale nonconvex optimization problem with general linear constraints.Based on the ideas of splitting and sequential quadratic optimization(SQO),a new feasible descent method fo...This paper discusses the two-block large-scale nonconvex optimization problem with general linear constraints.Based on the ideas of splitting and sequential quadratic optimization(SQO),a new feasible descent method for the discussed problem is proposed.First,we consider the problem of quadratic optimal(QO)approximation associated with the current feasible iteration point,and we split the QO into two small-scale QOs which can be solved in parallel.Second,a feasible descent direction for the problem is obtained and a new SQO-type method is proposed,namely,splitting feasible SQO(SF-SQO)method.Moreover,under suitable conditions,we analyse the global convergence,strong convergence and rate of superlinear convergence of the SF-SQO method.Finally,preliminary numerical experiments regarding the economic dispatch of a power system are carried out,and these show that the SF-SQO method is promising.展开更多
A method to synthesize anticancer drug N-( 4- hydroxyphenyl) retinamide (4-HPR)on a large scale is described. It consists of the preferred steps of reacting all-trans retinoic acid with thionyl chloride to form re...A method to synthesize anticancer drug N-( 4- hydroxyphenyl) retinamide (4-HPR)on a large scale is described. It consists of the preferred steps of reacting all-trans retinoic acid with thionyl chloride to form retinoyl chloride and then reacting with triethylamine to generate retinoyl ammonium salt which in turn is reacted with p-aminophenol to eventually produce 4-HPR. This process can overcome many scale-up challenges that exist in the methods reported in the literature and provide an easy, mild and high yield route for large scale synthesis of 4-HPR. Moreover, the effects of the molar ratios of the reagents on the yield are examined. The best molar ratios are a 2.0 molar equivalence of thionyl chloride and a 3.0 molar equivalence of paminophenol to retinoic acid, and the total yield is 80. 7%.展开更多
The present study proposes a sub-grid scale model for the one-dimensional Burgers turbulence based on the neuralnetwork and deep learning method.The filtered data of the direct numerical simulation is used to establis...The present study proposes a sub-grid scale model for the one-dimensional Burgers turbulence based on the neuralnetwork and deep learning method.The filtered data of the direct numerical simulation is used to establish thetraining data set,the validation data set,and the test data set.The artificial neural network(ANN)methodand Back Propagation method are employed to train parameters in the ANN.The developed ANN is applied toconstruct the sub-grid scale model for the large eddy simulation of the Burgers turbulence in the one-dimensionalspace.The proposed model well predicts the time correlation and the space correlation of the Burgers turbulence.展开更多
A new limited memory symmetric rank one algorithm is proposed. It combines a modified self-scaled symmetric rank one (SSR1) update with the limited memory and nonmonotone line search technique. In this algorithm, th...A new limited memory symmetric rank one algorithm is proposed. It combines a modified self-scaled symmetric rank one (SSR1) update with the limited memory and nonmonotone line search technique. In this algorithm, the descent search direction is generated by inverse limited memory SSR1 update, thus simplifying the computation. Numerical comparison of the algorithm and the famous limited memory BFGS algorithm is given. Comparison results indicate that the new algorithm can process a kind of large-scale unconstrained optimization problems.展开更多
Based on surveying the conditions of large -scale farms and commercial manure in the each county of Yangzhou city, the situations and problems for utilization of livestock manure resources were grasped. After an analy...Based on surveying the conditions of large -scale farms and commercial manure in the each county of Yangzhou city, the situations and problems for utilization of livestock manure resources were grasped. After an analysis of the potential value of livestock manure, the suggestion and strategy for utilization of livestock manure resources were proposed based on the actual conditions in Yangzhou city.展开更多
This study investigates the dominant modes of variability in monthly and seasonal rainfall over the India-China region mainly through Empirical Orthogonal Function (EOF) analysis. The EOFs have shown that whereas the ...This study investigates the dominant modes of variability in monthly and seasonal rainfall over the India-China region mainly through Empirical Orthogonal Function (EOF) analysis. The EOFs have shown that whereas the rainfall over India varies as one coherent zone, that over China varies in east-west oriented bands. The influence of this banded structure extends well into India.Relationship of rainfall with large scale parameters such as the subtropical ridge over the Indian and the western Pacific regions, Southern Oscillation, the Northern Hemispheric surface air temperature and stratospheric winds have also been investigated. These results show that the rainfall over the area around 40°N, 110°E over China is highly related with rainfall over India. The subtropical ridge over the Indian region is an important predictor over India as well an over the northern China region. '展开更多
We study how to use the SR1 update to realize minimization methods for problems where the storage is critical. We give an update formula which generates matrices using information from the last m iterations. The numer...We study how to use the SR1 update to realize minimization methods for problems where the storage is critical. We give an update formula which generates matrices using information from the last m iterations. The numerical tests show that the method is efficent.展开更多
Steel mesh is used as a passive skin confinement medium to supplement the active support provided by rock bolts for roof and rib control in underground coal mines. Thin spray-on liners(TSL) are believed to have the po...Steel mesh is used as a passive skin confinement medium to supplement the active support provided by rock bolts for roof and rib control in underground coal mines. Thin spray-on liners(TSL) are believed to have the potential to take the place of steel mesh as the skin confinement medium in underground mines.To confirm this belief, large scale laboratory experiments were conducted to compare the behaviour of welded steel mesh and a TSL, when used in conjunction with rock bolts, in reinforcing strata with weak bedding planes and strata prone to guttering, two common rock conditions which exist in coal mines. It was found that while the peak load taken by the simulated rock mass with weak bedding planes acting as the control sample(no skin confinement) was 2494 kN, the corresponding value of the sample with 5 mm thick TSL reinforcement reached 2856 kN. The peak load of the steel mesh reinforced sample was only2321 kN, but this was attributed to the fact that one of the rock bolts broke during the test. The TSL reinforced sample had a similar post-yield behaviour as the steel mesh reinforced one. The results of the large scale guttering test indicated that a TSL is better than steel mesh in restricting rock movement and thus inhibiting the formation of gutters in the roof.展开更多
Physical testing of large-scale ship models at sea is a new experimental method.It is a cheap and reliable way to research the environment adaptability of a ship in complex and extreme wave conditions.It is necessary ...Physical testing of large-scale ship models at sea is a new experimental method.It is a cheap and reliable way to research the environment adaptability of a ship in complex and extreme wave conditions.It is necessary to have a stable experimental system for the test.Since the experimental area is large, a remote control system and a telemetry system are essential, and were designed by the authors.An experiment was conducted on the Songhuajiang River to test the systems.The relationship between the model's speed and its electromotor's revolutions was also measured during the model test.The results showed that the two systems make it possible to carry out large-scale model tests at sea.展开更多
This study reexamines the propagation mechanism and geostrophic property of the classical two-dimensional Rossby waves in a non-divergent barotropic atmosphere. It will be found that propagation of large scale atmosph...This study reexamines the propagation mechanism and geostrophic property of the classical two-dimensional Rossby waves in a non-divergent barotropic atmosphere. It will be found that propagation of large scale atmospheric waves depends crucially on horizontal divergence. A small Rossby number in Rossby waves is not sufficient for the waves to have a small ageostrophic component, because the two-dimensional classical Rossby waves do not manifest the geostrophic balance as good as observed in the atmosphere.展开更多
To cope with various unpredictable changes in large scale parts,the concept of reconfigurable manufacturing system (RMS) for machining these components is presented.Considering with large-size space measurement and th...To cope with various unpredictable changes in large scale parts,the concept of reconfigurable manufacturing system (RMS) for machining these components is presented.Considering with large-size space measurement and the fixed-free manufacture mode,an automatically localizing machining method for large scale part is studied in this paper,and the architecture of the RMS for machining large scale parts is proposed.According to the method and structure,the automatically localizing model is established.The theoretical analysis and simulation examples demonstrate the feasibility and validity of the proposed method,and the results indicate that the method is suitable and effective for machining large scale components in significant scientific projects.展开更多
Photocatalytic degradation of organic pollutants has become a hot research topic because of its low energy consumption and environmental-friendly characteristics.Bismuth oxide(Bi2O3)nanocrystals with a bandgap ranging...Photocatalytic degradation of organic pollutants has become a hot research topic because of its low energy consumption and environmental-friendly characteristics.Bismuth oxide(Bi2O3)nanocrystals with a bandgap ranging from 2.0 eV to 2.8 eV have attracted increasing attention due to high activity of photodegradation of organic pollutants by utilizing visible light.Though several methods have been developed to prepare Bi2O3-based semiconductor materials over recent years,it is still difficult to prepare highly active Bi2O3 catalysts in large scale with a simple method.Therefore,developing simple and feasible methods for the preparation of Bi2O3 nanocrystals in large scale is important for the potential applications in industrial wastewater treatment.In this work,we successfully prepared porous Bi2O3 in large scale via etching commercial Bi Sn powders,followed by thermal treatment with air.The acquired porous Bi2O3 exhibited excellent activity and stability in photocatalytic degradation of methylene blue.Further investigation of the mechanism witnessed that the suitable band structure of porous Bi2O3 allowed the generation of reactive oxygen species,such as O2^-·and·OH,which effectively degraded MB.展开更多
We have examined, in Part Ⅰ, the propagation mechanism and geostrophic property of classical Rossby waves in a non-divergent barotropic atmosphere. As we found that the non-divergent Rossby waves do not propagate in ...We have examined, in Part Ⅰ, the propagation mechanism and geostrophic property of classical Rossby waves in a non-divergent barotropic atmosphere. As we found that the non-divergent Rossby waves do not propagate in a hydrostatically equilibrium atmosphere, and do not manifest a good geostrophic property, an alternative large scale circulation pattern of geostrophic waves has been proposed (McHall, 1991a). The propagation mechanism and geostrophic property of these waves are examined in the present study.展开更多
It is a challenging topic to develop an efficient algorithm for large scale classification problems in many applications of machine learning. In this paper, a hierarchical clustering and fixed- layer local learning (...It is a challenging topic to develop an efficient algorithm for large scale classification problems in many applications of machine learning. In this paper, a hierarchical clustering and fixed- layer local learning (HCFLL) based support vector machine(SVM) algorithm is proposed to deal with this problem. Firstly, HCFLL hierarchically dusters a given dataset into a modified clustering feature tree based on the ideas of unsupervised clustering and supervised clustering. Then it locally trains SVM on each labeled subtree at a fixed-layer of the tree. The experimental results show that compared with the existing popular algorithms such as core vector machine and decision.tree support vector machine, HCFLL can significantly improve the training and testing speeds with comparable testing accuracy.展开更多
Based on the annual frequency data of tropical cyclones from 1960 to 2005 and by the polynomial fit and statistical analysis, this work has discovered that TC activity in the 46a exhibits significant decadal-scale var...Based on the annual frequency data of tropical cyclones from 1960 to 2005 and by the polynomial fit and statistical analysis, this work has discovered that TC activity in the 46a exhibits significant decadal-scale variability. It has two high frequency periods (HFP) and two low frequency periods (LFP). Significant differences in the number of TCs between HFP and LFP are found in active TC seasons from July to October. Differences of large-scale circulation during HFP and LFP have been investigated with NCEP/NOAA data for the season. In HFP, the condition includes not only higher sea surface temperature, lower sea level pressure, larger divergence of upper air, larger relative vorticity at low levels and smaller vertical shear, but also 500-hPa wind vector being more available for TC activity and moving to western North Pacific, the position of the subtropical anticyclone over the western Pacific shifting more northward, and South Asian Anticyclone at 100-hPa being much smaller than that in LFP. The precipitation of western North Pacific has no clear influence on TC activity.展开更多
Eddy-damping quasinormal Markovian (EDQNM) theory is employed to calculate the resolved-scale spectrum and transfer spectrum, based on which we investigate the resolved-scale scaling law. Results show that the scali...Eddy-damping quasinormal Markovian (EDQNM) theory is employed to calculate the resolved-scale spectrum and transfer spectrum, based on which we investigate the resolved-scale scaling law. Results show that the scaling law of the resolved-scale turbulence, which is affected by several factors, is far from that of the full-scale turbulence and should be corrected. These results are then applied to an existing subgrid model to improve its performance. A series of simulations are performed to verify the necessity of a fixed scaling law in the subgrid modeling.展开更多
The optimal control problem for nonlinear interconnected large-scale dynamic systems is considered. A successive approximation approach for designing the optimal controller is proposed with respect to quadratic perfor...The optimal control problem for nonlinear interconnected large-scale dynamic systems is considered. A successive approximation approach for designing the optimal controller is proposed with respect to quadratic performance indexes. By using the approach, the high order, coupling,nonlinear two-point boundary value (TPBV) problem is transformed into a sequence of linear decoupling TPBV problems. It is proven that the TPBV problem sequence uniformly converges to the optimal control for nonlinear interconnected large-scale systems. A suboptimal control law is obtained by using a finite iterative result of the optimal control sequence.展开更多
Knowledge of the statistical characteristics of inversions and their effects on aerosols under different large-scale synoptic circulations is important for studying and modeling the diffusion of pollutants in the boun...Knowledge of the statistical characteristics of inversions and their effects on aerosols under different large-scale synoptic circulations is important for studying and modeling the diffusion of pollutants in the boundary layer. Based on results gen- erated using the self-organizing map (SOM) weather classification method, this study compares the statistical characteristics of surface-based inversions (SBIs) and elevated inversions (EIs), and quantitatively evaluates the effect of SBIs on aerosol condensation nuclei (CN) concentrations and the relationship between temperature gradients and aerosols for six prevailing synoptic patterns over the the Southern Great Plains (SGP) site during 2001-10. Large-scale synoptic patterns strongly influ- ence the statistical characteristics of inversions and the accumulation of aerosols in the low-level atmosphere. The activity, frequency, intensity, and vertical distribution of inversions are significantly different among these synoptic patterns. The verti- cal distribution of inversions varies diurnally and is significantly different among the different synoptic patterns. Anticyclonic patterns affect the accumulation of aerosols near the ground more strongly than cyclonic patterns. Mean aerosol CN con- centrations increase during SBIs compared to no inversion cases by 16.1%, 22.6%, 24.5%, 58.7%, 29.8% and 23.7% for the six synoptic patterns. This study confirms that there is a positive correlation between temperature gradients and aerosol CN concentrations near the ground at night under similar large-scale synoptic patterns. The relationship is different for different synoptic patterns and can be described by linear functions. These findings suggest that large-scale synoptic patterns change the static stability of the atmosphere and inversions in the lower atmosphere, thereby influencing the diffusion of aerosols near the ground.展开更多
The current research of large eddy simulation (LES) of turbulent flow in pumps mainly concentrates in applying conventional subgrid-scale (SGS) model to simulate turbulent flow, which aims at obtaining the flow fi...The current research of large eddy simulation (LES) of turbulent flow in pumps mainly concentrates in applying conventional subgrid-scale (SGS) model to simulate turbulent flow, which aims at obtaining the flow field in pump. The selection of SGS model is usually not considered seriously, so the accuracy and efficiency of the simulation cannot be ensured. Three SGS models including Smagorinsky-Lilly model, dynamic Smagorinsky model and dynamic mixed model are comparably studied by using the commercial CFD code Fluent combined with its user define function. The simulations are performed for the turbulent flow in a centrifugal pump impeller. The simulation results indicate that the mean flows predicted by the three SGS models agree well with the experimental data obtained from the test that detailed measurements of the flow inside the rotating passages of a six-bladed shrouded centrifugal pump impeller performed using particle image velocimetry (PIV) and laser Doppler velocimetry (LDV). The comparable results show that dynamic mixed model gives the most accurate results for mean flow in the centrifugal pump impeller. The SGS stress of dynamic mixed model is decompose into the scale similar part and the eddy viscous part. The scale similar part of SGS stress plays a significant role in high curvature regions, such as the leading edge and training edge of pump blade. It is also found that the dynamic mixed model is more adaptive to compute turbulence in the pump impeller. The research results presented is useful to improve the computational accuracy and efficiency of LES for centrifugal pumps, and provide important reference for carrying out simulation in similar fluid machineries.展开更多
Millimeter wave(mmWave) and large-scale multiple input multiple output(MIMO) are two emerging technologies in fifth-generation wireless communication systems. The power consumption and hardware cost of radio frequency...Millimeter wave(mmWave) and large-scale multiple input multiple output(MIMO) are two emerging technologies in fifth-generation wireless communication systems. The power consumption and hardware cost of radio frequency(RF) chains increase exponentially with the bit resolution of analog-to-digital converters(ADCs) and digital-to-analog converters(DACs). One promising solution is to employ few RF chains with low-bit ADCs and DACs. In this paper, we consider mmWave large-scale MIMO systems with low bits DACs and ADCs. Leveraging on the Bussgang theorem and the additive quantization noise model(AQNM), a closed-form expression of the achievable rate is derived to show the effect of the ADCs? and DACs? resolution. Moreover, an orthogonal matching pursuit(OMP) based hybrid precoding algorithm is proposed to increase the achievable rate. Our results show that the impact of DACs is more pronounced than the impact of ADCs. Furthermore, 5-bit ADCs and DACs are sufficient at the transceiver to operate without a significant performance loss.展开更多
基金supported by the National Natural Science Foundation of China(12171106)the Natural Science Foundation of Guangxi Province(2020GXNSFDA238017 and 2018GXNSFFA281007)the Shanghai Sailing Program(21YF1430300)。
文摘This paper discusses the two-block large-scale nonconvex optimization problem with general linear constraints.Based on the ideas of splitting and sequential quadratic optimization(SQO),a new feasible descent method for the discussed problem is proposed.First,we consider the problem of quadratic optimal(QO)approximation associated with the current feasible iteration point,and we split the QO into two small-scale QOs which can be solved in parallel.Second,a feasible descent direction for the problem is obtained and a new SQO-type method is proposed,namely,splitting feasible SQO(SF-SQO)method.Moreover,under suitable conditions,we analyse the global convergence,strong convergence and rate of superlinear convergence of the SF-SQO method.Finally,preliminary numerical experiments regarding the economic dispatch of a power system are carried out,and these show that the SF-SQO method is promising.
文摘A method to synthesize anticancer drug N-( 4- hydroxyphenyl) retinamide (4-HPR)on a large scale is described. It consists of the preferred steps of reacting all-trans retinoic acid with thionyl chloride to form retinoyl chloride and then reacting with triethylamine to generate retinoyl ammonium salt which in turn is reacted with p-aminophenol to eventually produce 4-HPR. This process can overcome many scale-up challenges that exist in the methods reported in the literature and provide an easy, mild and high yield route for large scale synthesis of 4-HPR. Moreover, the effects of the molar ratios of the reagents on the yield are examined. The best molar ratios are a 2.0 molar equivalence of thionyl chloride and a 3.0 molar equivalence of paminophenol to retinoic acid, and the total yield is 80. 7%.
基金supported by the National Key R&D Program of China(Grant No.2022YFB3303500).
文摘The present study proposes a sub-grid scale model for the one-dimensional Burgers turbulence based on the neuralnetwork and deep learning method.The filtered data of the direct numerical simulation is used to establish thetraining data set,the validation data set,and the test data set.The artificial neural network(ANN)methodand Back Propagation method are employed to train parameters in the ANN.The developed ANN is applied toconstruct the sub-grid scale model for the large eddy simulation of the Burgers turbulence in the one-dimensionalspace.The proposed model well predicts the time correlation and the space correlation of the Burgers turbulence.
基金the National Natural Science Foundation of China(10471062)the Natural Science Foundation of Jiangsu Province(BK2006184)~~
文摘A new limited memory symmetric rank one algorithm is proposed. It combines a modified self-scaled symmetric rank one (SSR1) update with the limited memory and nonmonotone line search technique. In this algorithm, the descent search direction is generated by inverse limited memory SSR1 update, thus simplifying the computation. Numerical comparison of the algorithm and the famous limited memory BFGS algorithm is given. Comparison results indicate that the new algorithm can process a kind of large-scale unconstrained optimization problems.
基金Cultivated Land Quality Monitoring Special Funds in Jiangsu Province,Jiangsu Agricultural Three Engineerings(sx(2010)229)Yangzhou Agricultural Science and Technology Project(YZ2010059)Aid
文摘Based on surveying the conditions of large -scale farms and commercial manure in the each county of Yangzhou city, the situations and problems for utilization of livestock manure resources were grasped. After an analysis of the potential value of livestock manure, the suggestion and strategy for utilization of livestock manure resources were proposed based on the actual conditions in Yangzhou city.
文摘This study investigates the dominant modes of variability in monthly and seasonal rainfall over the India-China region mainly through Empirical Orthogonal Function (EOF) analysis. The EOFs have shown that whereas the rainfall over India varies as one coherent zone, that over China varies in east-west oriented bands. The influence of this banded structure extends well into India.Relationship of rainfall with large scale parameters such as the subtropical ridge over the Indian and the western Pacific regions, Southern Oscillation, the Northern Hemispheric surface air temperature and stratospheric winds have also been investigated. These results show that the rainfall over the area around 40°N, 110°E over China is highly related with rainfall over India. The subtropical ridge over the Indian region is an important predictor over India as well an over the northern China region. '
文摘We study how to use the SR1 update to realize minimization methods for problems where the storage is critical. We give an update formula which generates matrices using information from the last m iterations. The numerical tests show that the method is efficent.
文摘Steel mesh is used as a passive skin confinement medium to supplement the active support provided by rock bolts for roof and rib control in underground coal mines. Thin spray-on liners(TSL) are believed to have the potential to take the place of steel mesh as the skin confinement medium in underground mines.To confirm this belief, large scale laboratory experiments were conducted to compare the behaviour of welded steel mesh and a TSL, when used in conjunction with rock bolts, in reinforcing strata with weak bedding planes and strata prone to guttering, two common rock conditions which exist in coal mines. It was found that while the peak load taken by the simulated rock mass with weak bedding planes acting as the control sample(no skin confinement) was 2494 kN, the corresponding value of the sample with 5 mm thick TSL reinforcement reached 2856 kN. The peak load of the steel mesh reinforced sample was only2321 kN, but this was attributed to the fact that one of the rock bolts broke during the test. The TSL reinforced sample had a similar post-yield behaviour as the steel mesh reinforced one. The results of the large scale guttering test indicated that a TSL is better than steel mesh in restricting rock movement and thus inhibiting the formation of gutters in the roof.
基金Supported by the National Defense Foundation under Grant No.51414030204CB0109
文摘Physical testing of large-scale ship models at sea is a new experimental method.It is a cheap and reliable way to research the environment adaptability of a ship in complex and extreme wave conditions.It is necessary to have a stable experimental system for the test.Since the experimental area is large, a remote control system and a telemetry system are essential, and were designed by the authors.An experiment was conducted on the Songhuajiang River to test the systems.The relationship between the model's speed and its electromotor's revolutions was also measured during the model test.The results showed that the two systems make it possible to carry out large-scale model tests at sea.
文摘This study reexamines the propagation mechanism and geostrophic property of the classical two-dimensional Rossby waves in a non-divergent barotropic atmosphere. It will be found that propagation of large scale atmospheric waves depends crucially on horizontal divergence. A small Rossby number in Rossby waves is not sufficient for the waves to have a small ageostrophic component, because the two-dimensional classical Rossby waves do not manifest the geostrophic balance as good as observed in the atmosphere.
基金Funded by the National Natural Science Foundation of Chinathe Development Program for Outstanding Young Teachers in Harbin Institute of Technology
文摘To cope with various unpredictable changes in large scale parts,the concept of reconfigurable manufacturing system (RMS) for machining these components is presented.Considering with large-size space measurement and the fixed-free manufacture mode,an automatically localizing machining method for large scale part is studied in this paper,and the architecture of the RMS for machining large scale parts is proposed.According to the method and structure,the automatically localizing model is established.The theoretical analysis and simulation examples demonstrate the feasibility and validity of the proposed method,and the results indicate that the method is suitable and effective for machining large scale components in significant scientific projects.
基金the National Natural Science Foundation of China(No.51801235,No.11875258,No.11505187,No.51374255,No.51802356,No.51572299,and No.41701359)the Innovation-Driven Project of Central South University(No.2018CX004)+4 种基金the Start-up Funding of Central South University(No.502045005)the Fundamental Research Funds for the Central Universities(No.WK2310000066,No.WK2060190081)Posdoctoral Science Foundation of China(No.2019M652797)Central South University Postdoctoral Research Opening Fundthe Fundamental Research Funds for the Central Universities of Central South University(No.2018zzts402)。
文摘Photocatalytic degradation of organic pollutants has become a hot research topic because of its low energy consumption and environmental-friendly characteristics.Bismuth oxide(Bi2O3)nanocrystals with a bandgap ranging from 2.0 eV to 2.8 eV have attracted increasing attention due to high activity of photodegradation of organic pollutants by utilizing visible light.Though several methods have been developed to prepare Bi2O3-based semiconductor materials over recent years,it is still difficult to prepare highly active Bi2O3 catalysts in large scale with a simple method.Therefore,developing simple and feasible methods for the preparation of Bi2O3 nanocrystals in large scale is important for the potential applications in industrial wastewater treatment.In this work,we successfully prepared porous Bi2O3 in large scale via etching commercial Bi Sn powders,followed by thermal treatment with air.The acquired porous Bi2O3 exhibited excellent activity and stability in photocatalytic degradation of methylene blue.Further investigation of the mechanism witnessed that the suitable band structure of porous Bi2O3 allowed the generation of reactive oxygen species,such as O2^-·and·OH,which effectively degraded MB.
文摘We have examined, in Part Ⅰ, the propagation mechanism and geostrophic property of classical Rossby waves in a non-divergent barotropic atmosphere. As we found that the non-divergent Rossby waves do not propagate in a hydrostatically equilibrium atmosphere, and do not manifest a good geostrophic property, an alternative large scale circulation pattern of geostrophic waves has been proposed (McHall, 1991a). The propagation mechanism and geostrophic property of these waves are examined in the present study.
基金National Natural Science Foundation of China ( No. 61070033 )Fundamental Research Funds for the Central Universities,China( No. 2012ZM0061)
文摘It is a challenging topic to develop an efficient algorithm for large scale classification problems in many applications of machine learning. In this paper, a hierarchical clustering and fixed- layer local learning (HCFLL) based support vector machine(SVM) algorithm is proposed to deal with this problem. Firstly, HCFLL hierarchically dusters a given dataset into a modified clustering feature tree based on the ideas of unsupervised clustering and supervised clustering. Then it locally trains SVM on each labeled subtree at a fixed-layer of the tree. The experimental results show that compared with the existing popular algorithms such as core vector machine and decision.tree support vector machine, HCFLL can significantly improve the training and testing speeds with comparable testing accuracy.
基金National Key Fundamental Research and Development Plan of China (2004CB418303)Natural Science Foundation of China (40425009 40233028)
文摘Based on the annual frequency data of tropical cyclones from 1960 to 2005 and by the polynomial fit and statistical analysis, this work has discovered that TC activity in the 46a exhibits significant decadal-scale variability. It has two high frequency periods (HFP) and two low frequency periods (LFP). Significant differences in the number of TCs between HFP and LFP are found in active TC seasons from July to October. Differences of large-scale circulation during HFP and LFP have been investigated with NCEP/NOAA data for the season. In HFP, the condition includes not only higher sea surface temperature, lower sea level pressure, larger divergence of upper air, larger relative vorticity at low levels and smaller vertical shear, but also 500-hPa wind vector being more available for TC activity and moving to western North Pacific, the position of the subtropical anticyclone over the western Pacific shifting more northward, and South Asian Anticyclone at 100-hPa being much smaller than that in LFP. The precipitation of western North Pacific has no clear influence on TC activity.
基金supported by the National Natural Science Foundation of China(11202013 and 51136003)the National Basic Research Program of China(2012CB720200)the Opening fundof State Key Laboratory of Nonlinear Mechanics
文摘Eddy-damping quasinormal Markovian (EDQNM) theory is employed to calculate the resolved-scale spectrum and transfer spectrum, based on which we investigate the resolved-scale scaling law. Results show that the scaling law of the resolved-scale turbulence, which is affected by several factors, is far from that of the full-scale turbulence and should be corrected. These results are then applied to an existing subgrid model to improve its performance. A series of simulations are performed to verify the necessity of a fixed scaling law in the subgrid modeling.
基金Supported by National Natural Science Foundation of P. R. China (60074001)the Natural Science Foundation of Shandong Province (Y2000G02)
文摘The optimal control problem for nonlinear interconnected large-scale dynamic systems is considered. A successive approximation approach for designing the optimal controller is proposed with respect to quadratic performance indexes. By using the approach, the high order, coupling,nonlinear two-point boundary value (TPBV) problem is transformed into a sequence of linear decoupling TPBV problems. It is proven that the TPBV problem sequence uniformly converges to the optimal control for nonlinear interconnected large-scale systems. A suboptimal control law is obtained by using a finite iterative result of the optimal control sequence.
基金sponsored by the U.S. Department of Energy (DOE)supported by the Ministry of Science and Technology of China (Grant Nos. 2010CB950804 and 2013CB955801)+1 种基金the "Strategic Priority Research Program" of the Chinese Academy of Sciences (Grant No. XDA05100300)the National Natural Science Foundation of China (Grant No. 41305011)
文摘Knowledge of the statistical characteristics of inversions and their effects on aerosols under different large-scale synoptic circulations is important for studying and modeling the diffusion of pollutants in the boundary layer. Based on results gen- erated using the self-organizing map (SOM) weather classification method, this study compares the statistical characteristics of surface-based inversions (SBIs) and elevated inversions (EIs), and quantitatively evaluates the effect of SBIs on aerosol condensation nuclei (CN) concentrations and the relationship between temperature gradients and aerosols for six prevailing synoptic patterns over the the Southern Great Plains (SGP) site during 2001-10. Large-scale synoptic patterns strongly influ- ence the statistical characteristics of inversions and the accumulation of aerosols in the low-level atmosphere. The activity, frequency, intensity, and vertical distribution of inversions are significantly different among these synoptic patterns. The verti- cal distribution of inversions varies diurnally and is significantly different among the different synoptic patterns. Anticyclonic patterns affect the accumulation of aerosols near the ground more strongly than cyclonic patterns. Mean aerosol CN con- centrations increase during SBIs compared to no inversion cases by 16.1%, 22.6%, 24.5%, 58.7%, 29.8% and 23.7% for the six synoptic patterns. This study confirms that there is a positive correlation between temperature gradients and aerosol CN concentrations near the ground at night under similar large-scale synoptic patterns. The relationship is different for different synoptic patterns and can be described by linear functions. These findings suggest that large-scale synoptic patterns change the static stability of the atmosphere and inversions in the lower atmosphere, thereby influencing the diffusion of aerosols near the ground.
基金supported by National Natural Science Foundation of China (Grant Nos. 51139007, 51079151, 51079152)Research Fundfor the Doctoral Program of Higher Education of China (Grant No. 0100008110012)
文摘The current research of large eddy simulation (LES) of turbulent flow in pumps mainly concentrates in applying conventional subgrid-scale (SGS) model to simulate turbulent flow, which aims at obtaining the flow field in pump. The selection of SGS model is usually not considered seriously, so the accuracy and efficiency of the simulation cannot be ensured. Three SGS models including Smagorinsky-Lilly model, dynamic Smagorinsky model and dynamic mixed model are comparably studied by using the commercial CFD code Fluent combined with its user define function. The simulations are performed for the turbulent flow in a centrifugal pump impeller. The simulation results indicate that the mean flows predicted by the three SGS models agree well with the experimental data obtained from the test that detailed measurements of the flow inside the rotating passages of a six-bladed shrouded centrifugal pump impeller performed using particle image velocimetry (PIV) and laser Doppler velocimetry (LDV). The comparable results show that dynamic mixed model gives the most accurate results for mean flow in the centrifugal pump impeller. The SGS stress of dynamic mixed model is decompose into the scale similar part and the eddy viscous part. The scale similar part of SGS stress plays a significant role in high curvature regions, such as the leading edge and training edge of pump blade. It is also found that the dynamic mixed model is more adaptive to compute turbulence in the pump impeller. The research results presented is useful to improve the computational accuracy and efficiency of LES for centrifugal pumps, and provide important reference for carrying out simulation in similar fluid machineries.
基金supported in part by the National Key R&D Program of China (No. 2016YFE0200900)Major Projects of Beijing Municipal Science and Technology Commission (No. Z181100003218010)+3 种基金National Natural Science Foundation of China (Nos. 61601020, 61725101 and U1834210)the Beijing Natural Science Foundation (Nos. 4182049, L171005 and L172020)the open research fund of National Mobile Communications Research Laboratory, Southeast University (No. 2018D04)Key Laboratory of Optical Communication and Networks (No. KLOCN2018002)
文摘Millimeter wave(mmWave) and large-scale multiple input multiple output(MIMO) are two emerging technologies in fifth-generation wireless communication systems. The power consumption and hardware cost of radio frequency(RF) chains increase exponentially with the bit resolution of analog-to-digital converters(ADCs) and digital-to-analog converters(DACs). One promising solution is to employ few RF chains with low-bit ADCs and DACs. In this paper, we consider mmWave large-scale MIMO systems with low bits DACs and ADCs. Leveraging on the Bussgang theorem and the additive quantization noise model(AQNM), a closed-form expression of the achievable rate is derived to show the effect of the ADCs? and DACs? resolution. Moreover, an orthogonal matching pursuit(OMP) based hybrid precoding algorithm is proposed to increase the achievable rate. Our results show that the impact of DACs is more pronounced than the impact of ADCs. Furthermore, 5-bit ADCs and DACs are sufficient at the transceiver to operate without a significant performance loss.