According to experimental data available for the complex refractive index of particular dielectrics, a dielectric spectrum formula is proposed by the least square fitting technique combined with selected natural frequ...According to experimental data available for the complex refractive index of particular dielectrics, a dielectric spectrum formula is proposed by the least square fitting technique combined with selected natural frequencies. From the dielectric spectrum formula, the spectra of optical and dielectric constants can be obtained in the whole frequency region. Three dielectrics, water, ethanol, and toluene, are taken as examples. In the region where the ex- perimental data are available, the spectra of the optical constants calculated by the formula are in good agreement with the real refractive spectrum obtained by Kramers-Kronig （K-K） transform and the experimental imaginary refractive spectrum. In the region where no ex- perimental data are available, the extrapolation of our formula can make predictions. The merits of the present treatment are that we are able to get the uniform spectrum formula, without splitting into different frequency sections, and the analytical form of the dielectric spectra will be useful in the theoretical description of solvation dynamics.展开更多
基金This work was supported by the National Natural Science Foundation of China （No.20533070 and No.20873087）.
文摘According to experimental data available for the complex refractive index of particular dielectrics, a dielectric spectrum formula is proposed by the least square fitting technique combined with selected natural frequencies. From the dielectric spectrum formula, the spectra of optical and dielectric constants can be obtained in the whole frequency region. Three dielectrics, water, ethanol, and toluene, are taken as examples. In the region where the ex- perimental data are available, the spectra of the optical constants calculated by the formula are in good agreement with the real refractive spectrum obtained by Kramers-Kronig （K-K） transform and the experimental imaginary refractive spectrum. In the region where no ex- perimental data are available, the extrapolation of our formula can make predictions. The merits of the present treatment are that we are able to get the uniform spectrum formula, without splitting into different frequency sections, and the analytical form of the dielectric spectra will be useful in the theoretical description of solvation dynamics.
