Based on the observation of a model test and in combination with some theoretical analysis, the researches of some basic hydrodynamics characteristics of cavity spiral flow in a large size level pipe with a shaft-inle...Based on the observation of a model test and in combination with some theoretical analysis, the researches of some basic hydrodynamics characteristics of cavity spiral flow in a large size level pipe with a shaft-inlet is presented in the paper, which include the basic flow pattern, formation condition of the cavity spiral flow, discharge Q, cavity diameter d0, wall pressure coefficient Cpw, velocity distribution, total energy dissipation rate η etc. The results show that the basic flow patterns can be divided into three zones according to the variations in amount of ventilation Ф, cavity diameter d0 and gas pressure p0 within cavity spiral flow when the upstream and downstream water level changes and that the basic hydrodynamics characteristics change with the flow pattern and have the different behaviour.展开更多
Traditional method to prevent stored grain from deterioration is to control grain temperature.A three dimensional(3-D)numerical model was established to study the temperature variation in outdoor squat silo and large ...Traditional method to prevent stored grain from deterioration is to control grain temperature.A three dimensional(3-D)numerical model was established to study the temperature variation in outdoor squat silo and large size horizontal warehouse at quasi-steady-state.In this research,porous media model and solar radiation model were adopted.Numerical and experimental results showed that grain temperature was influenced by temperature of wall,height of grain and the distance between grain and the wall.Temperature changes dramatically at the top layer of grain heap due to solar radiation and heat convection at air layer.Temperature of grain close to wall increased with the increasing of ambient temperature.The model established in this research is suitable for predicting grain temperature in outdoor squat silo and large size horizontal warehouse.展开更多
The pneumatic conveying system of coal particles can greatly reduce the dust and improve the environmental quality at underground mining workface and the surrounding of coal enterprises.The particle shape and the inte...The pneumatic conveying system of coal particles can greatly reduce the dust and improve the environmental quality at underground mining workface and the surrounding of coal enterprises.The particle shape and the interaction coefficients between particles and the contact surface play important roles in the pneumatic conveying and CFD-DEM simulation.In order to build the semblable shape models and obtain the accurate interaction coefficients of large coal particles,this article establishes the con tact model by the particle overlap method and describes the mathematical model of the shape characteristics for large coal particle.The particle models are simulated by adopting the multi-index mixed orthogonal experiments.The accumulation density,the porosity and the error between simulation and experiment are taken as the indexes,and the particle models and the particle contact coefficients are taken as the orthogonal test factors.As a result,three more accurate particle models and their interaction coefficients are obtained,which provide the model basis for the pneumatic conveying of large coal particles.展开更多
The kinetics of austenite formation in the surface and center regions of a 40 t forged ingot of a high-strength medium- carbon low-alloy steel was studied using high-resolution dilatometry. The starting microstructure...The kinetics of austenite formation in the surface and center regions of a 40 t forged ingot of a high-strength medium- carbon low-alloy steel was studied using high-resolution dilatometry. The starting microstructures from the surface or center regions had different proportions of bainite and residual austenite as well as different prior austenite grain sizes. Two heating rates representing the actual heating rates in the surface (5℃ s -1) and center regions (0.5℃ s -1) of large size forged blocks were utilized. Dilatometric curves revealed only one transformation step of austenite formation at both heating rates independent of grain size or proportion of phases. Optical microscopy, field emission gun scanning electron microscopy and X-ray diffraction were used to study microstructure evolution and confirm the results obtained by dilatometry. The kinetic parameters for austenite formation were determined from the dilatometry data by Johnson-Mehl- Avrami-Kolmogorov (JMAK) equation. The JMAK coefficients were determined for each condition of the investigated steels. The calculations indicated that the nucleation and growth of austenite in the surface region were accelerated more than 10,000 times due to a significantly smaller average prior austenite grain size, stability of initial retained austenite, and accumulation of coarse carbides at the surface. The results were discussed in the framework of classical nucleation and growth theories using the kinetic parameters for austenite formation.展开更多
Crystalline rare-earth(RE)carbonates having large particle size were prepared from the lixivium of weathered crust elution-deposited rare-earth ores using the precipitation method with ammonium bicarbonate as the prec...Crystalline rare-earth(RE)carbonates having large particle size were prepared from the lixivium of weathered crust elution-deposited rare-earth ores using the precipitation method with ammonium bicarbonate as the precipitant.Their chemical composition was studied using elemental and thermogravimetric analyses(TGA),and their structure and morphology were characterized using Fourier transform infrared(FTIR)spectroscopy,X-ray diffraction(XRD),and scanning electron microscopy(SEM).The results demonstrate that the crystalline rareearth carbonate is a hydrated basic carbonate or oxycarbonate and not astable intermediate carbonate in the process of thermal decomposition.The particle size of crystalline rare-earth carbonates with large particle size is in the range of 50–200μm.With an RE2O3 content of up to 95wt%,the quality of crystalline rare-earth carbonates is higher compared to the Chinese National Standard(GB/T 28882–2012).The quality of the product is superior to the Chinese National Standard.展开更多
After finishing 102 replicate constant amplitude crack initiation and growth tests on Ly12-CZ aluminum alloy plate, a statistical investigation of the fatigue crack initiation and growth process is conducted in this p...After finishing 102 replicate constant amplitude crack initiation and growth tests on Ly12-CZ aluminum alloy plate, a statistical investigation of the fatigue crack initiation and growth process is conducted in this paper. According to the post-mortem fractographic examination by scanning electron microscopy (SEM), some qualitative observations of the spacial correlation among fatigue striations are developed to reveal the statistical nature of material intrinsic inhomogeneity during the crack growth process. From the test data, an engineering division between crack initiation and growth is defined as the upper limit of small crack. The distributions of crack initiation life N-i, growth life N, and the statistical characteristics of crack growth rate da/dN are also investigated. It is hoped that the work will provide a solid test basis for the study of probabilistic fatigue, probabilistic fracture mechanics, fatigue reliability and its engineering applications.展开更多
A waterproof nanocrystalline soft magnetic alloy core with a size of O.D.850 mm×I.D.316 mm×H.25 mm for radio frequency acceleration was successfully developed by winding 18μm 1k107b MA ribbons.Theμ'_(p...A waterproof nanocrystalline soft magnetic alloy core with a size of O.D.850 mm×I.D.316 mm×H.25 mm for radio frequency acceleration was successfully developed by winding 18μm 1k107b MA ribbons.Theμ'_(p)Qf products reached 7.5,10,and 12 GHz at 1,3,and 5 MHz,respectively.Theμ'_(p)Qf products of the MA core(O.D.250 mm×I.D.100 mm×H.25 mm)manufactured using a 13μm MA ribbon further increased by 30%.Detailed improvements on the MA core manufacture process are discussed herein.Continuous high-power tests on the new MA cores demonstrated its good performance of waterproofness,particularly its stability of highμ'_(p)Qf products.The MA core with highμ'pQf product and large size can operate under a high average RF power,high electric field,and in deionized water,which will be used in the China Spallation Neutron Source PhaseⅡ(CSNS-Ⅱ).展开更多
The quality of MAPbI3 film prepared by solvent engineering process highly depends on environment and antisolvent control.Here,we provided a simple methylamine chloride(MACl)solution treatment using a two-step process ...The quality of MAPbI3 film prepared by solvent engineering process highly depends on environment and antisolvent control.Here,we provided a simple methylamine chloride(MACl)solution treatment using a two-step process to enlarge the perovskite crystal grain sizes to more than 1 lm.Other than treatment on the film surface,the MACl solution diffuses into the MAPbI_(3) films to assist the recrystallization of small crystal at the bottom of perovskite film.The imitative contact between perovskite and substrate is formed.Meanwhile,the enlargement of grain size and ten times enhancement of crystalline reduce trap-assisted recombination of perovskite films.Thus,the significant improvement of cell efficiency of 20.89%as well as device stability is obtained with the MACl treatment.展开更多
The non-noble metal modified sulfated zirconia was found easy to deactivate.Herein,highly active and highly stable non-noble core-shell Ni-S_(2)O_(8)^(2−)/Al_(2)O_(3)@ZrO_(2) catalysts(Ni-SA@Z-x,x=Al content in wt%)ha...The non-noble metal modified sulfated zirconia was found easy to deactivate.Herein,highly active and highly stable non-noble core-shell Ni-S_(2)O_(8)^(2−)/Al_(2)O_(3)@ZrO_(2) catalysts(Ni-SA@Z-x,x=Al content in wt%)have been successfully prepared and investigated for n-pentane isomerization.The results showed that the core-shell Ni-SA@Z-30 provided a sustained high isopentane yield(63.1%)with little or no deactivation within 5000 min at a mild reaction pressure of 2.0 MPa,which can be attributed to the following factors:(i)carbon deposition was greatly suppressed by the large pore size and huge pore volume;(ii)the loss of sulfur entities was suppressed because the small and highly dispersed tetragonal ZrO_(2) particles can bond with the S species strongly;(iii)strong Brønsted acidity can be maintained well after the isomerization.The pore structures and acid nature of the core-shell Ni-SA@Z-x are entirely different from those of the normal structure Ni-S_(2)O_(8)^(2−)/ZrO_(2)-Al_(2)O_(3),even though the Al content and the compositions of the individual components are the same.The Al_(2)O_(3)cores endow the catalysts with high internal surface area and high mechanical strength.Meanwhile,the ZrO_(2) shell,which consists of more and smaller tetragonal ZrO_(2) particles because of the large surface area of the Al_(2)O_(3)core,promotes the formation of more stable sulfur species and stronger binding sites.展开更多
Owing to its anisotropic optical and electrical properties,rhenium diselenide(ReSe2)has garnered considerable attention recently as a candidate material for polarization-sensitive photodetectors.However,the direct and...Owing to its anisotropic optical and electrical properties,rhenium diselenide(ReSe2)has garnered considerable attention recently as a candidate material for polarization-sensitive photodetectors.However,the direct and controllable synthesis of large-sized ReSe2 with a uniform thickness is still a great challenge.Herein,we have refined the synthesis method to obtain uniform monolayer ReSe2 flakes with a size of up to^106μm on sapphire via an ambient-pressure chemical vapor deposition technique using Na promoter from sodium chloride.Interestingly,optical pump-probe spectroscopy revealed a fast switching from saturable absorption(SA)to absorption enhancement(AE)in subpicosecond time scale,followed by a slower decay induced by exciton recombination.Furthermore,both AE and SA signals exhibited clear angular dependence with a periodicity of 180°,which reflected the dichroism in nonlinear absorption dynamics.In addition,the photocarrier dynamics including free-carrier transport and subpicosecond relaxation due to exciton formation or surface trapping was probed using time resolved terahertz spectroscopy.We believe that our study serves as a reference for atomically controlled synthesis of large-sized ReSe2 and provides useful insights on its optoelectronic properties for novel device applications.展开更多
Large size vessels sailing in continuous level ice and broken ice of high concentration are mostly assisted by icebreakers.This is done in order to provide for fast transportation through the North Sea Route and safe ...Large size vessels sailing in continuous level ice and broken ice of high concentration are mostly assisted by icebreakers.This is done in order to provide for fast transportation through the North Sea Route and safe operation in extreme ice conditions.Currently,new large size gas and oil carriers and container ships are being designed and built with beams much greater than the beams of existing icebreakers.At the same time,no mathematical description exists for the breaking mechanism of ice channel edges,when such vessels move under icebreaker escort.This paper suggests a simple method for assessment of the ice resistance in the case of a large ship running in an icebreaker channel;the method is based on modification of well-known semi-empirical methods for calculation of the ice resistance to ships in level and broken ice.The main feature of the proposed calculation scheme consists in that different methods are applied to estimate the ice resistance in broken ice and due to breaking of level ice edges.The combination of these methods gives a deliverable ice resistance of a large size vessel moving under icebreaker assistance in a newly made ice channel.In general,proposed method allows to define the speed of a carrier moving in an ice channel behind a modern linear icebreaker and could be applied at the ship design stage and during development of the marine transportation system.The paper also discusses the ways for further refinement of the assessment procedure suggested.展开更多
The largest movable mold EMS developed by POSCO in collaboration with Daineli-Rotelec for improving internal quality of a large CC bloom is being used at a large size bloom caster of POSCO since 2011.Internal quality ...The largest movable mold EMS developed by POSCO in collaboration with Daineli-Rotelec for improving internal quality of a large CC bloom is being used at a large size bloom caster of POSCO since 2011.Internal quality of carbon steel CC bloom of 700×700 mm~2 section size with the mold EMS was much improved compared with without the mold EMS.Equiaxed zone ratio increased from 50%to 100%and the grain of equiaxed structure became globular and fine.Top shrinkage was also much reduced by applying the movable mold EMS.展开更多
Perovskite solar cells in a fiber format have great potential for wearable electronics due to their excellent flexibility,efficient light harvesting,and potentially high power conversion efficiency(PCE).However,the fa...Perovskite solar cells in a fiber format have great potential for wearable electronics due to their excellent flexibility,efficient light harvesting,and potentially high power conversion efficiency(PCE).However,the fabrication of large-sized fiber perovskite solar cells(FPSCs)while maintaining high efficiency remains a major challenge because of the difficulty in the formation of uniform crystalline perovskite films on highly curved surfaces.Here,we report a scale-up automatic approach for the fabrication of large-sized FPSCs via sequential coating of active layers on fiber substrates and posttreatment of perovskite films.We focus on understanding the perovskite film formation process on fibers and manage to control the film thickness,morphology,and crystallinity by adjusting the coating speed,precursor solution aging time,and posttreatment.As a result,a 20.0-cm-long FPSC with a PCE of 7.63%is achieved,and this length is almost ten times longer than those of the previously reported FPSCs.Our work represents a breakthrough in fabricating large-sized high-efficiency FPSCs,which will ultimately lead to practical applications of FPSCs.展开更多
Due to their excellent physical and chemical properties,boron nitride nanosheets(BNNSs)have shown great application potential in many fields.However,the difficulty in scalable preparation of large-size BNNSs is still ...Due to their excellent physical and chemical properties,boron nitride nanosheets(BNNSs)have shown great application potential in many fields.However,the difficulty in scalable preparation of large-size BNNSs is still the current factor that limits this.Herein,a simple yet efficient microwave-assisted chemical exfoliation strategy is proposed to realize scalable preparation of BNNSs by using perchloric acid as the edge modifier and intercalation agent of h-BN.The as-obtained BNNSs behave a thin-layered structure(average thickness of 3.9 nm)with a high yield of~16%.Noteworthy,the size of BNNSs is maintained to the greatest extent so as to realize the preparation of BNNSs with ultra-large size(up to 7.1μm),which is the largest so far obtained for the top-down exfoliated BNNSs.Benefiting from the large size,it can significantly improve the thermal diffusion coefficient and the thermal conductivity of polyvinyl alcohol by 51 and 62 times respectively,both showing a higher value than the one previously reported.This demonstrates that the prepared BNNSs have great promise in enhancing the thermal conductivity of polymer materials.展开更多
Developing large,soft grippers with high omnidirectional load(above 40 kg)has always been challenging.We address this challenge by developing a powerful soft gripper that can grasp the human body based on a soft-enclo...Developing large,soft grippers with high omnidirectional load(above 40 kg)has always been challenging.We address this challenge by developing a powerful soft gripper that can grasp the human body based on a soft-enclosed grasping structure and a soft-rigid coupling structure.The envelope size of the proposed soft gripper is 611.6 mm×559 mm×490.7 mm,the maximum grasping size is 417 mm,and the payload on the human body is more than 90 kg,which has exceeded most existing soft grippers.Furthermore,the grasping force prediction of the gripper is achieved through theoretical modeling.The primary contribution of this work is to overcome the size and payload limits of current soft grippers and implement a human-grasping experiment based on the soft-grasping method.展开更多
Operations in assembling and joining large size aircraft components are changed to novel digital and flexible ways by digital measurement assisted alignment.Positions and orientations(P&O)of aligned components are ...Operations in assembling and joining large size aircraft components are changed to novel digital and flexible ways by digital measurement assisted alignment.Positions and orientations(P&O)of aligned components are critical characters which assure geometrical positions and relationships of those components.Therefore,evaluating the P&O of a component is considered necessary and critical for ensuring accuracy in aircraft assembly.Uncertainty of position and orientation(U-P&O),as a part of the evaluating result of P&O,needs to be given for ensuring the integrity and credibility of the result;furthermore,U-P&O is necessary for error tracing and quality evaluating of measurement assisted aircraft assembly.However,current research mainly focuses on the process integration of measurement with assembly,and usually ignores the uncertainty of measured result and its influence on quality evaluation.This paper focuses on the expression,analysis,and application of U-P&O in measurement assisted alignment.The geometrical and algebraical connotations of U-P&O are presented.Then,an analytical algorithm for evaluating the multi-dimensional U-P&O is given,and the effect factors and characteristics of U-P&O are discussed.Finally,U-P&O is used to evaluate alignment in aircraft assembly for quality evaluating and improving.Cases are introduced with the methodology.展开更多
The Compact Muon Solenoid (CMS) at LHC intends to use a high rate trapezoid MRPC for the muon system upgrade, but the size of the MRPC is limited by the dimensions of low resistivity glass. We have designed a protot...The Compact Muon Solenoid (CMS) at LHC intends to use a high rate trapezoid MRPC for the muon system upgrade, but the size of the MRPC is limited by the dimensions of low resistivity glass. We have designed a prototype of a large MRPC in which the electrodes are developed by gluing two pieces of glass plates. Simulation of the weighting field and cosmic ray test shows that the efficiency of the glued MRPC is higher than 96% and the time resolution is better than 71 ps.展开更多
Three-dimensional(3D)covalent organic frameworks(COFs)possess great potential applications in various fields.Constructing 3D COFs with large pore sizes is extremely challenging due to the interpenetration and collapse...Three-dimensional(3D)covalent organic frameworks(COFs)possess great potential applications in various fields.Constructing 3D COFs with large pore sizes is extremely challenging due to the interpenetration and collapse.Herein,we report a series of crystalline imine-linked 3D COFs(3D-bor-COF-1,3D-borCOF-2,3D-bor-COF-3)with mesoporous channels through rationally designing the topology configuration.These 3D-bor-COFs display permanent porosity and Brunauer–Emmett–Teller(BET)surfaces of 3205.5,1752.7,and 2077.3 m2 g−1(SLangmuir=4277.7,2480.3,and 2698.0 m2 g−1),respectively.The pore sizes of 3Dbor-COFs were confirmed by the lattice fringes from high-resolution transmission electron microscopy,as well as structural simulation and nitrogen adsorption isotherm analysis.3D-bor-COFs display large pore sizes(3.8 nm for 3D-borCOF-3),which is among the highest record of 3D COFs.Owing to the unstackedaromatic pore environment and high specific surface area,3D-bor-COFs display excellent adsorption capacity for benzene vapor(1203.9 mg g−1 for 3D-bor-COF-3)under 298 K,which is three times higher than that of the best-reported 2D COF.This work not only provides inspiration for designing 3D mesoporous imineCOFs,but also demonstrates a strategy for constructing aromatics adsorption materials.展开更多
An efficient and accurate exponential wave integrator Fourier pseudospectral (EWI-FP) method is proposed and analyzed for solving the symmetric regularized-long-wave (SRLW) equation, which is used for modeling the...An efficient and accurate exponential wave integrator Fourier pseudospectral (EWI-FP) method is proposed and analyzed for solving the symmetric regularized-long-wave (SRLW) equation, which is used for modeling the weakly nonlinear ion acoustic and space-charge waves. The numerical method here is based on a Gautschi-type exponential wave integrator for temporal approximation and the Fourier pseudospectral method for spatial discretization. The scheme is fully explicit and efficient due to the fast Fourier transform. Numerical analysis of the proposed EWI-FP method is carried out and rigorous error estimates are established without CFL-type condition by means of the mathematical induction. The error bound shows that EWI-FP has second order accuracy in time and spectral accuracy in space. Numerical results are reported to confirm the theoretical studies and indicate that the error bound here is optimal.展开更多
文摘Based on the observation of a model test and in combination with some theoretical analysis, the researches of some basic hydrodynamics characteristics of cavity spiral flow in a large size level pipe with a shaft-inlet is presented in the paper, which include the basic flow pattern, formation condition of the cavity spiral flow, discharge Q, cavity diameter d0, wall pressure coefficient Cpw, velocity distribution, total energy dissipation rate η etc. The results show that the basic flow patterns can be divided into three zones according to the variations in amount of ventilation Ф, cavity diameter d0 and gas pressure p0 within cavity spiral flow when the upstream and downstream water level changes and that the basic hydrodynamics characteristics change with the flow pattern and have the different behaviour.
基金National Natural Science Foundation of China(31271972)University Science and Technology Innovation Team Support Plan of Henan Province,China in 2016(16IRTSTHN009).
文摘Traditional method to prevent stored grain from deterioration is to control grain temperature.A three dimensional(3-D)numerical model was established to study the temperature variation in outdoor squat silo and large size horizontal warehouse at quasi-steady-state.In this research,porous media model and solar radiation model were adopted.Numerical and experimental results showed that grain temperature was influenced by temperature of wall,height of grain and the distance between grain and the wall.Temperature changes dramatically at the top layer of grain heap due to solar radiation and heat convection at air layer.Temperature of grain close to wall increased with the increasing of ambient temperature.The model established in this research is suitable for predicting grain temperature in outdoor squat silo and large size horizontal warehouse.
基金the Natural Science Foundation ofjiangsu Province(BK20170241)the National Natural Science Foundation of China(51705222 and 51675521)supported by the State Key Laboratory of Process Automation in Mining&Metallurgy and the Beijing Key Laboratory of Process Automation in Mining&Metallurgy(BGRIMM-KZSKL-2019-07).
文摘The pneumatic conveying system of coal particles can greatly reduce the dust and improve the environmental quality at underground mining workface and the surrounding of coal enterprises.The particle shape and the interaction coefficients between particles and the contact surface play important roles in the pneumatic conveying and CFD-DEM simulation.In order to build the semblable shape models and obtain the accurate interaction coefficients of large coal particles,this article establishes the con tact model by the particle overlap method and describes the mathematical model of the shape characteristics for large coal particle.The particle models are simulated by adopting the multi-index mixed orthogonal experiments.The accumulation density,the porosity and the error between simulation and experiment are taken as the indexes,and the particle models and the particle contact coefficients are taken as the orthogonal test factors.As a result,three more accurate particle models and their interaction coefficients are obtained,which provide the model basis for the pneumatic conveying of large coal particles.
文摘The kinetics of austenite formation in the surface and center regions of a 40 t forged ingot of a high-strength medium- carbon low-alloy steel was studied using high-resolution dilatometry. The starting microstructures from the surface or center regions had different proportions of bainite and residual austenite as well as different prior austenite grain sizes. Two heating rates representing the actual heating rates in the surface (5℃ s -1) and center regions (0.5℃ s -1) of large size forged blocks were utilized. Dilatometric curves revealed only one transformation step of austenite formation at both heating rates independent of grain size or proportion of phases. Optical microscopy, field emission gun scanning electron microscopy and X-ray diffraction were used to study microstructure evolution and confirm the results obtained by dilatometry. The kinetic parameters for austenite formation were determined from the dilatometry data by Johnson-Mehl- Avrami-Kolmogorov (JMAK) equation. The JMAK coefficients were determined for each condition of the investigated steels. The calculations indicated that the nucleation and growth of austenite in the surface region were accelerated more than 10,000 times due to a significantly smaller average prior austenite grain size, stability of initial retained austenite, and accumulation of coarse carbides at the surface. The results were discussed in the framework of classical nucleation and growth theories using the kinetic parameters for austenite formation.
基金This work was financially supported by the National Natural Science Foundation of China(Nos.51964021 and 51774156)the Jiangxi Province Nature Science Foundation,China(No.20181BAB206020)and China’s National Key R&D Plan Project(No.2019YFC0605000).
文摘Crystalline rare-earth(RE)carbonates having large particle size were prepared from the lixivium of weathered crust elution-deposited rare-earth ores using the precipitation method with ammonium bicarbonate as the precipitant.Their chemical composition was studied using elemental and thermogravimetric analyses(TGA),and their structure and morphology were characterized using Fourier transform infrared(FTIR)spectroscopy,X-ray diffraction(XRD),and scanning electron microscopy(SEM).The results demonstrate that the crystalline rareearth carbonate is a hydrated basic carbonate or oxycarbonate and not astable intermediate carbonate in the process of thermal decomposition.The particle size of crystalline rare-earth carbonates with large particle size is in the range of 50–200μm.With an RE2O3 content of up to 95wt%,the quality of crystalline rare-earth carbonates is higher compared to the Chinese National Standard(GB/T 28882–2012).The quality of the product is superior to the Chinese National Standard.
基金The project is supported by the Aeronautic Science Foundation,China
文摘After finishing 102 replicate constant amplitude crack initiation and growth tests on Ly12-CZ aluminum alloy plate, a statistical investigation of the fatigue crack initiation and growth process is conducted in this paper. According to the post-mortem fractographic examination by scanning electron microscopy (SEM), some qualitative observations of the spacial correlation among fatigue striations are developed to reveal the statistical nature of material intrinsic inhomogeneity during the crack growth process. From the test data, an engineering division between crack initiation and growth is defined as the upper limit of small crack. The distributions of crack initiation life N-i, growth life N, and the statistical characteristics of crack growth rate da/dN are also investigated. It is hoped that the work will provide a solid test basis for the study of probabilistic fatigue, probabilistic fracture mechanics, fatigue reliability and its engineering applications.
基金supported by the funds of the National Natural Science Foundation of China (Nos. 11175194, 11875270, and U1832210)Youth Innovation Promotion Association CAS (No. 2018015)Guangdong Basic and Applied Basic Research Foundation (No.2019B1515120046)
文摘A waterproof nanocrystalline soft magnetic alloy core with a size of O.D.850 mm×I.D.316 mm×H.25 mm for radio frequency acceleration was successfully developed by winding 18μm 1k107b MA ribbons.Theμ'_(p)Qf products reached 7.5,10,and 12 GHz at 1,3,and 5 MHz,respectively.Theμ'_(p)Qf products of the MA core(O.D.250 mm×I.D.100 mm×H.25 mm)manufactured using a 13μm MA ribbon further increased by 30%.Detailed improvements on the MA core manufacture process are discussed herein.Continuous high-power tests on the new MA cores demonstrated its good performance of waterproofness,particularly its stability of highμ'_(p)Qf products.The MA core with highμ'pQf product and large size can operate under a high average RF power,high electric field,and in deionized water,which will be used in the China Spallation Neutron Source PhaseⅡ(CSNS-Ⅱ).
基金financially supported by the National Key R&D Program of China (Grant No. 2020YFB1506404)the 111 Project (Grant No. B16016)+1 种基金the National Natural Science Foundation of China (Grant Nos. 51961165106, 51572080 and 61904053)the Fundamental Research Funds for the Central Universities (Grant Nos. 2019MS026, 2019MS027 and 2020MS080)。
文摘The quality of MAPbI3 film prepared by solvent engineering process highly depends on environment and antisolvent control.Here,we provided a simple methylamine chloride(MACl)solution treatment using a two-step process to enlarge the perovskite crystal grain sizes to more than 1 lm.Other than treatment on the film surface,the MACl solution diffuses into the MAPbI_(3) films to assist the recrystallization of small crystal at the bottom of perovskite film.The imitative contact between perovskite and substrate is formed.Meanwhile,the enlargement of grain size and ten times enhancement of crystalline reduce trap-assisted recombination of perovskite films.Thus,the significant improvement of cell efficiency of 20.89%as well as device stability is obtained with the MACl treatment.
文摘The non-noble metal modified sulfated zirconia was found easy to deactivate.Herein,highly active and highly stable non-noble core-shell Ni-S_(2)O_(8)^(2−)/Al_(2)O_(3)@ZrO_(2) catalysts(Ni-SA@Z-x,x=Al content in wt%)have been successfully prepared and investigated for n-pentane isomerization.The results showed that the core-shell Ni-SA@Z-30 provided a sustained high isopentane yield(63.1%)with little or no deactivation within 5000 min at a mild reaction pressure of 2.0 MPa,which can be attributed to the following factors:(i)carbon deposition was greatly suppressed by the large pore size and huge pore volume;(ii)the loss of sulfur entities was suppressed because the small and highly dispersed tetragonal ZrO_(2) particles can bond with the S species strongly;(iii)strong Brønsted acidity can be maintained well after the isomerization.The pore structures and acid nature of the core-shell Ni-SA@Z-x are entirely different from those of the normal structure Ni-S_(2)O_(8)^(2−)/ZrO_(2)-Al_(2)O_(3),even though the Al content and the compositions of the individual components are the same.The Al_(2)O_(3)cores endow the catalysts with high internal surface area and high mechanical strength.Meanwhile,the ZrO_(2) shell,which consists of more and smaller tetragonal ZrO_(2) particles because of the large surface area of the Al_(2)O_(3)core,promotes the formation of more stable sulfur species and stronger binding sites.
基金The work was supported by the National Key Research and Development Program of China(Nos.2018YFA0703700,2017YFA0304600,and 2017YFA0205700)the National Natural Science Foundation of China(Nos.51861135201,21473001,11774354,11674329,and 51727806)+4 种基金Beijing Natural Science Foundation(No.2192021)the Project funded by China Postdoctoral Science Foundation(No.2018M640023)Chinese Academy of Science(No.YZJJ201705)Open Research Fund Program of the State Key Laboratory of Low-dimensional Quantum Physics(No.KF201907)Start-up Funding of Peking University.
文摘Owing to its anisotropic optical and electrical properties,rhenium diselenide(ReSe2)has garnered considerable attention recently as a candidate material for polarization-sensitive photodetectors.However,the direct and controllable synthesis of large-sized ReSe2 with a uniform thickness is still a great challenge.Herein,we have refined the synthesis method to obtain uniform monolayer ReSe2 flakes with a size of up to^106μm on sapphire via an ambient-pressure chemical vapor deposition technique using Na promoter from sodium chloride.Interestingly,optical pump-probe spectroscopy revealed a fast switching from saturable absorption(SA)to absorption enhancement(AE)in subpicosecond time scale,followed by a slower decay induced by exciton recombination.Furthermore,both AE and SA signals exhibited clear angular dependence with a periodicity of 180°,which reflected the dichroism in nonlinear absorption dynamics.In addition,the photocarrier dynamics including free-carrier transport and subpicosecond relaxation due to exciton formation or surface trapping was probed using time resolved terahertz spectroscopy.We believe that our study serves as a reference for atomically controlled synthesis of large-sized ReSe2 and provides useful insights on its optoelectronic properties for novel device applications.
基金This work was funded by the Russian Science Foundation(Grant No.17-79-20162-П).
文摘Large size vessels sailing in continuous level ice and broken ice of high concentration are mostly assisted by icebreakers.This is done in order to provide for fast transportation through the North Sea Route and safe operation in extreme ice conditions.Currently,new large size gas and oil carriers and container ships are being designed and built with beams much greater than the beams of existing icebreakers.At the same time,no mathematical description exists for the breaking mechanism of ice channel edges,when such vessels move under icebreaker escort.This paper suggests a simple method for assessment of the ice resistance in the case of a large ship running in an icebreaker channel;the method is based on modification of well-known semi-empirical methods for calculation of the ice resistance to ships in level and broken ice.The main feature of the proposed calculation scheme consists in that different methods are applied to estimate the ice resistance in broken ice and due to breaking of level ice edges.The combination of these methods gives a deliverable ice resistance of a large size vessel moving under icebreaker assistance in a newly made ice channel.In general,proposed method allows to define the speed of a carrier moving in an ice channel behind a modern linear icebreaker and could be applied at the ship design stage and during development of the marine transportation system.The paper also discusses the ways for further refinement of the assessment procedure suggested.
文摘The largest movable mold EMS developed by POSCO in collaboration with Daineli-Rotelec for improving internal quality of a large CC bloom is being used at a large size bloom caster of POSCO since 2011.Internal quality of carbon steel CC bloom of 700×700 mm~2 section size with the mold EMS was much improved compared with without the mold EMS.Equiaxed zone ratio increased from 50%to 100%and the grain of equiaxed structure became globular and fine.Top shrinkage was also much reduced by applying the movable mold EMS.
基金supported by the National Natural Science Foundation of China(Grant No.52073002,51773003,and 51711540302)National Key Research and Development Program of China(Grant No.2020YFB1506400).
文摘Perovskite solar cells in a fiber format have great potential for wearable electronics due to their excellent flexibility,efficient light harvesting,and potentially high power conversion efficiency(PCE).However,the fabrication of large-sized fiber perovskite solar cells(FPSCs)while maintaining high efficiency remains a major challenge because of the difficulty in the formation of uniform crystalline perovskite films on highly curved surfaces.Here,we report a scale-up automatic approach for the fabrication of large-sized FPSCs via sequential coating of active layers on fiber substrates and posttreatment of perovskite films.We focus on understanding the perovskite film formation process on fibers and manage to control the film thickness,morphology,and crystallinity by adjusting the coating speed,precursor solution aging time,and posttreatment.As a result,a 20.0-cm-long FPSC with a PCE of 7.63%is achieved,and this length is almost ten times longer than those of the previously reported FPSCs.Our work represents a breakthrough in fabricating large-sized high-efficiency FPSCs,which will ultimately lead to practical applications of FPSCs.
基金Projects 52172052 and 51872253 supported by the National Natural Science Foundation of ChinaProject E2019203480 supported by the Hebei Natural Science Foundation of China.
文摘Due to their excellent physical and chemical properties,boron nitride nanosheets(BNNSs)have shown great application potential in many fields.However,the difficulty in scalable preparation of large-size BNNSs is still the current factor that limits this.Herein,a simple yet efficient microwave-assisted chemical exfoliation strategy is proposed to realize scalable preparation of BNNSs by using perchloric acid as the edge modifier and intercalation agent of h-BN.The as-obtained BNNSs behave a thin-layered structure(average thickness of 3.9 nm)with a high yield of~16%.Noteworthy,the size of BNNSs is maintained to the greatest extent so as to realize the preparation of BNNSs with ultra-large size(up to 7.1μm),which is the largest so far obtained for the top-down exfoliated BNNSs.Benefiting from the large size,it can significantly improve the thermal diffusion coefficient and the thermal conductivity of polyvinyl alcohol by 51 and 62 times respectively,both showing a higher value than the one previously reported.This demonstrates that the prepared BNNSs have great promise in enhancing the thermal conductivity of polymer materials.
基金supported by the National Natural Science Foundation of China (Grant No.51975505)the Ningbo Natural Science Foundation of China (Grant No.2022J134)the Open Research Project of the State Key Laboratory of Industrial Control Technology,Zhejiang University,China (Grant No.ICT 2022B14)。
文摘Developing large,soft grippers with high omnidirectional load(above 40 kg)has always been challenging.We address this challenge by developing a powerful soft gripper that can grasp the human body based on a soft-enclosed grasping structure and a soft-rigid coupling structure.The envelope size of the proposed soft gripper is 611.6 mm×559 mm×490.7 mm,the maximum grasping size is 417 mm,and the payload on the human body is more than 90 kg,which has exceeded most existing soft grippers.Furthermore,the grasping force prediction of the gripper is achieved through theoretical modeling.The primary contribution of this work is to overcome the size and payload limits of current soft grippers and implement a human-grasping experiment based on the soft-grasping method.
基金support of National Natural Science Foundation of China (No.50905010)Fund of National Engineering and Research Center for Commercial Aircraft Manufacturing (No.SAMC12-JS-15-044)
文摘Operations in assembling and joining large size aircraft components are changed to novel digital and flexible ways by digital measurement assisted alignment.Positions and orientations(P&O)of aligned components are critical characters which assure geometrical positions and relationships of those components.Therefore,evaluating the P&O of a component is considered necessary and critical for ensuring accuracy in aircraft assembly.Uncertainty of position and orientation(U-P&O),as a part of the evaluating result of P&O,needs to be given for ensuring the integrity and credibility of the result;furthermore,U-P&O is necessary for error tracing and quality evaluating of measurement assisted aircraft assembly.However,current research mainly focuses on the process integration of measurement with assembly,and usually ignores the uncertainty of measured result and its influence on quality evaluation.This paper focuses on the expression,analysis,and application of U-P&O in measurement assisted alignment.The geometrical and algebraical connotations of U-P&O are presented.Then,an analytical algorithm for evaluating the multi-dimensional U-P&O is given,and the effect factors and characteristics of U-P&O are discussed.Finally,U-P&O is used to evaluate alignment in aircraft assembly for quality evaluating and improving.Cases are introduced with the methodology.
基金Supported by National Natural Science Foundation of China(11420101004,11461141011,11275108)Ministry of Science and Technology(2015CB856905)
文摘The Compact Muon Solenoid (CMS) at LHC intends to use a high rate trapezoid MRPC for the muon system upgrade, but the size of the MRPC is limited by the dimensions of low resistivity glass. We have designed a prototype of a large MRPC in which the electrodes are developed by gluing two pieces of glass plates. Simulation of the weighting field and cosmic ray test shows that the efficiency of the glued MRPC is higher than 96% and the time resolution is better than 71 ps.
基金National Natural Science Foundation of China,Grant/Award Number:52073161Tsinghua Initiative Scientific Research Program,Grant/Award Number:2021Z11GHX010。
文摘Three-dimensional(3D)covalent organic frameworks(COFs)possess great potential applications in various fields.Constructing 3D COFs with large pore sizes is extremely challenging due to the interpenetration and collapse.Herein,we report a series of crystalline imine-linked 3D COFs(3D-bor-COF-1,3D-borCOF-2,3D-bor-COF-3)with mesoporous channels through rationally designing the topology configuration.These 3D-bor-COFs display permanent porosity and Brunauer–Emmett–Teller(BET)surfaces of 3205.5,1752.7,and 2077.3 m2 g−1(SLangmuir=4277.7,2480.3,and 2698.0 m2 g−1),respectively.The pore sizes of 3Dbor-COFs were confirmed by the lattice fringes from high-resolution transmission electron microscopy,as well as structural simulation and nitrogen adsorption isotherm analysis.3D-bor-COFs display large pore sizes(3.8 nm for 3D-borCOF-3),which is among the highest record of 3D COFs.Owing to the unstackedaromatic pore environment and high specific surface area,3D-bor-COFs display excellent adsorption capacity for benzene vapor(1203.9 mg g−1 for 3D-bor-COF-3)under 298 K,which is three times higher than that of the best-reported 2D COF.This work not only provides inspiration for designing 3D mesoporous imineCOFs,but also demonstrates a strategy for constructing aromatics adsorption materials.
文摘An efficient and accurate exponential wave integrator Fourier pseudospectral (EWI-FP) method is proposed and analyzed for solving the symmetric regularized-long-wave (SRLW) equation, which is used for modeling the weakly nonlinear ion acoustic and space-charge waves. The numerical method here is based on a Gautschi-type exponential wave integrator for temporal approximation and the Fourier pseudospectral method for spatial discretization. The scheme is fully explicit and efficient due to the fast Fourier transform. Numerical analysis of the proposed EWI-FP method is carried out and rigorous error estimates are established without CFL-type condition by means of the mathematical induction. The error bound shows that EWI-FP has second order accuracy in time and spectral accuracy in space. Numerical results are reported to confirm the theoretical studies and indicate that the error bound here is optimal.