Researches on Mischmetal Preventing Lead Segregation in High Lead Bronze

The effect of mischmetal addition on lead segregation in high lead bronze(grade ZQPb25-5)is studied in this paper.The testing results confirm that 0.5 to 1.0% misehmetal addition can effectively prevent lead from gravity and inverse segregation.The results of preventing lead from segregation respectively by mischmetal and nickel are also compared in the paper.The mischmetal addition in high lead bronze is distributed in the copper matrix mainly in the form of a compound which promotes early precipitation and refinement of α-dendrites, thus restraining the Pb-rich melt from either sinking to the bottom or escaping to the surface layer of the casting.As a result,the tendency of lead segregation is significantly decreased.Proper addition of mischmetal can also improve the mechanical properties,especially the ductility of high lead bronze.In addition,the contents of tin in high lead bronze can partially be substituted by mischmetal addition.

Microstructural characteristics and mechanical properties of bronze/steel bimetallic laminated composite prepared by protective atmosphere casting process

The bonding quality of bronze/steel bimetallic laminated composite is the key factor to whether it can be used in poor working conditions.In this study,bimetallic billets were prepared by the protective atmosphere casting process.The microstructural characteristics,mechanical properties and interface bonding mechanism of the bronze/steel bimetallic composites were analyzed comprehensively through a series of microstructure analysis(inicluding OM,SEM,and EDS)and mechanical properties tests.The experimental results demonstrate that the vaporization of lead(Pb)element in the bronze is only 0.4%in weight,and alloy elements are diffused into both sides at the interface.Moreover,the hardness in the bronze region exceeds 100.0 HV which indicates excellent wear resistance.Tensile and shear tests indicate that the fractures mainly occur on the bronze side with the interaction of the brittle fracture of Pb particles and the ductile fracture of Cu-Sn solid solution.The maximum tensile strength and shear strength reach 204.0 MPa and 211.0 MPa,respectively.These results demonstrate that the protective atmosphere casting process is applicable for the preparation of bronze/steel bimetallic laminated composite with high quality.