Laser induced breakdown Spectroscopy(LIBS)was applied for the elemental analysis and exposure of the heavy metals in betel leaves in air.Pulsed Nd∶YAG(1064 nm)in conjunction with a suitable detector(LIBS 2000+,Ocean ...Laser induced breakdown Spectroscopy(LIBS)was applied for the elemental analysis and exposure of the heavy metals in betel leaves in air.Pulsed Nd∶YAG(1064 nm)in conjunction with a suitable detector(LIBS 2000+,Ocean Optics,Inc)having the optical resolution of 0.06 nm was used to record the emission spectra from 220 to 720 nm.Elements like Al,Ba,Ca,Cr,Cu,P,Fe,K,Mg,Mn,Na,P,S,Sr,and Zn were found to present in the samples.The relative abundances of the observed elements were calculated through standard calibration curve method,integrated intensity ratio method,and weight percentage LIBS approach.LIBS findings were validated by comparing its results with the results obtained using a typical analytical technique of Inductively Coupled plasma-optical emission spectroscopy(ICP-OES).Limit of detection(LOD)of the LIBS system was also estimated for heavy metals.The experience gain through this work implies that LIBS could be highly applicable for testing the quality and purity of food products.展开更多
The influence of the energy of femtosecond laser pulses on the intensity of Fe I （371.99 nm） emission line and the continuous spectrum of the plasma generated on the surface of Fe^3＋ water solution by a Ti： sapphi...The influence of the energy of femtosecond laser pulses on the intensity of Fe I （371.99 nm） emission line and the continuous spectrum of the plasma generated on the surface of Fe^3＋ water solution by a Ti： sapphire laser radiation with pulse duration 〈45 fs and energies up to 7 mJ is determined. A calibration curve was obtained for Fe3＋ concentration range from 0.5 g/L to the limit of detection in water solution, and its saturation was detected for concentrations above 0.25 g/L, which is ascribed to self-absorption. The 3σ- limit of detection obtained for Fe in water solution is 2.6 mg/L in the case of 7 mJ laser pulse energy. It is found that an increase of laser pulse energy insignificantly affects on LOD in the time-resolved LIBS and leads to a slight improvement of the limit of detection.展开更多
The objective of this paper is to study systematically the dynamics and control strategy of a singular biological economic model that is described by a differential-algebraic equation. It is shown that when the econom...The objective of this paper is to study systematically the dynamics and control strategy of a singular biological economic model that is described by a differential-algebraic equation. It is shown that when the economic profit passes through zero, this model exhibits the transcritical bifurcation, the Hopf bifurcation, and the limit cycle. In particular, the system undergoes the singularity induced bifurcation at the positive equilibrium, which can result in impulse. Then, state feedback controllers closer to the actual control strategies are designed to eliminate the unexpected singularity induced bifurcation and stabilize the positive equilibrium under the positive profit. Finally, numerical simulations verify the results and illustrate the effectiveness of the controllers. Also, the model with positive economic profit is shown numerically to have different dynamics.展开更多
随着高比例可再生能源在电力系统中的广泛应用,可再生能源的波动性和随机性对电力系统静态电压稳定评估带来挑战,电力系统静态电压稳定域(static voltage stability region,SVSR)可以全面分析和监测电力系统电压稳定性,其关键是快速准...随着高比例可再生能源在电力系统中的广泛应用,可再生能源的波动性和随机性对电力系统静态电压稳定评估带来挑战,电力系统静态电压稳定域(static voltage stability region,SVSR)可以全面分析和监测电力系统电压稳定性,其关键是快速准确地构建稳定域边界。针对传统连续潮流法和非线性规划法计算量大的问题,提出一种基于SVSR边界拓扑性质的SVSR边界构建优化模型,根据边界连续且光滑的性质,由已知边界点通过预测-校正方法直接计算相邻边界点。在此模型基础上提出一种极限诱导分岔识别方法,构建考虑极限诱导分岔的SVSR边界。最后通过算例分析验证了所提方法的可行性和准确性。展开更多
文摘Laser induced breakdown Spectroscopy(LIBS)was applied for the elemental analysis and exposure of the heavy metals in betel leaves in air.Pulsed Nd∶YAG(1064 nm)in conjunction with a suitable detector(LIBS 2000+,Ocean Optics,Inc)having the optical resolution of 0.06 nm was used to record the emission spectra from 220 to 720 nm.Elements like Al,Ba,Ca,Cr,Cu,P,Fe,K,Mg,Mn,Na,P,S,Sr,and Zn were found to present in the samples.The relative abundances of the observed elements were calculated through standard calibration curve method,integrated intensity ratio method,and weight percentage LIBS approach.LIBS findings were validated by comparing its results with the results obtained using a typical analytical technique of Inductively Coupled plasma-optical emission spectroscopy(ICP-OES).Limit of detection(LOD)of the LIBS system was also estimated for heavy metals.The experience gain through this work implies that LIBS could be highly applicable for testing the quality and purity of food products.
基金supported by the Russian Science Foundation(agreement#14-50-00034)(measurements of limit of detection)Russian Foundation for Basic Research(NK 15-32-20878/15)obtained in the frame of "Organization of Scientific Research"in the Far Eastern Federal University supported by Ministry of Education and Science of Russian Federation
文摘The influence of the energy of femtosecond laser pulses on the intensity of Fe I （371.99 nm） emission line and the continuous spectrum of the plasma generated on the surface of Fe^3＋ water solution by a Ti： sapphire laser radiation with pulse duration 〈45 fs and energies up to 7 mJ is determined. A calibration curve was obtained for Fe3＋ concentration range from 0.5 g/L to the limit of detection in water solution, and its saturation was detected for concentrations above 0.25 g/L, which is ascribed to self-absorption. The 3σ- limit of detection obtained for Fe in water solution is 2.6 mg/L in the case of 7 mJ laser pulse energy. It is found that an increase of laser pulse energy insignificantly affects on LOD in the time-resolved LIBS and leads to a slight improvement of the limit of detection.
基金supported by National Natural Science Foundation of China (No.60974004)Science Foundation of Ministry of Housing and Urban-Rural Development (No.2011-K5-31)
文摘The objective of this paper is to study systematically the dynamics and control strategy of a singular biological economic model that is described by a differential-algebraic equation. It is shown that when the economic profit passes through zero, this model exhibits the transcritical bifurcation, the Hopf bifurcation, and the limit cycle. In particular, the system undergoes the singularity induced bifurcation at the positive equilibrium, which can result in impulse. Then, state feedback controllers closer to the actual control strategies are designed to eliminate the unexpected singularity induced bifurcation and stabilize the positive equilibrium under the positive profit. Finally, numerical simulations verify the results and illustrate the effectiveness of the controllers. Also, the model with positive economic profit is shown numerically to have different dynamics.
文摘随着高比例可再生能源在电力系统中的广泛应用,可再生能源的波动性和随机性对电力系统静态电压稳定评估带来挑战,电力系统静态电压稳定域(static voltage stability region,SVSR)可以全面分析和监测电力系统电压稳定性,其关键是快速准确地构建稳定域边界。针对传统连续潮流法和非线性规划法计算量大的问题,提出一种基于SVSR边界拓扑性质的SVSR边界构建优化模型,根据边界连续且光滑的性质,由已知边界点通过预测-校正方法直接计算相邻边界点。在此模型基础上提出一种极限诱导分岔识别方法,构建考虑极限诱导分岔的SVSR边界。最后通过算例分析验证了所提方法的可行性和准确性。
