The effect of fiber laser on MIG arc was investigated with 8 mm 7075-T6 high strength aluminum alloy as base material.The arc shape,droplet transfer form and electrical signal in the process of MIG welding and laser-M...The effect of fiber laser on MIG arc was investigated with 8 mm 7075-T6 high strength aluminum alloy as base material.The arc shape,droplet transfer form and electrical signal in the process of MIG welding and laser-MIG hybrid welding were analyzed.The stability of the hybrid welding process was evaluated by standard deviation analysis.The results show that with the increase of laser power,a large number of laser-induced plasma enters the arc column area,providing more conductive channels,which makes the heat of MIG arc more concentrated and the short circuit transition disappear.Due to the continuous effect of laser,the keyhole becomes a continuous electron emission source,and a stable cathode spot will be formed near the keyhole,which enhances the stability of MIG arc at the base current state.By using the method of standard deviation analysis,the voltage standard deviation of single MIG welding arc and laser-MIG hybrid arc within 4 seconds was calculated.The standard deviation of single MIG arc voltage was 1.05,and the standard deviation of MIG arc voltage in laser-MIG hybrid welding was 0.71–0.86,so the hybrid welding process was more stable.展开更多
LF6 aluminum alloy plates with 4.5 mm thickness are welded in this experiment. Welding is carried out by using the CO2 laser-MIG paraxial hybrid welding in fiat position. The experimental results indicate that the inh...LF6 aluminum alloy plates with 4.5 mm thickness are welded in this experiment. Welding is carried out by using the CO2 laser-MIG paraxial hybrid welding in fiat position. The experimental results indicate that the inherent droplet transfer cycle time of conventional MIG arc is changed due to the interaction between CO2 laser beam and MIG arc in the short-circuiting mode of laser-MIG hybrid welding. Because of the preheating action of CO2 laser to electrode and base material, the droplet transfer frequency of MIG arc is increased in the hybrid welding process. When laser power is increased to a certain degree, the droplet transfer frequency is decreased due to the effect of laser-induced keyhole. Furthermore, through analyzing the MIG welding current and arc voltage waveforms and the characteristics of droplet transfer in the hybrid welding process, the effect of laser energy and the action point between laser beam and arc on the frequency of droplet transfer and weld appearance is investigated in details.展开更多
In this paper, 3 mm 6061 aluminum alloy sheets were welded by laser MIG hybrid welding. Based on the experiment, the best welding parameters were determined to ensure the penetration welding. The detailed microstructu...In this paper, 3 mm 6061 aluminum alloy sheets were welded by laser MIG hybrid welding. Based on the experiment, the best welding parameters were determined to ensure the penetration welding. The detailed microstructure,tensile and fatigue fracture morphology and surface fatigue damage of the welded joints were analyzed by optical microscope(OM), scanning electron microscope(SEM) and energy dispersive spectrometer(EDS). The results show that there are two main kinds of precipitates, one is the long Si rich precipitates at the grain boundaries, the other is the intragranular Cu rich precipitates. The tensile test results show that the tensile strength of the joint is 224 MPa, which is only 70.2% of the base metal. Through the analysis of tensile fracture, there are great differences in the formation of tensile dimple. In the tensile-tensile fatigue test with a stress rate of 0.1, the conditional fatigue limits of base metal and welded joint are 101.9 MPa and 54.4 MPa, respectively. By comparing the fatigue fracture of the welded joints under different stress amplitudes, it was found that the main factor leading to the fracture of the joint is porosity. Through further analysis of the pore defects, it was found that there are transgranular and intergranular propagation ways of microcracks in the pores, and the mixed propagation way was also found.展开更多
A mathematical model was established to simulate the weld pool development and dynamic process in stationary iaser-MlG hybrid welding. Surface tension and buoyancy were considered to calculate liquid metal flow patter...A mathematical model was established to simulate the weld pool development and dynamic process in stationary iaser-MlG hybrid welding. Surface tension and buoyancy were considered to calculate liquid metal flow patter, moreover, typical phenomena of MIG welding, such as filler droplets impinging weld pool, electromagnetic force in the weld pool, and typical phenomena of laser beam welding, such as recoil pressure, Inverse Bremsstrahlung absorption, Fresnel absorption were all considered in the model. The laser beam and arc couple effect were introduced into this model by the plasma width during hybrid welding. The role of recoil pressure in the weld formation was discussed. Transient weld pool shape and complicated liquid metal velocity distribution from two kinds weld pool to an unified weld pool were calculated. The simulated weld bead geometry with consideration recoil pressure was in good agreement with experimental measurement.展开更多
Laser-MIG hybrid welding experiments of 7 mm thick Invar alloy are carried out.The macro appearance of joints is observed and the influence of arc energy on the cross-section morphology is analyzed.The distribution of...Laser-MIG hybrid welding experiments of 7 mm thick Invar alloy are carried out.The macro appearance of joints is observed and the influence of arc energy on the cross-section morphology is analyzed.The distribution of temperature field is simulated to explain the relationship between heat effect and microstructure.Besides,the average grain size of weld under different arc energies is quantitatively studied.The results indicate that welded joints with uniformity and good formation are obtained.The weld width and the weld seam area increase and the depth to width ratio decreases with the increase of arc heat input.The transition of columnar crystals to equiaxed crystals is observed from the fusion line to the weld center.It is found that the higher the arc energy,the coarser the columnar crystal.展开更多
Purpose–This study aims to solve the problem of weld quality inspection,for the aluminum alloy profile welding structure of high-speed train body has complex internal shape and thin plate thickness(2–4 mm),the conve...Purpose–This study aims to solve the problem of weld quality inspection,for the aluminum alloy profile welding structure of high-speed train body has complex internal shape and thin plate thickness(2–4 mm),the conventional nondestructive testing method of weld quality is difficult to implement.Design/methodology/approach–In order to solve this problem,the ultrasonic creeping wave detection technology was proposed.The impact of the profile structure on the creeping wave detection was studied by designing profile structural test blocks and artificial simulation defect test blocks.The detection technology was used to test the actual welded test blocks,and compared with the results of X-ray test and destructive test(tensile test)to verify the accuracy of the ultrasonic creeping wave test results.Findings–It is indicated that that X-ray has better effect on the inspection of porosities and incomplete penetration defects.However,due to special detection method and protection,the detection speed is slow,which cannot meet the requirements of field inspection of the welding structure of aluminum alloy thin-walled profile for high-speed train body.It can be used as an auxiliary detection method for a small number of sampling inspection.The ultrasonic creeping wave can be used to detect the incomplete penetration welds with the equivalent of 0.25 mm or more,the results of creeping wave detection correspond well with the actual incomplete penetration defects.Originality/value–The results show that creeping wave detection results correspond well with the actual non-penetration defects and can be used for welding quality inspection of aluminum alloy thin-wall profile composite welding joints.It is recommended to use the echo amplitude of the 10 mm 30.2 mm 30.5 mm notch as the criterion for weld qualification.展开更多
Composites are widely applied to the manufacturing of aircraft in aviation. Forming of large-scale composite component in aircraft requires the corresponding mold with precise size. The laser-MIG hybrid welding has a ...Composites are widely applied to the manufacturing of aircraft in aviation. Forming of large-scale composite component in aircraft requires the corresponding mold with precise size. The laser-MIG hybrid welding has a significant advantage in the manufacturing of Invar mold for aircraft composites. This paper mainly introduces the application of the laser-MIG hybrid welding,and the distribution of thermal field and flow field on the Invar alloy laser-MIG hybrid three-layer welding is analyzed and discussed specifically.展开更多
The weld appearance, deposition rate, welding efficiency, stability of arc, laser keyhole characteristic, and weld property were studied by using a novel laser-MIG hybrid welding process with filling wire of aluminum ...The weld appearance, deposition rate, welding efficiency, stability of arc, laser keyhole characteristic, and weld property were studied by using a novel laser-MIG hybrid welding process with filling wire of aluminum alloy. The results were also compared with those by conventional laser-MIG hybrid welding process. It was found that with the suitable process parameters this novel welding process for aluminum alloy was stable and final weld bead had fine appearance. Compared to conventional laser-MIG hybrid welding process, during this novel welding process the stability of arc, the laser keyhole characteristic and the weld property were similar, while the keyhole cycle frequency and keyhole opening area had differences of 1.23% and 15.34%, respectively, and the welding efficiency increased by about 31% without increasing heat input.展开更多
Laser-MIG hybrid welding process was dealt with 6 mm thick 5083Hl16 Al-Mg alloy plate in butt-joint configuration. Weld formation principle during hybrid welding was explained. The joint properties and microstructure ...Laser-MIG hybrid welding process was dealt with 6 mm thick 5083Hl16 Al-Mg alloy plate in butt-joint configuration. Weld formation principle during hybrid welding was explained. The joint properties and microstructure characteristics of welded joints were analyzed by tensile tests, fractographs observed by optical microscopy and scanning electron microscopy (SEM). Higher heat input could obtain better mechanical properties, and tensile strength and elongation reached 97.2%, 81% of the base metal, respectively. Fracture position traasited from fusion line to weld center in the higher heat input, and fracture location were only in the center of welded joints for the heat input relatively small.展开更多
The demand for adopting neural networks in resource-constrained embedded devices is continuously increasing.Quantization is one of the most promising solutions to reduce computational cost and memory storage on embedd...The demand for adopting neural networks in resource-constrained embedded devices is continuously increasing.Quantization is one of the most promising solutions to reduce computational cost and memory storage on embedded devices.In order to reduce the complexity and overhead of deploying neural networks on Integeronly hardware,most current quantization methods use a symmetric quantization mapping strategy to quantize a floating-point neural network into an integer network.However,although symmetric quantization has the advantage of easier implementation,it is sub-optimal for cases where the range could be skewed and not symmetric.This often comes at the cost of lower accuracy.This paper proposed an activation redistribution-based hybrid asymmetric quantizationmethod for neural networks.The proposedmethod takes data distribution into consideration and can resolve the contradiction between the quantization accuracy and the ease of implementation,balance the trade-off between clipping range and quantization resolution,and thus improve the accuracy of the quantized neural network.The experimental results indicate that the accuracy of the proposed method is 2.02%and 5.52%higher than the traditional symmetric quantization method for classification and detection tasks,respectively.The proposed method paves the way for computationally intensive neural network models to be deployed on devices with limited computing resources.Codes will be available on https://github.com/ycjcy/Hybrid-Asymmetric-Quantization.展开更多
The rational design of metal single-atom catalysts(SACs)for electrochemical nitrogen reduction reaction(NRR)is challenging.Two-dimensional metal-organic frameworks(2DMOFs)is a unique class of promising SACs.Up to now,...The rational design of metal single-atom catalysts(SACs)for electrochemical nitrogen reduction reaction(NRR)is challenging.Two-dimensional metal-organic frameworks(2DMOFs)is a unique class of promising SACs.Up to now,the roles of individual metals,coordination atoms,and their synergy effect on the electroanalytic performance remain unclear.Therefore,in this work,a series of 2DMOFs with different metals and coordinating atoms are systematically investigated as electrocatalysts for ammonia synthesis using density functional theory calculations.For a specific metal,a proper metal-intermediate atoms p-d orbital hybridization interaction strength is found to be a key indicator for their NRR catalytic activities.The hybridization interaction strength can be quantitatively described with the p-/d-band center energy difference(Δd-p),which is found to be a sufficient descriptor for both the p-d hybridization strength and the NRR performance.The maximum free energy change(ΔG_(max))andΔd-p have a volcanic relationship with OsC_(4)(Se)_(4)located at the apex of the volcanic curve,showing the best NRR performance.The asymmetrical coordination environment could regulate the band structure subtly in terms of band overlap and positions.This work may shed new light on the application of orbital engineering in electrocatalytic NRR activity and especially promotes the rational design for SACs.展开更多
In the mining industry,precise forecasting of rock fragmentation is critical for optimising blasting processes.In this study,we address the challenge of enhancing rock fragmentation assessment by developing a novel hy...In the mining industry,precise forecasting of rock fragmentation is critical for optimising blasting processes.In this study,we address the challenge of enhancing rock fragmentation assessment by developing a novel hybrid predictive model named GWO-RF.This model combines the grey wolf optimization(GWO)algorithm with the random forest(RF)technique to predict the D_(80)value,a critical parameter in evaluating rock fragmentation quality.The study is conducted using a dataset from Sarcheshmeh Copper Mine,employing six different swarm sizes for the GWO-RF hybrid model construction.The GWO-RF model’s hyperparameters are systematically optimized within established bounds,and its performance is rigorously evaluated using multiple evaluation metrics.The results show that the GWO-RF hybrid model has higher predictive skills,exceeding traditional models in terms of accuracy.Furthermore,the interpretability of the GWO-RF model is enhanced through the utilization of SHapley Additive exPlanations(SHAP)values.The insights gained from this research contribute to optimizing blasting operations and rock fragmentation outcomes in the mining industry.展开更多
Cation additives can efficiently enhance the total electrochemical capabilities of zinc-ion hybrid capacitors (ZHCs).However their energy storage mechanisms in zinc-based systems are still under debate.Herein,we modul...Cation additives can efficiently enhance the total electrochemical capabilities of zinc-ion hybrid capacitors (ZHCs).However their energy storage mechanisms in zinc-based systems are still under debate.Herein,we modulate the electrolyte and achieve dual-ion storage by adding magnesium ions.And we assemble several Zn//activated carbon devices with different electrolyte concentrations and investigate their electrochemical reaction dynamic behaviors.The zinc-ion capacitor with Mg^(2+)mixed solution delivers 82 mAh·g^(-1)capacity at 1 A·g^(-1) and maintains 91%of the original capacitance after 10000 cycling.It is superior to the other assembled zinc-ion devices in single-component electrolytes.The finding demonstrates that the double-ion storage mechanism enables the superior rate performance and long cycle lifetime of ZHCs.展开更多
Metal-organic framework(MOF)-derived carbon composites have been considered as the promising materials for energy storage.However,the construction of MOF-based composites with highly controllable mode via the liquid-l...Metal-organic framework(MOF)-derived carbon composites have been considered as the promising materials for energy storage.However,the construction of MOF-based composites with highly controllable mode via the liquid-liquid synthesis method has a great challenge because of the simultaneous heterogeneous nucleation on substrates and the self-nucleation of individual MOF nanocrystals in the liquid phase.Herein,we report a bidirectional electrostatic generated self-assembly strategy to achieve the precisely controlled coatings of single-layer nanoscale MOFs on a range of substrates,including carbon nanotubes(CNTs),graphene oxide(GO),MXene,layered double hydroxides(LDHs),MOFs,and SiO_(2).The obtained MOF-based nanostructured carbon composite exhibits the hierarchical porosity(V_(meso)/V_(micro)∶2.4),ultrahigh N content of 12.4 at.%and"dual electrical conductive networks."The assembled aqueous zinc-ion hybrid capacitor(ZIC)with the prepared nanocarbon composite as a cathode shows a high specific capacitance of 236 F g^(-1)at 0.5 A g^(-1),great rate performance of 98 F g^(-1)at 100 A g^(-1),and especially,an ultralong cycling stability up to 230000 cycles with the capacitance retention of 90.1%.This work develops a repeatable and general method for the controlled construction of MOF coatings on various functional substrates and further fabricates carbon composites for ZICs with ultrastability.展开更多
Vertically oriented carbon structures constructed from low-dimen-sional carbon materials are ideal frameworks for high-performance thermal inter-face materials(TIMs).However,improving the interfacial heat-transfer eff...Vertically oriented carbon structures constructed from low-dimen-sional carbon materials are ideal frameworks for high-performance thermal inter-face materials(TIMs).However,improving the interfacial heat-transfer efficiency of vertically oriented carbon structures is a challenging task.Herein,an orthotropic three-dimensional(3D)hybrid carbon network(VSCG)is fabricated by depositing vertically aligned carbon nanotubes(VACNTs)on the surface of a horizontally oriented graphene film(HOGF).The interfacial interaction between the VACNTs and HOGF is then optimized through an annealing strategy.After regulating the orientation structure of the VACNTs and filling the VSCG with polydimethylsi-loxane(PDMS),VSCG/PDMS composites with excellent 3D thermal conductive properties are obtained.The highest in-plane and through-plane thermal conduc-tivities of the composites are 113.61 and 24.37 W m^(-1)K^(-1),respectively.The high contact area of HOGF and good compressibility of VACNTs imbue the VSCG/PDMS composite with low thermal resistance.In addition,the interfacial heat-transfer efficiency of VSCG/PDMS composite in the TIM performance was improved by 71.3%compared to that of a state-of-the-art thermal pad.This new structural design can potentially realize high-performance TIMs that meet the need for high thermal conductivity and low contact thermal resistance in interfacial heat-transfer processes.展开更多
The Industrial Internet of Things(IIoT)has brought numerous benefits,such as improved efficiency,smart analytics,and increased automation.However,it also exposes connected devices,users,applications,and data generated...The Industrial Internet of Things(IIoT)has brought numerous benefits,such as improved efficiency,smart analytics,and increased automation.However,it also exposes connected devices,users,applications,and data generated to cyber security threats that need to be addressed.This work investigates hybrid cyber threats(HCTs),which are now working on an entirely new level with the increasingly adopted IIoT.This work focuses on emerging methods to model,detect,and defend against hybrid cyber attacks using machine learning(ML)techniques.Specifically,a novel ML-based HCT modelling and analysis framework was proposed,in which L1 regularisation and Random Forest were used to cluster features and analyse the importance and impact of each feature in both individual threats and HCTs.A grey relation analysis-based model was employed to construct the correlation between IIoT components and different threats.展开更多
基金supported by Science and Technology Programs of Inner Mongolia(2020GG0301).
文摘The effect of fiber laser on MIG arc was investigated with 8 mm 7075-T6 high strength aluminum alloy as base material.The arc shape,droplet transfer form and electrical signal in the process of MIG welding and laser-MIG hybrid welding were analyzed.The stability of the hybrid welding process was evaluated by standard deviation analysis.The results show that with the increase of laser power,a large number of laser-induced plasma enters the arc column area,providing more conductive channels,which makes the heat of MIG arc more concentrated and the short circuit transition disappear.Due to the continuous effect of laser,the keyhole becomes a continuous electron emission source,and a stable cathode spot will be formed near the keyhole,which enhances the stability of MIG arc at the base current state.By using the method of standard deviation analysis,the voltage standard deviation of single MIG welding arc and laser-MIG hybrid arc within 4 seconds was calculated.The standard deviation of single MIG arc voltage was 1.05,and the standard deviation of MIG arc voltage in laser-MIG hybrid welding was 0.71–0.86,so the hybrid welding process was more stable.
文摘LF6 aluminum alloy plates with 4.5 mm thickness are welded in this experiment. Welding is carried out by using the CO2 laser-MIG paraxial hybrid welding in fiat position. The experimental results indicate that the inherent droplet transfer cycle time of conventional MIG arc is changed due to the interaction between CO2 laser beam and MIG arc in the short-circuiting mode of laser-MIG hybrid welding. Because of the preheating action of CO2 laser to electrode and base material, the droplet transfer frequency of MIG arc is increased in the hybrid welding process. When laser power is increased to a certain degree, the droplet transfer frequency is decreased due to the effect of laser-induced keyhole. Furthermore, through analyzing the MIG welding current and arc voltage waveforms and the characteristics of droplet transfer in the hybrid welding process, the effect of laser energy and the action point between laser beam and arc on the frequency of droplet transfer and weld appearance is investigated in details.
基金Project(51971129) supported by the National Natural Science Foundation of ChinaProject(19ZR1421200) supported by the Shanghai Natural Science Foundation,China。
文摘In this paper, 3 mm 6061 aluminum alloy sheets were welded by laser MIG hybrid welding. Based on the experiment, the best welding parameters were determined to ensure the penetration welding. The detailed microstructure,tensile and fatigue fracture morphology and surface fatigue damage of the welded joints were analyzed by optical microscope(OM), scanning electron microscope(SEM) and energy dispersive spectrometer(EDS). The results show that there are two main kinds of precipitates, one is the long Si rich precipitates at the grain boundaries, the other is the intragranular Cu rich precipitates. The tensile test results show that the tensile strength of the joint is 224 MPa, which is only 70.2% of the base metal. Through the analysis of tensile fracture, there are great differences in the formation of tensile dimple. In the tensile-tensile fatigue test with a stress rate of 0.1, the conditional fatigue limits of base metal and welded joint are 101.9 MPa and 54.4 MPa, respectively. By comparing the fatigue fracture of the welded joints under different stress amplitudes, it was found that the main factor leading to the fracture of the joint is porosity. Through further analysis of the pore defects, it was found that there are transgranular and intergranular propagation ways of microcracks in the pores, and the mixed propagation way was also found.
文摘A mathematical model was established to simulate the weld pool development and dynamic process in stationary iaser-MlG hybrid welding. Surface tension and buoyancy were considered to calculate liquid metal flow patter, moreover, typical phenomena of MIG welding, such as filler droplets impinging weld pool, electromagnetic force in the weld pool, and typical phenomena of laser beam welding, such as recoil pressure, Inverse Bremsstrahlung absorption, Fresnel absorption were all considered in the model. The laser beam and arc couple effect were introduced into this model by the plasma width during hybrid welding. The role of recoil pressure in the weld formation was discussed. Transient weld pool shape and complicated liquid metal velocity distribution from two kinds weld pool to an unified weld pool were calculated. The simulated weld bead geometry with consideration recoil pressure was in good agreement with experimental measurement.
文摘Laser-MIG hybrid welding experiments of 7 mm thick Invar alloy are carried out.The macro appearance of joints is observed and the influence of arc energy on the cross-section morphology is analyzed.The distribution of temperature field is simulated to explain the relationship between heat effect and microstructure.Besides,the average grain size of weld under different arc energies is quantitatively studied.The results indicate that welded joints with uniformity and good formation are obtained.The weld width and the weld seam area increase and the depth to width ratio decreases with the increase of arc heat input.The transition of columnar crystals to equiaxed crystals is observed from the fusion line to the weld center.It is found that the higher the arc energy,the coarser the columnar crystal.
基金supported by the National Natural Science Foundation of China(51705470).
文摘Purpose–This study aims to solve the problem of weld quality inspection,for the aluminum alloy profile welding structure of high-speed train body has complex internal shape and thin plate thickness(2–4 mm),the conventional nondestructive testing method of weld quality is difficult to implement.Design/methodology/approach–In order to solve this problem,the ultrasonic creeping wave detection technology was proposed.The impact of the profile structure on the creeping wave detection was studied by designing profile structural test blocks and artificial simulation defect test blocks.The detection technology was used to test the actual welded test blocks,and compared with the results of X-ray test and destructive test(tensile test)to verify the accuracy of the ultrasonic creeping wave test results.Findings–It is indicated that that X-ray has better effect on the inspection of porosities and incomplete penetration defects.However,due to special detection method and protection,the detection speed is slow,which cannot meet the requirements of field inspection of the welding structure of aluminum alloy thin-walled profile for high-speed train body.It can be used as an auxiliary detection method for a small number of sampling inspection.The ultrasonic creeping wave can be used to detect the incomplete penetration welds with the equivalent of 0.25 mm or more,the results of creeping wave detection correspond well with the actual incomplete penetration defects.Originality/value–The results show that creeping wave detection results correspond well with the actual non-penetration defects and can be used for welding quality inspection of aluminum alloy thin-wall profile composite welding joints.It is recommended to use the echo amplitude of the 10 mm 30.2 mm 30.5 mm notch as the criterion for weld qualification.
基金supported by Shanghai Municipal Commission of Economy and Informatization(Grant No.15XI-1-15)the Priority Academic Program Development of Jiangsu Higher Education Institutions(Grant No.PAPD)
文摘Composites are widely applied to the manufacturing of aircraft in aviation. Forming of large-scale composite component in aircraft requires the corresponding mold with precise size. The laser-MIG hybrid welding has a significant advantage in the manufacturing of Invar mold for aircraft composites. This paper mainly introduces the application of the laser-MIG hybrid welding,and the distribution of thermal field and flow field on the Invar alloy laser-MIG hybrid three-layer welding is analyzed and discussed specifically.
基金supported by the Key Science and Technology of Jilin Province(Grant No.20140204070GX)
文摘The weld appearance, deposition rate, welding efficiency, stability of arc, laser keyhole characteristic, and weld property were studied by using a novel laser-MIG hybrid welding process with filling wire of aluminum alloy. The results were also compared with those by conventional laser-MIG hybrid welding process. It was found that with the suitable process parameters this novel welding process for aluminum alloy was stable and final weld bead had fine appearance. Compared to conventional laser-MIG hybrid welding process, during this novel welding process the stability of arc, the laser keyhole characteristic and the weld property were similar, while the keyhole cycle frequency and keyhole opening area had differences of 1.23% and 15.34%, respectively, and the welding efficiency increased by about 31% without increasing heat input.
文摘Laser-MIG hybrid welding process was dealt with 6 mm thick 5083Hl16 Al-Mg alloy plate in butt-joint configuration. Weld formation principle during hybrid welding was explained. The joint properties and microstructure characteristics of welded joints were analyzed by tensile tests, fractographs observed by optical microscopy and scanning electron microscopy (SEM). Higher heat input could obtain better mechanical properties, and tensile strength and elongation reached 97.2%, 81% of the base metal, respectively. Fracture position traasited from fusion line to weld center in the higher heat input, and fracture location were only in the center of welded joints for the heat input relatively small.
基金The Qian Xuesen Youth Innovation Foundation from China Aerospace Science and Technology Corporation(Grant Number 2022JY51).
文摘The demand for adopting neural networks in resource-constrained embedded devices is continuously increasing.Quantization is one of the most promising solutions to reduce computational cost and memory storage on embedded devices.In order to reduce the complexity and overhead of deploying neural networks on Integeronly hardware,most current quantization methods use a symmetric quantization mapping strategy to quantize a floating-point neural network into an integer network.However,although symmetric quantization has the advantage of easier implementation,it is sub-optimal for cases where the range could be skewed and not symmetric.This often comes at the cost of lower accuracy.This paper proposed an activation redistribution-based hybrid asymmetric quantizationmethod for neural networks.The proposedmethod takes data distribution into consideration and can resolve the contradiction between the quantization accuracy and the ease of implementation,balance the trade-off between clipping range and quantization resolution,and thus improve the accuracy of the quantized neural network.The experimental results indicate that the accuracy of the proposed method is 2.02%and 5.52%higher than the traditional symmetric quantization method for classification and detection tasks,respectively.The proposed method paves the way for computationally intensive neural network models to be deployed on devices with limited computing resources.Codes will be available on https://github.com/ycjcy/Hybrid-Asymmetric-Quantization.
基金supported by the National Natural Science Foundation of China(21905253,51973200,and 52122308)the Natural Science Foundation of Henan(202300410372)the National Supercomputing Center in Zhengzhou
文摘The rational design of metal single-atom catalysts(SACs)for electrochemical nitrogen reduction reaction(NRR)is challenging.Two-dimensional metal-organic frameworks(2DMOFs)is a unique class of promising SACs.Up to now,the roles of individual metals,coordination atoms,and their synergy effect on the electroanalytic performance remain unclear.Therefore,in this work,a series of 2DMOFs with different metals and coordinating atoms are systematically investigated as electrocatalysts for ammonia synthesis using density functional theory calculations.For a specific metal,a proper metal-intermediate atoms p-d orbital hybridization interaction strength is found to be a key indicator for their NRR catalytic activities.The hybridization interaction strength can be quantitatively described with the p-/d-band center energy difference(Δd-p),which is found to be a sufficient descriptor for both the p-d hybridization strength and the NRR performance.The maximum free energy change(ΔG_(max))andΔd-p have a volcanic relationship with OsC_(4)(Se)_(4)located at the apex of the volcanic curve,showing the best NRR performance.The asymmetrical coordination environment could regulate the band structure subtly in terms of band overlap and positions.This work may shed new light on the application of orbital engineering in electrocatalytic NRR activity and especially promotes the rational design for SACs.
基金Projects(42177164,52474121)supported by the National Science Foundation of ChinaProject(PBSKL2023A12)supported by the State Key Laboratory of Precision Blasting and Hubei Key Laboratory of Blasting Engineering,China。
文摘In the mining industry,precise forecasting of rock fragmentation is critical for optimising blasting processes.In this study,we address the challenge of enhancing rock fragmentation assessment by developing a novel hybrid predictive model named GWO-RF.This model combines the grey wolf optimization(GWO)algorithm with the random forest(RF)technique to predict the D_(80)value,a critical parameter in evaluating rock fragmentation quality.The study is conducted using a dataset from Sarcheshmeh Copper Mine,employing six different swarm sizes for the GWO-RF hybrid model construction.The GWO-RF model’s hyperparameters are systematically optimized within established bounds,and its performance is rigorously evaluated using multiple evaluation metrics.The results show that the GWO-RF hybrid model has higher predictive skills,exceeding traditional models in terms of accuracy.Furthermore,the interpretability of the GWO-RF model is enhanced through the utilization of SHapley Additive exPlanations(SHAP)values.The insights gained from this research contribute to optimizing blasting operations and rock fragmentation outcomes in the mining industry.
基金financially supported by the National Natural Science Foundation of China (No.52172218)。
文摘Cation additives can efficiently enhance the total electrochemical capabilities of zinc-ion hybrid capacitors (ZHCs).However their energy storage mechanisms in zinc-based systems are still under debate.Herein,we modulate the electrolyte and achieve dual-ion storage by adding magnesium ions.And we assemble several Zn//activated carbon devices with different electrolyte concentrations and investigate their electrochemical reaction dynamic behaviors.The zinc-ion capacitor with Mg^(2+)mixed solution delivers 82 mAh·g^(-1)capacity at 1 A·g^(-1) and maintains 91%of the original capacitance after 10000 cycling.It is superior to the other assembled zinc-ion devices in single-component electrolytes.The finding demonstrates that the double-ion storage mechanism enables the superior rate performance and long cycle lifetime of ZHCs.
基金financial support from Project funded by National Natural Science Foundation of China(52172038,22179017)funding from Dalian University of Technology Open Fund for Large Scale Instrument Equipment
文摘Metal-organic framework(MOF)-derived carbon composites have been considered as the promising materials for energy storage.However,the construction of MOF-based composites with highly controllable mode via the liquid-liquid synthesis method has a great challenge because of the simultaneous heterogeneous nucleation on substrates and the self-nucleation of individual MOF nanocrystals in the liquid phase.Herein,we report a bidirectional electrostatic generated self-assembly strategy to achieve the precisely controlled coatings of single-layer nanoscale MOFs on a range of substrates,including carbon nanotubes(CNTs),graphene oxide(GO),MXene,layered double hydroxides(LDHs),MOFs,and SiO_(2).The obtained MOF-based nanostructured carbon composite exhibits the hierarchical porosity(V_(meso)/V_(micro)∶2.4),ultrahigh N content of 12.4 at.%and"dual electrical conductive networks."The assembled aqueous zinc-ion hybrid capacitor(ZIC)with the prepared nanocarbon composite as a cathode shows a high specific capacitance of 236 F g^(-1)at 0.5 A g^(-1),great rate performance of 98 F g^(-1)at 100 A g^(-1),and especially,an ultralong cycling stability up to 230000 cycles with the capacitance retention of 90.1%.This work develops a repeatable and general method for the controlled construction of MOF coatings on various functional substrates and further fabricates carbon composites for ZICs with ultrastability.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.52130303,52327802,52303101,52173078,51973158)the China Postdoctoral Science Foundation(2023M732579)+2 种基金Young Elite Scientists Sponsorship Program by CAST(No.2022QNRC001)National Key R&D Program of China(No.2022YFB3805702)Joint Funds of Ministry of Education(8091B032218).
文摘Vertically oriented carbon structures constructed from low-dimen-sional carbon materials are ideal frameworks for high-performance thermal inter-face materials(TIMs).However,improving the interfacial heat-transfer efficiency of vertically oriented carbon structures is a challenging task.Herein,an orthotropic three-dimensional(3D)hybrid carbon network(VSCG)is fabricated by depositing vertically aligned carbon nanotubes(VACNTs)on the surface of a horizontally oriented graphene film(HOGF).The interfacial interaction between the VACNTs and HOGF is then optimized through an annealing strategy.After regulating the orientation structure of the VACNTs and filling the VSCG with polydimethylsi-loxane(PDMS),VSCG/PDMS composites with excellent 3D thermal conductive properties are obtained.The highest in-plane and through-plane thermal conduc-tivities of the composites are 113.61 and 24.37 W m^(-1)K^(-1),respectively.The high contact area of HOGF and good compressibility of VACNTs imbue the VSCG/PDMS composite with low thermal resistance.In addition,the interfacial heat-transfer efficiency of VSCG/PDMS composite in the TIM performance was improved by 71.3%compared to that of a state-of-the-art thermal pad.This new structural design can potentially realize high-performance TIMs that meet the need for high thermal conductivity and low contact thermal resistance in interfacial heat-transfer processes.
文摘The Industrial Internet of Things(IIoT)has brought numerous benefits,such as improved efficiency,smart analytics,and increased automation.However,it also exposes connected devices,users,applications,and data generated to cyber security threats that need to be addressed.This work investigates hybrid cyber threats(HCTs),which are now working on an entirely new level with the increasingly adopted IIoT.This work focuses on emerging methods to model,detect,and defend against hybrid cyber attacks using machine learning(ML)techniques.Specifically,a novel ML-based HCT modelling and analysis framework was proposed,in which L1 regularisation and Random Forest were used to cluster features and analyse the importance and impact of each feature in both individual threats and HCTs.A grey relation analysis-based model was employed to construct the correlation between IIoT components and different threats.