Semitransparent organic solar cells show attractive potential in the application of building-integrated photovoltaics,agrivoltaics,floating photovoltaics,and wearable electronics,as their multiple functionalities of e...Semitransparent organic solar cells show attractive potential in the application of building-integrated photovoltaics,agrivoltaics,floating photovoltaics,and wearable electronics,as their multiple functionalities of electric power generation,photopermeability,and color tunability.Design and exploration of semitransparent organic solar cells with optimal and balanced efficiency and average visible light transmittance and simultaneously high stability are in great demand.In this work,based on a layer-by-layer-processed active layer and an ultrathin metal electrode,inverted semitransparent organic solar cells(ITO/AZO/PM6/BTP-eC9/MoO_(3)/Au/Ag)were fabricated.Optimal and balanced efficiency and average visible light transmittance were demonstrated,and simultaneously promising thermal and light stability were achieved for the obtained devices.The power conversion efficiency of 13.78-12.29%and corresponding average visible light transmittance of 14.58-25.80%were recorded for the ST-OSC devices with 25-15 nm thick Ag electrodes,respectively.Superior thermal and light stability with~90%and~85%of initial efficiency retained in 400 h under 85°C thermal stress and AM1.5 solar illumination were demonstrated,respectively.展开更多
Effects of organosilicon coating with light stabilizer UV326,UV531 and 770 on ultraviolet (UV) aging resistance of bitumen were investigated by testing the viscosity,softening point and the changes of chemical compone...Effects of organosilicon coating with light stabilizer UV326,UV531 and 770 on ultraviolet (UV) aging resistance of bitumen were investigated by testing the viscosity,softening point and the changes of chemical component before and after UV aging. The results show that UV aging resistance of bitumen is improved due to the good weatherability of organosilicon. And the UV aging resistance of bitumen is further enhanced by adding light stabilizer into organosilicon coating due to the good UV absorption of light stabilizers. Bitumen coated with organosilicon coating containing UV326 exhibits better UV aging resistance in comparison with bitumen coated with organosilicon containing UV531 or 770.展开更多
Light is an environmental signaling,whereas Aux/IAA proteins and Auxin Response Factors(ARFs)are regulators of auxin signalling.Aux/IAA proteins are unstable,and their degradation dependents on 26S ubiquitin-proteasom...Light is an environmental signaling,whereas Aux/IAA proteins and Auxin Response Factors(ARFs)are regulators of auxin signalling.Aux/IAA proteins are unstable,and their degradation dependents on 26S ubiquitin-proteasome and is promoted by Auxin.Auxin binds directly to a SCF-type ubiquitin-protein ligase,TIR1,facilitates the interaction between Aux/IAA proteins and TIR1,and then the degradation of Aux/IAA proteins.A few studies have reported that some ARFs are also unstable proteins,and their degradation is also mediated by 26S proteasome.In this study,by using of antibodies recognizing endogenous ARF7 proteins,we found that protein stability of ARF7 was affected by light.By expressing MYC tagged ARF activators in protoplasts,we found that degradation of ARF7 was inhibited by 26 proteasome inhibitors.In addition,at least ARF5 and ARF19 were also unstable proteins,and degradation of ARF5 via 26S proteasome was further confirmed by using stable transformed plants overexpressing ARF5 with a GUS tag.展开更多
Over 2 x 10(8) tons of polymers are produced every year, and a large portion of polymers faces the degradation problem. There are many effective methods to protect polymers against degradation and the addition of stab...Over 2 x 10(8) tons of polymers are produced every year, and a large portion of polymers faces the degradation problem. There are many effective methods to protect polymers against degradation and the addition of stabilizers to polymer remains the most convenient and effective way of enhancing polymer life and performance. In this article, a series of effective stabilizers with optimal molecular weight (MW), including common, monomeric and polymeric stabilizers (antioxidant and light stabilizer) were synthesized using isocyanation, controlled isocyanation, hydrosilylation, epoxide addition, macroreaction of stabilizing functional compounds and polymerization of monomeric stabilizers. The structure and performance of these new stabilizers were characterized by using IR, NMR, MS, UV-spectra, XPS and elemental analysis. The current development of stabilizer synthesis was also reviewed.展开更多
基金the financial support from Ningbo Science and Technology Project(2022-DST-004)Ningbo key scientific and technological project(2022Z117)+2 种基金Ningbo Nature Science Foundation(2023J039,202003N4176)Zhejiang Provincial Natural Science Foundation of China(LY23F040004)the financial support by the State Key Lab of Luminescent Materials and Devices,South China University of Technology
文摘Semitransparent organic solar cells show attractive potential in the application of building-integrated photovoltaics,agrivoltaics,floating photovoltaics,and wearable electronics,as their multiple functionalities of electric power generation,photopermeability,and color tunability.Design and exploration of semitransparent organic solar cells with optimal and balanced efficiency and average visible light transmittance and simultaneously high stability are in great demand.In this work,based on a layer-by-layer-processed active layer and an ultrathin metal electrode,inverted semitransparent organic solar cells(ITO/AZO/PM6/BTP-eC9/MoO_(3)/Au/Ag)were fabricated.Optimal and balanced efficiency and average visible light transmittance were demonstrated,and simultaneously promising thermal and light stability were achieved for the obtained devices.The power conversion efficiency of 13.78-12.29%and corresponding average visible light transmittance of 14.58-25.80%were recorded for the ST-OSC devices with 25-15 nm thick Ag electrodes,respectively.Superior thermal and light stability with~90%and~85%of initial efficiency retained in 400 h under 85°C thermal stress and AM1.5 solar illumination were demonstrated,respectively.
基金a research project 51078300 supported by National Natural Science Foundation of chinasupported by self-determined and innovative research funds of WUT(2010-YB-04)
文摘Effects of organosilicon coating with light stabilizer UV326,UV531 and 770 on ultraviolet (UV) aging resistance of bitumen were investigated by testing the viscosity,softening point and the changes of chemical component before and after UV aging. The results show that UV aging resistance of bitumen is improved due to the good weatherability of organosilicon. And the UV aging resistance of bitumen is further enhanced by adding light stabilizer into organosilicon coating due to the good UV absorption of light stabilizers. Bitumen coated with organosilicon coating containing UV326 exhibits better UV aging resistance in comparison with bitumen coated with organosilicon containing UV531 or 770.
文摘Light is an environmental signaling,whereas Aux/IAA proteins and Auxin Response Factors(ARFs)are regulators of auxin signalling.Aux/IAA proteins are unstable,and their degradation dependents on 26S ubiquitin-proteasome and is promoted by Auxin.Auxin binds directly to a SCF-type ubiquitin-protein ligase,TIR1,facilitates the interaction between Aux/IAA proteins and TIR1,and then the degradation of Aux/IAA proteins.A few studies have reported that some ARFs are also unstable proteins,and their degradation is also mediated by 26S proteasome.In this study,by using of antibodies recognizing endogenous ARF7 proteins,we found that protein stability of ARF7 was affected by light.By expressing MYC tagged ARF activators in protoplasts,we found that degradation of ARF7 was inhibited by 26 proteasome inhibitors.In addition,at least ARF5 and ARF19 were also unstable proteins,and degradation of ARF5 via 26S proteasome was further confirmed by using stable transformed plants overexpressing ARF5 with a GUS tag.
基金The work cited in this review was supported by the National Natural Science Foundation of China (No, 928700801 and No 2880201)
文摘Over 2 x 10(8) tons of polymers are produced every year, and a large portion of polymers faces the degradation problem. There are many effective methods to protect polymers against degradation and the addition of stabilizers to polymer remains the most convenient and effective way of enhancing polymer life and performance. In this article, a series of effective stabilizers with optimal molecular weight (MW), including common, monomeric and polymeric stabilizers (antioxidant and light stabilizer) were synthesized using isocyanation, controlled isocyanation, hydrosilylation, epoxide addition, macroreaction of stabilizing functional compounds and polymerization of monomeric stabilizers. The structure and performance of these new stabilizers were characterized by using IR, NMR, MS, UV-spectra, XPS and elemental analysis. The current development of stabilizer synthesis was also reviewed.
