Tumor deposits in axillary adipose tissue in patients with breast cancer:Do they matter?

Tumor deposits(TDs)are defined as discrete,irregular clusters of tumor cells lying in the soft tissue adjacent to but separate from the primary tumor,and are usually found in the lymphatic drainage area of the primary tumor.By definition,no residual lymph node structure should be identified in these tumor masses.At present,TDs are mainly reported in colorectal cancer,with a few reports in gastric cancer.There are very few reports on breast cancer(BC).For TDs,current dominant theories suggest that these are the result of lymph node metastasis of the tumor with complete destruction of the lymph nodes by the tumor tissue.Even some pathologists classify a TD as two lymph node metastases for calculation.Some pathologists also believe that TDs belong to the category of disseminated metastasis.Therefore,regardless of the origin,TDs are an indicator of poor prognosis.Moreover,for BC,sentinel lymph node biopsy is generally used at present.Whether radical axillary lymph node dissection should be adopted for BC with TDs in axillary lymph nodes is still inconclusive.The present commentary of this clinical issue has certain guiding significance.It is aimed to increase the awareness of the scientific community towards this under-recognized problem in BC pathology.

Depositional process of hyperpycnal flow deposits:A case study on Lower Cretaceous Sangyuan outcrop in the Luanping Basin,Northeast China

Sedimentary process research is of great significance for understanding the distribution and characteristics of sediments.Through the detailed observation and measurement of the Sangyuan outcrop in Luanping Basin,this paper studies the depositional process of the hyperpycnal flow deposits,and divides their depositional process into three phases,namely,acceleration,erosion and deceleration.In the acceleration phase,hyperpycnal flow begins to enter the basin nearby,and then speeds up gradually.Deposits developed in the acceleration phase are reverse.In addition,the original deposits become unstable and are taken away by hyperpycnal flows under the eroding force.As a result,there are a lot of mixture of red mud pebbles outside the basin and gray mud pebbles within the basin.In the erosion phase,the reverse deposits are eroded and become thinner or even disappear.Therefore,no reverse grading characteristic is found in the proximal major channel that is closer to the source,but it is still preserved in the middle branch channel that is far from the source.After entering the deceleration phase,normally grading deposits appear and cover previous deposits.The final deposits in the basin are special.Some are reverse,and others are normal.They are superimposed with each other under the action of hyperpycnal flow.The analysis of the Sangyuan outcrop demonstrates the sedimentary process and distribution of hyperpycnites,and reasonably explain the sedimentary characteristics of hyperpycnites.It is helpful to the prediction of oil and gas exploration targets in gravity flow deposits.

Mineralogical study and significance of the basalt-hosted Carlin-type Au deposits in southwestern Guizhou Province,China

The Jiadi and Damaidi gold deposits in southwest Guizhou Province are the largest basalt-hosted Carlintype gold deposits recently discovered in China.This study uses the Tescan Integrated Mineral Analyzer,supported by detailed field investigations,regional geological data,and extensive sample collections,including mineralized ore,altered wall rock,and unaltered basalt samples,for orebearing and geochemical analyses.Comparative analysis between altered and unaltered basalt samples revealed a mineral assemblage of sericite,quartz,and pyrite.This mineral composition forms through the hydrothermal alteration of unaltered basalt,originally containing feldspar,pyroxene,and ilmenite.The wall rock primarily features sericite,quartz,and hematite.During the alteration process,major,trace,and rare earth elements notably migrate.In the Jiadi deposit,K_(2)O,Rb,Au,and REE significantly increase,while Na_(2)O,CaO,MgO,and MnO decrease.SiO_(2),Al_(2)O_(3),and Fe_(2)O_(3)levels remain relatively stable.In the Damaidi deposit,K_(2)O,Rb,and Au enrich,contrasting with the depletion of Na_(2)O,CaO,MgO,and MnO,while SiO_(2),Fe_(2)O_(3),Al_(2)O_(3),TiO_(2),and REE show no significant changes.In the wall rock,TiO_(2),Al_(2)O_(3),K_(2)O,and REE increase,while Na_(2)O,CaO,MgO,and MnO decrease;SiO_(2)and Fe_(2)O_(3)content remains unchanged.The mineralization process likely originated from mid-to low-temperature,reductive magmatic hydrothermal fluids rich in CO_(2),CH_(4),N_(2),H^(+),S^(2-),HS^(-),H_(3)AsO_(3),and[Au(HS_(2)]^(-).These fluids migrated to tectonically weak zones in the Lianhuashan area,where Emeishan basalts are present.They reacted with Fe-bearing minerals in the basalt,such as ferro-hornblende and ilmenite,forming pyrite,arsenic-bearing pyrite,and arsenopyrite,thus enriching Au in these minerals.Additionally,K^(+)and H^(+)in the fluid reacted with plagioclase in the basalt,forming sericite and quartz.As the fluid entered the wall rock from structural weak zones,its oxidation increased,leading to the complete or partial reaction of Fe-bearing minerals in the wall rock,resulting in the formation of hematite or magnetite.This mineralization process is similar to that observed in carbonate-hosted Carlin-type gold deposits in southwest Guizhou,with the primary distinction being the iron source.In carbonate deposits,iron originates from ferridolomite within the wall rock,while in basalt-hosted deposits,it derives from ferripyroxene and ilmenite.

Effects of soil crust on the collapsing erosion of colluvial deposits with granite residual soil

Collapsing erosion is a unique phenomenon commonly observed on the granite residue hillslopes in the tropical and subtropical regions of southern China,characterized by its abrupt occurrence and significant erosion volumes.However,the impacts of soil crust conditions on the erosion of colluvial deposits with granite residual soils have only been studied to a limited extent.To address this issue,this study investigates the impacts of three soil crust conditions(i.e.,without crust,10-minute crust,and 20-minute crust)on gully morphology,rainfall infiltration,and runoff and sediment yield during slope erosion of colluvial deposits with granite residues(classified as Acrisols)in Yudu County,Ganzhou City,Jiangxi Province,China,using simulated rainfall tests and photographic methods.The results showed that as the strength of the soil crust increased,the capacity of moisture infiltration and the width and depth of the gully as well as the sediment concentration and yield ratio decreased;at the same time,the runoff ratio increased.The sediment yield in the without-crust test was found to be 1.24 and 1.43 times higher than that observed in the 10-minute crust and 20-minute crust tests,respectively.These results indicate that soil crusts can effectively prevent slope erosion and moisture infiltration,while providing valuable insights for the management of soil erosion in natural environments.

A Novel Three-stage Tectonic Model for Mississippi Valleytype Zn-Pb Deposits in Orogenic Fold-and-Thrust Belts

Mississippi Valley-type(MVT) Zn-Pb deposits predominantly form within both orogenic forelands and fold-andthrust belts, yet the mineralization process within the latter tectonic setting remains inadequately understood. This study, through a comprehensive review of MVT deposits across global fold-and-thrust belts, introduces a novel model elucidating the mineralization process in the context of tectonic belt evolution. It is demonstrated that during the stage Ⅰ, regional compression is introduced by early stages of plate convergence, causing the folding and thrusting and creating structural or lithological traps such as evaporite diapirs and unconformity-related carbonate dissolution-collapse structures. Thereafter, in stage Ⅱ, hydrocarbons begin to migrate and accumulate within these traps, where reduced sulfur is generated through thermochemical or bacterial sulfate reduction concurrent with or preceding Zn-Pb mineralization. In the subsequent stage Ⅲ, as plate convergence persists, the regional stress transitions from compression to transpression or extension. Under these conditions, steeply-dipping extensional faults are generated, facilitating the ascent of metalliferous brines into early-formed structural or lithological traps. Precipitation of Zn and Pb sulfides occurs through the mixing of Zn-Pb-transporting fluids with pre-existing reduced sulfur or by interaction with hydrocarbons.

Research on the Application of Electromagnetic Method in the Exploration of Altered Rock-type Gold Deposits in the East Kunlun Metallogenic Belt

Introduction The East Kunlun Orogenic Belt is located in the northeastern part of the Qinghai–Tibet Plateau(Li et al.,2007),stretching from the East Kunlun to the Elashan area in an east–west direction(Guo et al.,2018).It is an important part of the Central Orogenic Belt(Xiong et al.,2023).It is considered one of the important gold mineralization regions in the Tethys tectonic domain(Norbu et al.,2023)and an essential potential base for mineral resources in China.Wulonggou and Gouli gold mines have been discovered successively,earning the reputation of the"Golden Belt of Qinghai Province"(Feng et al.,2004;He et al.,2023).

Storm Liquefaction Deposits:A Possibility of Time Reversal in Sedimentary Strata of an Estuarial Coastal Area

In the sedimentary strata dating of estuarial coastal areas,it is often found that there is phenomenon of time-reversal in strata.The seabed sediments could be liquefied under storm waves.A laboratory wave flume experiment demonstrated that storm-induced liquefaction deposits are formed by the oscillations of liquefied sediments.In this paper,the particle size distribution and ^(210)Pb_(ex) specific activity of the sediment samples from the liquefaction disturbed zone and adjacent stable zone of the Yellow River Delta were tested.The stratigraphic divisions based on storm liquefaction deposit sequence can effectively explain the vertical changes in particle size and ^(210)Pb_(ex) specific activity.Due to the differentiation of particles during the storm induced liquefaction,coarse and fine particles regrouped,which could explain the phenomenon of time-reversal in dating data.

Estimation of lead and zinc emissions from mineral exploitation based on characteristics of lead/zinc deposits in China

Nonferrous mining activities are some of the largest sources of heavy metals emissions into the environment and China is one of the largest producers and consumers of lead and zinc in the world.The cumulative productions and emissions of lead and zinc from mining-related activities in China were estimated.Up to 2007,the cumulative productions of lead and zinc in China were estimated to be about 6.69 and 12.59 Mt,respectively;and about 1.62 Mt lead and 3.32 Mt zinc emitted into the ambient environment during the mining,processing and smelting activities,representing 24.39% and 26.36% cumulative production,respectively.Among these three types of mining-related activities,mineral processing contributes the most to the total emission of 50.67% lead and 45.51% zinc.

Three-dimensional orebody modelling and intellectualized longwall mining for stratiform bauxite deposits

Acoupled biharmonic spline and linear interpolation algorithm was proposed to create a three-dimensional smooth deposit model with minimal curvature containing grade and position data. To obtain the optimal technical parameters, such as cuttingheight and drum diameter, a virtual longwall mining procedure was modelled by simulating the actual fully mechanized longwall mining process. Based on the above work, a bauxite deposit in a longwall mining panel was modelled by scattered grade data from ores sampled on the entry wall. The deposit was then demarcated by industrial indexes and sliced according to the virtual longwallmining procedure. The results show that the proposed interpolation algorithm can depict the stratiform structure of bauxite depositsand that the uncovered bauxite deposit has high proportions of high-grade and rich ore. The ranges of optimal cutting height and drum diameters are 1.72-2.84 m and 1.42-1.72 m, respectively. Finally, an intellectualized longwall mining procedure was designed to guide the mining process with the lowest dilution and loss rates.

The conjunction of factors that lead to formation of giant gold provinces and deposits in non-arc settings

It is quite evident that it is not anomalous metal transport,nor unique depositional conditions,nor any single factor at the deposit scale,that dictates whether a mineral deposit becomes a giant or not.A hierarchical approach thus is required to progressively examine controlling parameters at successively decreasing scales in the total mineral system to understand the location of giant gold deposits in non-arc environments.For giant orogenic,intrusion-related gold systems（IRGS） and Carlin-type gold deposits and iron oxide-copper-gold（IOCG） deposits,there are common factors among all of these at the lithospheric to crustal scale.All are sited in giant gold provinces controlled by complex fundamental fault or shear zones that follow craton margins or,in the case of most Phanerozoic orogenic giants,define the primary suture zones between tectonic terranes.Giant provinces of IRGS,IOCG,and Carlin-type deposits require melting of metasomatized lithosphere beneath craton margins with ascent of hybrid lamprophyric to granitic magmas and associated heat flux to generate the giant province.The IRGS and IOCG deposits require direct exsolution of volatile-rich magmatic-hydrothermal fluids,whereas the association of such melts with Carlin-type ores is more indirect and enigmatic.Giant orogenic gold provinces show no direct relationship to such magmatism.forming from metamorphic fluids,but show an indirect relationship to lamprophyres that reflect the mantle connectivity of controlling first-order structures.In contrast to their province scale similarities,the different giant gold deposit styles show contrasting critical controls at the district to deposit scale.For orogenic gold deposits,the giants appear to have formed by conjunction of a greater number of parameters to those that control smaller deposits,with resultant geometrical and lithostratigraphic complexity as a guide to their location.There are few giant IRGS due to their inferior fluid-flux systems relative to orogenic gold deposits,and those few giants are essentially preservational exceptions.Many Carlin-type deposits are giants due to the exceptional conjunction of both structural and lithological parameters that caused reactive and permeable rocks,enriched in syngenetic gold,to be located below an impermeable cap along antiformal ＂trends＂.Hydrocarbons probably played an important role in concentrating metal.The supergiant Post-Betze deposit has additional ore zones in strain heterogeneities surrounding the pre-gold Goldstrike stock.All unequivocal IOCG deposits are giant or near-giant deposits in terms of gold-equivalent resources,partly due to economic factors for this relatively poorly understood,low Cu-Au grade deposit type.The supergiant Olympic Dam deposit,the most shallowly formed deposit among the larger IOCGs,probably owes its origin to eruption of volatile-rich hybrid magma at surface,with formation of a large maar and intense and widespread brecciation,alteration and Cu-Au-U deposition in a huge rock volume.

In, Sn, Pb and Zn Contents and Their Relationships in Ore-forming Fluids from Some In-rich and In-poor Deposits in China

All the indium-rich deposits with indium contents in ores more than 100×10^-6 seems to be of cassiterite-sulfide deposits or Sn-bearing Pb-Zn deposits, e.g., in the Dachang Sn deposit in Guangxi, the Dulong Sn-Zn deposit in Yunnan, and the Meng＇entaolegai Ag-Pb-Zn deposit in Inner Mongolia, the indium contents in ores range from 98×10^-6 to 236×10^-6 and show a good positive correlation with contents of zinc and tin, and their correlation coefficients are 0.8781 and 0.7430, respectively. The indium contents from such Sn-poor deposits as the Fozichong Pb-Zn deposit in Guangxi and the Huanren Pb-Zn deposit in Liaoning are generally lower than 10×10^-6, i.e., whether tin is present or not in a deposit implies the enrichment extent of indium in ores. Whether the In enrichment itself in the ore -forming fluids or the ore-forming conditions has actually caused the enrichment/depletion of indium in the deposits？ After studying the fluid inclusions in quartz crystallized at the main stage of mineralization of several In-rich and In-poor deposits in China, this paper analyzed the contents and studied the variation trend of In, Sn, Pb and Zn in the ore-forming fluids. The results show that the contents of lead and zinc in the ore-forming fluids of In-rich and -poor deposits are at the same level, and the lead contents range from 22×10^-6 to 81×10^-6 and zinc from 164×10^-6 to 309×10^-6, while the contents of indium and tin in the ore-forming fluids of In-rich deposits are far higher than those of Inpoor deposits, with a difference of 1-2 orders of magnitude. Indium and tin contents in ore-forming fluid of In-rich deposits are 1.9×10^-6-4.1×10^-6 and 7×10^-6-55×10^-6, and there is a very good positive correlation between the two elements, with a correlation coefficient of 0.9552. Indium and tin contents in ore-forming fluid of In-poor deposits are 0.03×10^-6-0.09×10^-6 and 0.4×10^-6-2.0×10^-6, respectively, and there is no apparent correlation between them. This indicates, on one hand, that In-rich oreforming fluids are the material basis for the formation of In-rich deposits, and, on the other hand, tin probably played a very important role in the transport and enrichment of indium.

M agmatic Gold Mineralization in the Western Qinling Orogenic Belt: Geology and Metallogenesis of the Baguamiao,Liba and Xiaogouli Gold Deposits

The superlarge Baguamiao, large Liba and Xiaogouli gold deposits represent three typical gold deposits different from the Carlin type in the western Qinling Orogenic Belt. Based on Ar-Ar dating of quartz from ores, U-Pb dating of single zircon from granite, tracing of H and O isotopes and studies on the mineralogy and texture of spots and bleached alteration developed in wall rocks, this paper focuses the relations between gold deposits and granite to clarify the origin of gold deposits and the metallogenesis in the tectonic evolution of the Qinling Orogenic Belt. The comprehensive studies show that the age of the granite (148.1-244 Ma) is identical with that of the gold deposits (131.91-232.56 Ma). It is suggested that the granite has close temporal, spatial and genetic relationship with the gold deposits. The granite provides a heat source, water source and considerable amount of ore-forming material. Finally, it is concluded that the orogeny by collision, emplacement of the granite and positioning of the gold deposits represent a successive process. Both the granite and gold deposits resulted from the syn-orogeny and post-orogeny tectonic evolution.

Giant Mineral Deposits and Their Geodynamic Setting in the Lanping Basin, Yunnan, China

There are giant mineral deposits, including the Jinding Zn-Pb and Baiyangping Ag-Co-Cu, and otherimportant mineral deposits (e.g., Baiyangchang Ag-Cu, Jinman Cu deposits, etc.) in the Lanping Mesozoic-Cenozoic Basin, Yunnan Province, China. The tabular ore-bodies and some veins hosted in terrestrial clastic rocks of the Mesozoic-Cenozoic age and no outcropping of igneous rocks in the giant deposits lead to the proposal of syngenetic origin, but the giant mineral deposits are not stratabound (e.g. MVT, sandstone- and Sedex-type). They formed in a continental red basin with intense crust movement. The mineralization is controlled by structures and lithology and occurs in different strata, and no sedimentary nature and no exhalative sediments are identified in the deposits. The deposits show some relations with organic matter (now asphalt and petroleum) and evaporates (gypsum). The middle-low-temperature (mainly 110℃ to 280℃) mineralization took place at a depth of about 0.9 km to 3.1 km during the early Himalayan (58 to 67 Ma). The salinity of ore-forming fluids is surprisingly low (1.6% to 18.0 wt% (NaCl)eq). Affected by the collision of the Indian and Eurasian plates, the mantle is disturbed under the Lanping Basin. The large-scale mineralization is closely linked with the geodynamics of the crust movement, the mantle and mantle-flux upwelling and igneous activity. Giant mineral deposits and their geodynamic setting are unique in the Lanping Basin.

Laumontitization as an Exploration Indicator of Epithermal Gold Deposits: A Case Study of the Axi and Other Epithermal Systems in West Tianshan, China

In the light of field investigation, microscopic study, X\|ray phase analysis and mineral infrared spectral analysis, it is considered that laumontitization is of extensive occurrence in the Axi gold orefield. The development of laumontitization and its relationship to mineralization show that the laumontitization appeared mainly at the top of and in the periphery of orebodies, and occurred at the edge of the epithermal system or at the late stage of epithermal system evolution. Therefore, laumontitization can be used as an exploration indicator of epithermal gold deposits. The fluids responsible for laumontitization in the Axi gold orefield are similar to those producing hot spring\|type gold deposits or those from modern geothermal fields. Epithermal mineralization of the Axi gold deposit was dated at Carboniferous, indicating that the West Tianshan of China is a region favorable to epithermal\|type gold mineralization and preservation. Hence the West Tianshan of China is a target area for exploring epithermal gold deposits.

Control of Deep Tectonics on the Superlarge Deposits in China

Seventy-three large-superlarge deposits in China were formed in 4 metallogenic epochs, and located in 6 metallogenic domains. By combing their time-space distribution and the relevant data of crustal thickness, we discuss the control conditions of deep tectonics on superlarge deposits. The various spatial variation of the crustal thickness where deposits locate is closely related to their different tectonic setting. The crustal thickness of the region where deposits are in the Precatnbrian metallogenic epoch is 37.1 km and shows double-peak distribution, which is related to the different tectonic-mineralization processes in the Tarim-North China and Yangtze metallogenic domains. The crustal thickness of the region where deposits are in the Paleoproterozoic metallogenic epoch is 43.4 km and shows normal distribution, which is the result of 'pure' mineralization setting. The crustal thickness of the region where deposits are in the Late Palaeozoic-Early Mesozoic metallogenic epoch is about 41.2 km and shows multi-peak distribution, which can be related with dispersing distribution in the metallogenic domain of these superlarge deposits. The crustal thickness of the region where deposits are in the post-Indosinian metallogenic epoch is 37.3 km, and shows skew distribution, which resulted from different tectonic settings in eastern and western China.

Metallogenic Epoch of Nonferrous Metallic and Silver Deposits in the Jiaodong Peninsula, China and its Geological Significance

As China＇s most important gold-producing district, the Jiaodong Peninsula also contains copper, lead-zinc, molybdenum （tungsten）, and other nonferrous metal ore deposits, but the space-time and genetic relationships with gold deposits remain uncertain. To investigate the temporal relationship between these nonferrous metal and gold ore deposits, We collected the samples from a number of nonferrous metallic and silver deposits and metallogenetic rock bodies in the eastern Jiaodong Peninsula for isotopic dating. The results show that the Re-Os isotopic model ages of the Lengjia molybdenum deposit in Rongcheng range from 114.5 ± 1.8 Ma to 112.6 ± 1.5 Ma, with an average age of 113.6 ± 1.6 Ma; the LA-ICP-MS ^206pb/^238U ages of 33 zircons in the sericitization porphyritic monzogranite that hosts the Tongjiazhuang silver deposit in Rongcheng range between 122 Ma and 109 Ma, with a weighted mean age of 116.04 ± 0.95 Ma; the LA-ICP-MS ^206pb/^238U ages of 31 zircons in the copper metallogenic pyroxene monzodiorite that hosts the Kuangbei copper deposit in Rongcheng range from 126 Ma to 106 Ma, with a weighted mean age of 116.6 ± 1.7 Ma; and the LA-ICP-MS ^206pb/^238U ages of 19 zircons in the pyroxene monzodiorite surrounding the Dadengge gold and multimetal deposit in Weihai range from 113 Ma to 110 Ma, with a weighted mean age of 111.7 ± 0.6 Ma. All these results indicate that the metallogenic ages of the silver and nonferrous metallic deposits in the Jiaodong Peninsula are in a limited range from 118 Ma to 111 Ma. Previous studies have demonstrated that the isotopic ages of gold deposits in the Jiaodong Peninsula range from 123 Ma to 110 Ma, while Weideshanian magmatism occurred between 126 Ma to 108 Ma. Both these ranges are grossly consistent with the metallogenic ages of silver and nonferrous metallic deposits in this study, suggesting that the large-scale mineralization occurred in the Early Cretaceous when magmatic activities were strong. This epoch may be linked to the lithosphere thinning and the thermo-upwelling extension in eastern China at that time. In addition, field investigation also shows that gold and nonferrous metallic deposits are distributed nearby the Weideshanian granite, with the nonferrous metallic deposits lying within or surrounding the granite pluton and the gold deposits outside the granite pluton. We propose the following mineralization scenario： In the Early Cretaceous, an intensive lithospheric extension induced partial melting and degassing of the metasomatized lithospheric mantle, which resulted in the formation of mantle-derived fluids enriched in metal elements. During the rapid process of magma ascent and intrusion, crust-derived fluids were activated by the magmatic thermal dome and served to further extract ore-forming materials from the crust. These fluids may have mixed with the mantle-derived fluid to form a crust-mantle mixing-type ore-forming fluid. The high-temperature conditions in the center or in contact with the granitic magmatic thermal dome would have been favorable for the formation of porphyry-type, skarn-type, and hydrothermal-vein-type ores, thus forming a series of Mo（W）, Cu, and Pb-Zn deposits in the mid-eastern Jiaodong Peninsula. In contrast, the medium- to low-temperature conditions in the periphery of the magmatic thermal dome would have favored the deposition of gold （silver） ores under the appropriate physiochemical and structural conditions. The metaliogenic epoch of the molybdenum, copper, and silver deposits, and their spatio-temporal and genetic relations to the gold deposits, as demonstrated in this study, not only provide important insights to the study of regional metallogeny, our understanding of the metallogenesis of the Jiaodong type gold deposit, and the geodynamic background of the large-scale mineralization in the Jiaodong Peninsula, but also have practical value in guiding the mineral exploration.

Further Information of the Associated Li Deposits in the No.6 Coal Seam at Jungar Coalfield, Inner Mongolia, Northern China

Total 138 coal samples and 14 parting samples were taken from the No. 6 Seam of the Jungar Coalfield, Inner Mongolia. These samples were analysed by optical microscopy, sequential chemical extraction procedure （SCEP）, inductively coupled plasma mass spectrometry （ICP-MS）, X-ray powder diffraction （XRD）, and scanning electron microscope in conjunction with an energy-dispersive X-ray spectrometer （SEM-EDX） analysis. The results indicate that the Li contents have reached the industrial grade of the coal associated Li deposit, and the total Li reserves have reached 2406600 tons, that is, 5157000 tons Li2O in the No. 6 seam in the Jungar Coalfield. The sequential chemical extraction procedure results suggest that the Li concentration is mainly related to inorganic matter. The minerals in the coals consist of kaolinite, boehmite, chlorite-group mineral, quartz, calcite, pyrite, siderite and amorphous clay material. Some Li could be absorbed by clay minerals in the Li-bearing coal seam. The chlorite phase？could be？most likely the host for a part of Li. The Yinshan Oldland should be the most possible source of Li of the coal.

Re-Os geochronology of Cu and W-Mo deposits in the Balkhash metallogenic belt,Kazakhstan and its geological significance

The Central Asian metallogenic domain （CAMD） is a multi-core metallogenic system controlled by boundary strike-slip fault systems. The Balkhash metallogenic belt in Kazakhstan, in which occur many large and super-large porphyritic Cu--Mo deposits and some quartz vein- and greisen-type W-Mo deposits, is a well-known porphyritic Cu--Mo metallogenic belt in the CAMD. In this paper 11 molybdenite samples from the western segment of the Balkhash metallogenic belt are selected for Re--Os compositional analyses and Re--Os isotopic dating. Molybdenites from the Borly porphyry Cu deposit and the three quartz vein-greisen W--Mo deposits--East Kounrad, Akshatau and Zhanet--all have relatively high Re contents （2712--2772 μg/g for Borly and 2.267--31.50 μg/g for the other three W-Mo deposits）, and lower common Os contents （0.670-2.696 ng/g for Borly and 0.0051--0.056 ng/g for the other three）. The molybdenites from the Borly porphyry Cu--Mo deposit and the East Kounrad, Zhanet, and Akshatau quartz vein- and greisen-type W-Mo deposits give average model Re--Os ages of 315.9 Ma, 298.0 Ma, 295.0 Ma, and 289.3 Ma respectively. Meanwhile, molybde- nites from the East Kounrad, Zhanet, and Akshatan W-Mo deposits give a Re--Os isochron age of 297.9 Ma, with an MSWD value of 0.97. Re--Os dating of the molybdenites indicates that Cu-W-Mo metallogenesis in the western Balkhash metallogeuic belt occurred during Late Carboniferous to Early Permian （315.9--289.3 Ma）, while the porphyry Cu--Mo deposits formed at ~316 Ma, and the quartz vein-greisen W--Mo deposits formed at ~298 Ma. The Re--Os model and isochron ages thus suggest that Late Carboniferous porphyry granitoid and pegmatite magmatism took place during the late Hercy- nian movement. Compared to the Junggar-East Tianshan porphyry Cu metallogenic belt in northwestern China, the formation of the Cu-Mo metallogenesis in the Balkhash rnetallogenic belt occurred between that of the Tuwu-Yandong in East Tianshan and the Baogutu porphyry Cu deposits in West Junggar. Collectively, the large-scale Late Carboniferous porphyry Cu-Mo metallogenesis in the Central Asian metallogenic domain is related to Hercynian tectono-magmatic activities.

Geotectonic Settings of Large and Superlarge Mineral Deposits on the Southwestern Margin of the North China Plate

The geotectonic setting refers to the three-dimensional space and relatedevents based on which a metallogenic system is formed and an ore-forming process takes place. Thispaper discusses the tectonic evolution of the southwestern margin of the North China paleocontinentand related geotectonic settings in which large or superlarge deposits are formed. Emphasis is puton the geodynamic conditions of the Jinchuan nickel-copper deposit, the Baiyin copper-polymetallicdeposit and the Hanshan gold deposit. It is significant that the three deposits occur together as a'trinity' on the same paleocontinental margin. The Jinchuan nickel-copper deposit was formed duringthe early stage of rifting of the paleocontinental margin; the Baiyin copper-polymetallic depositwas formed during the splitting stage of a continental-margin arc. The continental-margin arcspitting resulted in an 'island arc rift' in the early stage of evolution. The Hanshan gold depositwas formed within the Altun sinistral strike-slip fault system and its provenance is the'intraoceanic arc' volcanic rocks.

From mantle to critical zone:A review of large and giant sized deposits of the rare earth elements

The rare earth elements are unusual when defining giant-sized ore deposits,as resources are often quoted as total rare earth oxide,but the importance of a deposit may be related to the grade for individual,or a limited group of the elements.Taking the total REE resource,only one currently known deposit（Bayan Obo） would class as giant（〉1.7×10^7 tonnes contained metal）,but a range of others classify as large（〉1.7×10^6 tonnes）.With the exception of unclassified resource estimates from the Olympic Dam 10 CG deposit,all of these deposits are related to alkaline igneous activity- either carbonatites or agpaitic nepheline syenites.The total resource in these deposits must relate to the scale of the primary igneous source,but the grade is a complex function of igneous source,magmatic crystallisation,hydrothermal modification and supergene enrichment during weathering.Isotopic data suggest that the sources conducive to the formation of large REE deposits are developed in subcontinental lithospheric mantle,enriched in trace elements either by plume activity,or by previous subduction.The reactivation of such enriched mantle domains in relatively restricted geographical areas may have played a role in the formation of some of the largest deposits（e.g.Bayan Obo）.Hydrothermal activity involving fluids from magmatic to meteoric sources may result in the redistribution of the REE and increases in grade,depending on primary mineralogy and the availability of ligands.Weathering and supergene enrichment of carbonatite has played a role in the formation of the highest grade deposits at Mount Weld（Australia） and Tomtor（Russia）.For the individual REE with the current highest economic value（Nd and the HREE）,the boundaries for the large and giant size classes are two orders of magnitude lower,and deposits enriched in these metals（agpaitic systems,ion absorption deposits） may have significant economic impact in the near future.