The hydrodynamics of active liquid crystal models has attracted much attention in recent years due to many applications of these models.In this paper,we study the weak-strong uniqueness for the Leray-Hopf type weak so...The hydrodynamics of active liquid crystal models has attracted much attention in recent years due to many applications of these models.In this paper,we study the weak-strong uniqueness for the Leray-Hopf type weak solutions to the incompressible active liquid crystals in R^(3).Our results yield that if there exists a strong solution,then it is unique among the Leray-Hopf type weak solutions associated with the same initial data.展开更多
In this paper,we are concerned with a three-dimensional non-isothermal model for the compressible nematic liquid crystal flows in a periodic domain.Under some smallness and structural assumptions imposed on the time-p...In this paper,we are concerned with a three-dimensional non-isothermal model for the compressible nematic liquid crystal flows in a periodic domain.Under some smallness and structural assumptions imposed on the time-periodic force,we establish the existence of the time-periodic solutions to the system by using a regularized approximation scheme and the topological degree theory.We also prove a uniqueness result via energy estimates.展开更多
We consider the Poiseuille flow of nematic liquid crystals via the full Ericksen-Leslie model.The model is described by a coupled system consisting of a heat equation and a quasilinear wave equation.In this paper,we w...We consider the Poiseuille flow of nematic liquid crystals via the full Ericksen-Leslie model.The model is described by a coupled system consisting of a heat equation and a quasilinear wave equation.In this paper,we will construct an example with a finite time cusp singularity due to the quasilinearity of the wave equation,extended from an earlier resultonaspecial case.展开更多
This article is devoted to the study of the so-called incompressible limit for solutions of the compressible liquid crystals system. We consider the problem in the whole space R^N and a bounded domain of R^N with Diri...This article is devoted to the study of the so-called incompressible limit for solutions of the compressible liquid crystals system. We consider the problem in the whole space R^N and a bounded domain of R^N with Dirichlet boundary conditions. Here we set the number of dimension N = 2 or 3.展开更多
Some diacetylene-containing copolyesters with different ratios of dipropargyl 1,10-decanate anddipropargyl terephthalate were synthesized. Properties of these copolymers were characterized by differentialscanning calo...Some diacetylene-containing copolyesters with different ratios of dipropargyl 1,10-decanate anddipropargyl terephthalate were synthesized. Properties of these copolymers were characterized by differentialscanning calorimetry and polarizing optical microscopy. The copolymer could be cross-linked easily by UVirradiation in a liquid crystal matrix without adding any photoinitiator. The preliminary studies showed thatthe diacetylene-containing polymer network can assist liquid crystal molecules to align with the externalelectric field, thus reducing the response time of display devices.展开更多
In this paper, a series of chiral non-symmetrical liquid crystals (nBA-chol) consisting of a cholesteryl ester moiety as chiral entity and a biphenyl aromatic core with different terminal alkyl chain has been synthe...In this paper, a series of chiral non-symmetrical liquid crystals (nBA-chol) consisting of a cholesteryl ester moiety as chiral entity and a biphenyl aromatic core with different terminal alkyl chain has been synthesized and investigated for their liquid crystalline properties. Effects of numbers of methylene units in the terminal alkyl chain on the phase transition temperatures and on the temperature-dependent pitch lengths of the chiral liquid crystals have been studied. The long terminal alkyl chain tends to exhibit smectic A mesophases. The pitch lengths of the cholesteric mesophases of the chiral liquid crystals decrease with increasing temperature and with increasing numbers of methylene units in the terminal alkyl chain, respectively.展开更多
In this article, we prove the global existence of weak solutions to the non- isothermal nematic liquid crystal system on T2, on the basis of a new approximate system which is different from the classical Ginzburg-Land...In this article, we prove the global existence of weak solutions to the non- isothermal nematic liquid crystal system on T2, on the basis of a new approximate system which is different from the classical Ginzburg-Landau approximation. Local in space energy inequalities are employed to recover the estimates on the second order spatial derivatives of the director fields locally in time, which cannot be derived from the basic energy balance. It is shown that these weak solutions satisfy the temperature equation, and also the total energy equation but away from at most finite many "singular" times, at which the energy concentration occurs and the director field losses its second order derivatives.展开更多
A high-resolution testing technique named liquid crystal thermography is used for the experimental study on jet array impingement to map out the distribution of heat transfer coefficients on the cooling surface. Effec...A high-resolution testing technique named liquid crystal thermography is used for the experimental study on jet array impingement to map out the distribution of heat transfer coefficients on the cooling surface. Effects of the impingement distance, the impinging hole arrangement and the initial crossflow on heat transfer characteristics are investigated. The thermal images show truly the features of local heat transfer for each jet impingement cooling. The applications of thermochromic liquid crystal are successful in the qualitative and quantitative measurement for heat transfer coefficients distribution.展开更多
A detailed theoretical analysis of determining the sum of flexoelectric coefficients in nematic liquid crystals using the capacitance method is given. In the strong anchoring parallel aligned nematic (PAN) and hybri...A detailed theoretical analysis of determining the sum of flexoelectric coefficients in nematic liquid crystals using the capacitance method is given. In the strong anchoring parallel aligned nematic (PAN) and hybrid aligned nematic (HAN) cells, the dependences of the capacitance on the sum of flexoelectric coefficients and the applied voltage are obtained by numerical simulations, and the distributions of the director and the electric potential for different applied voltages and flexoelectric coefficients are also given. Based on this theoretical analysis, we propose an experimental design for measuring the capacitance of a liquid crystal cell using the improved precision LCR meter E4980A (Agilent). Through comparing the experimental data with the simulated results, the sum of flexoeletric coefficients can be determined.展开更多
Eliminating topological defects to achieve monodomain liquid crystals is highly significant for the fundamental studies of soft matter and building long-range ordered materials.However,liquid crystals are metastable a...Eliminating topological defects to achieve monodomain liquid crystals is highly significant for the fundamental studies of soft matter and building long-range ordered materials.However,liquid crystals are metastable and sensitive to external stimuli,such as flow,confinement,and electromagnetic fields,which cause their intrinsic polycrystallinity and topological defects.Here,we achieve the monodomain liquid crystals of graphene oxide over 30 cm through boundary-free sheargraphy.The obtained monodomain liquid crystals exhibit large-area uniform alignment of sheets,which has the same optical polarized angle and intensity.The monodomain liquid crystals provide bidirectionally ordered skeletons,which can be applied as lightweight thermal management materials with bidirectionally high thermal and electrical conductivity.Furthermore,we extend the controllable topology of two-dimensional colloids by introducing singularities and disclinations in monodomain liquid crystals.Topological structures with defect strength from−2 to+2 were realized.This work provides a facile methodology to study the structural order of soft matter at a macroscopic level,facilitating the fabrication of metamaterials with tunable and highly anisotropic architectures.展开更多
The mesomorphie properties of title complexes are investigated by means of DSC and polarizing microscopy. The mesophase temperature ranges of complexes are wider than that of corresponding organic ligands. The bridgin...The mesomorphie properties of title complexes are investigated by means of DSC and polarizing microscopy. The mesophase temperature ranges of complexes are wider than that of corresponding organic ligands. The bridging groups of the complexes have profoand effects on the mesomorphic behavior, When the bridging groups are opticallhy active. the compleve show chiral smectic展开更多
The synthesis and characterization of two new star-like liquid crystals are reported.They are made of a silicon core and four alkoxyazobenzene monomers in the periphery. Theirphase behaviors and the structures are det...The synthesis and characterization of two new star-like liquid crystals are reported.They are made of a silicon core and four alkoxyazobenzene monomers in the periphery. Theirphase behaviors and the structures are determined by infrared absorption spectroscopy (IR),nuclear magnetic resonance spectroscopy (NMR), elemental analysis (EA), polarizing opticalmicroscope (POM) and differential scanning calorimetry (DSC).展开更多
The magnetic field is one of the most important parameters in solar physics,and a polarimeter is the key device to measure the solar magnetic field.Liquid crystals based Stokes polarimeter is a novel technology,and wi...The magnetic field is one of the most important parameters in solar physics,and a polarimeter is the key device to measure the solar magnetic field.Liquid crystals based Stokes polarimeter is a novel technology,and will be applied for magnetic field measurement in the first space-based solar observatory satellite developed by China,Advanced Space-based Solar Observatory.However,the liquid crystals based Stokes polarimeter in space is not a mature technology.Therefore,it is of great scientific significance to study the control method and characteristics of the device.The retardation produced by a liquid crystal variable retarder is sensitive to the temperature,and the retardation changes 0.09°per 0.10℃.The error in polarization measurement caused by this change is 0.016,which affects the accuracy of magnetic field measurement.In order to ensure the stability of its performance,this paper proposes a high-precision temperature control system for liquid crystals based Stokes polarimeter in space.In order to optimize the structure design and temperature control system,the temperature field of liquid crystals based Stokes polarimeter is analyzed by the finite element method,and the influence of light on the temperature field of the liquid crystal variable retarder is analyzed theoretically.By analyzing the principle of highprecision temperature measurement in space,a high-precision temperature measurement circuit based on integrated operational amplifier,programmable amplifier and 12 bit A/D is designed,and a high-precision space temperature control system is developed by applying the integral separation PI temperature control algorithm and PWM driving heating films.The experimental results show that the effect of temperature control is accurate and stable,whenever the liquid crystals based Stokes polarimeter is either in the air or vacuum.The temperature stability is within±0.0150℃,which demonstrates greatly improved stability for the liquid crystals based Stokes polarimeter.展开更多
In this paper,we investigate the bichromatic coherent random lasing actions from the dye-doped polymer stabilized blue phase liquid crystals.Two groups of lasing peaks,of which the full widith at half maximum is about...In this paper,we investigate the bichromatic coherent random lasing actions from the dye-doped polymer stabilized blue phase liquid crystals.Two groups of lasing peaks,of which the full widith at half maximum is about 0.3 nm,are clearly observed.The shorter-and longer-wavelength modes are associated with the excitation of the single laser dye(DCM) monomers and dimers respectively.The experimental results show that the competition between the two groups of the lasing peaks can be controlled by varying the polarization of the pump light.When the polarization of the pump light is rotated from 0?to 90?,the intensity of the shorter-wavelength lasing peak group reduces while the intensity of the longer-wavelength lasing peak group increases.In addition,a red shift of the longer-wavelength modes is also observed and the physical mechanisms behind the red-shift phenomenon are discussed.展开更多
A novel biomimetic protein-resistant modifier based on cellulose-based polymeric liquid crystals was described(PLCs). Two types of PLCs of propyl hydroxypropyl cellulose ester(PPC) and octyl hydroxypropyl cellulos...A novel biomimetic protein-resistant modifier based on cellulose-based polymeric liquid crystals was described(PLCs). Two types of PLCs of propyl hydroxypropyl cellulose ester(PPC) and octyl hydroxypropyl cellulose ester(OPC) were prepared by esterification from hydroxypropyl cellulose, and then were mixed with polyvinyl chloride and polyurethane to obtain composite films by solution casting, respectively. The surface morphology of PLCs and their composite films were characterized by polarized optical microscopy(POM) and scanning electron microscopy(SEM), suggesting the existence of microdomain separation with fingerprint texture in PLC composite films. Water contact angle measurement results indicated that hydrophilicity of PLC/polymer composite films was dependent on the type and content of PLC as well as the type of matrix due to their interaction. Using bovine serum albumin(BSA) as a model protein, protein adsorption results revealed that PLCs with protein-resistant property can obviously suppress protein adsorption on their composite films, probably due to their flexible LC state. Moreover, all PLCs and their composites exhibited non-toxicity by MTT assay, suggesting their safety for biomedical applications.展开更多
Disk-like liquid crystals(DLCs) can self-assemble to ordered columnar mesophases and are intriguing onedimensional organic semiconductors with high charge carrier mobility.To improve their applicable property of mes...Disk-like liquid crystals(DLCs) can self-assemble to ordered columnar mesophases and are intriguing onedimensional organic semiconductors with high charge carrier mobility.To improve their applicable property of mesomorphic temperature ranges,we exploit the binary mixtures of electronic donor-acceptor DLC materials.The electron-rich2,3,6,7,10,11-hexakis(alkoxy)triphenylenes(C4,C6,C8,C10,C12) and an electron-deficient tetrapentyl triphenylene-2,3,6,10-tetracarboxylate have been prepared and their binary mixtures have been investigated.The mesomorphism of the1:1(molar ratio) mixtures has been characterized by polarizing optical microscopy(POM),differential scanning calorimetry(DSC),and small angel x-ray scattering(SAXS).The self-assembled monolayer structure of a discogen on a solid-liquid interface has been imaged by the high resolution scanning tunneling microscopy(STM).The match of peripheral chain length has important influence on the mesomorphism of the binary mixtures.展开更多
Cholesteric liquid crystals(CLCs) have recently sparked an enormous amount of interest in the development of soft matter materials due to their unique ability to self-organize into a helical supra-molecular architec...Cholesteric liquid crystals(CLCs) have recently sparked an enormous amount of interest in the development of soft matter materials due to their unique ability to self-organize into a helical supra-molecular architecture and their excellent selective reflection of light based on the Bragg relationship.Nowadays,by the virtue of building the self-organized nanostructures with pitch gradient or non-uniform pitch distribution,extensive work has already been performed to obtain CLC films with a broad reflection band.Based on authors' many years' research experience,this critical review systematically summarizes the physical and optical background of the CLCs with broadband reflection characteristics,methods to obtain broadband reflection of CLCs,as well as the application in the field of intelligent optical modulation materials.Combined with the research status and the advantages in the field,the important basic and applied scientific problems in the research direction are also introduced.展开更多
Six novel rod-like magnetic liquid crystals have been prepared, in which trans-bicyclohexyl or trans-cyclohexylphenyl and biphenylcarboxylic acid phenyl ester mesogenic cores with n-propyl and n-pentyl substituents we...Six novel rod-like magnetic liquid crystals have been prepared, in which trans-bicyclohexyl or trans-cyclohexylphenyl and biphenylcarboxylic acid phenyl ester mesogenic cores with n-propyl and n-pentyl substituents were terminated by 4-hydroxyl- TEMPO (TEMPO = 2,2,6,6-tetramethylpiperidine-l-oxy). Their structures were confirmed by elemental analysis, IR and MS. Determined by SQUID, EPR, DSC and HS-POM (heat stage polarizing optical microscope), the six compounds all have both magnetic and liquid crystalline properties; their temperature ranges of mesophase were from 16.0 to 24.8 ℃, and the magnetic liquid crystal molecules could obviously improve the response sensitivity of liquid crystal materials.展开更多
In this article, we investigate the global behavior of weak solutions of a simplified Ericksen-Leslie system for compressible flows of nematic liquid crystals in time in a bounded three-dimension domain-arbitrary forc...In this article, we investigate the global behavior of weak solutions of a simplified Ericksen-Leslie system for compressible flows of nematic liquid crystals in time in a bounded three-dimension domain-arbitrary forces. By adapting the arguments for the compressible Navier-Stokes equations, and carefully analyzing the direction field of liquid crystals in the equations of angular momentum, we show the existence of bounded absorbing sets, global bounded trajectories, and global attractors to weak solutions of compressible flows of nematic liquid crystals with the adiabatic constant γ〉5/3.展开更多
We study the propagation of spatial solitons in nematic liquid crystals, using the self-similar method. Analytical solutions in the form of self-similar solitons are obtained exactly. We confirm the stability of these...We study the propagation of spatial solitons in nematic liquid crystals, using the self-similar method. Analytical solutions in the form of self-similar solitons are obtained exactly. We confirm the stability of these solutions by direct numerical simulation, and find that the stable spatial solitons can exist in various forms, such as Oaussian solitons, radially symmetric solitons, multipole solitons, and soliton vortices.展开更多
基金partially supported by NSFC(11831003,12031012)the Institute of Modern Analysis-A Frontier Research Center of Shanghai。
文摘The hydrodynamics of active liquid crystal models has attracted much attention in recent years due to many applications of these models.In this paper,we study the weak-strong uniqueness for the Leray-Hopf type weak solutions to the incompressible active liquid crystals in R^(3).Our results yield that if there exists a strong solution,then it is unique among the Leray-Hopf type weak solutions associated with the same initial data.
基金partially supported by the Science and Technology Research Program of Chongqing Municipal Education Commission(KJQN202100523,KJQN202000536)the National Natural Science Foundation of China(12001074)+3 种基金the Natural Science Foundation of Chongqing(cstc2020jcyj-msxmX0606)supported by the National Natural Science Foundation of Chongqing(CSTB2023NSCQ-MSX0278)the Science and Technology Research Program of Chongqing Municipal Education Commission(KJZD-K202100503)the Research Project of Chongqing Education Commission(CXQT21014)。
文摘In this paper,we are concerned with a three-dimensional non-isothermal model for the compressible nematic liquid crystal flows in a periodic domain.Under some smallness and structural assumptions imposed on the time-periodic force,we establish the existence of the time-periodic solutions to the system by using a regularized approximation scheme and the topological degree theory.We also prove a uniqueness result via energy estimates.
文摘We consider the Poiseuille flow of nematic liquid crystals via the full Ericksen-Leslie model.The model is described by a coupled system consisting of a heat equation and a quasilinear wave equation.In this paper,we will construct an example with a finite time cusp singularity due to the quasilinearity of the wave equation,extended from an earlier resultonaspecial case.
基金supported by National Natural Science Foundation of China-NSAF: 11071043, 11131005
文摘This article is devoted to the study of the so-called incompressible limit for solutions of the compressible liquid crystals system. We consider the problem in the whole space R^N and a bounded domain of R^N with Dirichlet boundary conditions. Here we set the number of dimension N = 2 or 3.
基金This work was supported by the National Natural Science Foundation of China
文摘Some diacetylene-containing copolyesters with different ratios of dipropargyl 1,10-decanate anddipropargyl terephthalate were synthesized. Properties of these copolymers were characterized by differentialscanning calorimetry and polarizing optical microscopy. The copolymer could be cross-linked easily by UVirradiation in a liquid crystal matrix without adding any photoinitiator. The preliminary studies showed thatthe diacetylene-containing polymer network can assist liquid crystal molecules to align with the externalelectric field, thus reducing the response time of display devices.
基金Financial support from National Natural Science foundation(No.20674005)National High Technology"863"Program of China(No.2006AA03Z108)National Science and Technology Supporting Item(No.2006BAI03A09)
文摘In this paper, a series of chiral non-symmetrical liquid crystals (nBA-chol) consisting of a cholesteryl ester moiety as chiral entity and a biphenyl aromatic core with different terminal alkyl chain has been synthesized and investigated for their liquid crystalline properties. Effects of numbers of methylene units in the terminal alkyl chain on the phase transition temperatures and on the temperature-dependent pitch lengths of the chiral liquid crystals have been studied. The long terminal alkyl chain tends to exhibit smectic A mesophases. The pitch lengths of the cholesteric mesophases of the chiral liquid crystals decrease with increasing temperature and with increasing numbers of methylene units in the terminal alkyl chain, respectively.
基金Hong Kong RGC Earmarked Research Grants 14305315,CUHK4041/11P and CUHK4048/13PThe Chinese University of Hong Kong,a Croucher Foundation-CAS Joint Grant,and a NSFC/RGC Joint Research Scheme(N-CUHK443/14)
文摘In this article, we prove the global existence of weak solutions to the non- isothermal nematic liquid crystal system on T2, on the basis of a new approximate system which is different from the classical Ginzburg-Landau approximation. Local in space energy inequalities are employed to recover the estimates on the second order spatial derivatives of the director fields locally in time, which cannot be derived from the basic energy balance. It is shown that these weak solutions satisfy the temperature equation, and also the total energy equation but away from at most finite many "singular" times, at which the energy concentration occurs and the director field losses its second order derivatives.
文摘A high-resolution testing technique named liquid crystal thermography is used for the experimental study on jet array impingement to map out the distribution of heat transfer coefficients on the cooling surface. Effects of the impingement distance, the impinging hole arrangement and the initial crossflow on heat transfer characteristics are investigated. The thermal images show truly the features of local heat transfer for each jet impingement cooling. The applications of thermochromic liquid crystal are successful in the qualitative and quantitative measurement for heat transfer coefficients distribution.
基金supported by the National Natural Science Foundation of China(Grant Nos.11274088,11374087,and 11304074)the Natural Science Foundation of Hebei Province,China(Grant No.A2014202123)+2 种基金the Research Project of Hebei Education Department,China(Grant Nos.Z2012061 and QN2014130)the Science and Technology Plan Project of Hebei Province,China(Grant No.134576260)the Key Subject Construction Project of Hebei Province University,China
文摘A detailed theoretical analysis of determining the sum of flexoelectric coefficients in nematic liquid crystals using the capacitance method is given. In the strong anchoring parallel aligned nematic (PAN) and hybrid aligned nematic (HAN) cells, the dependences of the capacitance on the sum of flexoelectric coefficients and the applied voltage are obtained by numerical simulations, and the distributions of the director and the electric potential for different applied voltages and flexoelectric coefficients are also given. Based on this theoretical analysis, we propose an experimental design for measuring the capacitance of a liquid crystal cell using the improved precision LCR meter E4980A (Agilent). Through comparing the experimental data with the simulated results, the sum of flexoeletric coefficients can be determined.
基金The authors gratefully acknowledge the support of National Key Research and Development Program of China(2020YFE0204400)National Natural Science Foundation of China(Nos.52090030,52122301,51973191)+3 种基金Shanxi-Zheda Institute of New Materials and Chemical Engineering(2012SZ-FR004)Hundred Talents Program of Zhejiang University(188020*194231701/113)China Postdoctoral Science Foundation(2021M692772)supported by the Fundamental Research Funds for the Central Universities(Nos.2021FZZX001-17).
文摘Eliminating topological defects to achieve monodomain liquid crystals is highly significant for the fundamental studies of soft matter and building long-range ordered materials.However,liquid crystals are metastable and sensitive to external stimuli,such as flow,confinement,and electromagnetic fields,which cause their intrinsic polycrystallinity and topological defects.Here,we achieve the monodomain liquid crystals of graphene oxide over 30 cm through boundary-free sheargraphy.The obtained monodomain liquid crystals exhibit large-area uniform alignment of sheets,which has the same optical polarized angle and intensity.The monodomain liquid crystals provide bidirectionally ordered skeletons,which can be applied as lightweight thermal management materials with bidirectionally high thermal and electrical conductivity.Furthermore,we extend the controllable topology of two-dimensional colloids by introducing singularities and disclinations in monodomain liquid crystals.Topological structures with defect strength from−2 to+2 were realized.This work provides a facile methodology to study the structural order of soft matter at a macroscopic level,facilitating the fabrication of metamaterials with tunable and highly anisotropic architectures.
文摘The mesomorphie properties of title complexes are investigated by means of DSC and polarizing microscopy. The mesophase temperature ranges of complexes are wider than that of corresponding organic ligands. The bridging groups of the complexes have profoand effects on the mesomorphic behavior, When the bridging groups are opticallhy active. the compleve show chiral smectic
文摘The synthesis and characterization of two new star-like liquid crystals are reported.They are made of a silicon core and four alkoxyazobenzene monomers in the periphery. Theirphase behaviors and the structures are determined by infrared absorption spectroscopy (IR),nuclear magnetic resonance spectroscopy (NMR), elemental analysis (EA), polarizing opticalmicroscope (POM) and differential scanning calorimetry (DSC).
基金the National Natural Science Foundation of China(Grant Nos.11427803,11427901 and 11773040)the Strategic Pioneer Program on Space Science,Chinese Academy of Sciences(CAS)(XDA04061002 and XDA15010800)the Public Technology Service Center,National Astronomical Observatories of CAS(829011V01)。
文摘The magnetic field is one of the most important parameters in solar physics,and a polarimeter is the key device to measure the solar magnetic field.Liquid crystals based Stokes polarimeter is a novel technology,and will be applied for magnetic field measurement in the first space-based solar observatory satellite developed by China,Advanced Space-based Solar Observatory.However,the liquid crystals based Stokes polarimeter in space is not a mature technology.Therefore,it is of great scientific significance to study the control method and characteristics of the device.The retardation produced by a liquid crystal variable retarder is sensitive to the temperature,and the retardation changes 0.09°per 0.10℃.The error in polarization measurement caused by this change is 0.016,which affects the accuracy of magnetic field measurement.In order to ensure the stability of its performance,this paper proposes a high-precision temperature control system for liquid crystals based Stokes polarimeter in space.In order to optimize the structure design and temperature control system,the temperature field of liquid crystals based Stokes polarimeter is analyzed by the finite element method,and the influence of light on the temperature field of the liquid crystal variable retarder is analyzed theoretically.By analyzing the principle of highprecision temperature measurement in space,a high-precision temperature measurement circuit based on integrated operational amplifier,programmable amplifier and 12 bit A/D is designed,and a high-precision space temperature control system is developed by applying the integral separation PI temperature control algorithm and PWM driving heating films.The experimental results show that the effect of temperature control is accurate and stable,whenever the liquid crystals based Stokes polarimeter is either in the air or vacuum.The temperature stability is within±0.0150℃,which demonstrates greatly improved stability for the liquid crystals based Stokes polarimeter.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11474021 and 51333001)the Key Program for International S&T Cooperation Projects of China(Grant No.2013DFB50340)+1 种基金the Issues of Priority Development Areas of the Research Fund for the Doctoral Program of Higher Education of China(Grant No.20120001130005)the Key(Key Grant)Project of Chinese Ministry of Education(Grant No.313002)
文摘In this paper,we investigate the bichromatic coherent random lasing actions from the dye-doped polymer stabilized blue phase liquid crystals.Two groups of lasing peaks,of which the full widith at half maximum is about 0.3 nm,are clearly observed.The shorter-and longer-wavelength modes are associated with the excitation of the single laser dye(DCM) monomers and dimers respectively.The experimental results show that the competition between the two groups of the lasing peaks can be controlled by varying the polarization of the pump light.When the polarization of the pump light is rotated from 0?to 90?,the intensity of the shorter-wavelength lasing peak group reduces while the intensity of the longer-wavelength lasing peak group increases.In addition,a red shift of the longer-wavelength modes is also observed and the physical mechanisms behind the red-shift phenomenon are discussed.
基金Funded by the National Natural Science Foundation of China(Nos.31170911 and 31040027)the Research Development and Innovation Fund of Jinan University(No.21611410)+1 种基金the Open Fund of the First Affiliated Hospital,Jinan University,Guangzhou(No.511005024)the Macao Science and Technology Development Fund(No.064/2013/A2)
文摘A novel biomimetic protein-resistant modifier based on cellulose-based polymeric liquid crystals was described(PLCs). Two types of PLCs of propyl hydroxypropyl cellulose ester(PPC) and octyl hydroxypropyl cellulose ester(OPC) were prepared by esterification from hydroxypropyl cellulose, and then were mixed with polyvinyl chloride and polyurethane to obtain composite films by solution casting, respectively. The surface morphology of PLCs and their composite films were characterized by polarized optical microscopy(POM) and scanning electron microscopy(SEM), suggesting the existence of microdomain separation with fingerprint texture in PLC composite films. Water contact angle measurement results indicated that hydrophilicity of PLC/polymer composite films was dependent on the type and content of PLC as well as the type of matrix due to their interaction. Using bovine serum albumin(BSA) as a model protein, protein adsorption results revealed that PLCs with protein-resistant property can obviously suppress protein adsorption on their composite films, probably due to their flexible LC state. Moreover, all PLCs and their composites exhibited non-toxicity by MTT assay, suggesting their safety for biomedical applications.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51273133 and 51443004)
文摘Disk-like liquid crystals(DLCs) can self-assemble to ordered columnar mesophases and are intriguing onedimensional organic semiconductors with high charge carrier mobility.To improve their applicable property of mesomorphic temperature ranges,we exploit the binary mixtures of electronic donor-acceptor DLC materials.The electron-rich2,3,6,7,10,11-hexakis(alkoxy)triphenylenes(C4,C6,C8,C10,C12) and an electron-deficient tetrapentyl triphenylene-2,3,6,10-tetracarboxylate have been prepared and their binary mixtures have been investigated.The mesomorphism of the1:1(molar ratio) mixtures has been characterized by polarizing optical microscopy(POM),differential scanning calorimetry(DSC),and small angel x-ray scattering(SAXS).The self-assembled monolayer structure of a discogen on a solid-liquid interface has been imaged by the high resolution scanning tunneling microscopy(STM).The match of peripheral chain length has important influence on the mesomorphism of the binary mixtures.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51573006,51573003,51203003,51303008,51302006,51402006,51272026,and 51273022)the Major Project of Beijing Science and Technology Program,China(Grant Nos.Z151100003315023 and Z141100003814011)the Fok Ying Tung Education Foundation,China(Grant No.142009)
文摘Cholesteric liquid crystals(CLCs) have recently sparked an enormous amount of interest in the development of soft matter materials due to their unique ability to self-organize into a helical supra-molecular architecture and their excellent selective reflection of light based on the Bragg relationship.Nowadays,by the virtue of building the self-organized nanostructures with pitch gradient or non-uniform pitch distribution,extensive work has already been performed to obtain CLC films with a broad reflection band.Based on authors' many years' research experience,this critical review systematically summarizes the physical and optical background of the CLCs with broadband reflection characteristics,methods to obtain broadband reflection of CLCs,as well as the application in the field of intelligent optical modulation materials.Combined with the research status and the advantages in the field,the important basic and applied scientific problems in the research direction are also introduced.
基金supported by Natural Science Foundation of Shaanxi Province Educational Department(No.07JK426)Science Foundation of Xianyang Normal University(No.07XSYK219).
文摘Six novel rod-like magnetic liquid crystals have been prepared, in which trans-bicyclohexyl or trans-cyclohexylphenyl and biphenylcarboxylic acid phenyl ester mesogenic cores with n-propyl and n-pentyl substituents were terminated by 4-hydroxyl- TEMPO (TEMPO = 2,2,6,6-tetramethylpiperidine-l-oxy). Their structures were confirmed by elemental analysis, IR and MS. Determined by SQUID, EPR, DSC and HS-POM (heat stage polarizing optical microscope), the six compounds all have both magnetic and liquid crystalline properties; their temperature ranges of mesophase were from 16.0 to 24.8 ℃, and the magnetic liquid crystal molecules could obviously improve the response sensitivity of liquid crystal materials.
文摘In this article, we investigate the global behavior of weak solutions of a simplified Ericksen-Leslie system for compressible flows of nematic liquid crystals in time in a bounded three-dimension domain-arbitrary forces. By adapting the arguments for the compressible Navier-Stokes equations, and carefully analyzing the direction field of liquid crystals in the equations of angular momentum, we show the existence of bounded absorbing sets, global bounded trajectories, and global attractors to weak solutions of compressible flows of nematic liquid crystals with the adiabatic constant γ〉5/3.
基金supported by National Natural Science Foundation of China under Grant No.2006CB921605the Science Research Foundation of Shunde College
文摘We study the propagation of spatial solitons in nematic liquid crystals, using the self-similar method. Analytical solutions in the form of self-similar solitons are obtained exactly. We confirm the stability of these solutions by direct numerical simulation, and find that the stable spatial solitons can exist in various forms, such as Oaussian solitons, radially symmetric solitons, multipole solitons, and soliton vortices.