The dissolution kinetics of calcined ulexite in ammonium chloride solutions at high solid-to-liquid ratios were investigated. In the experiments, calcination temperature, solution concentration, reaction temperature, ...The dissolution kinetics of calcined ulexite in ammonium chloride solutions at high solid-to-liquid ratios were investigated. In the experiments, calcination temperature, solution concentration, reaction temperature, and pre-hydration were chosen as parameters. It was observed that the dissolution rate increased with increasing calcination temperature, solution concentration, and reaction temperature, whereas it was not affected by pre-hydration. Employing graphical and statistic methods, the dissolution rate, based on homogeneous reaction model, can be given as: (1-X(B2O3))-1-1= k(c(NH4Cl))1.982t. The activation energy for the dissolution of the ulexite sample calcined at 160 ℃ was found to be 84.04 kJ·mol-1.展开更多
The present study is concerned with the reflection and transmission of plane waves at an interface between homogenous invisicid liquid half space and a micropolar liquid-saturated porous solid half space. The reflecti...The present study is concerned with the reflection and transmission of plane waves at an interface between homogenous invisicid liquid half space and a micropolar liquid-saturated porous solid half space. The reflection and transmission coefficients of various reflected and transmitted waves with the angle of incident have been obtained. Numerical calculation has been performed for amplitude ratios of various reflected and transmitted waves. Micropolarity and porosity effects on the reflection and transmission coefficients have been depicted graphically. Some particular cases have been deduced from the present formulation.展开更多
Solubilities of 2,4-dichlorobenzaldehyde in five single organic solvents,namely,n-propanol,n-butanol.cyclohexane,chloroform and dichloromethane as well as in two mixed solvents,namely,cyclohexane-acetone and cyclohexa...Solubilities of 2,4-dichlorobenzaldehyde in five single organic solvents,namely,n-propanol,n-butanol.cyclohexane,chloroform and dichloromethane as well as in two mixed solvents,namely,cyclohexane-acetone and cyclohexane n-butanol,have been measured.These data are correlated withWilson,NRTL and UNIQUAC activity coefficient models and can be used for the process design inthe purification of 2,4-dichlorobenzaldehyde.展开更多
文摘The dissolution kinetics of calcined ulexite in ammonium chloride solutions at high solid-to-liquid ratios were investigated. In the experiments, calcination temperature, solution concentration, reaction temperature, and pre-hydration were chosen as parameters. It was observed that the dissolution rate increased with increasing calcination temperature, solution concentration, and reaction temperature, whereas it was not affected by pre-hydration. Employing graphical and statistic methods, the dissolution rate, based on homogeneous reaction model, can be given as: (1-X(B2O3))-1-1= k(c(NH4Cl))1.982t. The activation energy for the dissolution of the ulexite sample calcined at 160 ℃ was found to be 84.04 kJ·mol-1.
文摘The present study is concerned with the reflection and transmission of plane waves at an interface between homogenous invisicid liquid half space and a micropolar liquid-saturated porous solid half space. The reflection and transmission coefficients of various reflected and transmitted waves with the angle of incident have been obtained. Numerical calculation has been performed for amplitude ratios of various reflected and transmitted waves. Micropolarity and porosity effects on the reflection and transmission coefficients have been depicted graphically. Some particular cases have been deduced from the present formulation.
文摘Solubilities of 2,4-dichlorobenzaldehyde in five single organic solvents,namely,n-propanol,n-butanol.cyclohexane,chloroform and dichloromethane as well as in two mixed solvents,namely,cyclohexane-acetone and cyclohexane n-butanol,have been measured.These data are correlated withWilson,NRTL and UNIQUAC activity coefficient models and can be used for the process design inthe purification of 2,4-dichlorobenzaldehyde.
