Environmental availability and ecological risk assessment of heavy metals in zinc leaching residue

Four different methods,namely mineralogical analysis,three-stage BCR sequential extraction procedure,dynamic leaching test and Hakanson Potential Ecological Risk Index Method were used to access the environmental activity and potential ecological risks of heavy metals in zinc leaching residue.The results demonstrate that the environmental activity of heavy metals declines in the following order：CdZnCuAsPb.Potential ecological risk indices for single heavy metal are CdZnCuAsPb.Cd has serious potential ecological risk to the ecological environment and contributes most to the potential toxicity response indices for various heavy metals in the residue.

Static and Dynamic Leaching Experiments of Heavy Metals from Fly Ash-Based Geopolymers

The feasibility of high calcium fly ash （CFA）-based geopolymers to fix heavy metals were studied. The CFA-based geopolymers were prepared from CFA, flue gas desulfurization gypsum （FGDG）, and water treatment residual （WTR）. The static leaching showed that heavy metals concentrations from CFA- based geopolymers were lower than their maximum concentration limits according to the U.S. environmental protection law. And the encapsulated and fixed ratios of heavy metals by the CFA-based geopolymers were 96.02%-99.88%. The dynamic real-time leaching experiment showed that concentration of Pb （II） was less than 1.μg / L, Cr （VI） less than 3.25 mg / L, while Hg （II） less than 4.0 μg / L. Additionally, dynamic accumulated leaching concentrations were increased at the beginning of leaching process then kept stable. During the dynamic leaching process, heavy metals migrated and accumulated in an area near to the solid-solution interface. When small part of heavy metals in ＂the accumulated area＂ breached through the threshold value of physical encapsulation and chemical fixation they migrated into solution. The dynamic leaching ratios and effective diffusion coefficients of heavy metals from CFA-based geopolymer were very low and the long-term security of heavy metals in CFA-based geopolymer was safe.