Let P∈C^(m×m)and Q∈C^(n×n)be Hermitian and{k+1}-potent matrices,i.e.,P k+1=P=P∗,Qk+1=Q=Q∗,where(·)∗stands for the conjugate transpose of a matrix.A matrix X∈C m×n is called{P,Q,k+1}-reflexive(an...Let P∈C^(m×m)and Q∈C^(n×n)be Hermitian and{k+1}-potent matrices,i.e.,P k+1=P=P∗,Qk+1=Q=Q∗,where(·)∗stands for the conjugate transpose of a matrix.A matrix X∈C m×n is called{P,Q,k+1}-reflexive(anti-reflexive)if P XQ=X(P XQ=−X).In this paper,the least squares solution of the matrix equation AXB=C subject to{P,Q,k+1}-reflexive and anti-reflexive constraints are studied by converting into two simpler cases:k=1 and k=2.展开更多
Inconel 718 is the most popular nickel-based superalloy and is extensively used in aerospace,automotive,and energy indus-tries owing to its extraordinary thermomechanical properties.The effects of different two-step s...Inconel 718 is the most popular nickel-based superalloy and is extensively used in aerospace,automotive,and energy indus-tries owing to its extraordinary thermomechanical properties.The effects of different two-step solid solution treatments on microstructure andδphase precipitation of Inconel 718 alloy were studied,and the transformation mechanism fromγ″metastable phase toδphase was clarified.The precipitates were statistically analyzed by X-ray diffractometry.The results show that theδphase content firstly increased,and then decreased with the temperature of the second-step solid solution.The changes in microstructure andδphase were studied by scanning electron microscopy and transmission electron microscopy.An intragranularδphase formed in Inconel 718 alloy at the second-[100]_(δ)[011]γ step solid solution temperature of 925℃,and its orientation relationship withγmatrix was determined as//and(010)_(δ)//(111)γ.Furthermore,the Vickers hardness of different heat treatment samples was measured,and the sample treated by second-step solid solution at 1010℃ reached the maximum hardness of HV 446.84.展开更多
Least squares projection twin support vector machine(LSPTSVM)has faster computing speed than classical least squares support vector machine(LSSVM).However,LSPTSVM is sensitive to outliers and its solution lacks sparsi...Least squares projection twin support vector machine(LSPTSVM)has faster computing speed than classical least squares support vector machine(LSSVM).However,LSPTSVM is sensitive to outliers and its solution lacks sparsity.Therefore,it is difficult for LSPTSVM to process large-scale datasets with outliers.In this paper,we propose a robust LSPTSVM model(called R-LSPTSVM)by applying truncated least squares loss function.The robustness of R-LSPTSVM is proved from a weighted perspective.Furthermore,we obtain the sparse solution of R-LSPTSVM by using the pivoting Cholesky factorization method in primal space.Finally,the sparse R-LSPTSVM algorithm(SR-LSPTSVM)is proposed.Experimental results show that SR-LSPTSVM is insensitive to outliers and can deal with large-scale datasets fastly.展开更多
In this paper, an efficient computational approach is proposed to solve the discrete time nonlinear stochastic optimal control problem. For this purpose, a linear quadratic regulator model, which is a linear dynamical...In this paper, an efficient computational approach is proposed to solve the discrete time nonlinear stochastic optimal control problem. For this purpose, a linear quadratic regulator model, which is a linear dynamical system with the quadratic criterion cost function, is employed. In our approach, the model-based optimal control problem is reformulated into the input-output equations. In this way, the Hankel matrix and the observability matrix are constructed. Further, the sum squares of output error is defined. In these point of views, the least squares optimization problem is introduced, so as the differences between the real output and the model output could be calculated. Applying the first-order derivative to the sum squares of output error, the necessary condition is then derived. After some algebraic manipulations, the optimal control law is produced. By substituting this control policy into the input-output equations, the model output is updated iteratively. For illustration, an example of the direct current and alternating current converter problem is studied. As a result, the model output trajectory of the least squares solution is close to the real output with the smallest sum squares of output error. In conclusion, the efficiency and the accuracy of the approach proposed are highly presented.展开更多
Near-infrared (NIR) spectroscopy was applied to reagent-free quantitative analysis of polysaccharide of a brand product of proprietary Chinese medicine (PCM) oral solution samples. A novel method, called absorbance up...Near-infrared (NIR) spectroscopy was applied to reagent-free quantitative analysis of polysaccharide of a brand product of proprietary Chinese medicine (PCM) oral solution samples. A novel method, called absorbance upper optimization partial least squares (AUO-PLS), was proposed and successfully applied to the wavelength selection. Based on varied partitioning of the calibration and prediction sample sets, the parameter optimization was performed to achieve stability. On the basis of the AUO-PLS method, the selected upper bound of appropriate absorbance was 1.53 and the corresponding wavebands combination was 400 - 1880 & 2088 - 2346 nm. With the use of random validation samples excluded from the modeling process, the root-mean-square error and correlation coefficient of prediction for polysaccharide were 27.09 mg·L<sup>-</sup><sup>1</sup> and 0.888, respectively. The results indicate that the NIR prediction values are close to those of the measured values. NIR spectroscopy combined with AUO-PLS method provided a promising tool for quantification of the polysaccharide for PCM oral solution and this technique is rapid and simple when compared with conventional methods.展开更多
In this paper, least-squaxes mirrorsymmetric solution for matrix equations (AX = B, XC = D) and its optimal approximation is considered. With special expression of mirrorsymmetric matrices, a general representation of...In this paper, least-squaxes mirrorsymmetric solution for matrix equations (AX = B, XC = D) and its optimal approximation is considered. With special expression of mirrorsymmetric matrices, a general representation of solution for the least-squares problem is obtained. In addition, the optimal approximate solution and some algorithms to obtain the optimal approximation are provided.展开更多
A real n×n symmetric matrix X=(x_(ij))_(n×n)is called a bisymmetric matrix if x_(ij)=x_(n+1-j,n+1-i).Based on the projection theorem,the canonical correlation de- composition and the generalized singular val...A real n×n symmetric matrix X=(x_(ij))_(n×n)is called a bisymmetric matrix if x_(ij)=x_(n+1-j,n+1-i).Based on the projection theorem,the canonical correlation de- composition and the generalized singular value decomposition,a method useful for finding the least-squares solutions of the matrix equation A^TXA=B over bisymmetric matrices is proposed.The expression of the least-squares solutions is given.Moreover, in the corresponding solution set,the optimal approximate solution to a given matrix is also derived.A numerical algorithm for finding the optimal approximate solution is also described.展开更多
Three types of expression in the dark-soliton perturbation theory based on squared Jost solutions are invesgigaged in ghis paper. It is shown that there are three formally different results about the effects of pertur...Three types of expression in the dark-soliton perturbation theory based on squared Jost solutions are invesgigaged in ghis paper. It is shown that there are three formally different results about the effects of perturbagion on a dark soliton, and it is proved by means of a transformation between two integral variables that they are essentially equivalent.展开更多
In the osmotic dehydration process of food,on-line estimation of concentrations of two components in ternary solution with NaCl and sucrose was performed based on multi-functional sensing technique.Moving Least Square...In the osmotic dehydration process of food,on-line estimation of concentrations of two components in ternary solution with NaCl and sucrose was performed based on multi-functional sensing technique.Moving Least Squares were adopted in approximation procedure to estimate the viscosity of such interested ternary solution with the given data set.As a result,in one mode of using total experimental data as calibration data and validation data,the relative deviations of estimated viscosities are less than ±1.24%.In the other mode,by taking total experimental data except the ones for estimation as calibration data,the relative deviations are less than ±3.47%.In the same way,the density of ternary solution can be also estimated with deviations less than ± 0.11% and ± 0.30% respectively in these two models.The satisfactory and accurate results show the extraordinary efficiency of Moving Least Squares behaved in signal approximation for multi-functional sensors.展开更多
A nonlinear problem of mean-square approximation of a real nonnegative continuous function with respect to two variables by the modulus of double Fourier integral dependent on two real parameters with use of the smoot...A nonlinear problem of mean-square approximation of a real nonnegative continuous function with respect to two variables by the modulus of double Fourier integral dependent on two real parameters with use of the smoothing functional is studied. Finding the optimal solutions of this problem is reduced to solution of the Hammerstein type two-dimensional nonlinear integral equation. The numerical algorithms to find the branching lines and branching-off solutions of this equation are constructed and justified. Numerical examples are presented.展开更多
Necessary and sufficient conditions are derived for some matrix equations that have a common least-squares solution.A general expression is provided when certain resolvable conditions are satisfied.This research exten...Necessary and sufficient conditions are derived for some matrix equations that have a common least-squares solution.A general expression is provided when certain resolvable conditions are satisfied.This research extends existing work in the literature.展开更多
This paper presents a new highly parallel algorithm for computing the minimum-norm least-squares solution of inconsistent linear equations Ax = b(A∈Rm×n,b∈R (A)). By this algorithm the solution x = A + b is obt...This paper presents a new highly parallel algorithm for computing the minimum-norm least-squares solution of inconsistent linear equations Ax = b(A∈Rm×n,b∈R (A)). By this algorithm the solution x = A + b is obtained in T = n(log2m + log2(n - r + 1) + 5) + log2m + 1 steps with P=mn processors when m × 2(n - 1) and with P = 2n(n - 1) processors otherwise.展开更多
Under the Flaschka-Newell Lax pair,the Darboux transformation for the Painlevé-Ⅱequation is constructed by the limiting technique.With the aid of the Darboux transformation,the rational solutions are represented...Under the Flaschka-Newell Lax pair,the Darboux transformation for the Painlevé-Ⅱequation is constructed by the limiting technique.With the aid of the Darboux transformation,the rational solutions are represented by the Gram determinant,and then we give the large y asymptotics of the determinant and the rational solutions.Finally,the solution of the corresponding Riemann-Hilbert problem is obtained from the Darboux matrices.展开更多
A norm of a quaternion matrix is defined. The expressions of the least square solutions of the quaternion matrix equation AX = B and the equation with the constraint condition DX = E are given.
Data coming from different sources have different types and temporal states. Relations between one type of data and another ones, or between data and unknown parameters are almost nonlinear. It is not accurate and rel...Data coming from different sources have different types and temporal states. Relations between one type of data and another ones, or between data and unknown parameters are almost nonlinear. It is not accurate and reliable to process the data in building the digital earth with the classical least squares method or the method of the common nonlinear least squares. So a generalized nonlinear dynamic least squares method was put forward to process data in building the digital earth. A separating solution model and the iterative calculation method were used to solve the generalized nonlinear dynamic least squares problem. In fact, a complex problem can be separated and then solved by converting to two sub problems, each of which has a single variable. Therefore the dimension of unknown parameters can be reduced to its half, which simplifies the original high dimensional equations.展开更多
In this paper, we discuss least squares symmetrizable solutions of matrix equations (AX = B, XC = D) and its optimal approximation solution. With the matrix row stacking, Kronecker product and special relations betwee...In this paper, we discuss least squares symmetrizable solutions of matrix equations (AX = B, XC = D) and its optimal approximation solution. With the matrix row stacking, Kronecker product and special relations between two linear subspaces are topological isomorphism, and we derive the general solutions of least squares problem. With the invariance of the Frobenius norm under orthogonal transformations, we obtain the unique solution of optimal approximation problem. In addition, we present an algorithm and numerical experiment to obtain the optimal approximation solution.展开更多
Let be a given Hermitian matrix satisfying . Using the eigenvalue decomposition of , we consider the least squares solutions to the matrix equation , with the constraint .
The synthesis of sodium ferrite and its desulfurization performance in S2 -bearing sodium aluminate solutions were investigated. The thermodynamic analysis shows that the lowest temperature is about 810 K for synthesi...The synthesis of sodium ferrite and its desulfurization performance in S2 -bearing sodium aluminate solutions were investigated. The thermodynamic analysis shows that the lowest temperature is about 810 K for synthesizing sodium ferrite by roasting the mixture of ferric oxide and sodium carbonate. The results indicate that the formation process of sodium ferrite can be completed at 1173 K for 60 min, meanwhile raising temperature and reducing NazCO3 particle size are beneficial to accelerating the formation of sodium ferrite. Sodium ferrite is an efficient desulfurizer to remove the S2- in aluminate solution, and the desulfurization rate can reach approximately 70% at 373 K for 60 min with the molar ratio of iron to sulfur of 1:1-1.5:1. Furthermore, the desulfurization is achieved by NaFeS2·2H2O precipitation through the reaction of Fe(OH)4 and S^2- in aluminate solution, and the desulfurization efficiency relies on the Fe(OH)4^- generated by dissolving sodium ferrite.展开更多
Linear Least Squares(LLS) problems are particularly difficult to solve because they are frequently ill-conditioned, and involve large quantities of data. Ill-conditioned LLS problems are commonly seen in mathematics...Linear Least Squares(LLS) problems are particularly difficult to solve because they are frequently ill-conditioned, and involve large quantities of data. Ill-conditioned LLS problems are commonly seen in mathematics and geosciences, where regularization algorithms are employed to seek optimal solutions. For many problems, even with the use of regularization algorithms it may be impossible to obtain an accurate solution. Riley and Golub suggested an iterative scheme for solving LLS problems. For the early iteration algorithm, it is difficult to improve the well-conditioned perturbed matrix and accelerate the convergence at the same time. Aiming at this problem, self-adaptive iteration algorithm(SAIA) is proposed in this paper for solving severe ill-conditioned LLS problems. The algorithm is different from other popular algorithms proposed in recent references. It avoids matrix inverse by using Cholesky decomposition, and tunes the perturbation parameter according to the rate of residual error decline in the iterative process. Example shows that the algorithm can greatly reduce iteration times, accelerate the convergence,and also greatly enhance the computation accuracy.展开更多
The three-way catalysts (TWCs) promoters Ce0.6Zr0.4- x TbxO2-y were prepared by sol-gel method. BET surface areas analysis indicated that an increase of the dopant Tb content from x = 0.05 to x = 0.15 favors an incr...The three-way catalysts (TWCs) promoters Ce0.6Zr0.4- x TbxO2-y were prepared by sol-gel method. BET surface areas analysis indicated that an increase of the dopant Tb content from x = 0.05 to x = 0.15 favors an increase of surface area from 66.8 to 80.4 m^2· g^-1 compared with the undoped sample Ce0 .6oZr0.40O2 65.1 m^2·g^- 1 after calcination at 650℃. Transmission electron microscopy (TEM) observation indicated that the doped samples have a higher thermal stability. The XRD and Raman spectra confirmed that the Ce0.6Zr0.4-xTbxO2-y cubic solid solution is formed. XPS analysis revealed that Ce and Tb mainly existed in the form of Ce^4+ and Tb^3 + , and Zr existed in the form of Zr^4+ on the surface of the samples. The doped samples were homogenous in composition ; the introduction of Tb into the CeO2-ZrO2 promoters resuited in the formation of a solid solution, and the concentration of surface lattice oxygen was increased.展开更多
基金Supported by the Education Department Foundation of Hebei Province(Grant No.QN2015218).
文摘Let P∈C^(m×m)and Q∈C^(n×n)be Hermitian and{k+1}-potent matrices,i.e.,P k+1=P=P∗,Qk+1=Q=Q∗,where(·)∗stands for the conjugate transpose of a matrix.A matrix X∈C m×n is called{P,Q,k+1}-reflexive(anti-reflexive)if P XQ=X(P XQ=−X).In this paper,the least squares solution of the matrix equation AXB=C subject to{P,Q,k+1}-reflexive and anti-reflexive constraints are studied by converting into two simpler cases:k=1 and k=2.
基金supported by the National Natural Science Foundation of China(Nos.52201203 and 52171107)the Hebei Provincial Natural Science Foundation,China(No.E2021501026)+1 种基金the National Natural Science Foundation of China-Joint Fund of Iron and Steel Research(No.U1960204)the“333”Talent Project of Hebei Province,China(No.B20221001).
文摘Inconel 718 is the most popular nickel-based superalloy and is extensively used in aerospace,automotive,and energy indus-tries owing to its extraordinary thermomechanical properties.The effects of different two-step solid solution treatments on microstructure andδphase precipitation of Inconel 718 alloy were studied,and the transformation mechanism fromγ″metastable phase toδphase was clarified.The precipitates were statistically analyzed by X-ray diffractometry.The results show that theδphase content firstly increased,and then decreased with the temperature of the second-step solid solution.The changes in microstructure andδphase were studied by scanning electron microscopy and transmission electron microscopy.An intragranularδphase formed in Inconel 718 alloy at the second-[100]_(δ)[011]γ step solid solution temperature of 925℃,and its orientation relationship withγmatrix was determined as//and(010)_(δ)//(111)γ.Furthermore,the Vickers hardness of different heat treatment samples was measured,and the sample treated by second-step solid solution at 1010℃ reached the maximum hardness of HV 446.84.
基金supported by the National Natural Science Foundation of China(6177202062202433+4 种基金621723716227242262036010)the Natural Science Foundation of Henan Province(22100002)the Postdoctoral Research Grant in Henan Province(202103111)。
文摘Least squares projection twin support vector machine(LSPTSVM)has faster computing speed than classical least squares support vector machine(LSSVM).However,LSPTSVM is sensitive to outliers and its solution lacks sparsity.Therefore,it is difficult for LSPTSVM to process large-scale datasets with outliers.In this paper,we propose a robust LSPTSVM model(called R-LSPTSVM)by applying truncated least squares loss function.The robustness of R-LSPTSVM is proved from a weighted perspective.Furthermore,we obtain the sparse solution of R-LSPTSVM by using the pivoting Cholesky factorization method in primal space.Finally,the sparse R-LSPTSVM algorithm(SR-LSPTSVM)is proposed.Experimental results show that SR-LSPTSVM is insensitive to outliers and can deal with large-scale datasets fastly.
文摘In this paper, an efficient computational approach is proposed to solve the discrete time nonlinear stochastic optimal control problem. For this purpose, a linear quadratic regulator model, which is a linear dynamical system with the quadratic criterion cost function, is employed. In our approach, the model-based optimal control problem is reformulated into the input-output equations. In this way, the Hankel matrix and the observability matrix are constructed. Further, the sum squares of output error is defined. In these point of views, the least squares optimization problem is introduced, so as the differences between the real output and the model output could be calculated. Applying the first-order derivative to the sum squares of output error, the necessary condition is then derived. After some algebraic manipulations, the optimal control law is produced. By substituting this control policy into the input-output equations, the model output is updated iteratively. For illustration, an example of the direct current and alternating current converter problem is studied. As a result, the model output trajectory of the least squares solution is close to the real output with the smallest sum squares of output error. In conclusion, the efficiency and the accuracy of the approach proposed are highly presented.
文摘Near-infrared (NIR) spectroscopy was applied to reagent-free quantitative analysis of polysaccharide of a brand product of proprietary Chinese medicine (PCM) oral solution samples. A novel method, called absorbance upper optimization partial least squares (AUO-PLS), was proposed and successfully applied to the wavelength selection. Based on varied partitioning of the calibration and prediction sample sets, the parameter optimization was performed to achieve stability. On the basis of the AUO-PLS method, the selected upper bound of appropriate absorbance was 1.53 and the corresponding wavebands combination was 400 - 1880 & 2088 - 2346 nm. With the use of random validation samples excluded from the modeling process, the root-mean-square error and correlation coefficient of prediction for polysaccharide were 27.09 mg·L<sup>-</sup><sup>1</sup> and 0.888, respectively. The results indicate that the NIR prediction values are close to those of the measured values. NIR spectroscopy combined with AUO-PLS method provided a promising tool for quantification of the polysaccharide for PCM oral solution and this technique is rapid and simple when compared with conventional methods.
基金supported by National Natural Science Foundation of China(1057,1047).
文摘In this paper, least-squaxes mirrorsymmetric solution for matrix equations (AX = B, XC = D) and its optimal approximation is considered. With special expression of mirrorsymmetric matrices, a general representation of solution for the least-squares problem is obtained. In addition, the optimal approximate solution and some algorithms to obtain the optimal approximation are provided.
文摘A real n×n symmetric matrix X=(x_(ij))_(n×n)is called a bisymmetric matrix if x_(ij)=x_(n+1-j,n+1-i).Based on the projection theorem,the canonical correlation de- composition and the generalized singular value decomposition,a method useful for finding the least-squares solutions of the matrix equation A^TXA=B over bisymmetric matrices is proposed.The expression of the least-squares solutions is given.Moreover, in the corresponding solution set,the optimal approximate solution to a given matrix is also derived.A numerical algorithm for finding the optimal approximate solution is also described.
基金The project supported by National Natural Science Foundation of China under Grant No. 10375022 and the Scientific Research Fund of the Education Department of Hunan Province of China under Grant No. 05C414
文摘Three types of expression in the dark-soliton perturbation theory based on squared Jost solutions are invesgigaged in ghis paper. It is shown that there are three formally different results about the effects of perturbagion on a dark soliton, and it is proved by means of a transformation between two integral variables that they are essentially equivalent.
基金Sponsored by the National Natural Science Foundation of China(Grant No.60672008)the Space Technology Innovation Foundation of China
文摘In the osmotic dehydration process of food,on-line estimation of concentrations of two components in ternary solution with NaCl and sucrose was performed based on multi-functional sensing technique.Moving Least Squares were adopted in approximation procedure to estimate the viscosity of such interested ternary solution with the given data set.As a result,in one mode of using total experimental data as calibration data and validation data,the relative deviations of estimated viscosities are less than ±1.24%.In the other mode,by taking total experimental data except the ones for estimation as calibration data,the relative deviations are less than ±3.47%.In the same way,the density of ternary solution can be also estimated with deviations less than ± 0.11% and ± 0.30% respectively in these two models.The satisfactory and accurate results show the extraordinary efficiency of Moving Least Squares behaved in signal approximation for multi-functional sensors.
文摘A nonlinear problem of mean-square approximation of a real nonnegative continuous function with respect to two variables by the modulus of double Fourier integral dependent on two real parameters with use of the smoothing functional is studied. Finding the optimal solutions of this problem is reduced to solution of the Hammerstein type two-dimensional nonlinear integral equation. The numerical algorithms to find the branching lines and branching-off solutions of this equation are constructed and justified. Numerical examples are presented.
文摘Necessary and sufficient conditions are derived for some matrix equations that have a common least-squares solution.A general expression is provided when certain resolvable conditions are satisfied.This research extends existing work in the literature.
基金This project is supported by the National Natural Science Foundation of China
文摘This paper presents a new highly parallel algorithm for computing the minimum-norm least-squares solution of inconsistent linear equations Ax = b(A∈Rm×n,b∈R (A)). By this algorithm the solution x = A + b is obtained in T = n(log2m + log2(n - r + 1) + 5) + log2m + 1 steps with P=mn processors when m × 2(n - 1) and with P = 2n(n - 1) processors otherwise.
基金Project supported by the National Natural Science Foundation of China (Grant No.12101246)。
文摘Under the Flaschka-Newell Lax pair,the Darboux transformation for the Painlevé-Ⅱequation is constructed by the limiting technique.With the aid of the Darboux transformation,the rational solutions are represented by the Gram determinant,and then we give the large y asymptotics of the determinant and the rational solutions.Finally,the solution of the corresponding Riemann-Hilbert problem is obtained from the Darboux matrices.
文摘A norm of a quaternion matrix is defined. The expressions of the least square solutions of the quaternion matrix equation AX = B and the equation with the constraint condition DX = E are given.
文摘Data coming from different sources have different types and temporal states. Relations between one type of data and another ones, or between data and unknown parameters are almost nonlinear. It is not accurate and reliable to process the data in building the digital earth with the classical least squares method or the method of the common nonlinear least squares. So a generalized nonlinear dynamic least squares method was put forward to process data in building the digital earth. A separating solution model and the iterative calculation method were used to solve the generalized nonlinear dynamic least squares problem. In fact, a complex problem can be separated and then solved by converting to two sub problems, each of which has a single variable. Therefore the dimension of unknown parameters can be reduced to its half, which simplifies the original high dimensional equations.
文摘In this paper, we discuss least squares symmetrizable solutions of matrix equations (AX = B, XC = D) and its optimal approximation solution. With the matrix row stacking, Kronecker product and special relations between two linear subspaces are topological isomorphism, and we derive the general solutions of least squares problem. With the invariance of the Frobenius norm under orthogonal transformations, we obtain the unique solution of optimal approximation problem. In addition, we present an algorithm and numerical experiment to obtain the optimal approximation solution.
文摘Let be a given Hermitian matrix satisfying . Using the eigenvalue decomposition of , we consider the least squares solutions to the matrix equation , with the constraint .
基金Project(51374239)supported by the National Natural Science Foundation of China
文摘The synthesis of sodium ferrite and its desulfurization performance in S2 -bearing sodium aluminate solutions were investigated. The thermodynamic analysis shows that the lowest temperature is about 810 K for synthesizing sodium ferrite by roasting the mixture of ferric oxide and sodium carbonate. The results indicate that the formation process of sodium ferrite can be completed at 1173 K for 60 min, meanwhile raising temperature and reducing NazCO3 particle size are beneficial to accelerating the formation of sodium ferrite. Sodium ferrite is an efficient desulfurizer to remove the S2- in aluminate solution, and the desulfurization rate can reach approximately 70% at 373 K for 60 min with the molar ratio of iron to sulfur of 1:1-1.5:1. Furthermore, the desulfurization is achieved by NaFeS2·2H2O precipitation through the reaction of Fe(OH)4 and S^2- in aluminate solution, and the desulfurization efficiency relies on the Fe(OH)4^- generated by dissolving sodium ferrite.
基金supported by Open Fund of Engineering Laboratory of Spatial Information Technology of Highway Geological Disaster Early Warning in Hunan Province(Changsha University of Science&Technology,kfj150602)Hunan Province Science and Technology Program Funded Projects,China(2015NK3035)+1 种基金the Land and Resources Department Scientific Research Project of Hunan Province,China(2013-27)the Education Department Scientific Research Project of Hunan Province,China(13C1011)
文摘Linear Least Squares(LLS) problems are particularly difficult to solve because they are frequently ill-conditioned, and involve large quantities of data. Ill-conditioned LLS problems are commonly seen in mathematics and geosciences, where regularization algorithms are employed to seek optimal solutions. For many problems, even with the use of regularization algorithms it may be impossible to obtain an accurate solution. Riley and Golub suggested an iterative scheme for solving LLS problems. For the early iteration algorithm, it is difficult to improve the well-conditioned perturbed matrix and accelerate the convergence at the same time. Aiming at this problem, self-adaptive iteration algorithm(SAIA) is proposed in this paper for solving severe ill-conditioned LLS problems. The algorithm is different from other popular algorithms proposed in recent references. It avoids matrix inverse by using Cholesky decomposition, and tunes the perturbation parameter according to the rate of residual error decline in the iterative process. Example shows that the algorithm can greatly reduce iteration times, accelerate the convergence,and also greatly enhance the computation accuracy.
基金Project supported by the Natural Science Basic Research Plan in Shaanxi Province of China (2004B13)
文摘The three-way catalysts (TWCs) promoters Ce0.6Zr0.4- x TbxO2-y were prepared by sol-gel method. BET surface areas analysis indicated that an increase of the dopant Tb content from x = 0.05 to x = 0.15 favors an increase of surface area from 66.8 to 80.4 m^2· g^-1 compared with the undoped sample Ce0 .6oZr0.40O2 65.1 m^2·g^- 1 after calcination at 650℃. Transmission electron microscopy (TEM) observation indicated that the doped samples have a higher thermal stability. The XRD and Raman spectra confirmed that the Ce0.6Zr0.4-xTbxO2-y cubic solid solution is formed. XPS analysis revealed that Ce and Tb mainly existed in the form of Ce^4+ and Tb^3 + , and Zr existed in the form of Zr^4+ on the surface of the samples. The doped samples were homogenous in composition ; the introduction of Tb into the CeO2-ZrO2 promoters resuited in the formation of a solid solution, and the concentration of surface lattice oxygen was increased.