Enhancing the stability of Ni Fe-layered double hydroxide nanosheet array for alkaline seawater oxidation by Ce doping

Electrocatalytic hydrogen production from seawater holds enormous promise for clean energy generation.Nevertheless,the direct electrolysis of seawater encounters significant challenges due to poor anodic stability caused by detrimental chlorine chemistry.Herein,we present our recent discovery that the incorporation of Ce into Ni Fe layered double hydroxide nanosheet array on Ni foam(Ce-Ni Fe LDH/NF)emerges as a robust electrocatalyst for seawater oxidation.During the seawater oxidation process,CeO_(2)is generated,effectively repelling Cl^(-)and inhibiting the formation of Cl O-,resulting in a notable enhancement in the oxidation activity and stability of alkaline seawater.The prepared Ce-Ni Fe LDH/NF requires only overpotential of 390 m V to achieve the current density of 1 A cm^(-2),while maintaining long-term stability for 500 h,outperforming the performance of Ni Fe LDH/NF(430 m V,150 h)by a significant margin.This study highlights the effectiveness of a Ce-doping strategy in augmenting the activity and stability of materials based on Ni Fe LDH in seawater electrolysis for oxygen evolution.

Three-Dimensional Convection in an Inclined Porous Layer Subjected to a Vertical Temperature Gradient

In this paper,we study the onset and development of three-dimensional convection in a tilted porous layer saturated with a liquid.The layer is subjected to a gravitational field and a strictly vertical temperature gradient.Typically,problems of thermal convection in tilted porous media saturated with a liquid are studied by assuming constant different temperatures at the boundaries of the layer,which prevent these systems from supporting conductive(non-convective)states.The boundary conditions considered in the present work allow a conductive state and are representative of typical geological applications.In an earlier work,we carried out a linear stability analysis of the conductive state.It was shown that at any layer tilt angles,the most dangerous type of disturbances are longitudinal rolls.Moreover,a non-zero velocity component exists in z-direction.In the present work,threedimensional non-linear convection regimes are studied.The original three-dimensional problem is reduced to two-dimensional one with an analytical expression for the velocity z-component v_(z)=v_(z)(x,y).It is shown that the critical Rayleigh number values obtained through numerical solutions of the obtained 2D problem by a finite difference method for different layer inclination angles,are in a good agreement with those predicted by the linear theory.The number of convective rolls realized in nonlinear calculations also fits the linear theory predictions for a given cavity geometry.Calculations carried out at low supercriticalities show that a direct bifurcation takes place.With increasing supercriticality,no transitions to other convective regimes are detected.The situation studied in this problem can be observed in oil-bearing rock formations under the influence of a geothermal temperature gradient,where the ensuing fluid convection can affect the distribution of oil throughout the layer.

Values of macular ganglion cell-inner plexiform layer and 10-2 visual field measurements in detecting and evaluating glaucoma

AIM:To assess the performance of macular ganglion cell-inner plexiform layer thickness(mGCIPLT)and 10-2 visual field(VF)parameters in detecting early glaucoma and evaluating the severity of advanced glaucoma.METHODS:Totally 127 eyes from 89 participants(36 eyes of 19 healthy participants,45 eyes of 31 early glaucoma patients and 46 eyes of 39 advanced glaucoma patients)were included.The relationships between the optical coherence tomography(OCT)-derived parameters and VF sensitivity were determined.Patients with early glaucoma were divided into eyes with or without central 10°of the VF damages(CVFDs),and the diagnostic performances of OCT-derived parameters were assessed.RESULTS:In early glaucoma,the mGCIPLT was significantly correlated with 10-2 VF pattern standard deviation(PSD;with average mGCIPLT:β=-0.046,95%CI,-0.067 to-0.024,P<0.001).In advanced glaucoma,the mGCIPLT was related to the 24-2 VF mean deviation(MD;with average mGCIPLT:β=0.397,95%CI,0.199 to 0.595,P<0.001),10-2 VF MD(with average mGCIPLT:β=0.762,95%CI,0.485 to 1.038,P<0.001)and 24-2 VF PSD(with average mGCIPLT:β=0.244,95%CI,0.124 to 0.364,P<0.001).Except for the minimum and superotemporal mGCIPLT,the decrease of mGCIPLT in early glaucomatous eyes with CVFDs was more severe than that of early glaucomatous eyes without CVFDs.The area under the curve(AUC)of the average mGCIPLT(AUC=0.949,95%CI,0.868 to 0.982)was greater than that of the average circumpapillary retinal nerve fiber layer thickness(cpRNFLT;AUC=0.827,95%CI,0.674 to 0.918)and rim area(AUC=0.799,95%CI,0.610 to 0.907)in early glaucomatous eyes with CVFDs versus normal eyes.CONCLUSION:The 10-2 VF and mGCIPLT parameters are complementary to 24-2 VF,cpRNFLT and ONH parameters,especially in detecting early glaucoma with CVFDs and evaluating the severity of advanced glaucoma in group level.

Dual-function protective layer for highly reversible Zn anode

The thermodynamic instability of zinc anodes in aqueous electrolytes leads to issues such as corrosion,hydrogen evolution reactions(HER), and dendrite growth, severely hindering the practical application of zinc-based aqueous energy storage devices. To address these challenges, this work proposes a dualfunction zinc anode protective layer, composed of Zn-Al-In layered double oxides(ILDO) by rationally designing Zn-Al layered double hydroxides(Zn-Al LDHs) for the first time. Differing from previous works on the LDHs coatings, firstly, the ILDO layer accelerates zinc-ion desolvation and also captures and anchors SO_(4)^(2-). Secondly, the in-situ formation of the Zn-In alloy phase effectively lowers the nucleation energy barrier, thereby regulating zinc nucleation. Consequently, the zinc anode with the ILDO protective layer demonstrates long-term stability exceeding 1900 h and low voltage hysteresis of 7.5 m V at 0.5 m A cm^(-2) and 0.5 m A h cm^(-2). Additionally, it significantly enhances the rate capability and cycling performance of Zn@ILDO//MnO_(2) full batteries and Zn@ILDO//activated carbon zinc-ion hybrid capacitors.This simple and effective dual-function protective layer strategy offers a promising approach for achieving high-performance zinc-ion batteries.

Non-Darcy flows in layered porous media(LPMs)with contrasting pore space structures

Compared to single layer porous media,fluid flow through layered porous media(LPMs)with contrasting pore space structures is more complex.This study constructed three-dimensional(3-D)pore-scale LPMs with different grain size ratios of 1.20,1.47,and 1.76.The flow behavior in the constructed LPMs and single layer porous media was numerically investigated.A total of 178 numerical experimental data were collected in LPMs and single layer porous media.In all cases,two different flow regimes(i.e.,Darcy and Non-Darcy)were observed.The influence of the interface of layers on Non-Darcy flow behavior in LPMs was analyzed based pore-scale flow data.It was found that the available correlations based on single layer porous media fail to predict the flow behavior in LPMs,especially for LPM with large grain size ratio.The effective permeability,which incorporated the influence of the interface is more accurate than the Kozeny-Carman equation for estimating the Darcy permeability of LPMs.The inertial pressure loss in LPMs,which determines the onset of the Non-Darcy flow,was underestimated when using a power law expression of mean grain size.The constant B,an empirical value in the classical Ergun equation,typically equals 1.75.The inertial pressure loss in LPMs can be significantly different from it in single lager porous media.For Non-Darcy flow in LPMs,it is necessary to consider a modified larger constant B to improve the accuracy of the Ergun empirical equation.

Surface-borehole electric potential survey in layered media and its applications

The method in which a source is set on the surface and electric potential is received in the borehole is called surface-borehole electric potential technique. Technique of surface-borehole electric potential was employed to study electric response of layered formation. The electric potential was obtained by solving Poisson equation with finite difference method. In the course of calculation, forward modeling wilth finite difference method was realized by adopting bandwidth non-zero storage technique and the incomplete Cholesky conjugate gradient method. The results show that method of surface-borehole can acquire anomalous electric potential corresponding tc geo-electric layers. In addition, application of appropriate mathematical operator can improve the resolution. Moreover, overburden low resistivity layers have severe influence on measuring results of surface-borehole electric potential. However, bottom low resistivity layers play a positive role in the measurement.

Dispersion function of Rayleigh waves in porous layered half-space system

Rayleigh wave exploration is based on an elastic layered half-space model. If practical formations contain porous layers, these layers need to be simplified as an elastic medium. We studied the effects of this simplification on the results of Rayleigh wave exploration. Using a half-space model with coexisting porous and elastic layers, we derived the dispersion functions of Rayleigh waves in a porous layered half-space system with porous layers at different depths, and the problem of transferring variables to matrices of different orders is solved. To solve the significant digit overflow in the multiplication of transfer matrices, we propose a simple, effective method. Results suggest that dispersion curves differ in a low- frequency region when a porous layer is at the surface; otherwise, the difference is small.

ON FREE WAVE PROPAGATION IN ANISOTROPIC LAYERED MEDIA

The method of reverberation-ray matrix （MRRM） is extended and modified for the analysis of free wave propagation in anisotropic layered elastic media. A general, numerically stable formulation is established within the state space framework. The compatibility of physical variables in local dual coordinates gives the phase relation, from which exponentially growing functions are excluded. The interface and boundary conditions lead to the scattering relation, which avoids matrix inversion operation. Numerical examples are given to show the high accuracy of the present MRRM.

Perfectly matched layer implementation for ADI-FDTD in dispersive media

Alternating direction implicit finite difference time domain （ADI-FDTD） method is unconditionally stable and the maximum time step is not limited by the Courant stability condition, but rather by numerical error. Compared with the conventional FDTD method, the time step of ADI-FDTD can be enlarged arbitrarily and the CPU cost can be reduced. 2D perfectly matched layer （PML） absorbing boundary condition is proposed to truncate computation space for ADI-FDTD in dispersive media using recursive convolution（RC） method and the 2D PML formulations for dispersive media are derived. ADI-FDTD formulations for dispersive media can be obtained from the simplified PML formulations. The scattering of target in dispersive soil is simulated under sine wave and Gaussian pulse excitations and numerical results of ADI-FDTD with PML are compared with FDTD. Good agreement is observed. At the same time the CPU cost for ADI-FDTD is obviously reduced.

Reflection Characteristics of Layered Media in Polar Mesopause Related to Polar Mesosphere Summer Echoes

Polar mesosphere summer echoes （PMSE） are very strong radar echoes from alti- tudes close to the polar summer mesopause. The data from sounding rocket campaigns indicate that the radar signal to noise ratio （SNR）, electron density and dust charge density of polar meso- sphere in summer show obvious layered structure. In this paper the theory of wave propagation in layered media is used to study the reflectance and SNR at each layer in polar mesosphere. The calculated SNR using theory of dusty plasma is found in good agreement with the experimental result, which may imply that the intensity of the radar echoes reflected by the layered structure in polar mesosphere where polar mesosphere summer echoes used to occur can interpret partially the phenomenon of PMSE. In other words, reflection may play an important role in the occurrence of PMSE.

Experimental investigation on rainfall infiltration and solute transport in layered porous and fractured media

Layered structures with upper porous and lower fractured media are widely distributed in the world. An experimen- tal investigation on rainfall infiltration and solute transport in such layered structures can provide the necessary foundation for effectively preventing and forecasting water bursting in mines, controlling contamination of mine water, and accomplishing ecological restoration of mining areas. A typical physical model of the layered structures with porous and fractured media was created in this study. Then rainfall infiltration experiments were conducted after salt solution was sprayed on the surface of the layered structure. The volumetric water content and concentration of chlorine ions at different specified positions along the profile of the experiment system were measured in real-time. The experimental results showed that the lower fractured media, with a considerably higher permeability than that of the upper porous media, had significant effects on preventing water infil- tration. Moreover, although the porous media were homogeneous statistically in the whole domain, spatial variations in the features of effluent concentrations with regards to time, or so called breakthrough curves, at various sampling points located at the horizontal plane in the porous media near the porous-fractured interface were observed, indicating the diversity of solute transport at small scales. Furthermore, the breakthrough curves of the outflow at the bottom, located beneath the underlying fractured rock, were able to capture and integrate features of the breakthrough curves of both the upper porous and fractured media, which exhibited multiple peaks, while the peak values were reduced one by one with time.

Desorption of Cl^(-) from Mg-Al layered double hydroxide intercalated with Cl^(-) using CO_(2) gas and water

Mg-Al layered double hydroxide intercalated with CO_(3)^(2-)(CO_(3)·Mg-Al LDH) is effective for treating HCl exhaust gas.HCl reacts with CO_(3)^(2-) in CO_(3)·Mg-Al LDH, resulting in the formation of Cl·Mg-Al LDH.We propose that CO_(2) can be used for the desorption of Cl^(-)from Cl·Mg-Al LDH to regenerate CO_(3)·Mg-Al LDH.Herein,we studied the desorption of a from CI-Mg-Al LDH by adding water to Cl·Mg-Al LDH and blowing CO_(2) into it.We also analyzed the effects of temperature and water addition speed on the desorption of CI^(-)from Cl·Mg-Al LDH.Our results show that the added water adhered to CI·Mg-Al LDH and that CO_(2) in the gaseous phase was dissolved in this adhered water,thus generating CO_(3)^(2-).Therefore,anion exchange occurred between CO_(3)^(2-) and Cl^(-)in the Cl·Mg-Al LDH,thus desorbing Cl^(-).

Effect of nitrite intercalated Mg-Al layered double hydroxides on mortar durability under Cl−and SO_(4)^(2-) coexisting environment

The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-) binding properties of Mg-Al LDH-NO_(2) in simulated concrete pore solutions,Cl−and SO_(4)^(2-) diffusion properties of mortars with Mg-Al LDHNO 2 were examined.The steel corrosion and resistance of mortar against SO_(4)^(2-) attack were also evaluated.The results indicate that Mg-Al LDH-NO_(2) can effectively adsorb the Cl−and SO_(4)^(2-) in simulated concrete pore solution,and inhibit the diffusion of Cl−and SO_(4)^(2-) into cement mortars.The presence of SO_(4)^(2-) can greatly affect the uptake amount of Cl−,and there is a coupled effect of Cl−and SO_(4)^(2-) on their penetration into mortar specimens.In addition,Mg-Al LDH-NO_(2) can greatly upgrade the resistance of mortars against SO_(4)^(2-) attack and well prevent the steel from corrosion.However,Cl−will aggravate the SO_(4)^(2-) attack and SO_(4)^(2-) can initially decrease and then increase the steel corrosion.

Promoting surface reconstruction of NiFe layered double hydroxides via intercalating[Cr(C_(2)O_(4))_(3)]^(3-)for enhanced oxygen evolution

Rationally manipulating surface reconstruction of catalysts for water oxidation,inducing formation and dynamic accumulation of catalytically active centers still face numerous challenges.Herein,the introduction of[Cr(C_(2)O_(4))_(3)]^(3-)into NiFe LDHs by intercalation engineering to promote surface reconstruction achieves an advanced oxygen evolution reaction(OER)activity.In view of the weak electronegativity of Cr^(3+) in[Cr(C_(2)O_(4))_(3)]^(3-),the intercalation of[Cr(C_(2)O_(4))_(3)]^(3-)is expected to result in an electron-rich structure of Fe sites in NiFe LDHs,and higher valence state of Ni can be formed with the charge transfer between Fe and Ni.The optimized electronic structure of NiFe-[Cr(C_(2)O_(4))_(3)]^(3-)-LDHs with more active Ni^(3+) species and the expedited dynamic generation of Ni^(3+) (Fe)OOH phase during the OER process contributed to its excellent catalytic property,revealed by in situ X-ray absorption spectroscopy,Raman spectroscopy,and quasi-in situ X-ray photoelectron spectroscopy.With the modulated electronic structure of metal sites,NiFe-[Cr(C_(2)O_(4))_(3)]^(3-)-LDHs exhibited promoted OER property with a lower overpotential of 236 mV at the current density of 10 mA cm^(-2).This work illustrates the intercalation of conjugated anion to dynamically construct desired Ni^(3+) sites with the optimal electronic environment for improved OER electrocatalysis.

DYNAMIC BEHAVIOR OF PILES EMBEDDED IN TRANSVERSELY ISOTROPIC LAYERED MEDIA

Dynamic behavior of single pile embedded in transversely isotropic layered media is investigated using the finite element method combined with dynamic stiffness matrices of the soil derived from Green's function for ring loads. The influence of soil anisotropy on the dynamic behavior of piles is examined through a series of parametric studies.

Apparent resistivity of azimuthal anisotropy layered media

The electric field, equations of boundary conditions and calculation formula of apparent resistivity are derived for the azimuthal anisotropy layered media with the DC method based on the anisotropic Ohm's law. Taking the Schlumberger symmetric system as an example and using the recurrence formula of nuclear function, the paper theoretically simulates a model of four layers with the same anisotropy coefficient for each layer. The deep sounding curves of resistivity and the pattern of contours are obtained for the model. The results show that the theoretical formula is correct, and the deep sounding curves not only exhibit the difference of resistivity among layers but also indicate the anisotropy characteristics of layers.

Shear-horizontal transverse-electric seismoelectric waves in cylindrical double layer porous media

The shear-horizontal(SH) waves excited by the shear source in a borehole are easy to analyze due to the simple waveform. The borehole-side structures make the formation properties discontinuous. We consider a cylindrical double layer structure and study the borehole shear-horizontal and transverse-electric(SH-TE) seismoelectric waves. We first derive the expressions of the basic field quantities, and simulate the acoustic field and electric field using the real axis integral method. Compared with the wave fields of an infinitely homogeneous porous medium outside the borehole, the cylindrical layered structure makes the multi-mode cylindrical Love waves and their accompanying electric fields excited.Next, in order to study the interface response law of the inducing electric fields, we use the secant integral method to calculate the interface converted electromagnetic waves and analyze the causes of each component. It is found that an interface response occurs each time the SH wave impinges the interface in the layered porous medium. The results show that the SH-TE mode has a potential application for borehole-side interface detection in geophysical logs.

Seismic Waves in a Layered Half-Space from an Arbitrary Buried Source

In this paper, a transfer matrix and a three-dimensional dynamic response of a layered half-space to an arbitrary buried source are derived with the aid of a technique which combines the Laplace and two-dimensional Fourier transforms in a rectangular coordinate system. This method is clear in concept, and the corresponding formulas given in the paper are simple and convenient for marine seismic prospecting and other fields' applications. An example is presented and the calculated results are in good agreement with those of the finite element method (FEM).

INVESTIGATION ON THE SCATTERINGOF ELASTIC WAVES (P OR SV) BY A PLANEINTERFACE CRACK IN LAYERED MEDIA

In this paper, the scattering of elastic waves by a plane interface crack in Layered media is investigated. By Fourier integral transform, the method of transfer matrix is extended to the scattering of elastic waves by a plane interface crack in layered media, and the problems are reduced to a set of dual integral equations in matrix form. As an example, the far field modes of scattering of elastic waves by a plane interface crack in a layered half space have been presented. Amplitudes in far field modes are plotted versus incident wave frequency for several groups of different material combinations, and the numerical results show that resonance peaks occur at some frequencies. The frequencies at which the resonanse peaks occur for P and SV waves are almost the same.

Study on Folds of Equal Thickness Multi-layerSandwiched in Different Thickness Media

The theoretical model and non-homogeneous differential equation of equal thickness multi-layer folds sandwiched in different thickness and same character media are established by elastic and plastic mechanics. The special answer of the non-homogeneous differential equation and the common answer of the homogeneous differential equation are deduced by applying logistic equation and special function, and the dominant wavelength theory of equal thickness multi-layer folds sandwiched in different thickness and same character media. In addition, the experimental folding in both elastic and sticky materials proves the dominant wavelength theory.