The gradient nanostructure is machined on the aluminum(Al)alloy by the two-dimensional ultrasonic surface burnishing process(2D-USBP).The mechanism of why the gradient nanostructure enhances wear resistance is investi...The gradient nanostructure is machined on the aluminum(Al)alloy by the two-dimensional ultrasonic surface burnishing process(2D-USBP).The mechanism of why the gradient nanostructure enhances wear resistance is investigated.The mechanical properties and microstructure characterization for the gradient nanostructure are performed by operating a nanoindenter,transmission electron microscopy(TEM),and electron backscattered diffraction(EBSD).Dry wear tests are performed on the samples before and after machining to evaluate the wear resistance and mechanisms.The effect of the gradient nanostructure on the wear resistance is explored by developing the crystal plasticity(CP)finite element and molecular dynamics(MD)models.The characterization results show that the 2D-USBP sample prepared a gradient structure of~600μm thick on the aluminum surface,increasing the surface hardness from 1.13 to 1.71 GPa and reducing the elastic modulus from 78.84 to 70.14 GPa.The optimization of the surface microstructure and the increase of the mechanical properties effectively enhance the wear resistance of the sample,with 41.20%,39.07%,and 54.58% of the wear scar areas for the 2D-USBP treated samples to the original samples under 5,10,and 15 N loads,respectively.The gradient nanostructure hinders the slip of dislocations inside the sample during the wear process and reduces the size and scope of plastic deformation;meanwhile,the resistance to deformation,adhesion,and crack initiation and propagation of the sample surface is improved,resulting in enhanced wear resistance.展开更多
Structural superlubricity is a theoretical concept stating that the friction force is absent between two rigid,incommensurate crystalline surfaces.However,elasticity of the contact pairs could modify the lattice regis...Structural superlubricity is a theoretical concept stating that the friction force is absent between two rigid,incommensurate crystalline surfaces.However,elasticity of the contact pairs could modify the lattice registry at interfaces by nucleating local slips,favoring commeasure.The validity of structural superlubricity is thus concerned for large-scale systems where the energy cost of elastic distortion to break the lattice registry is low.In this work,we study the size dependence of superlubricity between single-crystal graphite flakes.Molecular dynamics simulations show that with nucleation and propagation of out-of-plane dislocations and strained solitons at Bernal interfaces,the friction force is reduced by one order of magnitude.Elastic distortion is much weaker for non-Bernal or incommensurate ones,remaining notable only at the ends of contact.Lattice self-organization at small twist angles perturbs the state of structural superlubricity through a reconstructed potential energy surface.Theoretical models are developed to illustrate and predict the interfacial elastoplastic behaviors at length scales beyond those in the simulations.These results validate the rigid assumption for graphitic superlubricity systems at microscale,and reveal the intrinsic channels of mechanical energy dissipation.The understandings lay the ground for the design of structural superlubricity applications.展开更多
基金financially supported by the National Natural Science Foundation of China(NSFC)(52175194,52105215,and 52075047)Zhejiang Provincial Natural Science Foundation of China(LR23E050002).
文摘The gradient nanostructure is machined on the aluminum(Al)alloy by the two-dimensional ultrasonic surface burnishing process(2D-USBP).The mechanism of why the gradient nanostructure enhances wear resistance is investigated.The mechanical properties and microstructure characterization for the gradient nanostructure are performed by operating a nanoindenter,transmission electron microscopy(TEM),and electron backscattered diffraction(EBSD).Dry wear tests are performed on the samples before and after machining to evaluate the wear resistance and mechanisms.The effect of the gradient nanostructure on the wear resistance is explored by developing the crystal plasticity(CP)finite element and molecular dynamics(MD)models.The characterization results show that the 2D-USBP sample prepared a gradient structure of~600μm thick on the aluminum surface,increasing the surface hardness from 1.13 to 1.71 GPa and reducing the elastic modulus from 78.84 to 70.14 GPa.The optimization of the surface microstructure and the increase of the mechanical properties effectively enhance the wear resistance of the sample,with 41.20%,39.07%,and 54.58% of the wear scar areas for the 2D-USBP treated samples to the original samples under 5,10,and 15 N loads,respectively.The gradient nanostructure hinders the slip of dislocations inside the sample during the wear process and reduces the size and scope of plastic deformation;meanwhile,the resistance to deformation,adhesion,and crack initiation and propagation of the sample surface is improved,resulting in enhanced wear resistance.
基金This study was supported by the National Natural Science Foundation of China(Nos.11825203,11832010,11921002,and 52090032)The computation was performed on the Explorer 100 cluster system of Tsinghua National Laboratory for Information Science and Technology。
文摘Structural superlubricity is a theoretical concept stating that the friction force is absent between two rigid,incommensurate crystalline surfaces.However,elasticity of the contact pairs could modify the lattice registry at interfaces by nucleating local slips,favoring commeasure.The validity of structural superlubricity is thus concerned for large-scale systems where the energy cost of elastic distortion to break the lattice registry is low.In this work,we study the size dependence of superlubricity between single-crystal graphite flakes.Molecular dynamics simulations show that with nucleation and propagation of out-of-plane dislocations and strained solitons at Bernal interfaces,the friction force is reduced by one order of magnitude.Elastic distortion is much weaker for non-Bernal or incommensurate ones,remaining notable only at the ends of contact.Lattice self-organization at small twist angles perturbs the state of structural superlubricity through a reconstructed potential energy surface.Theoretical models are developed to illustrate and predict the interfacial elastoplastic behaviors at length scales beyond those in the simulations.These results validate the rigid assumption for graphitic superlubricity systems at microscale,and reveal the intrinsic channels of mechanical energy dissipation.The understandings lay the ground for the design of structural superlubricity applications.