Rare earth element （REE） concentrations were measured by ICP-MS for groundwater collected from deep seated Taiyuan Fm limestone aquifer （from -400 to -530 m） in Renlou Coal Mine, northern Anhui Province, China. It...Rare earth element （REE） concentrations were measured by ICP-MS for groundwater collected from deep seated Taiyuan Fm limestone aquifer （from -400 to -530 m） in Renlou Coal Mine, northern Anhui Province, China. It can be concluded that the groundwater is warm （34.0-37.2 ℃） C1-Ca, Na type water with circum-neutral pH （7.35-8.28） and high total dissolved solids （TDS, 1 746-2 849 mg/L）. The groundwater exhibits heavy REEs enrichment relative to light REEs compared with Post Archean Average Shale （PAAS）, as well as their aquifer rocks （limestone）. The enrichment of REEs is considered to be controlled by terrigeneous materials （e.g. zircon） in aquifer rocks, whereas the fractionation of REEs is controlled by marine derived materials （e.g. calcite）, to a less extent, terrigeneous materials and inorganic complexation. The Ce anomalies normalized to PAAS and aquifer rocks are weak, which probably reflects the signature of the aquifer rock rather than redox conditions or pH. The similarities of REE patterns between groundwater and aquifer rocks imply that aquifer rocks play important roles in controlling the REE characteristics of groundwater, and then provide a probability for discrimination of groundwater sources by using REEs.展开更多
The El Minia governorate lies within the Nile Valley,surrounded by calcareous plateaus to the east and west.The present study focuses on the hydrogeochemistry of the Eocene limestone aquifer at some wadis in the east ...The El Minia governorate lies within the Nile Valley,surrounded by calcareous plateaus to the east and west.The present study focuses on the hydrogeochemistry of the Eocene limestone aquifer at some wadis in the east El Minia governorate,Eastern Desert,Egypt.Hydrogeologically,two main aquifers are encountered in the study area,namely the Maghagha marly limestone and the Samalut chalky limestone aquifers.The Maghagha aquifer is composed of alternating layers of marly limestone and shale with thicknesses ranging from 3.49 m to 177.05 m and a groundwater depth ranging from 8.5 m to 59.27 m which reflects low groundwater potentiality.The groundwater salinity representing this aquifer ranges from 603.5 mg/L to 978.5 mg/L,reflecting fresh water type.Samalut aquifer is made up of chalky,cavernous and fractured limestone with thickness ranging from 30 m to 205 m and groundwater depth ranging from 9 m to 86.77 m,which indicates good groundwater potential.The groundwater salinity of the concerned aquifer ranges from 349.7 mg/L to 2043.9 mg/L,reflecting fresh to possibly brackish water types.Groundwater in the study area is of meteoric water origin;recent recharge is mainly controlled through the presence of fractures and their densities.The majority of groundwater samples in the study area are suitable for drinking and irrigation purposes.展开更多
基金Project(40873015) supported by the National Natural Science Foundation of ChinaProject(08010302062) supported by the Eleventh Five-year Scientific and Technological Program of Anhui Province,China
文摘Rare earth element （REE） concentrations were measured by ICP-MS for groundwater collected from deep seated Taiyuan Fm limestone aquifer （from -400 to -530 m） in Renlou Coal Mine, northern Anhui Province, China. It can be concluded that the groundwater is warm （34.0-37.2 ℃） C1-Ca, Na type water with circum-neutral pH （7.35-8.28） and high total dissolved solids （TDS, 1 746-2 849 mg/L）. The groundwater exhibits heavy REEs enrichment relative to light REEs compared with Post Archean Average Shale （PAAS）, as well as their aquifer rocks （limestone）. The enrichment of REEs is considered to be controlled by terrigeneous materials （e.g. zircon） in aquifer rocks, whereas the fractionation of REEs is controlled by marine derived materials （e.g. calcite）, to a less extent, terrigeneous materials and inorganic complexation. The Ce anomalies normalized to PAAS and aquifer rocks are weak, which probably reflects the signature of the aquifer rock rather than redox conditions or pH. The similarities of REE patterns between groundwater and aquifer rocks imply that aquifer rocks play important roles in controlling the REE characteristics of groundwater, and then provide a probability for discrimination of groundwater sources by using REEs.
基金This research did not receive any specific grant from funding agencies in the public,commercial or not-for-profit sectors.
文摘The El Minia governorate lies within the Nile Valley,surrounded by calcareous plateaus to the east and west.The present study focuses on the hydrogeochemistry of the Eocene limestone aquifer at some wadis in the east El Minia governorate,Eastern Desert,Egypt.Hydrogeologically,two main aquifers are encountered in the study area,namely the Maghagha marly limestone and the Samalut chalky limestone aquifers.The Maghagha aquifer is composed of alternating layers of marly limestone and shale with thicknesses ranging from 3.49 m to 177.05 m and a groundwater depth ranging from 8.5 m to 59.27 m which reflects low groundwater potentiality.The groundwater salinity representing this aquifer ranges from 603.5 mg/L to 978.5 mg/L,reflecting fresh water type.Samalut aquifer is made up of chalky,cavernous and fractured limestone with thickness ranging from 30 m to 205 m and groundwater depth ranging from 9 m to 86.77 m,which indicates good groundwater potential.The groundwater salinity of the concerned aquifer ranges from 349.7 mg/L to 2043.9 mg/L,reflecting fresh to possibly brackish water types.Groundwater in the study area is of meteoric water origin;recent recharge is mainly controlled through the presence of fractures and their densities.The majority of groundwater samples in the study area are suitable for drinking and irrigation purposes.
