Lead powder obtained by potentiostatic electrodeposition from alkaline electrolyte, based on hydroxide ions, was investigated. The shape of lead crystals strongly depends on overpotentials of electrodeposition. The re...Lead powder obtained by potentiostatic electrodeposition from alkaline electrolyte, based on hydroxide ions, was investigated. The shape of lead crystals strongly depends on overpotentials of electrodeposition. The regular crystals are formed in the ohmic control. The shape of dendrites formed in the control of diffusion has a function of overpotentials of the electrodeposition. Increasing overpotential leads to branching of dendrites from primary type to those with developed tertiary branches. Formation of the very branchy dendrites of the strong （111） preferred orientation is explained on the basis of the affiliation of this electrolyte to the group of the complex Pb electrolytes.展开更多
基金Project(172046)supported by the Ministry of Education,Science and Technological Development of the Republic of Serbia
文摘Lead powder obtained by potentiostatic electrodeposition from alkaline electrolyte, based on hydroxide ions, was investigated. The shape of lead crystals strongly depends on overpotentials of electrodeposition. The regular crystals are formed in the ohmic control. The shape of dendrites formed in the control of diffusion has a function of overpotentials of the electrodeposition. Increasing overpotential leads to branching of dendrites from primary type to those with developed tertiary branches. Formation of the very branchy dendrites of the strong （111） preferred orientation is explained on the basis of the affiliation of this electrolyte to the group of the complex Pb electrolytes.
