Development of hydrometallurgical process for indium recovery from waste liquid crystal display using Cyphos IL 101

The main goal of this study was to recover indium from the waste liquid crystal display(LCD)panel.In this context,an ionic liquid Cyphos IL 101 was explored.The extraction parameters such as equilibration period,acid concentration,chloride ion concentration,hydrogen ion concentration were examined on the extraction efficiency of Cyphos IL 101 towards In(III).Quantitative extraction of indium was found at 2.0 mol/L HCl using 0.005 mol/L Cyphos IL 101 and quantitative stripping with 1.0 mol/L H2SO4.Job’s method was used to determine the extracted species and R3R'PInCl4(R=C6H13;R′=C14H29)was proposed.Based on the observations on multi-metal studies,Cyphos IL 101 was further employed for the removal of indium,tin and copper from the leach liquors of waste LCDs.Optimized conditions were generated for the recovery of indium from waste LCDs.McCabe−Thiele diagram analysis,counter-current extraction and selective stripping were carried out to separate the metal ions,i.e.,indium,tin and copper.Two stages at O/A ratio of 1:3 were required for complete removal of tin from the feed and selective stripping of In and Sn was achieved using 0.1 mol/L H2SO4.A scheme for separating indium from the waste LCDs was proposed.

Optical simulation of in-plane-switching blue phase liquid crystal display using the finite-difference time-domain method

The finite-difference time-domain method is used to simulate the optical characteristics of an in-plane switching blue phase liquid crystal display.Compared with the matrix optic methods and the refractive method,the finite-difference timedomain method,which is used to directly solve Maxwell＇s equations,can consider the lateral variation of the refractive index and obtain an accurate convergence effect.The simulation results show that e-rays and o-rays bend in different directions when the in-plane switching blue phase liquid crystal display is driven by the operating voltage.The finitedifference time-domain method should be used when the distribution of the liquid crystal in the liquid crystal display has a large lateral change.

COMPENSATION EFFECT OF POLYIMIDE THIN FILMS ON NORMALLY WHITE TWISTED NEMATIC LIQUID CRYSTAL DISPLAYS

The disadvantages of Normally White Twisted Nematic Liquid Crystal Display (NW-TN-LCD) were discussed. The reason that the negative birefringent polyimide thin films were used to compensate NW-TN-LCD to decrease off-axis leakage, improve contrast ratios and enlarge viewing angles was explained in this paper. A certain polyimide thin film was taken as an example to show compensation effect on NW-TN-LCD.

Novel cell parameter determination of a twisted-nematic liquid crystal display

In this paper a novel method is proposed to determine the cell parameters including the twist angle, optic retardation and rubbing direction of twisted-nematic liquid crystal displays （TNLCD） by rotating the TNLCD. It is a single-wavelength method. Because using subtraction equation of transmittance as curve fitting equation, the influence of the light from environment and the absorption by polarizer, the sample of TNLCD and analyser on the transmittance is eliminated. Accurate results can also be obtained in imperfect darkness. By large numbers of experiments, we found that not only the experimental setup is quite simple and can be easily adopted to be carried out, but also the results are accurate.

NOVEL POLYMER WIDE VIEWING ANGLE COMPENSATION FILMS FOR LIQUID CRYSTAL DISPLAYS(LCDS)

We report on generating uniaxial negative birefringent compensation films, made of specifically designedpolyimides. These polymers were synthesized via a polycondensation of dianhydride [such as 2, 2' -bis(3, 4-dicarboxyphenyl)hexafluoropropane dianhydride] and 2, 2'-bis(trifluoromethyl)-4,4'-diaminobiphenyl. The uniaxial negative birefringent (n_x =n_y > n_z) polyimide substrates are achieved using a solution-casting method in conventional solvents, which exhibit thedesirable optical phase retardation [(n_x - n_z)×d] values from 50 to 400 nm varying with the film thickness. In thesepolyimide films, the long chain rigid molecules adopt intrinsic planar orientaion. In detail, the majority of phenylene-imiderings and phenylenes preferentially adopt nearly planar conformations parallel to the film substrae. In addition, these filmsalso possess high transparency (or transmittance) and little color shift. The unique color dispersion curve indicates that thistype of materials is very suitable for the applications in LCDs due to an excellent mimic for the retardation color dispersioncurve with respect to LC molecules. Significantly low in-plane retardation (< 1 nm) allows this new technology based film toachieve sufficiently high contrast ratio while highly negative retardation dramatically suppresses the gray scale inversion toimprove the viewing angle performance in a variety of new mode LCDs.

Low voltage transflective blue-phase liquid crystal display with a non-uniform etching substrate

A transflective polymer-stabilized blue-phase liquid crystal display（BP-LCD） with a non-uniform etching substrate is proposed.In-plane switching（IPS） electrodes on the bottom substrate are put on the different gaps,and the bottom substrate between the electrodes is etched into different depths in transmissive（T） and reflective（R） regions.This structure can balance the optical phase retardation in the two regions and is helpful to achieve well-matched voltag-dependent transmittance and reflectance curves.This transflective display has high optical efficiency,a wide viewing angle,and low operating voltage（approximately 6 V）.

Liquid crystal Fresnel lens display

A novel see-through display with a liquid crystal lens array was proposed.A liquid crystal Fresnel lens display（LCFLD） with a holographic screen was demonstrated.The proposed display system has high efficiency,simple fabrication,and low manufacturing cost due to the absence of a polarizer and color filter.

Liquid Crystal Motion Picture Projector

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Cinnamate-functionalized hyperbranched polymer as liquid crystal photo-alignment layer

In this work, 4-methoxylcinnamoyl chloride was reacted with a commercial hyperbranched polymer （Boltom-TM H30） to prepare a hyperbranched photosensitive polymer （H30-Ci）. The polymer was characterized by UV absorption spectrum and 1H- NMR spectrum. After processed by Linearly Polarized Polymerization （LPP） method, the spin-coated films of H30-Ci were used as photo-alignment layers to assemble liquid crystal （LC） cells containing nematic liquid crystal （5CB）. The observation by polarized microscope showed that the H30-Ci blended with a linear polymer （BP-AN-Ci） photo-alignment layers could align LC molecules in a very uniform way.

Electro-optical Properties of Liquid Crystal Composite Materials

The liquid crystal composite materials consist of microdroplets of liquid crystals which are spontaneously formed in a matrix of a polymer at the time of its polymerization. The director configuration in liquid crystal droplets, the model of orientation of droplets, and the contrast ratios of a cell are investigated. Droplet size, spacing and distribution are readily controlled in these materials to allow optimization of displays based upon electrically controlled light scattering from the liquid crystal droplets. Preliminary experimental and theoretical studies of the light scattering and electro-optic response of new material show that these materials can offer new features suitable for large area displays and light valves.

Elimination of Zig-zag Defects in Surface-stabilized Ferroelectric Liquid Crystal Cells

The elimination of zig-zag defects in polyimide-coated surface-stabilized ferroelectric liquid crystal(SSFLC) cells is carried out by applying a low-frequency electric field. It has been achieved when the thickness of SSFLC cell is 3 μm. The optical spectral transmittance measurement confirmed that there is no change of layer structure, and the memory capability was not improved. The different effects of low-frequency electric field applied on the different thickness FLC cells have been observed, and experimental results were presented.

Liquid crystal display and organic light-emitting diode display: present status and future perspectives

Recently,‘Liquid crystal display(LCD)vs.organic light-emitting diode(OLED)display:who wins?’has become a topic of heated debate.In this review,we perform a systematic and comparative study of these two flat panel display technologies.First,we review recent advances in LCDs and OLEDs,including material development,device configuration and system integration.Next we analyze and compare their performances by six key display metrics:response time,contrast ratio,color gamut,lifetime,power efficiency,and panel flexibility.In this section,we focus on two key parameters:motion picture response time(MPRT)and ambient contrast ratio(ACR),which dramatically affect image quality in practical application scenarios.MPRT determines the image blur of a moving picture,and ACR governs the perceived image contrast under ambient lighting conditions.It is intriguing that LCD can achieve comparable or even slightly better MPRT and ACR than OLED,although its response time and contrast ratio are generally perceived to be much inferior to those of OLED.Finally,three future trends are highlighted,including high dynamic range,virtual reality/augmented reality and smart displays with versatile functions.

Polymer-stabilized blue phase liquid crystal display with slanted wall-shaped electrodes

A polymer-stabilized blue phase liquid crystal display （BPLCD） with slanted wall-shaped electrodes is proposed. Compared with the traditional BPLCD with wall-shaped electrodes, the electrodes of the proposed BPLCD are slightly angled to obtain phase retardation in the entire cell even at the position of electrodes. The proposed BPLCD demonstrates a relatively higher average transmittance and overall brightness than the traditional BPLCD.

A fast-response in-plane switching liquid crystal display with a protrusion structure

The widespread use and application of in-plane switching liquid crystal displays （IPS-LCDs） is limited by their slow response. In this letter, a fast-response IPS-LCD with a protrusion structure is proposed. The gray-to-gray response time of the IPS-LCD is reduced by 20% to 30%. The difference in cell gap induced by the protrusion accounts for the faster response. Moreover, the viewing angle and ganmla shift of tile proposed IPS-LCD are simulated and found to be better than that of conventional IPS-LCDs.

Emerging Technologies of Liquid Crystal Displays

The general features and the emerging technologies of liquid crystal displays are described from the viewpoints of wide viewing and fast response technologies. The device applications of liquid crystals for optical communications are also described.

Homogeneous-aligned high-transmission and fast-response liquid crystal display with three-layer electrodes

A homogeneous-aligned, high-transmission, and fast-response liquid crystal display （LCD） with three-layer electrodes is proposed. The molecules of liquid crystals are more inclined to rotate above and between the pixel electrodes. This induces a much higher transmission than that of the cell driven by the fringe field switching method and a wide viewing angle simultaneously because of the combined fringe and in-plane electric fields. Furthermore, a trigger pulse voltage is applied between the top and common electrodes to forcibly align the liquid crystal molecules vertically to show the transient dark state, which results in a very fast turn-off time （-1 ms）. With high degree of transmission and fast response time, this kind of LCD is a potential candidate for large LCD panels.

Color holographic display based on azo-dye-doped liquid crystal(Invited Paper)

A multiplexed holographic display video has been achieved by using a passive azo-dye-doped liquid crystal （LC） cell. Holograms formed in this cell can be refreshed in the order of several milliseconds. By angular multiplexing technique, dynamically multiplexed holographic videos are realized. Moreover, the reconstructed RGB images are merged into a color image, which illustrates the possibility of a color holographic three-dimensional （3D） display by holographic multiplexing of the LC cell.

TN型废液晶热解产物研究

氮气气氛下,以TN型液晶为实验材料,利用TGA-FTIR联用仪研究热解失重特征及过程产物;同时利用GC-MS对管式炉实验系统热解产物进行分析。结果表明,TN型液晶热解失重起始温度为120℃,剧烈失重温度为220℃-430℃;热解产物除了含CO2外,还含有1-5个碳原子官能团的苯、苯酚、苯呋喃等组成的芳香族化合物、多环芳烃以及丙烷为主的烃类有机物。这些有机物绝大多数是有毒有害物质,可进一步通过焚烧热解产物来实现TN型废液晶无害化处理。

液晶字符识别的CNN和SVM组合分类器

针对仪表液晶显示字符识别问题,提出一种结合了卷积神经网络(CNN)和支持向量机(SVM)的字符识别方法。分别采用具有并联结构的CNN模型和基于梯度方向直方图(HOG)特征的SVM方法构建基本分类器,当2个分类器的结果存在冲突时,利用CNN的softmax输出最大值判决最终结果,当其大于设定阈值时采用CNN分类器的结果,反之采用SVM分类器的结果。建立字符图像的误差模型并利用仿真方法构建了数据集用于分类器的训练和测试,给出一种基于投票原理的最优阈值的估计算法。在MNIST和仿真数据集上的测试实验结果表明,最优阈值估计算法的结果可靠,组合分类器的准确率较2种单一分类器均有提高,在实际测试系统上其准确率达到99.81%,验证了该组合分类器方法对液晶字符识别问题的有效性;在CIFAR-10数据集上的实验结果验证了该方法也可用于其他分类问题。

TFT-LCD用偏光片的研究与进展

偏光片作为液晶显示器的主要零部件之一,在平板显示领域有着广泛的应用前景。该文阐述了TFT-LCD用偏光片的工作原理、性能指标及影响因素,介绍了偏光片的结构、分类及制造工艺,简要分析了目前偏光片的产业及市场的发展状况和趋势,以及国内相关产业政策对国内偏光片行业的发展所起的作用。