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基于多尺度Laws纹理能量和低秩分解的织物疵点检测算法
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作者 王振华 张周强 +1 位作者 昝杰 刘江浩 《纺织学报》 EI CAS CSCD 北大核心 2024年第4期96-104,共9页
为提高织物疵点检测算法对简单纹理织物、模式纹理织物及条纹纹理织物检测时的普适性和准确性,提出了一种基于多尺度Laws纹理能量和低秩分解的织物疵点检测算法。首先,对织物图像进行直方图均衡化并将处理后的图像均匀划分为子图像块;其... 为提高织物疵点检测算法对简单纹理织物、模式纹理织物及条纹纹理织物检测时的普适性和准确性,提出了一种基于多尺度Laws纹理能量和低秩分解的织物疵点检测算法。首先,对织物图像进行直方图均衡化并将处理后的图像均匀划分为子图像块;其次,对每个子图像块提取28个纹理能量特征(利用7个Laws滤波模板在4个尺度上提取),计算所有子图像块提取到的特征均值并组成特征矩阵;然后,利用特征矩阵构建低秩分解模型,通过方向交替方法(ADM)优化求解,得到低秩部分和稀疏部分;最后,由稀疏部分生成疵点显著图,采用迭代阈值分割法对其进行分割,得到织物疵点检测结果。为验证该算法的有效性,在织物图像数据集选取了包含错纬、断经、跳花、破洞等常见疵点的织物图像,并将实验结果与已有3种算法进行了对比。实验结果表明,该算法在简单纹理织物、模式纹理织物及条纹纹理织物检测上具有更好的普适性和准确性,且检测效率具有一定优势。 展开更多
关键词 织物疵点 疵点检测 laws纹理 纹理能量 特征提取 矩阵低秩分解
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Nonuniform Dependence on the Initial Data for Solutions of Conservation Laws
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作者 John M.Holmes Barbara Lee Keyfitz 《Communications on Applied Mathematics and Computation》 EI 2024年第1期489-500,共12页
In this paper,we study systems of conservation laws in one space dimension.We prove that for classical solutions in Sobolev spaces H^(s),with s>3/2,the data-to-solution map is not uniformly continuous.Our results a... In this paper,we study systems of conservation laws in one space dimension.We prove that for classical solutions in Sobolev spaces H^(s),with s>3/2,the data-to-solution map is not uniformly continuous.Our results apply to all nonlinear scalar conservation laws and to nonlinear hyperbolic systems of two equations. 展开更多
关键词 Conservation laws Data-to-solution map Nonuniform dependence
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Literature overview of basic characteristics and flotation laws of flocs
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作者 Wanzhong Yin Yu Xie Zhanglei Zhu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第5期943-958,共16页
Flocculation flotation is the most efficient method for recovering fine-grained minerals,and its essence lies in flotation and recovery of flocs.Fundamental physical characteristics of flocs are mainly determined by t... Flocculation flotation is the most efficient method for recovering fine-grained minerals,and its essence lies in flotation and recovery of flocs.Fundamental physical characteristics of flocs are mainly determined by their apparent particle size and structure(density and morphology).Substantial researches have been conducted regarding the effect of floc characteristics on particle settling and water treatment.However,the influence of floc characteristics on flotation has not been widely studied.Based on the floc formation and flocculation flotation,this study reviews the fundamental physical characteristics of flocs from the perspectives of floc particle size and structure,summarizing the interaction between floc particle size and structure.Moreover,it thoroughly discusses the effect of floc particle size and structure on floc floatability,further revealing the influence of floc characteristics on bubble collision and adhesion and elucidating the mechanisms of interaction between flocs and bubbles.Thus,it is observed that floc particle size is not the only factor influencing flocculation flotation.Within the appropriate apparent particle size range,flocs with a compact structure exhibit higher efficiency in bubble collision and adhesion during flotation,thereby resulting in enhanced flotation performance.This study aims to provide a reference for flocculation flotation,targeting the development of more efficient and refined flocculation flotation processes in the future. 展开更多
关键词 FLOCS basic characteristics particle size and structure flotation laws BUBBLES
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Dimension by Dimension Finite Volume HWENO Method for Hyperbolic Conservation Laws
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作者 Feng Zheng Jianxian Qiu 《Communications on Applied Mathematics and Computation》 EI 2024年第1期605-624,共20页
In this paper,we propose a finite volume Hermite weighted essentially non-oscillatory(HWENO)method based on the dimension by dimension framework to solve hyperbolic conservation laws.It can maintain the high accuracy ... In this paper,we propose a finite volume Hermite weighted essentially non-oscillatory(HWENO)method based on the dimension by dimension framework to solve hyperbolic conservation laws.It can maintain the high accuracy in the smooth region and obtain the high resolution solution when the discontinuity appears,and it is compact which will be good for giving the numerical boundary conditions.Furthermore,it avoids complicated least square procedure when we implement the genuine two dimensional(2D)finite volume HWENO reconstruction,and it can be regarded as a generalization of the one dimensional(1D)HWENO method.Extensive numerical tests are performed to verify the high resolution and high accuracy of the scheme. 展开更多
关键词 Finite volume Dimension by dimension HWENO Hyperbolic conservation laws
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On the Use of Monotonicity-Preserving Interpolatory Techniques in Multilevel Schemes for Balance Laws
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作者 Antonio Baeza Rosa Donat Anna Martinez-Gavara 《Communications on Applied Mathematics and Computation》 EI 2024年第2期1319-1341,共23页
Cost-effective multilevel techniques for homogeneous hyperbolic conservation laws are very successful in reducing the computational cost associated to high resolution shock capturing numerical schemes.Because they do ... Cost-effective multilevel techniques for homogeneous hyperbolic conservation laws are very successful in reducing the computational cost associated to high resolution shock capturing numerical schemes.Because they do not involve any special data structure,and do not induce savings in memory requirements,they are easily implemented on existing codes and are recommended for 1D and 2D simulations when intensive testing is required.The multilevel technique can also be applied to balance laws,but in this case,numerical errors may be induced by the technique.We present a series of numerical tests that point out that the use of monotonicity-preserving interpolatory techniques eliminates the numerical errors observed when using the usual 4-point centered Lagrange interpolation,and leads to a more robust multilevel code for balance laws,while maintaining the efficiency rates observed forhyperbolic conservation laws. 展开更多
关键词 Hyperbolic balance laws Well-balanced schemes Multilevel schemes Harten's multiresolution
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基于Laws与Gabor滤波的田间西兰花花球识别技术 被引量:3
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作者 赵雄 徐港吉 +2 位作者 陈建能 俞高红 代丽 《农业机械学报》 EI CAS CSCD 北大核心 2023年第4期313-322,共10页
正确识别西兰花田间位置是实现西兰花自动化采收的基础,西兰花花球颜色与植株的叶片、茎秆相似,仅通过颜色特征无法对西兰花进行识别,本文以成熟期的田间西兰花为研究对象,提出了一种基于纹理特征与颜色特征的西兰花识别算法。首先通过... 正确识别西兰花田间位置是实现西兰花自动化采收的基础,西兰花花球颜色与植株的叶片、茎秆相似,仅通过颜色特征无法对西兰花进行识别,本文以成熟期的田间西兰花为研究对象,提出了一种基于纹理特征与颜色特征的西兰花识别算法。首先通过预处理以及Laws滤波对图像进行边界纹理强化,再通过Gabor滤波对图像进行纹理特征向量提取,并对提取后的纹理特征向量进行z⁃score标准化,随后对标准化后的纹理特征向量进行K⁃means聚类与开运算,获取花球潜在存在区域。同时对RGB图像进行HSV转换,通过对图像的H分量进行阈值分割达到滤除地面像素的效果。最终对纹理特征识别与颜色特征识别的结果进行融合,实现对田间西兰花的识别。算法通过结合纹理与颜色特征,对田间西兰花进行了识别,解决了西兰花的花球与茎叶等背景颜色相近难以识别的问题。本文共使用792幅图像进行试验,试验结果表明,本方法可以准确地对西兰花田间图像进行识别,其精确率为96.96%,召回率为94.41%,F1值为95.67%。通过对3组不同拍摄环境的数据集进行算法识别,3组数据集的F1值始终保持在94%以上,具有良好的拍摄环境适应性,为农业机器人进行西兰花自动化采收奠定了基础。 展开更多
关键词 图像识别 西兰花 纹理强化 laws滤波 GABOR滤波
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Regularity of Fluxes in Nonlinear Hyperbolic Balance Laws
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作者 Matania Ben-Artzi Jiequan Li 《Communications on Applied Mathematics and Computation》 2023年第3期1289-1298,共10页
This paper addresses the issue of the formulation of weak solutions to systems of nonlinear hyperbolic conservation laws as integral balance laws.The basic idea is that the“meaningful objects”are the fluxes,evaluate... This paper addresses the issue of the formulation of weak solutions to systems of nonlinear hyperbolic conservation laws as integral balance laws.The basic idea is that the“meaningful objects”are the fluxes,evaluated across domain boundaries over time intervals.The fundamental result in this treatment is the regularity of the flux trace in the multi-dimensional setting.It implies that a weak solution indeed satisfies the balance law.In fact,it is shown that the flux is Lipschitz continuous with respect to suitable perturbations of the boundary.It should be emphasized that the weak solutions considered here need not be entropy solutions.Furthermore,the assumption imposed on the flux f(u)is quite minimal-just that it is locally bounded. 展开更多
关键词 Balance laws Hyperbolic conservation laws MULTI-DIMENSIONAL Discontinuous solutions Finite-volume schemes FLUX Trace on boundary
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Relationship between the Three Laws of Dialectics of Nature and Agricultural Development
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作者 Qianru ZHU 《Asian Agricultural Research》 2023年第7期20-21,共2页
Based on the three laws of dialectics of nature-the law of unity of opposites, the law of mutual change of quality and the law of negation of negation, this paper analyzes the relationship between the three laws and a... Based on the three laws of dialectics of nature-the law of unity of opposites, the law of mutual change of quality and the law of negation of negation, this paper analyzes the relationship between the three laws and agricultural development, and proposes making good use of the three laws to promote the better development of agriculture and realize agricultural modernization. 展开更多
关键词 Dialectics of nature law of unity of opposites law of mutual change of quality law of negation of negation Agricultural development
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Simulation of the Behaviour Laws in the Thermal Affected Zones of the 13Cr-4Ni Martensitic Stainless Steel
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作者 Marcel Julmard Ongoumaka Yandza Harmel Obami-Ondon Christian Tathy 《Modern Mechanical Engineering》 2023年第4期63-76,共14页
During the welding, many phenomena occur. The materials deform under the action of residual stresses. This tendency is due to the high gradients of temperature during the process. These deformations are really difficu... During the welding, many phenomena occur. The materials deform under the action of residual stresses. This tendency is due to the high gradients of temperature during the process. These deformations are really difficult for many professionals operating in the area. In the goal to predict these variations, one has established the behaviour laws which will be applied to evaluate residual stresses and strains. This research is focused on the study of the Thermal Affected Zone (TAZ) during the welding of the 13Cr-4Ni martensitic stainless steel. The TAZ does not know any change of state (solid/liquid). It only knows the metallurgical phase change (austenite/martensite). There are three types of behaviour laws in this study: thermal, mechanical and metallurgical behaviour laws. The thermal behaviour law serves to evaluate the temperature field which induces the mechanical strains. The mechanical behaviour law serves to evaluate spherical stress (pressure) and deviatoric stress which compose the residual stress. It also helps to measure the total strain. The metallurgical behaviour law serves for the evaluation of the metallurgical phase proportions. To validate the modelling developed in this study, one has made the simulations to compare the results obtained with the analytical and experimental data. 展开更多
关键词 Behaviour laws Martensitic Stainless Steel Residual Stresses Strain Numerical Simulation
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Darboux transformation,infinite conservation laws,and exact solutions for the nonlocal Hirota equation with variable coefficients
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作者 刘锦洲 闫鑫颖 +1 位作者 金梦 辛祥鹏 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第12期263-269,共7页
This article presents the construction of a nonlocal Hirota equation with variable coefficients and its Darboux transformation.Using zero-seed solutions,1-soliton and 2-soliton solutions of the equation are constructe... This article presents the construction of a nonlocal Hirota equation with variable coefficients and its Darboux transformation.Using zero-seed solutions,1-soliton and 2-soliton solutions of the equation are constructed through the Darboux transformation,along with the expression for N-soliton solutions.Influence of coefficients that are taken as a function of time instead of a constant,i.e.,coefficient functionδ(t),on the solutions is investigated by choosing the coefficient functionδ(t),and the dynamics of the solutions are analyzed.This article utilizes the Lax pair to construct infinite conservation laws and extends it to nonlocal equations.The study of infinite conservation laws for nonlocal equations holds significant implications for the integrability of nonlocal equations. 展开更多
关键词 infinite conservation laws nonlocal Hirota equation with variable coefficient soliton solutions Darboux transformation
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Exploration of the Inner Laws of Urbanization Economic Operation and Application Analysis
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作者 Tingting Yu 《Open Journal of Applied Sciences》 2023年第12期2291-2305,共15页
Exploring the inner law of the economic operation of urbanization can understand the regulation mechanism of the optimal distribution of urban resource allocation. In this regard, we propose to explore and analyze the... Exploring the inner law of the economic operation of urbanization can understand the regulation mechanism of the optimal distribution of urban resource allocation. In this regard, we propose to explore and analyze the inner law of urbanization economic operation and its application. The study found that the urbanization economy originated from the urban agglomeration effect, which includes the agglomeration economic operation mechanism and spillover effect operation mechanism, based on which three kinds of inner laws of urbanization economic operation are explored, combined with the economic operation law, the non-equilibrium state of the declining cities are regulated and applied, and the results show that the analysis of the inner laws of urbanization economic operation has a direct significance in guiding the real economic process. 展开更多
关键词 ECONOMY URBANIZATION laws Operational Mechanisms
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On High-Resolution Entropy-Consistent Flux with Slope Limiter for Hyperbolic Conservation Laws
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作者 Xuan Ren Jianhu Feng +2 位作者 Supei Zheng Xiaohan Cheng Yang Li 《Communications on Applied Mathematics and Computation》 EI 2023年第4期1616-1643,共28页
This paper proposes a new version of the high-resolution entropy-consistent(EC-Limited)flux for hyperbolic conservation laws based on a new minmod-type slope limiter.Firstly,we identify the numerical entropy productio... This paper proposes a new version of the high-resolution entropy-consistent(EC-Limited)flux for hyperbolic conservation laws based on a new minmod-type slope limiter.Firstly,we identify the numerical entropy production,a third-order differential term deduced from the previous work of Ismail and Roe[11].The corresponding dissipation term is added to the original Roe flux to achieve entropy consistency.The new,resultant entropy-consistent(EC)flux has a general and explicit analytical form without any corrective factor,making it easy to compute and a less-expensive method.The inequality constraints are imposed on the standard piece-wise quadratic reconstruction to enforce the pointwise values of bounded-type numerical solutions.We design the new minmod slope limiter as combining two separate limiters for left and right states.We propose the EC-Limited flux by adding this reconstruction data method to the primitive variables rather than to the conservative variables of the EC flux to preserve the equilibrium of the primitive variables.These resulting fluxes are easily applied to general hyperbolic conservation laws while having attractive features:entropy-stable,robust,and non-oscillatory.To illustrate the potential of these proposed fluxes,we show the applications to the Burgers equation and the Euler equations. 展开更多
关键词 Hyperbolic conservation laws Entropy production Entropy-consistent(EC)flux Slope limiter High-resolution entropy-consistent(EC-Limited)flux
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Triple reverse order law for the Drazin inverse
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作者 WANG Hua ZHONG Cheng-cheng 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2024年第1期55-68,共14页
In this paper,we investigate the reverse order law for Drazin inverse of three bound-ed linear operators under some commutation relations.Moreover,the Drazin invertibility of sum is also obtained for two bounded linea... In this paper,we investigate the reverse order law for Drazin inverse of three bound-ed linear operators under some commutation relations.Moreover,the Drazin invertibility of sum is also obtained for two bounded linear operators and its expression is presented. 展开更多
关键词 Drazin inverse reverse order law space decomposition
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The Development of Human Rights Protection in Cross-border Personality Rights and Tort Conflict Laws
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作者 徐伟功 张亚军 LI Donglin(Translated) 《The Journal of Human Rights》 2023年第6期1319-1346,共28页
Personality rights are basic rights related to human dignity in the concept of human rights protection,and respect for personality rights is the basic prerequisite for safeguarding other human rights.Human rights prot... Personality rights are basic rights related to human dignity in the concept of human rights protection,and respect for personality rights is the basic prerequisite for safeguarding other human rights.Human rights protection exerts a profound impact on the value of legislation and enforcement practices of private international laws in the field of cross-border personality rights infringement in various countries,which is mainly manifested in the integration of substantive justice and the humanistic care concept of protecting the rights of vulnerable groups into formal justice,and expands the development space of human rights protection ideas in cross-border personality rights and tort conflict laws.the diversity of human rights protection values determines that cross-border personality rights infringement may lead to conflicts between personality rights and other basic rights,such as freedom of speech.to reconcile such conflicts,a workable method is to prioritize personality rights protection in accordance with the hierarchy of rights theory in the value judgment of public order reservation or to clarify the limits of the right holder’s tolerance obligation through the limited application of the principle of proportionality.China’s current cross-border personality rights and tort conflict law can optimize the protection of the rights of vulnerable groups by diversifying the options of available legal methods,and establish a balancing mechanism between personality rights and freedom of speech,so as to improve China’s legal protection system for human rights in the field of foreign-related civil and commercial affairs. 展开更多
关键词 human rights protection protection of the rights of vulnerable groups substantive justice personality rights and tort conflict laws
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Distribution law and susceptibility of geohazards across a gradient belt of the Western Sichuan Plateau
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作者 LI Tianbin WANG Jianfeng +4 位作者 HE Chaoyang MENG Lubo LI Chaofei MA Junjie WEI Daqiang 《Journal of Mountain Science》 SCIE CSCD 2024年第6期1849-1867,共19页
Across a gradient belt of the Western Sichuan Plateau,geohazards have seriously limited economic and social development.According to incomplete statistics,15,673 geohazards have been recorded in the study area.In orde... Across a gradient belt of the Western Sichuan Plateau,geohazards have seriously limited economic and social development.According to incomplete statistics,15,673 geohazards have been recorded in the study area.In order to mitigate the threat of geohazards to human engineering activities in the region,an overall understanding of the distribution pattern of geohazards and susceptibility assessment are necessary.In this paper,a gradient belt of the Western Sichuan Plateau and its zoning criteria were defined.Subsequently,on the basis of relief amplitude,distance to faults,rainfall,and human activities,three indicators of endogenic process were introduced:Bouguer gravity anomaly gradient,vertical deformation gradient,and horizontal deformation gradient.Thereafter,the distribution patterns of geohazards were investigated through mathematical statistics and ArcGIS software.By randomly selecting 10,449 hazards,a geohazard susceptibility map was generated using the Information Value(IV)model.Finally,the IV model was validated against 5224 hazards using the Area Under Curve(AUC)method.The results show that 47.6%of the geohazards were distributed in the zone of steep slope.Geohazards showed strong responses to distance to faults,human activities,and annual rainfall.The distribution of geohazards in the gradient belt of the Western Sichuan Plateau is more sensitive to vertical internal dynamics factors(such as vertical deformation gradient and Bouguer gravity anomaly gradient)without any apparent sensitivity to horizontal internal dynamics factors.The areas of high and very-high risk account for up to 32.22%,mainly distributed in the Longmenshan and Anning River faults.According to the AUC plot,the success rate of the IV model for generating the susceptibility map is 76%.This susceptibility map and geohazard distribution pattern can provide a reference for geological disaster monitoring,preparation of post-disaster emergency measures,and town planning. 展开更多
关键词 Gradient belt GEOHAZARDS Distribution law Bouguer Gravity anomaly gradient Vertical deformation gradient SUSCEPTIBILITY
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Nuclear magnetic resonance experiments on the time-varying law of oil viscosity and wettability in high-multiple waterflooding sandstone cores
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作者 JIA Hu ZHANG Rui +2 位作者 LUO Xianbo ZHOU Zili YANG Lu 《Petroleum Exploration and Development》 SCIE 2024年第2期394-402,共9页
A simulated oil viscosity prediction model is established according to the relationship between simulated oil viscosity and geometric mean value of T2spectrum,and the time-varying law of simulated oil viscosity in por... A simulated oil viscosity prediction model is established according to the relationship between simulated oil viscosity and geometric mean value of T2spectrum,and the time-varying law of simulated oil viscosity in porous media is quantitatively characterized by nuclear magnetic resonance(NMR)experiments of high multiple waterflooding.A new NMR wettability index formula is derived based on NMR relaxation theory to quantitatively characterize the time-varying law of rock wettability during waterflooding combined with high-multiple waterflooding experiment in sandstone cores.The remaining oil viscosity in the core is positively correlated with the displacing water multiple.The remaining oil viscosity increases rapidly when the displacing water multiple is low,and increases slowly when the displacing water multiple is high.The variation of remaining oil viscosity is related to the reservoir heterogeneity.The stronger the reservoir homogeneity,the higher the content of heavy components in the remaining oil and the higher the viscosity.The reservoir wettability changes after water injection:the oil-wet reservoir changes into water-wet reservoir,while the water-wet reservoir becomes more hydrophilic;the degree of change enhances with the increase of displacing water multiple.There is a high correlation between the time-varying oil viscosity and the time-varying wettability,and the change of oil viscosity cannot be ignored.The NMR wettability index calculated by considering the change of oil viscosity is more consistent with the tested Amott(spontaneous imbibition)wettability index,which agrees more with the time-varying law of reservoir wettability. 展开更多
关键词 SANDSTONE high-multiple waterflooding nuclear magnetic resonance oil viscosity rock wettability time-varying law
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Malus’ Law Derived from Deterministic Particle Behavior
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作者 Peter Schuttevaar 《Journal of High Energy Physics, Gravitation and Cosmology》 CAS 2024年第3期958-966,共9页
A polarized beam of energy is usually interpreted as a set of particles, all having the same polarization state. Difference in behavior between the one and the other particle is then explained by a number of counter-i... A polarized beam of energy is usually interpreted as a set of particles, all having the same polarization state. Difference in behavior between the one and the other particle is then explained by a number of counter-intuitive quantum mechanical concepts like probability distribution, superposition, entanglement and quantized spin. Alternatively, I propose that a polarized beam is composed of a set of particles with a cosine distribution of polarization angles within a polarization area. I show that Malus’ law for the intensity of a beam of polarized light can be derived in a straightforward manner from this distribution. I then show that none of the above-mentioned counter-intuitive concepts are necessary to explain particle behavior and that the ontology of particles, passing through a polarizer, can be easily and intuitively understood. I conclude by formulating some questions for follow-up research. 展开更多
关键词 Quantum Mechanics BELL Malus law SUPERPOSITION ENTANGLEMENT Quantum Fields Spin Hidden Variables LOCALITY NON-LOCALITY
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Weber Law Based Approach for Multi-Class Image Forgery Detection
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作者 Arslan Akram Javed Rashid +3 位作者 Arfan Jaffar Fahima Hajjej Waseem Iqbal Nadeem Sarwar 《Computers, Materials & Continua》 SCIE EI 2024年第1期145-166,共22页
Today’s forensic science introduces a new research area for digital image analysis formultimedia security.So,Image authentication issues have been raised due to the wide use of image manipulation software to obtain a... Today’s forensic science introduces a new research area for digital image analysis formultimedia security.So,Image authentication issues have been raised due to the wide use of image manipulation software to obtain an illegitimate benefit or createmisleading publicity by using tempered images.Exiting forgery detectionmethods can classify only one of the most widely used Copy-Move and splicing forgeries.However,an image can contain one or more types of forgeries.This study has proposed a hybridmethod for classifying Copy-Move and splicing images using texture information of images in the spatial domain.Firstly,images are divided into equal blocks to get scale-invariant features.Weber law has been used for getting texture features,and finally,XGBOOST is used to classify both Copy-Move and splicing forgery.The proposed method classified three types of forgeries,i.e.,splicing,Copy-Move,and healthy.Benchmarked(CASIA 2.0,MICCF200)and RCMFD datasets are used for training and testing.On average,the proposed method achieved 97.3% accuracy on benchmarked datasets and 98.3% on RCMFD datasets by applying 10-fold cross-validation,which is far better than existing methods. 展开更多
关键词 Copy-Move and splicing non-overlapping block division texture features weber law spatial domain xgboost
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Rate Law for Photoelectrochemical Water Splitting Over CuO
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作者 Bo-Yuan Gao Wen-HuaLeng 《电化学(中英文)》 CAS 北大核心 2024年第8期17-27,共11页
Photocatalytic splitting of water over p-type semiconductors is a promising strategy for production of hydrogen.However,the determination of rate law is rarely reported.To this purpose,copper oxide(CuO)is selected as ... Photocatalytic splitting of water over p-type semiconductors is a promising strategy for production of hydrogen.However,the determination of rate law is rarely reported.To this purpose,copper oxide(CuO)is selected as a model photocathode in this study,and the photogenerated surface charge density,interfacial charge transfer rate constant and their relation to the water reduction rate(in terms of photocurrent)were investigated by a combination of(photo)electrochemical techniques.The results showed that the charge transfer rate constant is exponential-dependent on the surface charge density,and that the photocurrent equals to the product of the charge transfer rate constant and surface charge density.The reaction is first-order in terms of surface charge density.Such an unconventional rate law contrasts with the reports in literature.The charge density-dependent rate constant results from the Fermi level pinning(i.e.,Galvani potential is the main driving force for the reaction)due to accumulation of charge in the surface states and/or Frumkin behavior(i.e.,chemical potential is the main driving force).This study,therefore,may be helpful for further investigation on the mechanism of hydrogen evolution over a CuO photocathode and for designing more efficient CuO-based photocatalysts. 展开更多
关键词 CUO Photoelectrochemical water splitting Electrochemical impedance spectroscopy Rate law Kinetics of photogenerated carriers
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Not Athenian or a Stranger:The Veiled Critique of Aristotle in Plato’s Laws
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作者 Philip Vogt 《Philosophy Study》 2023年第12期517-537,共21页
Plato’s last dialogue,the Laws,occupies an anomalous position within his larger body of work.An individual identified as the“Athenian stranger”replaces Socrates and reverses key Socratic teachings,most notably by e... Plato’s last dialogue,the Laws,occupies an anomalous position within his larger body of work.An individual identified as the“Athenian stranger”replaces Socrates and reverses key Socratic teachings,most notably by endorsing tyranny.Scholars conclude that Plato abandoned his earlier political recommendations in favor of a more pragmatic vision.In that case,the Laws should be treated as Plato’s definitive work,the ultimate statement of his thought,when in fact,much more attention is paid to earlier dialogues,particularly the Republic.The problem is resolved and the true significance of the Laws revealed when the text is read as Plato’s ironic critique of his brilliant-but-rebellious student,Aristotle.Reasoning from Aristotelian premises,the Athenian stranger arrives at conclusions that Platonists and Aristotelians alike would find unpalatable or absurd.The alleged rupture between Plato’s earlier and later work disappears.The esoteric writings that are thought to have been the product of Aristotle’s later career are shown to have emerged from ideas that Plato himself was familiar with and rejected. 展开更多
关键词 PLATO Plato’s laws Platonic irony ARISTOTLE Aristotle’s Politics TYRANNY
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