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威力FORCE2-8PCH型高频电刀的故障维修 被引量:2
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作者 吴汉曦 王国宏 《医疗设备信息》 2002年第11期60-60,共1页
关键词 force2-8PCH型 高频电刀 故障维修
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Modal and Fatigue Life Analysis on Beam with Multiple Cracks Subjected to Axial Force 被引量:1
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作者 Ma Yijiang Chen Guoping Wu Xinhai 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2018年第5期874-882,共9页
Based on the transfer matrix method and Forman equation,a new method is proposed to conduct the modal and fatigue life analysis of a beam with multiple transverse cracks.In the modal analysis,the damping loss factor i... Based on the transfer matrix method and Forman equation,a new method is proposed to conduct the modal and fatigue life analysis of a beam with multiple transverse cracks.In the modal analysis,the damping loss factor is introduced by the complex elastic modulus,bending springs without mass are used to replace the transverse cracks,and the characteristic transfer matrix of the whole cracked beam can be derived.In the fatigue life analysis,considering the interaction of the beam vibration and fatigue cracks growth,the fatigue life of the cracked beam is predicted by the timing analysis method.Numerical calculation shows that cracks have a significant influence on the modal and fatigue life of the beam. 展开更多
关键词 BEAM cracks AXIAL force NATURAL frequency FATIGUE life
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Pressure Gradient Force,Saffman Lift,and Magnus Lift on the Fiber-like Particle in Fluid 被引量:5
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作者 朱泽飞 林建忠 《Journal of China Textile University(English Edition)》 EI CAS 2000年第2期23-27,共5页
Flher-like particle suspensions are common in both na-ture and industry, but there is little work reported on it.The forces acting on the fiber - like particle in fluid arestudied in this paper, and the Magnus lift, S... Flher-like particle suspensions are common in both na-ture and industry, but there is little work reported on it.The forces acting on the fiber - like particle in fluid arestudied in this paper, and the Magnus lift, Saffman lift,pressure gradient force, and then the dynamics modelhave been received. The numerical study of the simpleshear flow past the cylinders shows that the particles ’motion is controlled by the vortex. 展开更多
关键词 multi - phase FLUID FIBER - LIKE PARTICLE force analysis
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Reducing force transmissibility in multiple degrees of freedom structures through anti-symmetric nonlinear viscous damping 被引量:4
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作者 Z.-K.Peng Z.-Q.Lang +1 位作者 G.Meng S.A.Billings 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2012年第5期1436-1448,共13页
In the present study, the Volterra series theory is adopted to theoretically investigate the force transmissibility of multiple degrees of freedom (MDOF) structures, in which an isolator with nonlinear anti-symmetri... In the present study, the Volterra series theory is adopted to theoretically investigate the force transmissibility of multiple degrees of freedom (MDOF) structures, in which an isolator with nonlinear anti-symmetric viscous damping is assembled. The results reveal that the anti-symmetric nonlinear viscous damping can significantly reduce the force trans- missibility over all resonance regions for MDOF structures with little effect on the transmissibility over non-resonant and isolation regions. The results indicate that the vibration isolators with an anti-symmetric damping characteristic have great potential to solve the dilemma occurring in the design of linear viscously damped vibration isolators where an increase of the damping level reduces the force transmissibility over resonant frequencies but increases the transmissibility over non-resonant frequency regions. This work is an extension of a previous study in which MDOF structures installed on the mount through an isolator with cubic nonlinear damping are considered. The theoretical analysis results are also verified by simulation studies. 展开更多
关键词 Nonlinear viscous damping force transmissibility - Vibration isolation Volterra series
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Numerical Analysis of the Adhesive Forces in Nano-Scale Structure 被引量:1
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作者 Young-Sam Cho Houkseop Han Wan-Doo Kim 《Journal of Bionic Engineering》 SCIE EI CSCD 2006年第4期209-216,共8页
Nanohairs, which can be found on the epidermis of Tokay gecko's toes, contribute to the adhesion by means of van der Waals force, capillary force, etc. This structure has inspired many researchers to fabricate the at... Nanohairs, which can be found on the epidermis of Tokay gecko's toes, contribute to the adhesion by means of van der Waals force, capillary force, etc. This structure has inspired many researchers to fabricate the attachable nano-scale structures. However, the efficiency of artificial nano-scale structures is not reliable sufficiently. Moreover, the mechanical parameters related to the nano-hair attachment are not yet revealed qualitatively. The mechanical parameters which have influence on the ability of adhesive nano-hairs were investigated through numerical simulation in which only van der Waals force was considered. For the numerical analysis, finite element method was utilized and van der Waals force, assumed as 12-6 Lennard-Jones potential, was implemented as the body force term in the finite element formulation. 展开更多
关键词 NUMERICAL analysis adhesive force nano-scale structure finite element model van der Waals force 12-6 L-J potential
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An integrated approach for the optimization of wheel-rail contact force measurement systems 被引量:3
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作者 S.Papini L.Pugi +1 位作者 A.Rindi E.Meli 《Journal of Modern Transportation》 2013年第2期95-102,共8页
A comprehension of railway dynamic behavior implies the measure of wheel-rail contact forces which are affected by disturbances and errors that are often difficult to be quantified. In this study, a benchmark test cas... A comprehension of railway dynamic behavior implies the measure of wheel-rail contact forces which are affected by disturbances and errors that are often difficult to be quantified. In this study, a benchmark test case is proposed, and a bogie with a layout used on some European locomotives such as SIEMENS El90 is studied. In this layout, an additional shaft on which brake disks are installed is used to transmit the braking torque to the wheelset through a single-stage gearbox. Using a mixed approach based on finite element techniques and statistical considerations, it is possible to evaluate an optimal layout for strain gauge positioning and to optimize the measurement system to diminish the effects of noise and disturbance. We also conducted preliminary evaluations on the precision and frequency response of the proposed system. 展开更多
关键词 Wheel-rail interaction Contact force - Straingauge
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Steady vortex force theory and slender-wing flow diagnosis 被引量:1
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作者 Y.T.Yang R.K.Zhang +1 位作者 Y.R.An J.Z.Wu 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2007年第6期609-619,共11页
The concept vortex force in aerodynamics is sys- tematically examined based on a new steady vortex-force theory (Wu et al., Vorticity and vortex dynamics, Springer, 2006) which expresses the aerodynamic force (and ... The concept vortex force in aerodynamics is sys- tematically examined based on a new steady vortex-force theory (Wu et al., Vorticity and vortex dynamics, Springer, 2006) which expresses the aerodynamic force (and moment) by the volume and boundary integrals of the Lamb vector. In this paper, the underlying physics of this theory is explored, including the general role of the Lamb vector in non- linear aerodynamics, its initial formation, and its relevance to the total-pressure non-uniformity. As a typical example, the theory is applied to the flow over a slender delta wing at a large angle of attack. The highly localized flow structures with high Lamb-vector peaks are identified in terms of their net contribution to various constituents of the total aerody-namic force. This vortex-force diagnosis sheds new light on the flow control and configuration optimization. 展开更多
关键词 Vortex force - Delta-wing - Flow control
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An aqueous BiI_(3)-Zn battery with dual mechanisms of Zn^(2+)(de)intercalation and I^(-)/I_(2)redox
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作者 Qi Deng Fangzhong Liu +3 位作者 Xiongwei Wu Changzhu Li Weibin Zhou Bei Long 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期670-678,I0014,共10页
The development of aqueous battery with dual mechanisms is now arousing more and more interest.The dual mechanisms of Zn^(2+)(de)intercalation and I^(-)/I_(2)redox bring unexpected effects.Herein,differing from previo... The development of aqueous battery with dual mechanisms is now arousing more and more interest.The dual mechanisms of Zn^(2+)(de)intercalation and I^(-)/I_(2)redox bring unexpected effects.Herein,differing from previous studies using Zn I_(2)additive,this work designs an aqueous Bi I_(3)-Zn battery with selfsupplied I^(-).Ex situ tests reveal the conversion of Bi I_(3)into Bi(discharge)and Bi OI(charge)at the 1st cycle and the dissolved I^(-)in electrolyte.The active I^(-)species enhances the specific capacity and discharge medium voltage of electrode as well as improves the generation of Zn dendrite and by-product.Furthermore,the porous hard carbon is introduced to enhance the electronic/ionic conductivity and adsorb iodine species,proven by experimental and theoretical studies.Accordingly,the well-designed Bi I_(3)-Zn battery delivers a high reversible capacity of 182 m A h g^(-1)at 0.2 A g^(-1),an excellent rate capability with 88 m A h g^(-1)at 10 A g^(-1),and an impressive cyclability with 63%capacity retention over 20 K cycles at 10 A g^(-1).An excellent electrochemical performance is obtained even at a high mass loading of 6 mg cm^(-2).Moreover,a flexible quasi-solid-state Bi I_(3)-Zn battery exhibits satisfactory battery performances.This work provides a new idea for designing high-performance aqueous battery with dual mechanisms. 展开更多
关键词 Aqueous BiI_(3)-Zn battery Dual mechanisms I^(-)-induced uniform zinc deposition Ultralong cyclic life Flexible quasi-solid-state battery
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Calculation of Radii and Density of ^(7-19)B Isotopes Using Effective Skyrme Force
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作者 E.Tel S.Okuducu +2 位作者 G.Tatar N.N.Akti M.H.Blükdemir 《Communications in Theoretical Physics》 SCIE CAS CSCD 2008年第3期696-702,共7页
Abstract In this study, the proton and neutron densities, charge densities, rms nuclear charge radii, rms nuclear mass radii, rms nuclear proton, neutron radii, and neutron skin thickness are calculated by using Harfr... Abstract In this study, the proton and neutron densities, charge densities, rms nuclear charge radii, rms nuclear mass radii, rms nuclear proton, neutron radii, and neutron skin thickness are calculated by using Harfree-Fock method with an effective nucleon-nucleon Skyrme interactions with SⅠ, SⅡ, SⅣ, T3, SKM, and SKM^* parameters. These nuclear properties for the neutron-rich isotopes of B (Boron) are presented. The calculated results are compared with the experimental and theoretical results of other researchers. 展开更多
关键词 ^7-9B isotopes halo nuclei Skyrme force Hartree-Fock calculations
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China's WTO Accession and Sustainable Development ----- 2002 Report by Task Force on WTO and Environment, November 23-25, 2002, Beijing, China
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《China Population Today》 2002年第Z1期27-36,共10页
关键词 WTO China’s WTO Accession and Sustainable Development November 23-25 Report by Task force on WTO and Environment BEIJING China
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Quantization of the 1-D Forced Harmonic Oscillator in the Space (<i>x</i>, <i>v</i>)
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作者 Gustavo V. López Omar J. P. Bravo 《Journal of Modern Physics》 2021年第3期284-294,共11页
The quantization of the forced harmonic oscillator is studied with the quantum variable (<em>x</em>, <span style="white-space:nowrap;"><em><sub>v</sub><sup style="... The quantization of the forced harmonic oscillator is studied with the quantum variable (<em>x</em>, <span style="white-space:nowrap;"><em><sub>v</sub><sup style="margin-left:-8px;">∧</sup></em></span>), with the commutation relation <img src="Edit_28f5b839-7de4-41e5-9ed8-69dc1bf72c2c.bmp" alt="" />, and using a Schr<span style="white-space:nowrap;"><span style="white-space:nowrap;"><span style="white-space:nowrap;">&ouml;</span></span></span>dinger’s like equation on these variable, and associating a linear operator to a constant of motion <em>K</em> (<em>x, v, t</em>) of the classical system, The comparison with the quantization in the space (<em>x, p</em>) is done with the usual Schr<span style="white-space:nowrap;"><span style="white-space:nowrap;"><span style="white-space:nowrap;">&ouml;</span></span></span>dinger’s equation for the Hamiltonian <em>H</em><span style="white-space:normal;">(</span><em style="white-space:normal;">x, p, t</em><span style="white-space:normal;">)</span>, and with the commutation relation <img src="Edit_cca7e318-5b35-4c55-8f09-6089970ce9a2.bmp" alt="" />. It is found that for the non-resonant case, both forms of quantization bring about the same result. However, for the resonant case, both forms of quantization are different, and the probability for the system to be in the exited state for the (<em style="white-space:normal;">x</em><span style="white-space:normal;">, </span><em><sub>v</sub><sup style="margin-left:-8px;">∧</sup></em>) quantization has fewer oscillations than the (<em style="white-space:normal;">x</em><span style="white-space:normal;">, </span><em style="white-space:normal;"><sub>p</sub><sup style="margin-left:-8px;">∧</sup></em>) quantization, the average energy of the system is higher in (<em style="white-space:normal;">x</em><span style="white-space:normal;">, </span><em style="white-space:normal;"><sub>p</sub><sup style="margin-left:-8px;">∧</sup></em>) quantization than on the (<em style="white-space:normal;">x</em><span style="white-space:normal;">, </span><em style="white-space:normal;"><sub>v</sub><sup style="margin-left:-8px;">∧</sup></em>) quantization, and the Boltzmann-Shannon entropy on the (<em style="white-space:normal;">x</em><span style="white-space:normal;">, </span><em style="white-space:normal;"><sub>p</sub><sup style="margin-left:-8px;">∧</sup></em>) quantization is higher than on the (<em style="white-space:normal;">x</em><span style="white-space:normal;">, </span><em style="white-space:normal;"><sub>v</sub><sup style="margin-left:-8px;">∧</sup></em>) quantization. 展开更多
关键词 forced Harmonic Oscillator (x v style="margin-left:-8px ">∧) Quantization Constant of Motion
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早期辞赋中的身体治疾与山水观想研究--以《七发》为中心
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作者 岳进 《文艺理论研究》 CSSCI 北大核心 2023年第2期151-161,共11页
早期辞赋中的山水的观看与想象和身体疾病的治愈、本能欲望的满足联系在一起。以枚乘《七发》为中心,对比宋玉《高唐赋》、汉初竹书《反淫》,在以治疾为目的的讲述和倾听中,山水广大、惊骇的美感,进入观看和想象,以观想的方式牵引着身... 早期辞赋中的山水的观看与想象和身体疾病的治愈、本能欲望的满足联系在一起。以枚乘《七发》为中心,对比宋玉《高唐赋》、汉初竹书《反淫》,在以治疾为目的的讲述和倾听中,山水广大、惊骇的美感,进入观看和想象,以观想的方式牵引着身体的微妙感受,绾合气血和精神的起伏变化,深深地铭刻在身体的记忆中,开启山水审美化的进程。 展开更多
关键词 身体 山水 气类感应 欲望 精神
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Fatigue life evaluation on key components of high-speed railway catenary system 被引量:6
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作者 QI Guang-feng XIAO Xiao-hui +1 位作者 ZHAO Hui CHEN Jian-fang 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第8期1958-1965,共8页
The fatigue load spectrum and operation life evaluation of key components in the catenary system under the high speed train running condition were investigated.Firstly,based on the catenary model and pantograph model,... The fatigue load spectrum and operation life evaluation of key components in the catenary system under the high speed train running condition were investigated.Firstly,based on the catenary model and pantograph model,the couple dynamic equations of pantograph–catenary were built with the Lagrange’s method;then the dynamic contact force was obtained by the Newmark method at the train speeds of 250,280 and 300 km/h,respectively.Secondly,the finite element model(FEM)of one anchor section’s catenary was built to analyze its transient response under the contact force as train running;then the loading time history of messenger wire base,steady arm,registration tube,oblique cantilever,and straight cantilever were extracted.Finally,the key components’fatigue spectrum was carried out by the rain-flow counting method,and operation life was estimated in consideration of such coefficients,such as stress concentration,shape and dimension,surface treatment.The results show that the fatigue life of the catenary system reduces with the increasing of train speed;specifically,the evaluated fatigue life of the steady arm is shorter than other components. 展开更多
关键词 fatigue spectrum fatigue life evaluation pantograph–catenary’s contact force high-speed railway
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Modelling and simulation of contact force in cold rotary forging 被引量:2
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作者 秦训鹏 《Journal of Central South University》 SCIE EI CAS 2014年第1期35-42,共8页
Cold rotary forging is an advanced and complex metal forming technology with continuous local plastic deformation.Investigating the contact force between the dies and the workpiece has a great significance to improve ... Cold rotary forging is an advanced and complex metal forming technology with continuous local plastic deformation.Investigating the contact force between the dies and the workpiece has a great significance to improve the life of the dies in cold rotary forging.The purpose of this work is to reveal the contact force responses in cold rotary forging through the modelling and simulation.For this purpose,a 3D elastic-plastic dynamic explicit FE model of cold rotary forging is developed using the FE code ABAQUS/Explicit.Through the modelling and simulation,the distribution and evolution of the contact force in cold rotary forging is investigated in detail.The experiment has been conducted and the validity of the 3D FE model of cold rotary forging has been verified.The results show that: 1) The contact force distribution is complex and exhibits an obvious non-uniform characteristic in the radial and circumferential directions; 2) The maximum contact force between the upper die and the workpiece is much larger than that between the lower die and the workpiece; 3) The contact force evolution history is periodic and every period experiences three different stages; 4) The total normal contact force is much larger than the total shear contact force at any given time. 展开更多
关键词 cold rotary forging metal forming SIMULATION contact force die life
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A two-parameter model to predict fatigue life of high-strength steels in a very high cycle fatigue regime 被引量:7
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作者 Chengqi Sun Xiaolong Liu Youshi Hong 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2015年第3期383-391,共9页
In this paper, ultrasonic (20 kHz) fatigue tests were performed on specimens of a high-strength steel in very high cycle fatigue (VHCF) regime. Experimental results showed that for most tested specimens failed in ... In this paper, ultrasonic (20 kHz) fatigue tests were performed on specimens of a high-strength steel in very high cycle fatigue (VHCF) regime. Experimental results showed that for most tested specimens failed in a VHCF regime, a fatigue crack originated from the interior of specimen with a fish-eye pattern, which contained a fine granular area (FGA) centered by an inclusion as the crack origin. Then, a two-parameter model is proposed to predict the fatigue life of high-strength steels with fish-eye mode failure in a VHCF regime, which takes into account the inclusion size and the FGA size. The model was verified by the data of present experiments and those in the literature. Furthermore, an analytic formula was obtained for estimating the equivalent crack growth rate within the FGA. The results also indicated that the stress intensity factor range at the front of the FGA varies within a small range, which is irrespective of stress amplitude and fatigue life. 展开更多
关键词 Very high-cycle fatigue - High-strength steels Fatigue life Inclusion size Crack growth rate
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Safety evaluation for railway vehicles using an improved indirect measurement method of wheel–rail forces 被引量:8
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作者 Jing Zeng Lai Wei Pingbo Wu 《Journal of Modern Transportation》 2016年第2期114-123,共10页
The wheel-rail force measurement is of great importance to the condition monitoring and safety evaluation of railway vehicles. In this paper, an improved indirect method for wheel-rail force measurement is proposed to... The wheel-rail force measurement is of great importance to the condition monitoring and safety evaluation of railway vehicles. In this paper, an improved indirect method for wheel-rail force measurement is proposed to evaluate the running safety of railway vehicles. In this method, the equilibrium equations of a suspended wheelset are derived and the wheel-rail forces are then be obtained from measured suspension and inertia forces. This indirect method avoids structural modifications to the wheelset and is applicable to the long-term operation of railway vehicles. As the wheel-rail lateral forces at two sides of the wheelset are difficult to separate, a new derailment criterion by combined use of wheelset derailment coefficient and wheel unloading ratio is proposed. To illustrate its effectiveness, the indirect method is applied to safety evaluation of rail- way vehicles in different scenarios, such as the cross wind safety of a high-speed train and the safety of a metro vehicle with hunting motions. Then, the feasibility of using this method to identify wheel-rail forces for low-floor light rail vehicles with resilient wheels is discussed. The values identified by this method is compared with that by Simpack simulation for the same low-floor vehicle, which shows a good coincidence between them in the time domain of the wheelset lateral force and the wheel-rail vertical force. In addition, use of the method to determine the high-frequency wheel-rail interaction forces reveals that it is possible to identify the high-frequency wheel-rail forces through the accelerations on the axle box. 展开更多
关键词 Wheel-rail force Safety evaluation - Indirect method Union safety domain Wheelset derailment coefficient Hunting motions Cross wind Low-floor vehicle
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LiFe_(1-0.01x)Ni_(0.01x)PO_4薄膜干燥温度对其光学性质及气敏性的影响
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作者 帕提曼.尼扎木丁 燕音 阿布力孜.伊米提 《化学研究与应用》 CAS CSCD 北大核心 2015年第10期1502-1509,共8页
将水热合成的Li Fe1-0.01xNi0.01xPO4(x=0.5,1.0)粉体作为敏感试剂,用旋转-甩涂法涂于锡掺杂玻璃光波导表面,在不同温度下进行热处理。采用紫外-可见分光光度计,测厚仪和平面玻璃光波导气敏测试系统(自组装)研究了薄膜干燥温度对Li ... 将水热合成的Li Fe1-0.01xNi0.01xPO4(x=0.5,1.0)粉体作为敏感试剂,用旋转-甩涂法涂于锡掺杂玻璃光波导表面,在不同温度下进行热处理。采用紫外-可见分光光度计,测厚仪和平面玻璃光波导气敏测试系统(自组装)研究了薄膜干燥温度对Li Fe1-0.01xNi0.01xPO4薄膜光学及气敏特性的影响。研究结果表明,450℃下干燥的薄膜具有良好的光学透明性并对应的敏感元件显出良好的气敏特性。相同浓度的不同挥发性有机气体中,Li Fe0.99Ni0.01PO4传感元件对二甲苯气体有较大的响应,其检测响应范围为1×10^-7~1×10^-3(V/V0),响应-恢复时间分别小于5s和70s。 展开更多
关键词 光波导气敏元件 热处理 life1-0.01xNi0.01xPO4薄膜 气敏性 二甲苯检测
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The Life Predictions in Whole Process Realized with Different Variables and Conventional Materials Constants for Elastic-Plastic Materials Behaviors under Unsymmetrical Cycle Loading 被引量:1
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作者 Yangui Yu 《Journal of Mechanics Engineering and Automation》 2015年第4期241-250,共10页
Author researches a lot of the mathematical models and the related conventional material constants in the traditional and the modem mechanics; to adopt two types of variables a and D, for the fatigue-damage-fracture b... Author researches a lot of the mathematical models and the related conventional material constants in the traditional and the modem mechanics; to adopt two types of variables a and D, for the fatigue-damage-fracture behaviors to elastic-plastic steels contained flaws, to put forward several calculation models, which are the driving force and the life prediction expressions at each stage and in whole process; for the key parameters .A1 and ,A2 in two stages, there are functional relation with other conventional material constants σF,m1 and M2,λ2, they are defined as the new calculable comprehensive material constants, and indicate their physical and geometrical meanings. In addition, for conversion methods between two types of variables, relevant calculating example is provided. Thereby, make a linking between the fracture mechanics and the damage mechanics, communicating their relationships. This works for saving man powers and funds on fatigue-damage-fracture testing that will be having practical significance. 展开更多
关键词 life in whole process variables of two types driving force elastic-plastic materials conventional material constants.
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Bi-variable damage model for fatigue life prediction of metal components 被引量:1
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作者 Miao Zhang Qing-Chun Meng Xing Zhang Wei-Ping Hu 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2011年第3期416-425,共10页
Based on the theory of continuum damage mechanics,a bi-variable damage mechanics model is developed,which,according to thermodynamics,is accessible to derivation of damage driving force,damage evolution equation and d... Based on the theory of continuum damage mechanics,a bi-variable damage mechanics model is developed,which,according to thermodynamics,is accessible to derivation of damage driving force,damage evolution equation and damage evolution criteria. Furthermore,damage evolution equations of time rate are established by the generalized Drucker's postulate. The damage evolution equation of cycle rate is obtained by integrating the time damage evolution equations,and the fatigue life prediction method for smooth specimens under repeated loading with constant strain amplitude is constructed. Likewise,for notched specimens under the repeated loading with constant strain amplitude,the fatigue life prediction method is obtained on the ground of the theory of conservative integral in damage mechanics. Thus,the material parameters in the damage evolution equation can be obtained by reference to the fatigue test results of standard specimens with stress concentration factor equal to 1,2 and 3. 展开更多
关键词 Bi-variable damage model - Damage evolution equation . life prediction - Fatigue . Damage mechanics
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Molecular Engineering Design for High-Performance Aqueous Zinc-Organic Battery 被引量:6
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作者 Tianjiang Sun Weijia Zhang +1 位作者 Qingshun Nian Zhanliang Tao 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第3期98-111,共14页
Novel small sulfur heterocyclic quinones(6a,16adihydrobenzo[b]naphtho[2′,3′:5,6][1,4]dithiino[2,3-i]thianthrene-5,7,9,14,16,18-hexaone(4S6Q)and benzo[b]naphtho[2′,3′:5,6][1,4]dithiino[2,3-i]thianthrene-5,9,14,18-t... Novel small sulfur heterocyclic quinones(6a,16adihydrobenzo[b]naphtho[2′,3′:5,6][1,4]dithiino[2,3-i]thianthrene-5,7,9,14,16,18-hexaone(4S6Q)and benzo[b]naphtho[2′,3′:5,6][1,4]dithiino[2,3-i]thianthrene-5,9,14,18-tetraone(4S4Q))are developed by molecule structural design method and as cathode for aqueous zincorganic batteries.The conjugated thioether(–S–)bonds as connected units not only improve the conductivity of compounds but also inhibit their dissolution by both extendedπ-conjugated plane and constructed flexible molecular skeleton.Hence,the Zn//4S6Q and Zn//4S4Q batteries exhibit satisfactory electrochemical performance based on 3.5 mol L-1(M)Zn(ClO4)2electrolyte.For instance,the Zn//4S6Q battery obtains 240 and 208.6 mAh g^(-1)of discharge capacity at 150 mA g^(-1)and 30 A g^(-1),respectively.The excellent rate capability is ascribed to the fast reaction kinetics.This system displays a superlong life of 20,000 cycles with no capacity fading at 3 A g^(-1).Additionally,the H+-storage mechanism of the 4S6Q compound is demonstrated by ex situ analyses and density functional theory calculations.Impressively,the battery can normally work at-60℃benefiting from the anti-freezing electrolyte and maintain a high discharge capacity of 201.7 mAh g^(-1),which is 86.2%of discharge capacity at 25℃.The cutting-edge electrochemical performances of these novel compounds make them alternative electrode materials for Zn-organic batteries. 展开更多
关键词 Aqueous Zn-organic battery Small sulfur heterocyclic quinones Conjugated thioether skeleton Superlong cycling life H+-involved mechanism -60℃
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